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Abstract Dielectric polymer composites for film capacitors have advanced significantly in recent decades, yet their practical implementation in industrial-scale, thin-film processing faces challenges, particularly due to limited biaxial stretchability. Here, we introduce a mechanochemical solution that applies liquid metal onto rigid dielectric fillers (e.g. boron nitride), dramatically transforming polymer-filler interface characteristics. This approach significantly reduces modulus mismatch and stress concentration at the interface region, enabling polypropylene composites to achieve biaxial stretching ratio up to 450 × 450%. Furthermore, liquid metal integration enhances boron nitride’s dielectric polarization while maintaining inherent insulation, producing high-dielectric-constant, low-loss films. These films, only microns thick yet quasi square meters in area, achieve a 55% increase in energy density over commercial biaxially-oriented polypropylene (from 2.9 to 4.5 J cm−3 at 550 MV/m), keeping 90% discharge efficiency. Coupled with improved thermal conductivity, durability, and device capacitance, this distinctive interface engineering approach makes these composites promising for high-performance film capacitors.

Abstract Low‐temperature rechargeable aqueous zinc metal batteries (AZMBs) as highly promising candidates for energy storage are largely hindered by huge desolvation energy barriers and depressive Zn2+ migration kinetics. In this work, a superfast zincophilic ion conductor of layered zinc silicate nanosheet (LZS) is constructed on a metallic Zn surface, as an artificial layer and ion diffusion accelerator. The experimental and simulation results reveal the zincophilic ability and layer structure of LZS not only promote the desolvation kinetics of [Zn(H2O)6]2+ but also accelerate the Zn2+ transport kinetics across the anode/electrolyte interface, guiding uniform Zn deposition. Benefiting from these features, the LZS‐modified Zn anodes showcase long‐time stability (over 3300 h) and high Coulombic efficiency with ≈99.8% at 2 mA cm−2, respectively. Even reducing the environment temperature down to 0 °C, ultralong cycling stability up to 3600 h and a distinguished rate performance are realized. Consequently, the assembled Zn@LZS//V2O5‐x full cells deliver superior cyclic stability (344.5 mAh g−1 after 200 cycles at 1 A g−1) and rate capability (285.3 mAh g−1 at 10 A g−1) together with a low self‐discharge rate, highlighting the bright future of low‐temperature AZMBs.

Abstract Low‐temperature zinc batteries (LT‐ZIBs) based on aqueous electrolytes show great promise for practical applications owing to their natural resource abundance and low cost. However, they suffer from sluggish kinetics with elevated energy barriers due to the dissociation of bulky Zn(H2O)62+ solvation structure and free Zn2+ diffusion, resulting in unsatisfactory lifespan and performance. Herein, dissimilar to solvation shell tuning or layer spacing enlargement engineering, delocalized electrons in cathode through constructing intrinsic defect engineering is proposed to achieve a rapid electrocatalytic desolvation to obtain free Zn2+ for insertion/extraction. As revealed by density functional theory calculations and interfacial spectroscopic characterizations, the intrinsic delocalized electron distribution propels the Zn(H2O)62+ dissociation, forming a reversible interphase and facilitating Zn2+ diffusion across the electrolyte/cathode interface. The as‐fabricated oxygen defect‐rich V2O5 on hierarchical porous carbon (ODVO@HPC) electrode exhibits high capacity robustness from 25 to −20°C. Operating at −20°C, the ODVO@HPC delivers 191 mAh g−1 at 50 A g−1 and lasts for 50 000 cycles at 10 A g−1, significantly enhancing the power density and lifespan under low‐temperature environments in comparison to previous reports. Even with areal mass loading of ~13 mg cm−2, both coin cells and pouch batteries maintain excellent stability and areal capacities, realizing practical high‐performance LT‐ZIBs.

