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Over the past decade, significant advancements have been made in phase engineering of two-dimensional transition metal dichalcogenides (TMDCs), thereby allowing controlled synthesis of various phases of TMDCs and facile conversion between them. Recently, there has been emerging interest in TMDC coexisting phases, which contain multiple phases within one nanostructured TMDC. By taking advantage of the merits from the component phases, the coexisting phases offer enhanced performance in many aspects compared with single-phase TMDCs. Herein, this review article thoroughly expounds the latest progress and ongoing efforts on the syntheses, properties, and applications of TMDC coexisting phases. The introduction section overviews the main phases of TMDCs (2H, 3R, 1T, 1T', 1T d ), along with the advantages of phase coexistence. The subsequent section focuses on the synthesis methods for coexisting phases of TMDCs, with particular attention to local patterning and random formations. Furthermore, on the basis of the versatile properties of TMDC coexisting phases, their applications in magnetism, valleytronics, field-effect transistors, memristors, and catalysis are discussed. Lastly, a perspective is presented on the future development, challenges, and potential opportunities of TMDC coexisting phases. This review aims to provide insights into the phase engineering of 2D materials for both scientific and engineering communities and contribute to further advancements in this emerging field.

Since the emergence of 2D magnets in 2017, the diversity of these materials has greatly expanded. Their 2D nature (atomic-scale thickness) endows these magnets with strong magnetic anisotropy, layer-dependent and switchable magnetic order, and quantum-confined quasiparticles, which distinguish them from conventional 3D magnetic materials. Moreover, the 2D geometry facilitates light incidence for opto-spintronic applications and potential on-chip integration. In analogy to optoelectronics based on optical-electronic interactions, opto-spintronics use light-spin interactions to process spin information stored in the solid state. In this review, opto-spintronics is divided into three types with respect to the wavelengths of radiation interacting with 2D magnets: 1) GHz (microwave) to THz (mid-infrared), 2) visible, and 3) UV to X-rays. It is focused on the recent research advancements on the newly discovered mechanisms of light-spin interactions in 2D magnets and introduces the potential design of novel opto-spintronic applications based on these interactions., (© 2023 Wiley-VCH GmbH.)

Spin-wave nonreciprocity arising from dipole-dipole interaction is insignificant for magnon wavelengths in the sub-100 nm range. Our micromagnetic simulations reveal that for the nanoscale magnonic crystals studied, such nonreciprocity can be greatly enhanced via synthetic antiferromagnetic coupling. The nonreciprocity is manifested as highly asymmetric magnon dispersion curves of the magnonic crystals. Furthermore, based on the study of the dependence of the nonreciprocity on an applied magnetic field, the antiparallel alignment of the magnetizations is shown to be responsible for the enhancement. Our findings would be useful for magnonic and spintronics applications.

The interfacial Dzyaloshinskii-Moriya interaction in an in-plane anisotropic Pt(4  nm)/Co(1.6  nm)/Ni(1.6  nm) film has been directly observed by Brillouin spectroscopy. It is manifested as the asymmetry of the measured magnon dispersion relation, from which the Dzyaloshinskii-Moriya interaction constant has been evaluated. Linewidth measurements reveal that the lifetime of the magnons is asymmetric with respect to their counter-propagating directions. The lifetime asymmetry is dependent on the magnon frequency, being more pronounced, the higher the frequency. Analytical calculations of the magnon dispersion relation and linewidth agree well with experiments.

Phononic and magnonic dispersions of a linear array of periodic alternating Ni80Fe20 and bottom anti-reflective coating nanostripes on a Si substrate have been measured using Brillouin light scattering. The observed phononic gaps are considerably larger than those of laterally patterned multi-component crystals previously reported, mainly a consequence of the high elastic and density contrasts between the stripe materials. Additionally, the phonon hybridization bandgap has an unusual origin in the hybridization and avoided crossing of the zone-folded Rayleigh and pseudo-Sezawa waves. The magnonic band structure features near-dispersionless branches, with unusual vortex-like dynamic magnetization profiles, some of which lie below the highly-dispersive fundamental mode branch. Finite element calculations of the phononic and magnonic dispersions of the magphonic crystal accord well with experimental data.

