1. Synthesis and Reactivity of New Aminophenolate Complexes of Nickel
- Author
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Siqi Yu, Huan Wang, Jill E. Sledziewski, Venkata N. Madhira, Cyrus G. Takahashi, Michelle K. Leon, Yulia B. Dudkina, Yulia H. Budnikova, and David A. Vicic
- Subjects
nickel ,cross-coupling ,coordination chemistry ,paramagnetic complexes ,Organic chemistry ,QD241-441 - Abstract
New well-defined, paramagnetic nickel complexes have been prepared and characterized by X-ray crystallography. The complexes were found to be active for the cross-coupling of alkyl electrophiles (especially ethyl 2-bromobutyrate) with alkyl Grignard reagents. The ligand architecture in these new complexes could potentially be rendered chiral, opening up future possibilities for performing asymmetric cross-coupling reactions.
- Published
- 2014
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