Abstract Phase change materials (PCMs) are expected to achieve dual-mode thermal management for heating and cooling Li-ion batteries (LIBs) according to real-time thermal conditions, guaranteeing the reliable operation of LIBs in both cold and hot environments. Herein, we report a liquid metal (LM) modified polyethylene glycol/LM/boron nitride PCM, capable of dual-mode thermal managing the LIBs through photothermal effect and passive thermal conduction. Its geometrical conformation and thermal pathways fabricated through ice-template strategy are conformable to the LIB’s structure and heat-conduction characteristic. Typically, soft and deformable LMs are modified on the boron nitride surface, serving as thermal bridges to reduce the contact thermal resistance among adjacent fillers to realize high thermal conductivity of 8.8 and 7.6 W m−1 K−1 in the vertical and in-plane directions, respectively. In addition, LM with excellent photothermal performance provides the PCM with efficient battery heating capability if employing a controllable lighting system. As a proof-of-concept, this PCM is manifested to heat battery to an appropriate temperature range in a cold environment and lower the working temperature of the LIBs by more than 10 °C at high charging/discharging rate, opening opportunities for LIBs with durable working performance and evitable risk of thermal runaway.

The environmental pollution caused by antibiotics is becoming more serious. In this study, the Mn/BiPO4/g-C3N4 composite (Mn-BPC) and the Ti/g-C3N4/BiPO4 composite (Ti-BPC) were prepared by hydrothermal reaction method and solvent method, respectively, and applied to the degradation of tetracycline (TC) in an aqueous environment. The XRD and HRTEM results showed that these materials had the crystalline rod-like structure of BiPO4 and abundant carbon, nitrogen and carbon–oxygen surface functional groups. The degradation of TC by Ti-BPC and Mn-BPC were nearly 92% and 79%, respectively. The degradation processes of TC were well consistent with the pseudo-second-order kinetics model and R2 values were closer to 1. The trapping experiment showed that electron holes (h+) were the main reactive species for the degradation of tetracycline, OH· and O2− also have certain effects. Also, the possible photocatalytic degradation mechanism of Ti-BPC and Mn-BPC composites was thereby proposed. TC was firstly adsorbed on the surface of catalysts, and subsequently degraded by reactive species such as h+, OH· and O2− generated under visible light excitation. This study shows that the Ti-BPC and Mn-BPC photocatalysts have great potential in antibiotic degradation and can provide new ideas for antibiotic removal in aqueous environments.

Abstract In past decades, high‐entropy (HE) materials, containing five or more elements with approximately equal atomic ratio, are extensively investigated due to their desirable properties in a series of applications. Recently, HE two‐dimensional (2D) materials have become promising materials, which not only endow the advantages from their bulk form but also exhibit unusual properties due to their 2D features. So far, the HE 2D transition metal carbides (MXenes), dichalcogenides (TMDs), hydrotalcites (LDHs), and oxides have been successfully synthesized and performed well in different electrochemical reactions, which is originated from the synergistic effect of multicomponents and atomic thin characteristics. Here, the challenges on processing, characterization, and property predictions of HE 2D materials are emphasized. Finally, viable strategies, advanced processing, fundamental understanding, in‐depth characterization of new HE 2D materials are proposed.

High-speed railways play an important role in transportation electrification and transportation efficiency. Affected by the high air temperature and strong solar radiation in hot regions, the upper surface of the ballastless track plate on the high-speed railway suffers from high temperatures. The large temperature difference between the upper and lower surfaces of the ballastless track plates will cause engineering damages such as seams and fractures, and further threatens the durability, driving comfort, and safety of high-speed railways. To address this risk, a thermal management technology using cooling tubes is proposed to control the temperature and minimize the temperature maldistribution of ballastless track plates. A multiphysics model is built to characterize the temperature distribution of a high-speed railway in Guangzhou (hot region). The influences of typical factors (ambient temperature, solar radiation, and geological conditions) on the performance of thermal management of the track plates are analyzed. The results show that the maximum temperature difference between the upper and lower surfaces of an ordinary ballastless track plate can reach 18.78 °C. The maximum temperature gradient along the depth direction occurs at the center of the track plate, which is 0.94 °C/cm, and the uniformity coefficient in the track plate domain is 8.53. By integrating the thermal management tubes, the temperature difference is effectively reduced to 5 °C, lower by 70%, and the temperature gradient along the depth at the center of the track plate is reduced to 0.25 °C/cm. The uniformity coefficient is reduced to 3.60. The research is expected to eliminate the deformation problem caused by the temperature maldistribution of ballastless track plates and ensure the smooth and effective operation of high-speed railways in hot weather.