The magnonic band structures for exchange spin waves propagating in one-dimensional magnonic crystal waveguides of different material combinations are investigated using micromagnetic simulations. The waveguides are periodic arrays of alternating nanostripes of different ferromagnetic materials. Our results show that the widths and center frequencies of the bandgaps are controllable by the component materials, the stripe widths, and the orientation of the applied magnetic field. One salient feature of the bandgap frequency plot against stripe width is that there are n-1 zero-width gaps for the nth bandgap for both transversely and longitudinally magnetized waveguides. Additionally, the largest bandgap widths are primarily dependent on the exchange constant contrast between the component materials of the nanostructured waveguides.

Most experimental investigations into magnonic bandgaps are based on structures composed of single-constituent magnetic materials. Here we report Brillouin and numerical studies of the spin dynamics of a bi-component magnonic crystal, viz. a one-dimensional periodic array of alternating permalloy and cobalt 150 nm-wide nanostripes. Our measurements, together with those for a similar crystal composed of 250 nm-wide nanostripes, suggest that for a stripe width ratio of 1:1, the bandgap width of such magnonic arrays increases with crystal lattice constant. The bandgap parameters are strongly dependent on external magnetic field. This magnetic-field tunability of the bandgap is expected to be a crucial property of devices based on magnonic crystals. The agreement between numerical calculations, based on finite element analysis, and the experimental data is generally good.

Just as a photonic crystal is a periodic composite composed of materials with different dielectric constants, its lesser known magnetic analogue, the magnonic crystal can be considered as a periodic composite comprising different magnetic materials. Magnonic crystals are excellent candidates for the fabrication of nanoscale microwave devices, as the wavelengths of magnons in magnonic crystals are orders of magnitude shorter than those of photons, of the same frequency, in photonic crystals. Using advanced electron beam lithographic techniques, we have fabricated a series of novel bicomponent magnonic crystals which exhibit well-defined frequency bandgaps. They are in the form of laterally patterned periodic arrays of alternating cobalt and permalloy stripes of various widths ranging from 150 to 500 nm. Investigations by Brillouin light scattering and computer modeling show that the dispersion spectrum of these crystals is strongly dependent on their structural dimensions. For instance, their first frequency bandgap is found to vary over a wide range of 1.4-2.6 gigahertz. Such a functionality permits the tailoring of the bandgap structure which controls the transmission of information-carrying spin waves in devices based on these crystals. Additionally, it is observed that the bandgap width decreases with increasing permalloy stripe width, but increases with increasing cobalt stripe width, and that the bandgap center frequency is more dependent on the stripe width of permalloy than that of cobalt. This information would be of value in the design of magnonic crystals for potential applications in the emerging field of magnonics.

Brillouin measurements have been made of the spin dynamics of high-density two-dimensional hexagonally ordered 20 nm diameter Fe48Co52 nanowire arrays, with various interwire spacings, as a function of longitudinal magnetic field. The experimental data are analyzed within the Arias-Mills theory based on interwire dipolar couplings in the arrays. The results provide conclusive evidence of collective spin waves arising from the dipolar coupling which is manifested as a reduction in spin wave frequency with decreasing interwire spacing.

CO on Ru[1010] was investigated by broadband femtosecond sum-frequency spectroscopy at 200 K. Approximately half of the frequency shift of 71 cm(-1) over the coverage range from 0.15 to 1.22 monolayers is shown to originate from dipole-dipole coupling, with the remainder due to a chemical shift. Despite low adlayer-surface registration at the highest coverages, the linewidth of the C-O stretch is comparatively low, and is described by homogeneous broadening according to sum-frequency free-induction decay measurements in the time domain. This can be explained by the dominance of the CO dipole coupling strength over the static disorder present in a coincidence structure. As the coverage decreases below 0.3 monolayer, the linewidth increases considerably, indicative of inhomogeneous broadening. Supported by a concomitant frequency change we suggest that at low coverages CO molecules form chains of irregular length in the [0001] direction, as has been shown for other surfaces with similar symmetry., ((c) 2004 American Institute of Physics.)