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Phosphorus (P) availability in soils controls critical functions and properties of terrestrial ecosystems. Vertical distribution patterns of P concentration and speciation in soil profiles provide historical records of how pedogenic processes redistribute and transform P and thus change its availability in soils, which, however, remain poorly understood. We determined the patterns in three forest soil profiles of contrasting climate, using fine sampling intervals, P K-edge X-ray absorption near edge (XANES) spectroscopy and chemical extractions. The major features of the patterns persist under the contrasting climate. The total P concentration decreases from A to B horizons, reaches a minimum in the B horizons, and then increases towards the upper C horizons, but with little variations with depth in the lower C horizons. Both calcium-bound inorganic P (Ca–Pi) and organic P (Po) decrease and Fe- and Al-bound Pi [(Fe + Al)–Pi] increases in proportion downward in the A horizons because dust inputs and accumulation of organic matter both decline with increasing depth. Ca–Pi is negligible and (Fe + Al)–Pi is dominant in the B horizons due to strong weathering. There is a strong downward increase in Ca–Pi proportion and decrease in (Fe + Al)–Pi proportion from the lower B to the upper C horizons. New Ca–Pi seems to form in the upper C horizons where downward leaching Ca2+ and phosphate accumulate due to the low water permeability of the soils. In the lower C horizons, Ca–Pi increases and (Fe + Al)–Pi decreases with increasing depth due to decreasing chemical weathering. Regarding P bioavailability, the proportion of occluded P (Pocc) shows an increasing and decreasing trend with increasing depth, being the highest in the B horizons; however, there are no consistent trends for non-occluded P (Pn-occ). While the P vertical patterns can be understood by considering the relative importance of different pedogenic processes, climate affects the intensities of these processes and thus the details of the patterns. When depth-integrated, warmer/wetter climate results in decreases in the proportions of both Ca–Pi and Pn-occ but increases in the P loss and the proportions of Po, (Fe + Al)–Pi, and Pocc. Regardless of soil depth and climate, the Pi speciation, i.e., the relative proportions of Ca–Pi and (Fe + Al)–Pi over total Pi, correlates well with soil pH and weathering degree (Chemical Index of Alteration, CIA), and the Po concentration correlates with pedogenic Fe and Al and organic carbon concentration. The correlations suggest that the Pi speciation is primarily controlled by soil geochemistry/mineralogy, and the Po concentration by both soil geochemistry/mineralogy and biological activities. Pocc correlates with CIA, and thus is mainly controlled by soil mineralogy; but Pn-occ correlates weakly with soil properties, probably due to its susceptibility to combined influences of dust inputs, leaching, biological activities, and adsorption on minerals. The above quantitative relationships may help predict P speciation and availability in diverse soils. We further show that soil profiles, and climate and CIA gradients are useful tools for studying P transformations, particularly for the Pi pool, during pedogenesis. This study provides an integration and synthesis of controls of climatic and edaphic variables on P dynamics in forest soils.

Tracing pedogenic processes is fundamental for reconstructing climatic and environmental changes using loess deposits. Lithium isotopes can serve as a sensitive tracer to unravel these processes, owing to its active behaviors without effect by redox and biological reactions. This study investigated the Li contents and δ7Li values of leachate and residue ([Li]leachate, [Li]residue, δ7Lileachate and δ7Liresidue) of the upper 12.5 m Luochuan loess-paleosol sediment (since the last interglacial) on the Chinese Loess Plateau, in order to better understand pedogenic processes in loess. The [Li]leachate, varying from 0.39 to 1.97 μg/g, is mainly derived from the adsorption phase, with a significant variation in δ7Lileachate, from −6.55‰ to +12.88‰. Both [Li]leachate and δ7Lileachate variations reflect weathering and adsorption processes during different periods. The [Li]residue vary from 34.4 to 46.3 μg/g (averaging 38.4 μg/g) and their δ7Liresidue vary from −3.66‰ to +2.44‰ (averaging −0.22 ± 1.68‰), both in agreement with the upper continental crust values. At initial stage after loess deposited (stage I), high [Li]leachate but low δ7Lileachate are results of preferential adsorption of 6Li by clays and migration of 7Li with soil solution during weathering and eluviation processes. When overlying loess was deposited and experienced pedogenesis as the stage I, 7Li migrated downward and was adsorbed by clays (stage II), resulting in high [Li]leachate and δ7Lileachate in underlying loess. When loess has superimposed pedogenic and adsorption processes as the stages I and II, loess became as paleosol with highest δ7Lileachate in underlying carbonate accumulation layer. A persistent increase in δ7Lileachate indicates dominant control of post-depositional adsorptions on Li fractionation along solution migrations during weathering and eluviation of overlying deposits, and vice versa. These results highlight that variations in [Li]leachate and δ7Lileachate can be used to trace soil water migration processes and the magnitude of pedogenic processes in loess-paleosol sediment at different periods.