The performance of existing rice-paddy weeding machines is not optimal. In this study, the influence of the installation angle of the weeding-wheel blade on cutting resistance and soil-slippage ability was analyzed. The optimal blade angle of the weeding wheel (i.e., the angle at which the resistance to the weeding wheel is minimal and the disturbance speed of the soil maximal) was shown to be< 20°; numerical simulation showed the actual optimal value to be 0°. Different weeding depths (30, 40, and 50 mm), rotation speed of weeding wheel (120, 180, and 240 r/min), and weeder forward speeds (0.3, 0.6, and 0.9 m/s) were used as test factors, and the rates of seedling injury and weeding were used as performance-evaluation criteria to optimize the machine in a secondary orthogonal-rotation combination test. Field experiments showed that the weeding wheel can exhibit optimal working performance under the operating conditions of weeding depth of 39 mm, rotation speed of 175 r/min, and forward speed of 0.6 m/s. The seedling injury and weeding rates were 4.4% and 88.2%, respectively, which were consistent with the numerically predicted results and met the agronomic requirements. This study provides a technical reference for the improvement of paddy-field weeding components.

Sandy loam soils are widespread and important for agricultural soil use. The lateral stress caused by the loosening shovel of a subsoiler produces lateral disturbances in sandy loam soil, reducing compaction and improving soil structure. To explore the variation and transmission of lateral stress due to the operation of a double-wing subsoiler in sandy loam soil, a lattice of point-type soil sensors was arranged in a soil bin, and the lateral stress generated by subsoiling was measured in the shallow, medium, and deep soil layers. The experimental results show that when the lateral stress generated by the double-wing subsoiler is transferred to the lateral position of different distances.The lateral stress shows a sinusoidal fluctuation law with time, the sine wave frequency range is: shallow (0.366–0.549); middle (0.306–0.494); and deep (0.088–0.501). There were greater fluctuation amplitudes in the transfer process for the shallow and deep soil layers than for the middle layer. Shallow soil had the largest final stable lateral stress (0.1617 N), and middle soil the smallest (0.0733 N). Thus, lateral stress from deep loosening has the greatest effect on shallow soil and the least effect on middle soil. These results indicate that the fluctuating lateral stresses generated by double-wing-subsoiler operation drive a fluctuating soil disturbance that can improve soil structure, and that they are greater for shallow and deep soils than for middle soils.

ZnIn2S4 (ZIS) is widely used in the field of photocatalytic hydrogen production due to its unique photoelectric properties. Nonetheless, the photocatalytic performance of ZIS usually faces problems of poor conductivity and rapid recombination of charge carriers. Heteroatom doping is often regarded as one of the effective strategies for improving the catalytic activity of photocatalysts. Herein, phosphorus (P)-doped ZIS was prepared by hydrothermal method, whose photocatalytic hydrogen production performance and energy band structure were fully studied. The band gap of P-doped ZIS is about 2.51 eV, which is slightly smaller than that of pure ZIS. Moreover, due to the upward shift of its energy band, the reduction ability of P-doped ZIS is enhanced, and P-doped ZIS also exhibits stronger catalytic activity than pure ZIS. The optimized P-doped ZIS exhibits a hydrogen production rate of 1566.6 μmol g−1 h−1, which is 3.8 times that of the pristine ZIS (411.1 μmol g−1 h−1). This work provides a broad platform for the design and synthesis of phosphorus-doped sulfide-based photocatalysts for hydrogen evolution.

There are three weaknesses in previous Fast-flux domain name detection method on the aspects of stability,targeting,and applicability to common real-world DNS traffic environment.For this,a method based on DNS traffic,called Fast-flucos was proposed.Firstly,the traffic anomaly filtering and association matching algorithms were used for improving detection stability.Secondly,the features,quantified geographical width,country list,and time list,were applied for better targeting Fast-flux domains.Lastly,the feature extraction were finished by the more suitable samples for trying to adapt to common real-world DNS traffic.Several machine learning algorithms including deep learning are tried for determining the best classifier and feature combination.The experimental result based on real-world DNS traffic shows that Fast-flucos’ recall rate is 0.998 6,precision is 0.976 7,and ROC_AUC is 0.992 9,which are all better than the current main stream approaches,such as EXPOSURE,GRADE and AAGD.

