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In the present work, a hierarchical braided polymer composite consists of Polytetrafluoroethylene (PTFE) fibers, reinforcement fibers, and epoxy resin was designed as a self-lubricant composite and bearing. Different reinforcements such as glass, carbon, and Kevlar fibers were employed to investigate the effect of reinforcement on the wear characteristics of composites. Besides, the influence of 2D/3D braid fabric was examined on the wear behavior of samples. Also, 90 and 120 N loads were applied to assess the load impact. Results illustrated that compared to glass and Kevlar, carbon could lead to a greater wear weight loss and friction coefficient. However, PTFE tribofilm was observed according to scanning electron microscopy (SEM)/energy-dispersive X-ray spectroscopy (EDS) analysis. Moreover, with the increase of load, the wear stability of the composites faded significantly. Furthermore, the tribological features became inappropriate with the deployment of the 3D braid structure. Finally, the modeling of tribological parameters was carried out using response surface methodology-based D-optimal design. The adequacy of the models was checked by analysis of variance. Results implied that there is an excellent correlation between the model and the experiments. [ABSTRACT FROM AUTHOR]

This research has investigated the optical properties of zinc sulfide commercial powder sintered via hot pressure (HP) and spark plasma sintering (SPS) methods. SEM images indicated that zinc sulfide commercial powder had spherical morphology, whereby nano rods smaller than 100 nm formed on spherical particles. Investigation of optical properties indicated that the zinc sulfide transparent ceramic prepared via HP (75%) had higher infrared transmission as compared to SPS (69%) within 8–12 micrometer. The stoichiometric ratio of S to Zn in the commercial powder was 1.5, which decreased to 1.1–1.3 after the sintering process. [ABSTRACT FROM AUTHOR]

Functionalized nanofibrous membranes have been produced via electrospinning with a polymer solution of 19% (w/w) of nylon 66 prepared in a formic acid/chloroform mixture (75:25 v/v). The optimum parameters of electrospinning, like voltage, flow rate, tip and collector distances, were achieved and produced nanofiber membranes with a thickness of 287 nm. Then the nanofiber membranes were functionalized by (3-mercaptopropyl)trimethoxysilane (TMPTMS) at various amounts. Three different initial concentrations of metal ions and three different levels of pH were chosen. The effect of filtration process parameters such as the initial concentration of metal solution, pH of the solution, and the amount of functionalizer trimethoxysilane (TMPTMS) on the adsorption was studied. In surveying filtration process parameters, the results showed that metal ion rejection increased by increasing the pH of the solution and decreased by increasing the initial concentration of the effluent. By increasing the amount of functionalizer, removal efficiency increased. The results showed that the maximum efficiency of absorption of cadmium and nickel were 93.0 and 97.6%, respectively, and the filtering mechanism of the membrane is the blocking pores type. The adsorption data of cadmium and nickel ions fitted particularly well with the Freundlich isotherm. [ABSTRACT FROM AUTHOR]

In this study hybrid polytetrafluoroethylene (PTFE)/glass fibers were employed in hierarchical braided structure as a composite reinforcement. PTFE-covered glass fibers were braided to achieve the hierarchical structure, then the composites were prepared through vacuum assisted resin transfer molding (VARTM) process. Tribological experiments were performed on the composites. The results showed self-lubricating and lower dynamic friction coefficient due to the PTFE transfer film formation. SEM micrographs confirmed the transfer film formation. Friction coefficient of 0.112, 0.105 and 0.096 were obtained under loading of 20, 30 and 40 N forces, respectively. The experimental coefficient of friction results were confirmed by mixture theory. The self-lubricating feature of PTFE-glass braided epoxy composite along with its mechanical characteristics makes it a feasible alternative for traditional wet bearing parts. [ABSTRACT FROM AUTHOR]