Pyrite oxidation and sedimentary sulfate dissolution are the primary components of riverine sulfate (SO

Painful diabetic neuropathy (PDN) is a diabetes mellitus complication. Unfortunately, the mechanisms underlying PDN are still poorly understood. Adenosine triphosphate (ATP)-gated P2X7 receptor (P2X7R) plays a pivotal role in non-diabetic neuropathic pain, but little is known about its effects on streptozotocin (STZ)-induced peripheral neuropathy. Here, we explored whether spinal cord P2X7R was correlated with the generation of mechanical allodynia (MA) in STZ-induced type 1 diabetic neuropathy in mice. MA was assessed by measuring paw withdrawal thresholds and western blotting. Immunohistochemistry was applied to analyze the protein expression levels and localization of P2X7R. STZ-induced mice expressed increased P2X7R in the dorsal horn of the lumbar spinal cord during MA. Mice injected intrathecally with a selective antagonist of P2X7R and P2X7R knockout (KO) mice both presented attenuated progression of MA. Double-immunofluorescent labeling demonstrated that P2X7R-positive cells were mostly co-expressed with Iba1 (a microglia marker). Our results suggest that P2X7R plays an important role in the development of MA and could be used as a cellular target for treating PDN.

Dissolved heavy metals (DHMs) contamination has raised global concern for ecological and human health development. Weathering of sulfide-bearing ore metals can produce acidic, sulfate-rich solutions in the presence of water and oxygen (O

Characterization of spatiotemporal variation of the stable isotopes δ18O and δD in surface water is essential to trace the water cycle, indicate moisture sources, and reconstruct paleoaltimetry. In this study, river water, rainwater, and groundwater samples were collected in the Yarlung Tsangpo River (YTR) Basin before (BM) and after the monsoon precipitation (AM) to investigate the δ18O and δD spatiotemporal variation of natural water. Most of the river waters are distributed along GMWL and the line of d-excess = 10‰, indicating that they are mainly originated from precipitation. Temporally, the δ18O and δD of river water are higher in BM series (SWL: δD = 10.26δ18O+43.01, R2 = 0.98) than AM series (SWL: δD = 9.10δ18O + 26.73, R2 = 0.82). Spatially, the isotopic compositions of tributaries increase gradually from west to east (BM: δ18O = 0.65Lon (°)-73.89, R2 = 0.79; AM: δ18O = 0.45Lon (°)-57.81, R2 = 0.70) and from high altitude to low (BM: δ18O = −0.0025Alt(m)-73.89, R2 = 0.66; AM: δ18O = −0.0018Alt(m)-10.57, R2 = 0.58), which conforms to the “continent effect” and “altitude effect” of precipitation. In the lower reaches of the mainstream, rainwater is the main source, so the variations of δ18O and δD are normally elevated with the flow direction. Anomalously, in the middle reaches, the δ18Omainstream and δDmainstream values firstly increase and then decrease. From the Saga to Lhaze section, the higher positive values of δ18Omainstream are mainly caused by groundwater afflux, which has high δ18O and low d-excess values. The δ18Omainstream decrease from the Lhaze to Qushui section is attributed to the combined action of the import of depleted 18O and D groundwater and tributaries. Therefore, because of the recharge of groundwater with markedly different δ18O and δD values, the mainstream no longer simply inherits the isotopic composition from precipitation. These results suggest that in the YTR Basin, if the δ18O value of surface water is used to trace moisture sources or reconstruct the paleoaltimetry, it is necessary to rule out the influence from groundwater.

Based on Terrestrial Cosmogenic Nuclide (TCN) constraints from depth profiles of one granitic regolith from Wumingshan and five fluvial terraces from Xianshuihe and Zagunao rivers, we discuss the timing of the last deglaciation, the landscape-scale denudation and fluvial incision rates across the eastern Tibetan Plateau, in relation to previous work. We present a three-dimensional-graph visualization approach and corresponding constraints to better assess the feasibility and applicability of cosmogenic nuclides depth-profile dating. The exposure age (older than 19.4 ka) of the Wumingshan regolith corresponds to the retreat of the palaeo-Daocheng ice cap, which covered the Yidun terrane during the Last Glacial Maximum (LGM). Most basin-wide denudation rate data in the eastern Tibetan Plateau are lower than 130 mm/ka (47%, n = 90), which is consistent with the Wumingshan regolith denudation rate (lower than 52.8 mm/ka), and thus indicate that the landscape-scale denudation has been stabilized after the last deglaciation. Considering the reduction of integrated bulk density due to the accumulation of lower-density loess, we estimate mean exposure ages of Xianshuihe and Zagunao river terraces of 4.0 ± 0.7 ka, 5.9 ± 0.3 ka, 13.4 ± 2.0 ka, and 16.6 ± 1.4 ka. The observed increase in incision rate from 0.39 mm/yr over long timescale (∼600 ka) to 5.88 mm/yr over the last 15 ka at the Xianshuihe river site is probably due to the transition from glacial to interglacial climatic conditions. The fewer abandoned terraces along the Zagunao river after the Heinrich event 1 (H1) indicates that the climate change during the latest glacial-interglacial transition impacted less the landscape evolution in a relatively lower elevation area. Comparison with previously reported fluvial incision rates elsewhere across the eastern margin of the Tibetan Plateau indicates that incision rates are mainly influenced by abrupt climate change or intensified summer monsoon since the early Holocene, but probably controlled by regional tectonic uplift or fluvial headward retreat as the timescale increases. Overall, we propose a synthetic pattern of landscape evolution mainly dominated by long-term tectonic uplift together with fluvial headward erosion, episodically influenced by climatic change throughout the late Quaternary.

