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2. Origin of renal proximal tubular injuries by Fe(III)-nta chelate

Author

Takahiro Satoh, Yuuta Ito, and Yuzo Nishida

Subjects
Transferrin, chemistry.chemical_element, Electrophoresis, Capillary, Glutathione, Ethylenediamines, Iron Chelating Agents, Oxygen, Peroxide, General Biochemistry, Genetics and Molecular Biology, Adduct, Rats, Kidney Tubules, Proximal, chemistry.chemical_compound, Capillary electrophoresis, chemistry, Polymer chemistry, Animals, Humans, Chelation, Apoproteins, Kidney tubules
Abstract

Interaction between apo-transferrin and several iron(III) chelates has been investigated in terms of the capillary electrophoresis method. Based on the results, it has been clarified that (i) a binuclear iron(III) unit with an oxo-bridge is necessary for the facile transfer of an iron atom from the iron(III) chelate to apo-transferrin, and (ii) the renal proximal tubular injuries by Fe(III)-nitrilotriacetate (Fe-nta) should be due to the unique binuclear structure of this complex, which gives a peroxide adduct of the binuclear Fe-nta in the presence of glutathione cycle and oxygen

Published
2007

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