Material interfaces are highly crucial to improve device performances. Here, the authors report interfacial reconstruction at the Au {001} substrate surface and the top MoS2 and WS2 monolayers due to the formation of a metastable interfacial Au4S4 phase. The reconstructed interface results in a p-type Schottky contact with reduced barrier height.

Sandy clay loam has the characteristics of both sand and clay. Because of these characteristics, both frictional resistance and adhesive resistance occur between the soil and tillage tool. The combined effect of the two frictional forces increases the external friction angle between the soil and tillage tool, thus increasing the working resistance. To address this issue, this study investigated the coupling effect of high pressure and hot air on the external friction angle by using a self-developed device to measure the external friction angle. Test results showed that high-pressure air between the soil and tillage tool formed a high-pressure air curtain layer which acted as a lubricant, thereby reducing the external friction angle. The external friction angle decreased as the airflow pressure increased. The reduction in the moisture content of the subsoil to less than 30% by the high-pressure hot air reduced the resistance between the soil and tillage tool. The approach with the high-pressure hot air curtain was verified in tests on a subsoiling shovel; the working resistance of the shovel under high-pressure hot air was reduced by 14.8%, demonstrating that this approach was effective in reducing the working resistance of the shovel.

Angiotensin-converting enzyme 2 (ACE2), a functional receptor for SARS-CoV, now appears likely to mediate 2019-nCoV entry into human cells. However, inhibitors such as PAP-1 and bergamottin have been discovered; both of them can preferentially bind to ACE2, prevent RBD Spike S protein from binding to ACE2, and reduce the binding sites for RBD Spike S protein. In addition, we investigated the binding energy of PAP-1 and bergamottin with ACE2 through molecular docking with bio-layer interferometry (BLI) and found relatively high binding affinity (KD = 48.5 nM, 53.1 nM) between the PAP-1 and bergamottin groups. In addition, the nanomolar fraction had no effect on growth of the AT-II cell, but 150 µM PAP-1 and 75 µM bergamottin inhibited the proliferation of AT-II cells in vitro by 75% and 68%, respectively. Meanwhile, they significantly reduced ACE2 mRNA and proteins by 67%, 58% and 55%, 41%, respectively. These results indicate that psoralen compounds PAP-1 and bergamottin binding to ACE2 protein could be further developed in the fight against COVID-19 infection during the current pandemic. However, attention should be paid to the damage to human alveolar type II epithelial cells.

Abstract Electrically insulating polymers are indispensable for electronic and energy applications, but their poor thermal conduction has increasingly become a bottleneck for high‐performance devices. Highly drawn low‐dimensional polymeric fibers and thin films can exhibit metallic conductivity. Extending this to bulk materials required by real world applications is prohibitive due to the additional interfacial thermal conduction barriers. It is demonstrated that highly aligned ultrahigh molecular weight polyethylene microfibers can be incorporated into a silicone matrix to yield a fully organic bulk polymer composite with a continuous vertical phonon pathway. This leads to a perpendicular thermal conductivity of 38.27 W m−1 K−1, at par with metals and two orders of magnitude higher than other bulk organic polymers. Taking further advantage of the mechanical flexibility of the microfibers, the processing method offers the freedom to tailor heat transfer pathways in a macroscopic 3D space. The material/process opens up opportunities for efficient thermal management in high‐performance devices.

Single‐atom sites on MXenes (SASs‐MXenes) have attracted widespread attention for energy storage and conversion due to their highest atom utilization efficiency, intriguing intrinsic properties, unusual performance, and improved robustness. In addition, the large surface area and abundant anchor sites make MXenes ideal substrates for supporting single atoms via covalent interaction. Herein, the main strategies for synthesis of SASs‐MXenes are first summarized, which cover capturing single atoms by cation vacancies, coordinating single atoms with heterodopants, and inheriting single atoms from MAX phases. Then, disclosing the crucial roles SASs‐MXenes play in tuning the kinetics and thermodynamics of various catalytic reactions, i.e., hydrogen evolution reaction, nitrogen reduction reaction, CO2 reduction reaction, CO2 functionalization, polysulfide conversion, and other redox reactions involved in rechargeable batteries, is focused on. Finally, the challenges and future opportunities for developing highly active SASs‐MXenes are discussed.

