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The crystal-chemical variations of spinels grown as a function of cooling rate (ΔT/Δt) were analyzed via X-ray electron-microprobe (EPMA) maps. Maps were collected serially by using a fixed distance. Spinels solidified from a tholeiitic MOR basaltic liquid (B100) cooled at cooling rates (ΔT/Δt) of 1, 7, 60, and 180 °C/h, between 1300 and 800 °C and at ambient P and fO2. As ΔT/Δt increases, the amount of spinel is invariably <5 area% and its size decreases. Compared to the previous data set collected by common single and selected EPMA analytical points (112 analyses), the kinetic effects induced by ΔT/Δt are here quantitatively captured by a large number of analyses (2052). The TiO2, Al2O3, MgO, and FeOtot show large compositional variations at low cooling rates (from 1 to 60 °C/h), and only the average TiO2 concentration shows a well-defined trend as a function of ΔT/Δt. However, calculated average cation amounts (apfu) unveil quantitative kinetic effects. When ΔT/Δt increases (from 1 to 180 °C/h), only Ti4+ shows a linear decreasing trend, whereas the other major Al3+, Fe3+, Fe2+, and Mg2+ cations alone are scattered. Conversely, the sums of trivalent (Al3++Fe3+) and divalent (Mg2++Fe2+) cations quantitatively capture the effect of the ΔT/Δt. These new outcomes could be the base of novel geospeedometers with significant implications in volcanology, geophysics, and material sciences in regard to silicate melt rheology on Earth. They should be extended to high-pressure, hydrated, and low oxygen fugacity conditions. Furthermore, the analytical approach used here to capture kinetic effects on spinel growth and compositions can be also applied to other crystalline phases grown from silicate liquids. [ABSTRACT FROM AUTHOR]

Due to the incorrect speciation of iron during thermometry modelling, Coulthard et al. (2024) produced an incorrect olivine‐liquid equilibrium diagram, which failed to identify multiple potential equilibrium olivine‐melt pairs. With the new pairs identified here, the temperatures inferred from olivine‐groundmass pairs move closer in temperature space to those inferred from olivine‐glass pairs. Additionally, it is recognised that the most significant difference between these thermometry data is due to differences in inferred melt water mass fraction. If a mean value of water is used for all thermometry, the mean temperatures calculated for olivine‐glass and olivine‐groundmass pairs converge to within 10 °C of one another. This indicates that groundmass compositions inferred via the defocused beam analysis of a polyphase groundmass may reproduce enough information to confidently perform olivine‐melt thermometry despite the glass and groundmass data representing significantly different compositions in multivariate space. [ABSTRACT FROM AUTHOR]

Polyphase groundmasses (micro‐scale minerals with or without glass) are generated from silicate liquids during the cooling of natural lavas often alongside larger minerals formed long before eruption. Many researchers have posited that compositions gleaned from the analysis of groundmasses closely approximate the compositions of the melts they were derived from, and these have been used frequently to model pre‐eruptive magma conditions. However, it is difficult to confidently identify and sample these groundmasses once they are formed. Using a sample of lava that exhibits a wide degree of textural variation (ranging from holocrystalline to hypohyaline) we show that compositions of groundmasses sampled using defocused electron beams are significantly different from glass compositions in terms of mean composition and covariance. Despite this, several groundmass compositions qualify as 'in equilibrium' with matrix/rim olivine. When processed using available thermometers, however, modelled equilibrium temperatures are significantly higher than those produced using glass data, on average. Because of this, we prescribe caution in using polyphase groundmass data generated using defocused beam analysis even as a rudimentary approach. [ABSTRACT FROM AUTHOR]

The residence timescales of antecrystic minerals contribute a key piece of information regarding the petrologic evolution of transcrustal magmatic systems and may be inferred using a combination of observations derived from microanalytical chemistry and diffusion modelling. Here, we present state-of-the-art stacked CMOS-type active pixel sensor (SCAPS) isotopographic images of tephra-hosted plagioclase microantecrysts from Tongariro Volcanic Centre in the southern Taupo Volcanic Zone, New Zealand. These crystals exhibit high-frequency Sr and anorthite zonation at sub-micron spatial resolution. We also find that all crystals display high-frequency intracrystalline Sr chemical potential variations, indicating that they have not resided at magmatic temperature for diffusive relaxation to advance significantly. To quantify crystal residence times at the well-constrained magmatic temperatures of these tephras, we first forward-modeled intracrystalline Sr diffusion over time using numerical methods. Results were then analyzed using novel spatial Fourier-transform techniques developed to understand the systematics the diffusive decay of Sr disequilibria in the spatial frequency domain. This ultimately permitted the estimation of Sr concentration profiles at crystal formation, prior to uptake into the carrier melt at the onset of eruption. Our data imply residence times of hours to days for the studied microantecrysts. This is inconsistent with long antecryst residence times in magmatic mushes at elevated temperatures, pointing instead to a cool plutonic nature of the magmatic plumbing system beneath the southern Taupo Volcanic Zone. [ABSTRACT FROM AUTHOR]

Whereas arc magmas typically undergo early degassing-induced crystallization and viscous stagnation at mid-crustal levels, hotter and less hydrous melts that are associated with elevated surface heat flux may experience delayed crystallization at shallower levels. Using MELTS modelling, we demonstrate here that high-Mg andesites, which have been regarded as particularly hydrous primary melts generated in equilibrium with mantle peridotite, can form by crystal fractionation from low-[H.sub.2]O primitive arc basalts in the upper crust. This is consistent with many characteristics previously attributed to their primary origin, including forsteritic olivines that contain chromite inclusions and lack significant reaction rims, and Cr-rich pyroxenes. Supplementary material: Mineral compositional variations and partition coefficients are available at http:// www.geolsoc.org.uk/SUP18428. doi: 10.1144/0016-76492010-070.

Using global correlations of effusive eruption style with convergence rates and surface heat flux at volcanic arcs, this study identifies several arcs with excess surface heat flux, related to the presence of unusually hot and [H.sub.2]O-poor magmas. Geophysical evidence suggests that these melts are linked to discontinuities in the subducting slab, which would facilitate upwelling of hot sub-slab asthenospheric mantle. It is demonstrated that excess heat flux arcs are sites where Sr-rich adakitic compositions ate generated, and that the arc proportion erupting Sr-rich adakitic magmas is directly proportional to the degree of observed heat flux excess. A model is presented in which the formation of Sr-rich adakitic compositions, which require garnet as a residual phase, is facilitated at excess heat flux arcs as a result of a decrease in [H.sub.2]O content through contributions from sub-slab asthenospheric mantle, leading to an expansion of the garnet stability field. Future geochemical, geophysical and experimental work required to test this model is addressed.