Accurate determination of lithium (Li)isotopic composition in natural geological samples is the basis for Li isotope geochemical studies. In this study, a method contained preparation of geological materials (water and rock) and accurate determination of Li isotopic composition was set up. The separation of Li from water and rock samples was implemented by a single column containing 1.5 mL of Bio-Rad AG 50W-X12 (200–400 mesh) resin, with 0.40 M HCl and 1.0 M HCl as eluents. Only 8.5 and 14 mL of eluents were used to separate Li from water and rock samples with this method, respectively. Blank signal of the operation procedure was (2.4 ± 0.1) mV, which was almost same as the 2.3 mV of the 2% HNO3 signal used in this study. Experimental results showed that Li isotopic fractionation during leaching process was significant and deviation of δ7Li values in these samples with incompletely recovered Li reached up to 50‰. Lithium isotopic ratios were determined by multi-collector ICP-MS (Nu Plasma II) using the sample standard bracketing (SSB) method. L-SVEC standard with similar Li concentration to samples (about 80 ng mL−1) was used in this study. The external precision (2σ) of this technique, determined by repeated measurement of pure Li standard solutions and seawater was

The evolution of atmospheric CO2 and the pH of the ocean can be reconstructed by the boron isotopic composition (δ11B) of marine carbonates, which is influenced by the δ11B of the seawater. Boron (B) in the ocean is primarily affected by continental weathering through rivers. Thus, it is essential to understand the behavior of B and B isotopes in rivers and the factors affecting riverine B, which require a better understanding of sources and processes of B in river systems. This review evaluates the inventories of B reservoirs contributing to rivers and investigates the processes regulating the B isotope geochemistry of rivers. B is widespread at the Earth’s surface and shows a wide range of concentrations between reservoirs. Different reservoirs also exhibit significant variations in B isotopic compositions. Mixing and Rayleigh effects are mainly responsible for the variations in the δ11B values of meteoric precipitation, which result in marine (δ11B = +37 ± 7‰), anthropogenic (δ11B = +9 ± 10‰), and mixing types (δ11B = +17 ± 13‰) of meteoric precipitation. The contribution of B to rivers from carbonate dissolution is negligible. Marine and non-marine evaporites have distinct δ11B values (marine δ11B: + 27 ± 9.4‰ and non-marine δ11B: −2 ± 8.6‰) that primarily reflect their different depositional environments. S-type granites that are tourmaline-free have an estimated δ11B value of −14.2 ± 4.9‰ and a Na/B value of 140 ± 34. Non-S-type granites have a δ11B value of −8.9 ± 6.7‰ and a Na/B value of 1190 ± 170. Intraplate basalts exhibit a δ11B value of −5.2 ± 4.4‰ and a Na/B value of 3300 ± 770. Subduction-related basalts have a δ11B value of + 0.3 ± 7.3‰ and a Na/B value of 1060 ± 830. Shale has high B contents of siliciclastic sedimentary rocks (104 ± 92 ppm). The inferred δ11B values of marine and continental shales are −8‰ and −16‰, respectively. The effects of metamorphism can vary widely depending on the geologic setting and type of protolith. The δ11B values of wastewater are investigated based on their industrial, agricultural, and urban sources. This inventory of B reservoirs can be useful for studies on rivers on a continental scale. In regolith and groundwater, B isotopic fractionation mainly occurs due to water-rock interactions and the biological cycle of B, whereas adsorption on sediments leads to minor B isotopic fractionation in rivers. In groundwater, the reactive transport model reveals that the δ11B value of river water is sensitive to hydrological conditions. In regolith, the steady-state mass balance model is used to predict the B isotope behavior of soil solution in different weathering regimes. In the supply-limited regime (where chemical weathering is limited by tectonic forcing), the precipitation of secondary minerals controls the variations in the δ11B values of soil solution, leading to an increase in the difference in the δ11B values between soil solution and parent rock (δ11Bdiss−δ11Brock) with lower denudation rates, whereas secondary mineral dissolution produces the opposite change in δ11B. In the kinetically limited regime (where chemical weathering is limited by climate), the biological cycle controls the variations in the δ11B values of soil solution, and the δ11B values of soil solution generally become closer to those of parent rock with higher denudation rates. The relationship between the denudation rates and δ11Bdiss−δ11Brock is thus not monotonous, indicating that additional constraints are required to distinguish between the two regimes. Understanding of B isotope geochemistry of rivers can be improved by better constraints on B end-member estimates, investigation of the B isotopic fractionation caused by weathering and biological cycling in regolith, and assessment of atmospheric and biological sub-cycle.

A novel method named as surface spinning strengthening (3S) is proposed to achieve gradient microstructures in the surface layer of a high-Mn twinning induced plasticity (TWIP) steel. A hardened layer with depth larger than 1 mm is found in the 3Sed sample, accompanied by a gradient grain-size transition from ~300 nm to ~50 µm. In comparison with the as-received sample, the high-cycle fatigue property of the graded sample is enhanced mainly by suppressing the initiation of fatigue cracks, which has its origin from the structure and strength gradient.

Sulfur (S) dynamics in soils formed from granite remain poorly understood despite its importance as an essential plant macronutrient and component of soil organic matter. We used stable S isotope ratios to trace the sources and biogeochemical processes of S in four forest soil profiles developed on granite under contrasting climate conditions. The soil S is derived mainly from decomposing litter; no significant geogenic contribution to its content is noted as a result of the low S concentration of the granite (~ 5 μg/g). Colder/drier climate results in high organic S retention at the surface due to weak mineralization of organic S. Although warmer/wetter climate increases the S mineralization and leaching loss, SO42− adsorption is an important S retention process in the subsurface. The vertical distribution of S isotope compositions in the soil profiles across the four sites indicates (i) a downward increase in δ34S values in the upper profiles due to continuous mineralization of organic S with an occasional decrease in δ34S values in the subsurface due to dissimilatory sulfate reduction (DSR), (ii) constantly high δ34S values in the middle profiles due to the low water permeability, and (iii) a downward decrease in δ34S values in the low profiles due to increased contribution of bedrock with depth. Regardless of the variation in soil depth and climate, the total S concentration is proportional to the pedogenic Fe/Al minerals, suggesting the important role of secondary Fe/Al minerals in retaining S in soils. This study provides an integration and synthesis of controls of climatic and edaphic variables on S dynamics in forest soil profiles developed on granite.

