1. Establishment and Validation of a Two-Component Surrogate Fuel Chemical Kinetic Skeletal Model for Fischer–Tropsch Fuel Synthesized from Coal
- Author
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Ruiqing Liu, Ruiliang Zhang, Yizhuo Feng, and Tiantian Yang
- Subjects
chemical kinetic ,skeletal mechanism ,f–t surrogate model ,Technology - Abstract
Fischer−Tropsch (F−T) fuel, synthesized from coal-to-liquid (CTL), is an alternative fuel with clean and efficient characteristics. In this study, a surrogate fuel model was developed, including n-dodecane (n-C12H26) and iso-octane (i-C8H18), which represents the n-alkane and iso-alkane in F−T fuel synthesized from CTL, respectively. The proportions of the components in the surrogate fuel are determined by the characteristics of the practical fuel, including cetane number (CN), C/H ration and component composition. For the establishment of the skeletal mechanism model, firstly, based on a two-step direct relationship graph (DRG) and the computational singular perturbation (CSP) importance index method, a reduced model of n-dodecane was developed involving 159 species and 399 reactions, while the detailed n-dodecane mechanism consists of 1279 species and 5056 reactions. Then, the n-dodecane skeletal mechanism was constructed based on a decoupling methodology, involving the skeletal C12 mechanism from the reduced mechanism, a C2-C3 sub mechanism and a detailed H2/CO/C1 sub mechanism. Finally, the skeletal mechanism for the F−T surrogate fuel was developed, including the n-dodecane skeletal mechanism and an iso-octane macromolecular skeletal mechanism. The final mechanism for the F−T diesel surrogate fuel consists of 169 species and 406 reactions. The n-dodecane skeletal mechanism and iso-octane skeletal mechanism were validated on various fundamental experiments, including the ignition delay in shock tubes, the primary species concentrations in jet-stirred reactors and the premixed laminar flame over wide operating conditions, which show great agreement between the predictions and measurements. Moreover, an F−T surrogate fuel mechanism was employed to simulate the combustion characteristics of an engine using computational fluid dynamics (CFD). The results show that the mechanism can predict the performance of F−T fuel combustion in engine accurately.
- Published
- 2020
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