1. Prussian blue analogs photocatalyst promote the evolution of value‐added platform compounds via CoCNZn covalent bonds
- Author
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Junming Shi, Guoyang Gao, Can Jin, Hongqing Wu, Weizhen Wang, Yulong An, Zhen Zhou, Zhanhua Huang, and Wenshuai Chen
- Subjects
biomass ,covalent bond ,heterojunctions ,Prussian blue analog ,value‐added platform compounds ,Renewable energy sources ,TJ807-830 ,Environmental sciences ,GE1-350 - Abstract
Abstract Value‐added conversion of lignocellulose is a sustainable approach. Photo‐refining biomass is in line with current environmental protection strategies. However, photo‐reforming biomass suffers from poor catalyst stability and low conversion efficiency. Here, we designed fructose as a lignocellulosic model. The heterogeneous structure of Prussian blue coating was constructed with a special covalent bond structure of CoCNZn. This structure has a catalytic conversion mechanism that can accelerate electron transfer. Fructose was simultaneously converted to value‐added platform compounds (5‐HMF and formic acid) and gaseous fuels (CO, CH4) with a conversion rate of up to 92.5%, which is more than 1.7 times than that of catalysts without adding Prussian blue. Hydrogen transfer and carbon transfer on the carbon atoms of fructose facilitates the production and accelerates the spillover of CO from formic acid. This work provides new ideas for the development of Prussian blue catalysts and the conversion of pentose.
- Published
- 2024
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