Author: "Yessengazin, Azamat" - Searchworks@Jio Institute Digital Library Search Results

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Author: Yessengazin, Azamat, Seisenkul, Bakdaulet, Tussupbayev, Samat, Andizhanova, Tolganay, and Khalimon, Andrey Y.
Subjects: *HYDROBORATION, *ESTERS, *LACTONES, *BORANES, *AMMONIA
Abstract: Herein we describe an efficient methodology for metal‐free hydroborative cleavage of lactones and esters with HBPin (Pin=pinacol) to the corresponding alcohol derivatives using ammonia borane as a pre‐catalyst. The reactions proceed under mild conditions, can be performed in a solvent‐free manner, and do not require an inert atmosphere. Combined experimental and computational mechanistic studies suggest a novel mechanism that involves μ‐aminodiboranes as catalytically active species. [ABSTRACT FROM AUTHOR]
Published: 2024
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Author: Fitzsimmons, Matthew C., primary, Yessengazin, Azamat, additional, Hatzis, Gillian P., additional, Stevens, Jeremiah E., additional, Moore, Curtis E., additional, and Thomas, Christine M., additional
Published: 2023
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Author: Adilkhanova, Aziza, primary, Frolova, Valeriya F., additional, Yessengazin, Azamat, additional, Öztopçu, Özgür, additional, Gudun, Kristina A., additional, Segizbayev, Medet, additional, Matsokin, Nikita A., additional, Dmitrienko, Anton, additional, Pilkington, Melanie, additional, and Khalimon, Andrey Y., additional
Published: 2023
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