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Your search keyword '"Yue, Chenglong"' showing total 15 results
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15 results on '"Yue, Chenglong"'

4. MALT1 is a potential therapeutic target in glioblastoma and plays a crucial role in EGFR‐induced NF‐κB activation

Author

Liu, Xuejiao, primary, Yue, Chenglong, additional, Shi, Lin, additional, Liu, Guanzheng, additional, Cao, Qiyu, additional, Shan, Qianqian, additional, Wang, Yifeng, additional, Chen, Xiangyu, additional, Li, Huan, additional, Wang, Jie, additional, Gao, Shangfeng, additional, Niu, Mingshan, additional, and Yu, Rutong, additional

Published
2020
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5. Inhibition of chromosomal region maintenance 1 suppresses the migration and invasion of glioma cells via inactivation of the STAT3/MMP2 signaling pathway

Author

Shan, Qianqian, primary, Li, Shengsheng, additional, Cao, Qiyu, additional, Yue, Chenglong, additional, Niu, Mingshan, additional, Chen, Xiangyu, additional, Shi, Lin, additional, Li, Huan, additional, Gao, Shangfeng, additional, Liang, Jun, additional, Yu, Rutong, additional, and Liu, Xuejiao, additional

Published
2020
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14. Highly Stable Chiral Zirconium–Metallosalen Frameworks for CO2Conversion and Asymmetric C–H Azidation

Author

Li, Jiawei, Ren, Yanwei, Yue, Chenglong, Fan, Yamei, Qi, Chaorong, and Jiang, Huanfeng

Abstract

The engineering of highly stable metal–organic frameworks (MOFs) will unveil the intrinsic potential of these materials for practical applications, especially for heterogeneous catalyzes. However, it is fairly challenging to rationally design robust MOFs serving as highly effective and reusable heterogeneous catalysts. Here, for the first time, we report the construction of four robust UiO-type chiral zirconium–metallosalen frameworks, denoted ZSF-1–4. Single-crystal X-ray-diffraction reveals that the frameworks consist of twelve-connected Zr6O8clusters with privileged chiral metallosalen ligands anchored at ideal positions, generating confined chiral cages that enable synergistic activation. Unlike UiO-68 that is highly sensitive to aqueous solutions, ZSF-1–4 exhibit excellent chemical stability in aqueous solutions with a wide range of pH owing to the abundant hydrophobic groups within metallosalen ligands. These features render ZSF-1 and ZSF-2 to be excellent recycled heterogeneous catalysts for the conversion of imitated industrial CO2with epoxides into cyclic carbonates with the highest reported turnover numbers in Zr-MOFs. With regard to asymmetric catalysis, ZSF-3 and ZSF-4 can effectively catalyze C–H azidation reaction in water medium with ee value up to 94%. Moreover, these robust ZSFs can be further extended to other analogues with various metal centers through demetallization–remetallization strategy, which renders them to be an excellent platform for broader fields.

Published
2018
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15. Highly Stable Chiral Zirconium-Metallosalen Frameworks for CO 2 Conversion and Asymmetric C-H Azidation.

Author

Li J, Ren Y, Yue C, Fan Y, Qi C, and Jiang H

Abstract

The engineering of highly stable metal-organic frameworks (MOFs) will unveil the intrinsic potential of these materials for practical applications, especially for heterogeneous catalyzes. However, it is fairly challenging to rationally design robust MOFs serving as highly effective and reusable heterogeneous catalysts. Here, for the first time, we report the construction of four robust UiO-type chiral zirconium-metallosalen frameworks, denoted ZSF-1-4. Single-crystal X-ray-diffraction reveals that the frameworks consist of twelve-connected Zr 6 O 8 clusters with privileged chiral metallosalen ligands anchored at ideal positions, generating confined chiral cages that enable synergistic activation. Unlike UiO-68 that is highly sensitive to aqueous solutions, ZSF-1-4 exhibit excellent chemical stability in aqueous solutions with a wide range of pH owing to the abundant hydrophobic groups within metallosalen ligands. These features render ZSF-1 and ZSF-2 to be excellent recycled heterogeneous catalysts for the conversion of imitated industrial CO 2 with epoxides into cyclic carbonates with the highest reported turnover numbers in Zr-MOFs. With regard to asymmetric catalysis, ZSF-3 and ZSF-4 can effectively catalyze C-H azidation reaction in water medium with ee value up to 94%. Moreover, these robust ZSFs can be further extended to other analogues with various metal centers through demetallization-remetallization strategy, which renders them to be an excellent platform for broader fields.

Published
2018
Full Text
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