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Abstract: We present a comprehensive study on the controlled phase synthesis and thermal decomposition of Cd(BH2)4, a material for solid state hydrogen storage obtained via the metathesis reaction of LiBH4 with CdCl2. By adjusting the stochiometry of the reactants and controlling the mechanical milling vial temperature, we have isolated the tetragonal (P42mn) low temperature phase and the cubic () high temperature phase of the cadmium borohydride. Cd(BH2)4 has a low thermodynamic stability and decomposes with fast kinetic at 348K, when heated at 1Kmin−1 against a backpressure of 1bar H2. A semi-quantitative analysis reveals that the decomposition gases are composed of 1:1 H2 +B2H6 and that only Cd remains as solid crystalline phase. [Copyright &y& Elsevier]

The Clean Energy Package expects a fundamental contribute for the decarbonisation of European energy system from Distributed Energy Resources (DERs), pushing Member States to favour the diffusion of energy production plants for individual and collective self-consumption. At the same time, DERs are required to contribute to system security mainly providing dispatching resources. The model developed includes the possibility to provide real-time balancing flexibility in a generic architecture where different energy vectors can be integrated through energy production, consumption and storage facilities. The optimization problem is built over a weekly time horizon with a stepwise approach where internal and external energy exchanges are defined updating meteorological forecasts, energy demands and markets results while approaching real-time operations. According to the Italian Authority consultation document 322/2019, both energy-only and capacity remunerated services are included in the model. The aim of the model is both to estimate the economic opportunities coming from energy markets participation for smart energy districts in the future energy framework, and to assess the actual capability and reliability of diverse DERs aggregates to provide flexibility to the external electric grid. These evaluations are carried out applying the presented model to a university campus case study where different energy conversion and storage plants are integrated at a Distribution Network level.

Energy Communities (ECs) are gaining a key role in supporting the transition towards a low carbon economy in EU, since they combine the promotion of efficient energy practices with an expected positive social impact. Legislators are resorting to the concept of collective self-consumption as a tool to favor the electrification of energy needs and the diffusion of renewable energy sources. This work presents the first results in this field of the ENERGYNIUS project, co-funded by Regione Emilia-Romagna, focusing on the economic feasibility of investment decisions that would increase energy efficiency and renewables’ penetration in the household sector. To this purpose, a mathematical model has been developed, featuring an hourly time step definition of the internal and external energy exchanges and an accurate modelling of the electricity billing. It has been applied to an Italian condominium case study where the energy requirements of the inhabitants – in terms of electricity, heating, cooling and private transportation – have been considered. Thanks to the model, it is possible to compare increasing levels of electrification (e.g., photovoltaic panels, heat pumps, electric vehicles and batteries) and assess the benefits of collective selfconsumption on the condominium cash flows and environment (fossil CO2 emissions).