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A metal-free oxidative dearomatization of indoles with aromatic ketones mediated by TEMPO oxoammonium salt is described. The dearomatization proceeds smoothly and displays a broad substrate scope with respect to both indoles and aromatic ketones in the presence of H2 SO4 , affording the corresponding 2,2-disubstituted indolin-3-ones in good yields. [ABSTRACT FROM AUTHOR]

A gold‐catalyzed reaction of 2H‐tetrazoles with alkynes was described for the efficient synthesis of a variety of N‐alkenylated tetrazole derivatives, including N‐1 and N‐2 vinyl functionalized products which are readily isolated by column chromatography. The reaction mechanism was proposed to be a nucleophilic addition process to the alkyne motif activated by gold catalyst. The reaction features mild reaction condition, simple operation and high yields. [ABSTRACT FROM AUTHOR]

Abstract Space debris division of PMO is devoted to play an important role in the research of orbital mechanics and the development of space debris observation techniques in China. To support the work, this division builds and operates a large optical network across China. The observational network include two major subsets, large field survey telescopes and precise tracking telescopes. The main objective of the network is to maintain cataloged orbital debris and detect uncatalogued debris. CHES at YaoAn site is the most recent facility, for higher orbits survey. New operational software and data pipeline that aims at detecting unresolved objects has being developed. This paper presents the details of this facility and related activities.

The asymmetric construction of vicinal quaternary carbon stereocenters with at least one moiety in acyclic systems is a formidable challenge. We disclose a solution involving diastereo- and enantioselective oxidative 1,6-conjugate addition. The practical asymmetric cross-dehydrogenative coupling of 2,2-diarylacetonitriles and diverse α-substituted cyclic 1,3-dicarbonyls proceeds, for vicinal quaternary carbon stereocenters with one center in acyclic systems, in excellent yields and stereoselectivities. The generality of the approach is further demonstrated by the stereoselective creation of vicinal quaternary carbon stereocenters with both centers in acyclic systems using acyclic β-ketoesters as coupling partners. Computational studies elucidate the origins of both diastereo- and enantioselectivity., (© 2021 Wiley-VCH GmbH.)