The present study seeks to evaluate the application of the 238U-234U-230Th radioactive disequilibrium methodology for the determination of the regolith production rates in thick weathering profiles marked by long histories, encountered under various climate regimes, but still very little studied by these techniques. For this purpose, 238U-234U-230Th disequilibria have been analyzed in a ≈ 11 m-deep profile developed on a granitic bedrock in south China (Longnan, Jiangxi Province) under a subtropical climate. The results demonstrate that in such deep weathering profiles the determination of weathering rates from the analysis of U-series nuclides in bulk rock samples cannot be recovered by applying in one step to the entire alteration profile the modeling approach classically used to interpret the U-series nuclides, i.e. the “gain and loss” model. The modeling has to be made on subsections of relatively small size (10Be data from the same profile, when assuming non steady-state erosion of the upper part of the profile. Slow denudation rates similar to the U-series derived production rates of 2 m/Ma can thus be obtained with a minimum exposure time of 40 ky, and an inherited component of 20-25*104 at/g originating from the exhumed deeper part of the profile. Altogether the data demonstrate that the combined analysis of U-series and cosmogenic nuclides, which has the potential to become a relevant approach to constrain the dynamics of continental surfaces, requires (a) dense and deep sampling for both nuclides studies, and (b) also to consider more systematically the polyphased and variable history of erosion of the continental surface during the Quaternary. These results have implications for the interpretation of long-term accumulation of 10Be at depth and 10Be data variations in granitic alteration profiles.

Coking plants are a substantial source of potentially toxic elements (PTEs) in soil. In this study, we examined the concentration of PTEs, the soil physicochemical properties, and the Pb isotopes in the soil inside and around a coking plant in an industrial city in northern China. We analyzed the spatial distribution of PTEs and the pollution risk areas by Igeo index, the enrichment factor (EF), and the Nemerow index, and we quantitatively identified the contribution of PTE pollution sources in the soil on a small- and medium-scale (plant and work section). Our results indicated that the Hg concentration inside the plant and the Cd concentration in the agricultural land around the plant were both relatively high. A comprehensive analysis of the soil in the study area was performed using the positive matrix factorization model and Pb isotope (206/207Pb, 208/206Pb) tracing method, based on the MixSIAR model, this analysis indicated that burning coal was the main source of Pb both inside (46.8%) and outside (26.3%) the coking plant. The pollution emission sources with significant influence on the soil outside the coking plant were diesel vehicles (12.5%), gas tanks (12.4%), and coke ovens (11.5%), while the sources inside the plant were quenching sections (11.1%), atmospheric deposition (11.0%), coke oven sections (9.6%), and diesel vehicles (6.1%). The results of PTE pollution risk zoning and Pb isotope tracing indicated that pollution is more serious in the western part of the plant, which is the area where coking and gas production takes place, and the most serious pollution outside the plant is mainly distributed to the southeast. This study provides theoretical and practical data indicating the contribution of industrial enterprises to soil pollution, and will help identify pollution responsibility and the management of pollution sources.

Exploring the relationship between weathering and erosion is essential for understanding the evolution of landscapes and formation of soil under the influence of climate, tectonics, and topography. We measured the bulk chemistry of regoliths and calculated their weathering rates and intensity in three locations in China: Inner Mongolia in the mid-temperate semi-humid zone; Jiangxi Province, in the mid-subtropical humid zone; and Hainan Province, in the tropical humid zone. These profiles exhibited increased weathering with increasing temperature and precipitation. The low-gradient profile exhibited stronger weathering of saprolite than of soil, whereas the high-gradient profile showed a more constant weathering pattern. The regolith in the cold climate was the product of easily weatherable minerals, whereas weathering of K-feldspar and even secondary minerals occurred in hot and humid climates. The weathering of subtropical profiles was both supply- and kinetic-limited, controlled by weathering and erosion. The tropical profile experienced supply-limited weathering, indicating slow erosion and an intense weathering profile; the mid-temperate profile was not classifiable due to weak erosion and weathering. Long-term weathering fluxes of these profiles show that Si, Na, and K (or Mg) represent the bulk of the mass lost through weathering. This study underscores that weathering of granitic regolith is controlled by both climatic conditions and landscape.

