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Anatase titanium dioxide (TiO2) has emerged as a potential anode material for sodium-ion hybrid capacitors (SICs) in terms of its nontoxicity, high structure stability and cost-effectiveness. However, its inherent poor electrical conductivity and limited reversible capacity greatly hinder its practical application. Here, ultrathin TiO2 nanoplates were synthesized utilizing a hydrothermal technique. The electrochemical kinetics and reversible capacity were significantly improved through sulfur and nitrogen co-doping combined with carbon coating (SN-TiO2/C). Sulfur and nitrogen co-doping generated oxygen vacancies and introduced additional active sites within TiO2, facilitating accelerated Na-ion diffusion and enhancing its reversible capacity. Furthermore, carbon coating provided stable support for electron transfer in SN-TiO2/C during repeated cycling. This synergistic strategy of sulfur and nitrogen co-doping with carbon coating for TiO2 led to a remarkable capacity of 335.3 mAh g−1 at 0.1 A g−1, exceptional rate property of 148.3 mAh g−1 at 15 A g−1 and a robust cycling capacity. Thus, the SN-TiO2/C//AC SIC delivered an impressive energy density of 177.9 W h kg−1. This work proposes an idea for the enhancement of reaction kinetics for energy storage materials through a synergistic strategy.

Nd2Sn2O7 NPs were synthesized by employing a straightforward synthetic method along with aromatic ring-doped g-C3N4 nanosheets loaded onto dendritic filamentous nanotitanium (DFNT/Ar-g-C3N4@Nd2Sn2O7). The inclusion of DFNT in this process was found to offer an abundance of O-H groups for the uniform charging of g-C3N4 through chemical bonding interaction. The topography and mesoporous anatomy of the DFNT/Ar-g-C3N4@Nd2Sn2O7 composite remained unchanged upon Ar-g-C3N4@Nd2Sn2O7 loading, indicating the sustained crystalline shape. This extraordinary catalyst exhibits a noteworthy capacity in facilitating the N-formylation reaction by establishing N-C bonds through the reaction between amine and carbon dioxide, all while conforming to environmentally favourable circumstances. Here, the DFNT/Ar-g-C3N4@Nd2Sn2O7 photocatalyst was synthesized utilizing a solvothermal approach for the N-formylation of N-methylaniline. The main products obtained were mono-N-formylated compounds, with favourable to excellent yields for all amines. Lastly, an explanation for the reaction between amine and carbon dioxide is put forward by conducting control experiments and verifying spectra.

Amidst escalating fuel expenses and growing concerns over greenhouse gas pollution, the adoption of renewable alternative energy sources has become increasingly imperative. In response, scientists are fervently dedicated to identifying energy-saving solutions that are readily adaptable. Notably, silica aerogels have demonstrated remarkable efficacy in temperature management under both hot and cold conditions, while phase change materials are renowned for their capacity to store thermal energy. The study examines the effect of initial pressure on the thermal performance of silica aerogel/PCM/CuO nanostructure in a cylindrical duct. This was investigated using MD simulations and the LAMMPS software. The study will investigate several elements, such as density, velocity, temperature patterns, heat flux, thermal conductivity, and charge time or discharge time of the simulated structure. According to the results, with an increase in the initial pressure, the maximum density increases from 0.0838 atom/Å3 to 0.0852 atom/Å3, and the maximum velocity decreases from 0.0091 Å/fs to 0.0081 Å/fs. Also, the findings show that, by increasing the initial pressure, the temperature decreases from 931.42 K to 895.63 K, and thermal conductivity and heat flux decrease to 1.56 W/m.K and 56.66 W/m2 with increasing the initial pressure to 5 bar. Finally, the results show that charging time increases to 6.34 ns at 5 bar. The increase in charging time with increasing initial pressure may be attributed to the reduced mobility of particles within the structure as a result of the higher pressure. The findings of this study can help for a better understanding of energy-saving solutions, advanced thermal management systems, and the design of efficient energy storage technologies tailored to specific pressure-related operating conditions.

In the context of “double carbon,” waste disposal has become a critical issue so far, and how to deal with it is the key to ensuring compliance with the double carbon target, the most practical treatment is still incineration, and how to establish the site selection and legal compensation mechanism is crucial. This paper establishes an environmental dynamic monitoring system for waste incineration power plants based on the Gaussian model and successfully solves the health risk of surrounding residents. Regarding the economic compensation issues, we first applied the AHP to analyze the pollutants comprehensively, constructed the judgment matrix, and conducted a consistency test, determined the weight of each index, and integrated various emissions into one pollutant, which is convenient for the concentration of pollutants. Then, by taking into account the effects of wind direction, rainfall, topography, and other factors on the diffusion of pollutants, we calculated the pollutants around the waste incineration power plant site based on the “elevated continuous point source” “diffusion model.” To obtain the concentration distribution, monitoring points were set up at representative locations, and the environmental monitoring system of the waste incineration power plant was established. Finally, Matlab software was used to draw the contour map of pollutant concentration, and the concentration level of pollutants was divided according to waste incineration. Given the income of the power plant, the economic level of the surrounding residents, the amount of compensation from the local government, and the pollution level, economic compensation plans for the surrounding residents were developed. Through analyzing the proposed compensation scheme, it can be known that the compensation scheme can satisfy the surrounding residents. The highlights of this paper can be described as follows: First, the analytic hierarchy process is used to comprehensively consider the pollutants, simplifying the establishment process of the model. Second, the pollutant concentration is graded, and the concentration equivalent map is drawn to make the monitoring point layout more representative. The economic compensation plan is more reasonable and more convincing to the public.

In this study, hybrid AA1050/Al2O3/TiO2 composites have been produced via combined liquid casting and powder metallurgy techniques. Degassing was utilized to improve the wettability of molten aluminum alloys, and then successful bonding was generated between aluminum matrix and reinforcement particles during the powder metallurgy technique. As the base matrix and reinforcements, AA1050 alloy, Al2O3 and TiO2 particles were taken, respectively. Then, content values of 5Wt.% of Al2O3 in the mesh size of 20 μm and 2.5 and 5 wt. % of TiO2 particles with mesh size of 5μm were added to the AA1050 matrix. For each composite sample, ceramic particles were warmed to 600°C in order to improve wettability and distribution. An identical scattering of subdivisions was observed through aluminum (as matrix) in the microstructural study. To measure the wear resistance, the mechanism of rotary wear test was used. The achieved results illustrated that the fabrication of hybrid composites is an ideal approach to improve the wear resistance of Al-based composites. By increasing of TiO2 Wt.% up to 5% for all composite samples, the wear rate improved to less than half of the monolithic Al alloy value for each composite sample.

In this work, we develop single-mode fiber devices of an InAs/GaAs quantum dot (QD) by bonding a fiber array with large smooth facet, small core, and small numerical aperture to QDs in a distributed Bragg reflector planar cavity with vertical light extraction that prove mode overlap and efficient output for plug-and-play stable use and extensive study. Modulated Si doping as electron reservoir builds electric field and level tunnel coupling to reduce fine-structure splitting (FSS) and populate dominant XX and higher excitons XX+ and XXX. Epoxy package thermal stress induces light hole (lh) with various behaviors related to the donor field: lh h1 confined with more anisotropy shows an additional XZ line (its space to the traditional X lines reflects the field intensity) and larger FSS; lh h2 delocalized to wetting layer shows a fast h2–h1 decay; lh h2 confined shows D3h symmetric higher excitons with slow h2–h1 decay and more confined h1 to raise h1–h1 Coulomb interaction.