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From a coordination chemistry perspective, we aimed to advance the knowledge of Sr/Cs separation in the scheme of spent nuclear fuel reprocessing. Based on data mining of crystal structures and deep learning architecture, we summarized and analyzed coordination chemistry properties of Sr/Cs from complex structures(ca. 3.3×104 samples) of 8 alkaline and alkaline earth elements, especially focusing on coordination bond lengths as a representative figure of merit. Applying a Bayesian optimization approach, we were able to establish a high-performing transformer model which could predict the(differential) coordinative affinities toward Sr/Cs of ligand molecules, with exceptional accuracy. As a proof-of-concept, we systematically analyzed ca. 9.1×103 ligand molecules in terms of potential coordinative selectivity toward Sr/Cs and ranked them. In addition, we also determined different contribution of various functional groups for future molecular design of ligands with selectivity. The present study presented fundamental knowledge for coordination chemistry information in the context of radiochemistry and spent nuclear fuel reprocessing, provided guidance and reference for subsequent experiments regarding Sr/Cs separation.

Objective: By analyzing bacteriostasis and efficacy, the possibility of Artemisia argyi extract to be a plant extract preservative is clarified. It provides a message for the development of natural non-irritating plant extract preservative. Methods: Water and ethanol extracts of A. argyi were prepared. The content of its main active components was determined. Its inhibitory effect and stability on Escherichia coli and Staphylococcus aureus were analyzed. Antioxidant activity, ultraviolet absorption capacity and security were also discussed. Results: The ethanol extract of A. argyi had a significant inhibitory effect on the two kinds of bacteria, which was related to the content of active components to some extent. Temperature and UV irradiation had no significant effect on antibacterial activity, while pH had a greater effect on antibacterial activity. At the concentration of 0.96 mg/mL, ethanol extract of A. argyi leaves could eliminate 98% of DPPH and ABTS free radicals, and more than 50% of superoxide anion and hydroxyl free radicals. When the concentration was 0.5 mg/mL, the two extracts had good ultraviolet absorption capacity. The HET-CAM test showed that the extract of A. argyi had high security at the concentration of 62.5 mg/mL. Conclusion: The ethanol extract of A. argyi has good and stable bacteriostatic effect, certain antioxidant activity, ultraviolet absorption performance and security.

The hydraulic conductivity function of unsaturated soil spans several orders of magnitude. Traditional measurement methods often take several months, and it is difficult to measure the hydraulic conductivity in the full suction range. In order to realize the rapid measurement of hydraulic conductivity in the full suction range, the wetting front advancing method is combined with the instantaneous profile method (here referred to as the combined determination method) in this study. A self-developed soil column infiltration device was used to measure the hydraulic conductivity of Qinghai silty clay in the full suction range under different dry densities. The test results show that in the combined determination method, the wetting front advancing method is suitable for the measurement of hydraulic conductivity in the high suction range ( > 25 kPa), while the instantaneous profile method is suitable for measuring the hydraulic conductivity in the low suction range ( ≤25 kPa). The hydraulic conductivity determined by the two methods in the overlapped suction range is basically consistent. The combined determination method can reduce the measurement time of hydraulic conductivity in the full suction range by about one week with good accuracy. In addition, the error sources of the two measurement methods are also analyzed and discussed in this work. The results show that the combined determination method can realize the rapid measurement of hydraulic conductivity in the full suction range, which is expected to make the measurement of the hydraulic conductivity of unsaturated soil become a routine test in soil mechanics.

Diels-Alder (DA) addition is an efficient method to repair damages at mild conditions. It is often used in self-healing polyurethanes and epoxy resins and seldom used in cross-linked polyamides (cPAs). Michael addition becomes a useful method to synthesize cPAs. However, no efficient way has been established to conduct double-addition of primary amines. In this work, organic catalyzed Michael addition and polycondensation were established to prepare polyamide oligomers with furan pendent groups (pFU-PAs), and a DA addition was adopted to prepare self-healing cross-linked polyamides (SH-cPAs). A bulk double Michael addition of furfurylamine and methyl acrylate was performed at 30-70[degrees]C in the presence of 1,5,7-triazabicyclo[4.4.0] dec-5-ene (TBD), 7-methyl-1,5,7-triazabicyclo[4.4.0]dec-5-ene (MTBD), or 4-(N,N-dimethylamino) pyridine (DMAP), and a high yield of furfurylamine-N,N-bis(methyl propionate) (FA-BMP) was prepared. The catalytic activity order is MTBD>TBD >> DMAP in Michael addition. Melt polycondensation of FA-BMP with bis(2-aminopropyl) polypropyleneglycol and hexamethylene diamine was catalyzed by MTBD and N,N'-diphenylthiourea. The DA addition of 1,5-bismaleimido-2-methylpentane and pFU-PAs was monitored by FT-IR, [sup.1]H NMR, DSC, polarizing optical microscopy, and gel content. In these catalyzed processes, the structures of FA-BMP, pFU-PAs, and SH-cPAs were controlled easily, and the SH-cPAs showed good mechanical property and excellent self-healing performance of 88%-98%. KEYWORDS Diels-Alder addition, Michael addition, organic catalysts, polycondensation, self-healing polyamides, 1 | INTRODUCTION Thermoset polymers have a three-dimensional cross-linked structure, and they exhibit remarkable advantages, such as solvent resistance, heat resistance, dimensional stability, and excellent mechanical properties. [1-3] During their [...]