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The electron microscopy and differential scanning calorimetry (DSC) investigation of spark-eroded Ni-Mn-Ga powders is discussed. The investigation reveals the presence of thermoelastic martensitic transitions in annealed powders.

Powders of Ni-Mn-Ga ferromagnetic shape memory alloy (FSMA) were produced by spark erosion. Powders quenched in liquid nitrogen are primarily hollow spherical particles, whereas those quenched in liquid argon are mostly solid spheres. Electron microscopy observations of powders as-sparked in nitrogen show highly disordered nanocrystalline grains with an average size of less than 100 nm whereas those sparked in liquid argon display extensive crystallinity. Magnetic measurements indicate that the powders do not become fully ferromagnetic until after annealing at 973 K for 5 h. Investigations of annealed powders using differential scanning calorimetry reveal thermoelastic martensitic transition behavior. The annealed powders have a microtwinned martensite with many large grains showing a five-layer period modulation. These Ni-Mn-Ga powders should be suitable for the development of magnetic-field-driven FSMA powder/polymer microcomposites. © 2004 American Institute of Physics. [ABSTRACT FROM AUTHOR]