Piedmont alluvial fans have, for a long time, supported clean groundwater for human development worldwide. Rapid urbanization in China has over-exploited groundwater and resulted in severe groundwater nitrate pollution in piedmont alluvial fans, which has led to both human health concerns and clean water shortages, especially in rural residential areas where drinking water is mainly derived from shallow groundwater. However, sources of nitrate in groundwater and their pathways are still unclear. In this study, we hypothesized that untreated manure and domestic sewage are the primary nitrate sources in a residential area, and that an unconfined aquifer would be more vulnerable to nitrate pollution than a confined aquifer due to nitrate infiltration via the vadose zone. To verify this hypothesis, groundwater nitrate pollution in a well-characterized piedmont alluvial fan was studied through hydrochemical composition and multi-isotope (δ15NNO3, δ34SSO4, δ18OSO4, δ13CDIC) data over four seasons. Seasonal variations for both NO3− concentrations and δ15NNO3 values in unconfined groundwater (UGW) and confined groundwater (CGW) were observed. Mixing of nitrate sourced from manure/sewage, precipitation, soil nitrogen, and synthetic fertilizer controlled the groundwater nitrate level, and manure/sewage contributed 52.4%, 32.4%, and 33.7% nitrate to UGW, CGW, and surface water (SFW), respectively, based on Stable Isotope Mixing Models in R (SIMMR) analysis. Denitrification had a minor effect on groundwater nitrate levels in a residential area, and nitrate pollution in CGW was partly due to nitrate migration through geological faults and fracture zones in a piedmont alluvial fan. Nitrate pollution sources and pathways in residential areas were confirmed through multiple isotopes (δ15NNO3, δ13CDIC, δ34SSO4, and δ18OSO4). Collectively, these results highlight the roles of the hydrogeological setting and anthropogenic activities in groundwater N pollution beneath piedmont alluvial fans.

In order to assess the impact of the monsoonal climate on denudation, physical erosion, and chemical weathering processes, we measured cosmogenic nuclides 10Be, 26Al and immobile element Zr in five granitic regolith profiles across Northeast to South China. The 10Be and 26Al concentrations are 2.98 × 104–25.20 × 104 atoms g−1 and 2.18 × 105–16.62 × 105 atoms g−1, respectively. Compiling previous depth profile data from Leymon and Beacon Heights, we find that the 26Al/10Be ratios systematically increase or decrease with the depth. Our numerical model shows that muons contributions can produce higher 26Al/10Be ratios (greater than 6.75) in both steady-state and non-steady state scenarios, which can result in underestimated burial age (initial 26Al/10Be ratio) and exaggerated denudation rates (due to non-negligible production from muons) for the application of dual-nuclide in Earth Science. The denudation rates, chemical weathering rates and physical erosion rates derived from cosmogenic nuclides and Zr are 28–45, 9–31 and 6–22 m Ma−1, respectively. Chemical weathering rates, excluding the JLN profile, comprise a large proportion of the denudation rates (greater than 50%). Despite the wide range of mean annual precipitation (MAP) and mean annual temperature (MAT), the denudation rates vary without an apparent gradient from northeast to south. However, the physical erosion and chemical weathering results show good relationships with climate, suggesting the limitation type changed from kinetic-limited in the north, to supply-limited in the south. Chemical weathering indices (chemical index of alteration, CIA and weathering intensity factor, WIF) also indicate that the extent of chemical weathering strengthens from northeast to south and increases with chemical weathering rates, but decreases with physical erosion rates.

The present study seeks to evaluate the application of the 238U-234U-230Th radioactive disequilibrium methodology for the determination of the regolith production rates in thick weathering profiles marked by long histories, encountered under various climate regimes, but still very little studied by these techniques. For this purpose, 238U-234U-230Th disequilibria have been analyzed in the top 11 m of a lateritic profile developed on a granitic bedrock in south China (Longnan, Jiangxi Province) under a subtropical climate. The results demonstrate that in such a weathering profile the determination of weathering rates from the analysis of U-series nuclides in bulk rock samples cannot be recovered by applying in one step to the entire alteration profile the modeling approach classically used to interpret the U-series nuclides, i.e. the “gain and loss” model. The modeling has to be made on subsections of relatively small size (

The distribution and anomalies of rare earth elements (REEs) of granitic regolith were studied in Inner Mongolia and Hainan Island, China. One profile showed slight REE enrichment of an upper layer and no obvious light REE/heavy REE (LREE/HREE) fractionation (LaN/YbN of 0.9). The second profile was significantly enriched in REEs and enriched in LREEs in the upper portion (LaN/YbN > 1.8). Eu, Ce, and Gd anomalies of the two profiles are different. Slightly negative Eu, Ce, and Gd anomalies in NMG-3-1 indicate slow dissolution of primary minerals and little secondary products; in contrast, a positive Eu anomaly in HN-2 suggests the vegetation cycle may contribute to soil. The Ce anomaly of HN-2 reflects oxidation of Ce and coprecipitation by Fe- and Mn-oxides and organic matter. Correlation between Ce and Gd anomalies in HN-2 suggests Ce and Gd are both influenced by redox-reduction.

Rare earth elements (REEs) can record geologic and geochemical processes. We studied two granitic regolith profiles from different climatic zones in eastern Tibetan Plateau and found that (1) ΣREEs ranged from 119.65 to 275.33 mg/kg in profile ND and 5.11–474.55 mg/kg in profile GTC, with average values of 205.79 and 161 mg/kg, respectively. ΣREEs was higher in accumulation horizon and semi-regolith; (2) Influenced by climate, the fractionation of light and heavy REEs (LREEs and HREEs) varied during weathering. The ratio of LREEs/HREEs in pedosphere was higher than semi-regolith in tropical profile; (3) A negative Eu anomaly in both profiles was the result of bedrock weathering. A positive Ce anomaly was observed in all layers of profile ND, and only in the upper 100 cm of profile GTC. This indicates that redox conditions along the regolith profile varied considerably with climate. (4) Normalized by chondrite, LREEs accumulated much more than HREEs; REE distribution curves were right-leaning with a V-type Eu anomaly in both profiles.

