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In this paper, substantial domestic and foreign research results of microscopic shale reservoir space were systemically reviewed, the research history consisting of simple observation and qualitative classification, quantitative research, the combination of qualitative and quantitative research successively as well as the characteristics of each research stage were summarized. In addition, the current problems existing in the characterization methods of shale reservoir space were also analyzed. Furthermore, based on massive actual detection of typical core samples obtained from more than 50 global shale gas wells and relevant practical experience, a comprehensive characterization method of combining qualitative with the semi-quantitative characterization was put forward. In detail, the indicators of the qualitative characterization include pore combination type and organic-matter microscopic morphology type, while the core elements of the semi-quantitative characterization include the percentage of the organic-matter area and the plane porosity of the pores of different types. Based on the reference of the naming and classification of rocks, the three-end-member diagram method was used to characterize microscopic shale reservoir space. This is achieved by plotting the three end-member diagram of 3 kinds of first-order critical reservoir spaces, i.e., organic-matter pores, matrix pores, and micro-fractures, in order to intuitively present the features of the microscopic pore combination. Meanwhile, statistic histograms of organic-matter microscopic morphology type and the plane porosity of different types of pores were adopted to characterize the development degree of second-order pores quantitatively. By this comprehensive characterization method, the importance of both pore combination and the microscopic morphology of organic matter were emphasized, revealing the control of organic-matter microscopic morphology over the organic-matter pores. What is more, high-resolution FE-SEM was adopted to obtain semi-quantitative statistics results. In this way, the features of pore development and pore combination were quantified, not only reflecting the types and storage capacity of the microscopic shale reservoir space, but also presenting the hydrocarbon-generating potential of organic matter in shale. Therefore, the results of this research are capable of providing in-depth microscopic information for the assessment and exploration and development of shale gas resources.

A novel circularly polarized (CP) antenna with wide angular coverage is presented. The proposed antenna is formed by a 45 ° slot cut in the center of a rectangular patch antenna and a square ring around it. It can achieve an impedance bandwidth of 110 MHz and a 3 dB axial ratio bandwidth of 25 MHz. For this design, very stable and symmetrical radiation patterns are obtained. The 3 dB axial ratio beamwidth for the antenna is 160 °, compared with the antenna that without the metal square ring, the antenna with square ring has 19 ° more 3 dB axial ratio beamwidth. This antenna has been successfully applied on passive keyless entry system on door lock. © 2016 Wiley Periodicals, Inc. Microwave Opt Technol Lett 58:672–675, 2016

Changes in marine productivity and redox conditions during the end-Ordovician (Hirnantian) glaciation and Ordovician–Silurian transition were investigated through Mo-isotope and major- and trace-element analyses of the Wangjiawan (Hubei Province) and Nanbazi (Guizhou Province) sections from the Yangtze Platform of South China. Katian shales of the Wufeng Formation, which yield the graptolites Dicellograptus complanatus , Dicellograptus complexus , and Paraorthograptus pacificus , were deposited under euxinic conditions at both localities, as shown by high Mo EF , U EF , and δ 98 Mo values. A major sea-level regression during the Hirnantian glaciation resulted in shallowing and a shift toward better-oxygenated conditions within the Yangtze Sea, as well as deposition of thin-bedded siliceous sediments, calcirudite debris flows, and limestone turbidites of the Kuanyinchiao Formation, the base of which correlates with the first phase of the end-Ordovician mass extinction. The termination of the Hirnantian glaciation at the top of the Kuanyinchiao Formation was associated with a major sea-level transgression, a rapid expansion of euxinia in the Yangtze Sea (as documented by a return of high Mo EF , U EF , and δ 98 Mo values), and the second phase of the mass extinction, during which the cool-adapted Hirnantian Fauna went extinct. The long-term cooling trend of the Middle and Late Ordovician, which culminated in the Hirnantian glaciation, was driven by enhanced burial of organic carbon, as documented by δ 13 C carb , δ 13 C org , and δ 34 S py records. Increased organic carbon burial was linked to high rates of marine productivity, as shown by high TOC and biogenic Ba concentrations especially at the deeper, less-restricted Wangjiawan locale, producing the HICE (Hirnantian Isotopic Curve Excursion) δ 13 C carb excursion. The locus of organic carbon burial during the Hirnantian crisis shifted to deeper-water environments that were located outside the study region. The relatively rapid onset and termination of the Hirnantian glaciation were probably due to crossing of tipping points in the Late Ordovician climatic–oceanic system.

A bandwidth enhanced method of a low-profile substrate integrated waveguide (SIW) cavity-backed slot antenna is presented in this paper. Bandwidth enhancement is achieved by simultaneously exciting two hybrid modes in the SIW-backed cavity and merging them within the required frequency range. These two hybrid modes, whose dominant fields are located in different half parts of the SIW cavity, are two different combinations of the and resonances. This design method has been validated by experiments. Compared with those of a previously presented SIW cavity-backed slot antenna, fractional impedance bandwidth of the proposed antenna is enhanced from 1.4% to 6.3%, its gain and radiation efficiency are also slightly improved to 6.0 dBi and 90%, and its SIW cavity size is reduced about 30%. The proposed antenna exhibits low cross polarization level and high front to back ratio. It still retains advantages of low-profile, low fabrication cost, and easy integration with planar circuits.