In response to the HTTP malicious traffic detection problem,a preprocessing method based on cutting mechanism and statistical association was proposed to perform statistical information correlation as well as normalization processing of traffic.Then,a hybrid neural network was proposed based on the combination of raw data and empirical feature engineering.It combined convolutional neural network (CNN) and multilayer perceptron (MLP) to process text and statistical information.The effect of the model was significantly improved compared with traditional machine learning algorithms (e.g.,SVM).The F1value reached 99.38% and had a lower time complexity.At the same time,a data set consisting of more than 450 000 malicious traffic and more than 20 million non-malicious traffic was created.In addition,prototype system based on model was designed with detection precision of 98.1%~99.99% and recall rate of 97.2%~99.5%.The application is excellent in real network environment.

The highly thermo-conductive but electrically insulating film, with desirable mechanical performances, is extremely demanded for thermal management of portable and wearable electronics. The integration of boron nitride nanosheets (BNNSs) with regenerated cellulose (RC) is a sustainable strategy to satisfy these requirements, while its practical application is still restricted by the brittle fracture and loss of toughness of the composite films especially at the high BNNS addition. Herein, a dual-crosslinked strategy accompanied with uniaxial pre-stretching treatment was introduced to engineer the artificial RC/BNNS film, in which partial chemical bonding interactions enable the effective interfiber slippage and prevent any mechanical fracture, while non-covalent hydrogen bonding interactions serve as the sacrifice bonds to dissipate the stress energy, resulting in a simultaneous high mechanical strength (103.4 MPa) and toughness (10.2 MJ/m3) at the BNNS content of 45 wt%. More importantly, attributed to the highly anisotropic configuration of BNNS, the RC/BNNS composite film also behaves as an extraordinary in-plane thermal conductivity of 15.2 W/m·K. Along with additional favorable water resistance and bending tolerance, this tactfully engineered film ensures promised applications for heat dissipation in powerful electronic devices.

Efflux pumps in Gram-negative bacteria such as Pseudomonas aeruginosa provide intrinsic antimicrobial resistance by facilitating the extrusion of a wide range of antimicrobials. Approaches for combating efflux-mediated multidrug resistance involve, in part, developing indirect antimicrobial agents capable of inhibiting efflux, thus rescuing the activity of antimicrobials previously rendered inactive by efflux. Herein, TXA09155 is presented as a novel efflux pump inhibitor (EPI) formed by conformationally constraining our previously reported EPI TXA01182. TXA09155 demonstrates strong potentiation in combination with multiple antibiotics with efflux liabilities against wild-type and multidrug-resistant (MDR) P. aeruginosa. At 6.25 µg/mL, TXA09155, showed ≥8-fold potentiation of levofloxacin, moxifloxacin, doxycycline, minocycline, cefpirome, chloramphenicol, and cotrimoxazole. Several biophysical and genetic studies rule out membrane disruption and support efflux inhibition as the mechanism of action (MOA) of TXA09155. TXA09155 was determined to lower the frequency of resistance (FoR) to levofloxacin and enhance the killing kinetics of moxifloxacin. Most importantly, TXA09155 outperformed the levofloxacin-potentiation activity of EPIs TXA01182 and MC-04,124 against a CDC/FDA panel of MDR clinical isolates of P. aeruginosa. TXA09155 possesses favorable physiochemical and ADME properties that warrant its optimization and further development.