This study focuses on the chemical and Sr isotopic compositions of the dissolved load of the rivers in the Liao River basin, which is one of the principal river systems in northeast China. Water samples were collected from both the tributaries and the main channel of the Liao River, Daling River and Hun-Tai River. Chemical and isotopic analyses indicated that four major reservoirs (carbonates (+gypsum), silicates, evaporites and anthropogenic inputs) contribute to the total dissolved solutes. Other than carbonate (+gypsum) weathering, anthropogenic inputs provide the majority of the solutes in the river water. The estimated chemical weathering rates (as TDS) of silicate, carbonate (+gypsum) and evaporites are 0.28, 3.12 and 0.75 t/km2/yr for the main stream of the Liao River and 7.01, 25.0 and 2.80 t/km2/yr for the Daliao River, respectively. The associated CO2 consumption rates by silicate weathering and carbonate (+gypsum) weathering are 10.1 and 9.94 × 103 mol/km2/yr in the main stream of the Liao River and 69.0 and 80.4 × 103 mol/km2/yr in the Hun-Tai River, respectively. The Daling River basin has the highest silicate weathering rate (TDSsil, 3.84 t/km2/yr), and the Hun-Tai River has the highest carbonate weathering rate (TDScarb, 25.0 t/km2/yr). The Raoyang River, with an anthropogenic cation input fraction of up to 49%, has the lowest chemical weathering rates, which indicates that human impact is not a negligible parameter when studying the chemical weathering of these rivers. Both short-term and long-term study of riverine dissolved loads are needed to a better understanding of the chemical weathering and controlling factors.

Aims To investigate the roles of cyclooxygenases (COX) and their metabolites in C57/BL6 mice with 5/6 nephrectomy, an animal model of chronic renal failure. Main methods C57/BL6 mice were grouped into sham-operated (2K), one kidney removal (1K) and 5/6 nephrectomy groups (5/6Nx). Renal resistive index was measured by ultrasonography. Blood, aortae, renal arteries and renal cortex were collected for measurement of kidney function, assessment of vascular responsiveness, Western blotting, immuohistochemistry and enzyme-linked immunosorbent assays. Key findings After four weeks, acetylcholine-induced relaxations were blunted in renal arteries of 1K and 5/6Nx mice; indomethacin, a non-selective COX inhibitor, improved the response in 5/6Nx, but not in 1K renal arteries. In 5/6Nx renal arteries, but not in 1K preparations, the protein presence of endothelial nitric oxide synthase (eNOS) was decreased, while that of COX-2 and its products [prostacyclin and thromboxane A 2 ] were increased. The renal resistive index was lower in 5/6Nx mice, suggesting a lower resistance in the renal microvasculature. In the renal cortex of 5/6Nx mice, eNOS protein presence was increased; while the presence of COX-2 was not detectable. The prostaglandin E 2 level was lower in the 5/6Nx cortex than in the other two groups. Significance The early stage of renal mass removal is associated with increased renal arterial constriction and reduced microvascular resistance. The former is due to downregulation of eNOS and upregulation of COX-2, leading to an increased production of prostacyclin and thromboxane A 2 . A reduced production of PGE 2 in the renal cortex is important for maintaining normal renal function.

Objective. Postincision pain often occurs after surgery and is an emergency to be treated in clinic. Electroacupuncture (EA) is a Chinese traditional treatment widely used to cure acute or chronic pain, but its mechanism is not clear. Interleukin-10 (IL-10) is a powerful anti-inflammatory cytokine that shows neuroprotective effects in inflammation and injury in the CNS. The present study attempts to reveal that IL-10 is crucial for EA analgesia on postincision pain. Methods. A model of incision pain was established in C57BL/6J mice. The pain threshold was detected by behavioral test, and the expression of IL-10 and its receptor was detected by an immunohistochemical method. C-fiber-evoked field potentials were recorded by in vivo analysis. Results. The mechanical allodynia induced by paw incision was significantly inhibited by pretreatment of EA in mice. Intrathecal injection of IL-10 neutralizing antibody (2 µg/10 µL) but not intraplantar injection (10 µg/10 µL) reversed the analgesia of EA. The upregulations of IL-10 mRNA and protein were induced by EA at 6 h and 1 d after incision, respectively. Spinal long-term potentiation (LTP), a substrate for central sensitization, was also suppressed by EA with IL-10. IL-10 recombinant protein (1 µg/10 µL, i.t.) mimicked the analgesia of EA on mechanical allodynia and inhibition on the spinal LTP. Posttreatment of EA after incision also transitorily relieved the mechanical allodynia, which can be blocked by spinal IL-10 antibody. IL-10 and its receptor, IL-10RA, are predominantly expressed in the superficial spinal astrocytes. Conclusions. These results suggested that pretreatment of EA effectively prevented postincision pain and IL-10 in spinal astrocytes was critical for the analgesia of EA and central sensitization.

Since the use of single feature is difficult to establish the satisfied music classification model, a music classification model based on BP neural network is proposed to help users to find their favorite music. The music characteristics with multiple types are extracted to describe the music information accurately. The characteristics are combined as the input vector of the music classification model, and the intelligent learning of BP neural network is adopted to establish the music classification model.The multimusic classification experiment was carried out on Matlab 2016 platform. The results show that the model can over⁃come the limitations of the single feature providing simple information, improve the classification accuracy of the music, has perfect real⁃ time performance of music classification, and is used to study the music retrieval on the network.