Single fed low profile cavity backed crossed slot antennas for dual frequency dual linear polarization and circular polarization applications are first presented in this paper. By employing the substrate integrated waveguide (SIW) technique in the antenna designs, the low profile backed cavity structure can be realized by using only a single layer of low cost printed circuit board (PCB) substrate. A single grounded coplanar waveguide (GCPW) is employed as the feeding element to excite the TE 120 and TE 210 modes in the SIW cavity. A crossed slot structure is used as the radiating element in order to radiate the desired dual linearly or circularly polarized wave. From the measurement results, it is seen that these novel antennas retain the advantages of conventional metallic cavity backed antennas, including high gain, high front-to-back ratio (FTBR), and low cross polarization level (CPL). Furthermore, the proposed antennas also possess the advantages of low profile, light weight, low fabrication cost, and easy integration with planar circuits.

A novel design method of low profile cavity backed planar slot antenna has been described in this paper. The whole antenna including backed cavity and feeding element is completely constructed at a single substrate by using substrate integrated waveguide technique and grounded coplanar waveguide. An example with 1.7% bandwidth has been presented, which has 5.4 dBi gain, 16.1 dB front-to-back ratio and -19 dB maximum cross polarized radiation level with its total thickness less than lambda0/50. The proposed antenna keeps good radiation performance of conventional cavity backed antenna and has advantages of conventional planar antenna including low profile, light weight, easy fabrication with low cost and convenient integration with planar circuit.

A 60GHz patch monopole Antenna-on-chip (AoC) with a cross-shape Artificial Magnetic Conductor (AMC) is presented based on standard 0.18um CMOS process. The novel cross-shape AMC acts as a shield between the radiating element and the lossy silicon substrate. Both AMC and the patch antenna are optimized to achieve a wideband operating performance covering 57–66 GHz. The optimized AoC has a compact size of 0.9×2.1mm2 and provide a high gain of 1.53 dBi.

A wideband 60GHz monopole on-chip antenna based on 0.18μm CMOS process with an artificial magnetic conductor (AMC) is presented. The structure of the proposed on-chip antenna consists of a circular ring-shaped monopole antenna fed by a 50Ω coplanar waveguide (CPW). Results show that the proposed circular ring-shaped monopole antenna mounted on AMC plane can offer higher gain, higher radiation efficiency and wider impedance bandwidth, while has a smaller antenna size.

We present Mo isotopic ratios of molybdenite from five porphyry molybdenum deposits (Chagele, Sharang, Jiru, Qulong, and Zhuonuo) and one quartz-molybdenite vein-type deposit (Jigongcun) along the Gangdese metallogenic belt in the Tibetan Plateau. These deposits represent a sequence of consecutive events of the India-Asia collision at different periods. Additional molybdenite samples from the Henderson Mo deposit (USA), the oceanic subduction-related El Teniente (Chile), and Bingham (USA) porphyry Cu-(Mo) deposits were analyzed for better understanding the controls on the Mo isotope systematics of molybdenite. The results show that molybdenite from Sharang, Jiru, Qulong, and Zhuonuo deposits have similar δ97Mo (∼0 ‰), in agreement with the values of the Henderson Mo deposit (−0.10 ‰). In contrast, samples from the Changle and Jigongcun deposit have δ97Mo of 0.85 ‰ to 0.88 ‰ and −0.48 %, respectively. Molybdenite from the El Teniente and Bingham deposits yields intermediate δ97Mo of 0.27 and 0.46 ‰, respectively. The Mo isotopes, combined with Nd isotope data of the ore-bearing porphyries, indicate that source of the ore-related magmas has fundamental effects on the Mo isotopic compositions of molybdenite. Our study indicates that molybdenite related to crustal-, and mantle-derived magmas has positive or negative δ97Mo values, respectively, whereas molybdenite from porphyries formed by crust-mantle mixing has δ97Mo close to 0 ‰. It is concluded that the Mo isotope composition in the porphyry system is a huge source signature, without relation to the tectonic setting under which the porphyry deposits formed.

The design of circularly polarized microstrip patch antenna (MPA) with wide axial ratio beamwidth working at 2.4GHz band is proposed. The wide axial ratio beamwidth is achieved by a 45° rotated slot cut in the center of the square MPA. By placing two back-to-back MPAs on intelligent door lock, the function of indoor-outdoor recognition has been successfully realized.

A circularly polarized antenna realized by a power divider fed cavity backed slot antenna is presented in this article.The cavity backed slot antenna is constructed on a single layer substrate by using substrate integrated waveguide (SIW) technique. A T-junction power divider with equal magnitude and 90° phase difference outputs is adopted as the parallel feed to excite the SIW backed cavity. Circularly polarized radiation can be generated when two orthogonal cavity modes are excited simultaneously in the backed cavity. © 2011 Wiley Periodicals, Inc. Microwave Opt Technol Lett 54:107–109, 2012; View this article online at wileyonlinelibrary.com. DOI 10.1002/mop.26482