1. Tuning trion binding energy and oscillator strength in a laterally finite 2D system: CdSe nanoplatelets as a model system for trion properties
- Author
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Alexander W. Achtstein, Nina Owschimikow, Mikhail Artemyev, Guillaume H. V. Bertrand, Sihem Jaziri, Ulrike Woggon, Iwan Moreels, Michael T. Quick, Sabrine Ayari, and Sotirios Christodoulou
- Subjects
NEGATIVELY CHARGED EXCITONS ,DYNAMICS ,Technology and Engineering ,Materials science ,ZINCBLENDE CDSE ,Oscillator strength ,Exciton ,Binding energy ,02 engineering and technology ,SEMICONDUCTORS ,7. Clean energy ,01 natural sciences ,Molecular physics ,Condensed Matter::Materials Science ,0103 physical sciences ,COHERENCE ,General Materials Science ,010306 general physics ,Condensed Matter::Quantum Gases ,SPECTROSCOPY ,Condensed Matter::Other ,business.industry ,Condensed Matter::Mesoscopic Systems and Quantum Hall Effect ,021001 nanoscience & nanotechnology ,LIFETIMES ,2-PHOTON ABSORPTION ,Semiconductor ,Physics and Astronomy ,Quantum dot ,COLLOIDAL NANOPLATELETS ,Quantum efficiency ,Trion ,EMISSION ,0210 nano-technology ,business ,ddc:600 ,Lasing threshold - Abstract
We present a theoretical study combined with experimental validations demonstrating that CdSe nanoplatelets are a model system to investigate the tunability of trions and excitons in laterally finite 2D semiconductors. Our results show that the trion binding energy can be tuned from 36 meV to 18 meV with the lateral size and decreasing aspect ratio, while the oscillator strength ratio of trions to excitons decreases. In contrast to conventional quantum dots, the trion oscillator strength in a nanoplatelet at low temperature is smaller than that of the exciton. The trion and exciton Bohr radii become lateral size tunable,e.g.from similar to 3.5 to 4.8 nm for the trion. We show that dielectric screening has strong impact on these properties. By theoretical modeling of transition energies, binding energies and oscillator strength of trions and excitons and comparison with experimental findings, we demonstrate that these properties are lateral size and aspect ratio tunable and can be engineered by dielectric confinement, allowing to suppresse.g.detrimental trion emission in devices. Our results strongly impact further in-depth studies, as the demonstrated lateral size tunable trion and exciton manifold is expected to influence properties like gain mechanisms, lasing, quantum efficiency and transport even at room temperature due to the high and tunable trion binding energies.
- Published
- 2020
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