The ecosystem of extra-high mountain areas is very fragile. Understanding local vegetation changes is crucial for projecting ecosystem dynamics. In this paper, we make a case for Himalayan mountain areas to explore vegetation dynamics and their influencing factors. Firstly, the interannual trends of the normalized difference vegetation index (NDVI) were extracted by the Ensemble Empirical Mode Decomposition (EEMD) algorithm and linear regression method. Moreover, the influence of environmental factors on interannual NDVI trends was assessed using the Random Forests algorithm and partial dependence plots. Subsequently, the time-lag effects of seasonal NDVI on different climatic factors were discussed and the effects of these factors on seasonal NDVI changes were determined by partial correlation analysis. The results show that (1) an overall weak upward trend was observed in NDVI variations from 1982 to 2015, and 1989 is considered to be the breakpoint of the NDVI time series; (2) interannual temperature trends and the shortest distance to large lakes were the most important factors in explaining interannual NDVI trends. Temperature trends were positively correlated with NDVI trends. The relationship between the shortest distance to large lakes and the NDVI trend is an inverted U-shaped; (3) the time-lags of NDVI responses to four climatic factors were shorter in Autumn than that in Summer. The NDVI responds quickly to precipitation and downward long-wave radiation; (4) downward long-wave radiation was the main climate factor that influenced NDVI changes in Autumn and the growing season because of the warming effect at night. This study is important to improve the understanding of vegetation changes in mountainous regions.

High levels of dissolved arsenic (As) have been reported in many rivers running though the Tibetan Plateau (TP), the “Water Tower of Asia”. However, the source, spatiotemporal variations, and geochemical behavior of dissolved As in these rivers remain poorly understood. In this study, hot spring, river water, and suspended particulate material samples collected from the Yarlung Tsangpo River (YTR) (upper reaches of the Brahmaputra River) system in 2017 and 2018 were analyzed. Spatial results shown that the upper reaches of YTR (Zone I) have comparatively high levels of dissolved As ([As]dissolved: mean 31.7 μg/L; 4.7–81.6 μg/L; n = 16), while the tributaries of the lower reaches (Zone II) have relatively low levels (mean 0.54 μg/L; 0.11–1.3 μg/L; n = 7). Seasonal results shown that the high [As]dissolved (6.1–22.4 μg/L) were found in September to June and low [As]dissolved (1.4–3.7 μg/L) were observed in July to August. Geothermal water is suspected as the main source of the elevated As levels in YTR due to the extremely high [As]dissolved in hot springs (1.13–9.76 mg/L) and abundance of geothermal systems throughout TP. However, the seasonal results suggested that weathering of As-containing rocks and minerals is also a key factor affecting the [As]dissolved in the river water in July to August (wet-season). Natural attenuation of As in main channel is dominated by dilution process due to the lower As concentrations in tributaries, but mostly occurred by both dilution and adsorption (or co-precipitation) processes in tributaries. This work highlights that the weathering process may have an important contribution to the dissolved As in the river waters in wet-season, and the geochemical behavior of As is largely transported conservatively in the main channel and relative non-conservatively in the tributaries in YTR system.

Lithium isotope is potentially useful tracer of continental weathering. However, the factors affecting Li isotope composition in highly weathered saprolites are still largely unclear. In the present study, Li and Nd isotope compositions in saprolites developed on granite from Huizhou, southern China, were analyzed and Li isotope composition in quartz samples separated from the saprolites was determined. The Nd isotope composition of saprolites (eNd = −6.1 ± 0.4, 1σ) was almost identical to that of parent granite (eNd = −5.7), suggesting the eolian deposition in this profile is negligible. The δ7Li value in saprolites varied greatly from −7.7‰ to +14.0‰. Below a depth of 3 m, almost all saprolites were isotopically lighter than the parent granite (+1.0‰). However, above 3 m, δ7Li values were higher in saprolites (+2.2‰ to +14.0‰, average + 7.6‰) than in the parent granite and showed a significant increasing trend toward the surface. Moreover, the δ7Li value showed a negative correlation with the CIA value below 3 m, but a positive correlation above 3 m. Compared with the parent granite, quartz separates had a higher Li concentration (1.1–28.9 mg/kg, average 9.5 mg/kg) and δ7Li value (+12.1‰ to +13.9‰). As weathering progressed, the formation of secondary minerals (such as kaolinite) led to the incorporation of lighter 6Li, which may have contributed significantly to the low δ7Li value in saprolites below 3 m. However, this mechanism could not explain the relative enrichment of heavy 7Li in the upper layer saprolites. The relative enrichment of quartz may contribute significantly to the increase of δ7Li in saprolites. The direct evidence was that Li was abundant and distinctly isotopically heavier in quartz separates. Moreover, quartz content correlated positively with Li concentration (R2 = 0.90, p