The ability to rescue the activity of antimicrobials that are no longer effective against bacterial pathogens such as Pseudomonas aeruginosa is an attractive strategy to combat antimicrobial drug resistance. Herein, novel efflux pump inhibitors (EPIs) demonstrating strong potentiation in combination with levofloxacin against wild-type P. aeruginosa ATCC 27853 are presented. A structure activity relationship of aryl substituted heterocyclic carboxamides containing a pentane diamine side chain is described. Out of several classes of fused heterocyclic carboxamides, aryl indole carboxamide compound 6j (TXA01182) at 6.25 µg/mL showed 8-fold potentiation of levofloxacin. TXA01182 was found to have equally synergistic activities with other antimicrobial classes (monobactam, fluoroquinolones, sulfonamide and tetracyclines) against P. aeruginosa. Several biophysical and genetic studies rule out membrane disruption and support efflux inhibition as the mechanism of action (MOA) of TXA01182. TXA01182 was determined to lower the frequency of resistance (FoR) of the partner antimicrobials and enhance the killing kinetics of levofloxacin. Furthermore, TXA01182 demonstrated a synergistic effect with levofloxacin against several multidrug resistant P. aeruginosa clinical isolates.

Molecular oxygen activated by visible light to generate radicals with high oxidation ability exhibits great potential in environmental remediation The efficacy of molecular oxygen activation mainly depends on the separation and migration efficiency of the photoinduced charge carriers. In this work, 2D/2D CdIn2S4/g-C3N4 heterojunctions with different weight ratios were successfully fabricated by a simple electrostatic self-assembled route. The optimized sample with a weight ratio of 5:2 between CdIn2S4 and g-C3N4 showed the highest photocatalytic activity for tetracycline hydrochloride (TCH) degradation, which also displayed good photostability. The enhancement of the photocatalytic performance could be ascribed to the 2D/2D heterostructure; this unique 2D/2D structure could promote the separation and migration of the photoinduced charge carriers, which was beneficial for molecular oxygen activation, leading to an enhancement in photocatalytic activity. This work may possibly provide a scalable way for molecular oxygen activation in photocatalysis.

To study the loading rate dependence of acoustic emissions and the failure mechanism of fractured rock, biaxial compression tests performed on granite were numerically simulated using the bonded particle model in Particle Flow Code (PFC). Uniaxial tests on a sample containing a single open fracture were simulated under different loading rates ranging from 0.005 to 0.5 m/s. Our results demonstrate the following. (1) The overall trends of stress and strain changes are not affected by the loading rate; the loading rate only affects the strain required to reach each stage. (2) The strain energy rate and acoustic emission (AE) events are affected by the loading rate in fractured rock. With an increase in the loading rate, AE events and the strain energy rate initially increase and then decrease, forming a fluctuating trend. (3) Under an external load, the particles within a specimen are constantly squeezed, rotated, and displaced. This process is accompanied by energy dissipation via the production of internal tensile and shear cracks; their propagation and coalescence result in the formation of a macroscopic rupture zone.

The anchoring mechanism of a bolted joint subjected to a shear load was investigated using a bilinear constitutive model via the inner-embedded FISH language of particle flow code based on the discrete element method. The influences of the anchoring system on the macro-/micromechanical response were studied by varying the inclination angle of the bolt. The results indicate a clear relationship between the mechanical response of a bolted rock joint and the mechanical properties of the anchoring angle. By optimizing the anchorage angle, the peak strength can be increased by nearly 50% relative to that at an anchorage angle of 90°. The optimal anchorage angle ranges from 45° to 75°. The damage mechanism at the optimal anchorage angle joint is revealed from a macroscopic mechanical perspective. The concentration of the contact force between disks will appear in the joint and around the bolt, resulting in crack initiation. These cracks are mainly tensile cracks, which are consistent with the formation mechanism for compression-induced tensile cracks. Therefore, the macroscopic peak shear stress in the joint and the microscopic damage to the anchoring system should be considered when determining the optimal anchoring angle to reinforce a jointed rock mass.

This paper constructs a series of modules from modular Lie superalgebras W(0∣n), S(0∣n), and K(n) over a field of prime characteristic p≠2. Cartan subalgebras, maximal vectors of these modular Lie superalgebras, can be solved. With certain properties of the positive root vectors, we obtain that the sufficient conditions of these modules are irreducible L-modules, where L=W(0∣n), S(0∣n), and K(n).

This paper is concerned with the natural filtration of Lie superalgebra S(n,m) of special type over a field of prime characteristic. We first construct the modular Lie superalgebra S(n,m). Then we prove that the natural filtration of S(n,m) is invariant under its automorphisms.