Lithium (Li) isotopes have been shown to be fractionated significantly during chemical weathering of silicate rocks. However, previous research has mainly been focused on basalt weathering, whereas the behavior of Li isotopes during the weathering of granite remains unclear. The Li isotopic compositions in the saprolite profile developed on granite was analyzed, as well as several individual primary minerals (K-feldspar, plagioclase, quartz and biotite) in the parent granite. Lithium concentration and the isotopic compositions of the individual primary minerals appear to be heterogeneous. Biotite is rich in Li (369.4 mg/kg), but the Li concentration is very low in other minerals (1.3–11.3 mg/kg). Quartz has the highest δ7Li value (+19.9‰); other minerals contain δ7Li within a fairly narrow range (+5.8‰ to +9.0‰). The saprolite samples were mainly composed of primary minerals and were characterized by low weathering intensity (CIA = 52–60). Lithium was distinctly lost in the saprolites relative to parent granite. Meanwhile, δ7Li values of saprolites were all lower than those of parent granites (−2.0‰ to +3.9‰ vs. +7.1‰, respectively), which systematically decreased with increasing weathering intensity. The mineralogical composition and 87Sr/86Sr ratio in the saprolites suggest that the biotite was preferentially weathered below 120 cm depth in the examined profile, whereas plagioclase weathering mainly occurred above 120 cm depth. The Li released during granite weathering was characteristically different from the isotopes in the primary minerals. Lithium isotopic fractionation during granite weathering is affected by adsorption and/or incorporation of Li by secondary minerals (or clay minerals), and the release of Li from biotite. This study highlights the fact that significant Li isotope fractionation occurs during Li leaching (relatively higher 7Li/6Li ratios) from biotite in the incipient stage of granite weathering, which may help to explain the higher δ7Li values found in the dissolved load from the catchments of low weathering intensity.

Frequent droughts in a warming climate tend to induce the degeneration of vegetation. Quantifying the response of vegetation to variations in drought events is therefore crucial for evaluating the potential impacts of climate change on ecosystems. In this study, the standardized precipitation index (SPI) was calculated using the precipitation data sourced from the China Meteorological Forcing Dataset (CMFD), and then the drought events in southern Tibet from 1982 to 2015 were identified based on the SPI index. The results showed that the frequency, severity, and intensity of drought events in southern Tibet decreased from 1982 to 2015, and the highest frequency of drought was found between 1993 and 2000. To evaluate the impact of drought events on vegetation, the vegetation characteristic indexes were developed based on the normalized difference vegetation index (NDVI) and the drought characteristics. The assessment of two drought events showed that the alpine grasslands and alpine meadows had high vegetation vulnerability (AI). The assessment of multiple drought events showed that responses of vegetation to drought were spatially heterogeneous, and the total explain rate of environmental factors to the variations in AI accounted for 40%. Among the many environmental factors investigated, the AI were higher at middle altitudes (2000–3000 m) than low altitudes (

Bulk chemical composition and mineralogy were examined in three soil profiles and a deeper 11-meter profile weathering on a granite ridgeline under subtropical climate conditions in south China. The weathering sequence is delineated by mineralogy and major element variations. Apatite, biotite, hornblende and plagioclase dissolve early during weathering, resulting in nearly 100% Ca and Na loss and significant Mg, Fe and P depletion at depth. The K-feldspar reaction front begins at the depth of depletion of plagioclase, leading to a loss of ~ 80% of the K at the land surface near the bottom of the ridgeline and almost 100% at the top. Dissolution of quartz and other silicates releases about 60% of Si in the profiles. Kaolinite is the dominant clay mineral and it transforms to gibbsite in the uppermost layer. The soil horizon (upper 100 cm) is the zone dominated by pedogenic processes, including active biological activity, physical erosion and influx of high concentrations of atmospheric components (especially CO2 and O2). The pedogenic processes are characterized by low pH (~ 4.54 to 5.85), high clay content (kaolinite: 6–16 wt.%; gibbsite: 2–8 wt.%) and total organic carbon content (0.13–3.93%) and intensive fracturing and dissolution of quartz and K-feldspar compared with the lower horizons. Accumulation of organic material and resistant minerals downslope is attributed to down-ridge movement of water (termed here, interflow) and weathering products in the uppermost 100 cm down the ridgeline. Using a mass balance model calculation for the catena that assumes steady-state soil thickness at all sites, the bottom profile shows the highest apparent total chemical weathering loss rate (~ 14 g m− 2 y− 1) whereas the middle position shows the highest physical erosion loss rate (~ 44 g m− 2 y− 1). SiO2 accounts for about 84% of the chemical weathering outflux from the soil horizons along the ridgeline hillslope. Chemical weathering rates at the bottom of the hillslope may be accelerated by high concentrations of organic material and by dissolution of kaolinite. This study demonstrates that mineral reaction fronts in granite become separated over depth intervals of meters and that elemental fluxes and release mechanisms vary with position along a ridgeline catena.

The magnesium (Mg) isotopic composition of river waters is mainly controlled by riverine Mg sources and geochemical processes. It is meaningful to characterize Mg isotope behavior for us in understanding chemical weathering and other geochemical processes, such as secondary mineral formation linked to environmental conditions. The Huanghe basin was chosen to investigate the behavior of Mg isotopes during river erosion in temperate-semiarid and arid climate. Dissolved Mg shows a wide range of δ26Mg values, ranging from − 1.53 ‰ to − 0.11 ‰, with most values being close to − 1.09 ‰. By comparison, most of the suspended loads are enriched in heavy Mg isotope, with δ26Mg values ranging from − 2.00 ‰ to − 0.62 ‰, which is controlled by mineralogy. The Mg isotopic composition in the upstream is mainly determined by the mixture between carbonate and silicate sources. When the Huanghe flows through the Loess Plateau, the dissolved Mg decreased due to the dissolution of easily dissoluble phases in loess, such as MgCl2 or MgSO4. Carbonates weathering and evaporites dissolution are the major controlling factor of the evolution of Mg isotopic composition in dissolved phase, though evaporation-related precipitation of secondary carbonates also influences the dissolved Mg isotope composition in some tributaries. The strong relationships between δ26Mg and pH, temperature, and δ18O suggest that the Mg isotope system bears significant information about the hydrogeochemical characteristics and climate conditions of the Huanghe basin.