Search

Despite its biogeneic and astrochemical importance, sulfur (S), the 10th most abundant element in the interstellar medium (ISM) with a total abundance of S/H~2.2E-5, largely remains undetected in molecular clouds. Even in the diffuse ISM where S was previously often believed to be fully in the gas phase, in recent years observational evidence has suggested that S may also be appreciably depleted from the gas. What might be the dominant S reservoir in the ISM remains unknown. Solid sulfides like MgS, FeS and SiS_2 are excluded as a major S reservoir due to the undetection of their expected infrared spectral bands in the ISM. In this work, we explore the potential role of sulfurated polycyclic aromatic hydrocarbon (PAH) molecules -- PAHs with sulfur heterocycles (PASHs) -- as a sink for the missing S. Utilizing density function theory, we compute the vibrational spectra of 18 representative PASH molecules. It is found that these molecules exhibit a prominent, C--S stretching band at ~10 micron and two relatively weak, C--S deformation bands at 15 and 25 micron that are not mixed with the nominal PAH bands at 6.2, 7.7, 8.6, 11.3 and 12.7 micron If several parts per million of S (relative to H) are locked up in PAHs, the 10 micron C--S band would be detectable by Spitzer and JWST. To quantitatively explore the amount of S/H depleted in PASHs, detailed comparison of the infrared emission spectra of PASHs with the Spitzer and JWST observations is needed., Comment: 35 pages, 9 figures, 5 tables; accepted for publication in The Astrophysical Journal

We combined a principal component analysis (PCA) and spectroscopy to investigate the origin of the soft excess in narrow-line Seyfert 1 galaxy Ark 564 with XMM-Newton observations over a period of ten years. We find that the principal components in different epochs are very similar, suggesting stable variability patterns in this source. More importantly, although its spectra could be equally well fitted by the two soft excess models, simulations show that the principal components from the relativistically smeared reflection model match the data well. At the same time, the principal components from the warm corona model show significant inconsistency. This finding indicates that the soft excess in Ark 564 originates from the relativistically smeared reflection, rather than the Comptonization in the warm corona, thereby favoring the reflection origin or the "hybrid" origin of the soft excess. Furthermore, the presence of the narrow absorption features in the spectra suggests that the soft excess is unlikely to originate from absorptions due to possible outflowing winds. Our results indicate that the PCA coupled with spectral analysis is a promising approach to exploring the origin of the soft excess in active galactic nuclei (AGNs)., Comment: 9 pages, 6 figures, Accepted for publication in A&A

Deuterium (D) was exclusively generated in the Big Bang and the standard Big Bang Nucleosynthesis (BBN) model predicts a primordial abundance of D/H~26ppm. As the Galaxy evolves, D/H gradually decreases because of astration. The Galactic chemical evolution (GCE) model predicts a present-day abundance of D/H~20ppm. However, observations of the local interstellar medium (ISM) have revealed that the gas-phase interstellar D/H varies considerably from one region to another and has a median abundance of D/H~13ppm, substantially lower than predicted from the BBN and GCE models. It has been suggested that the missing D atoms of D/H~7ppm could have been locked up in deuterated polycyclic aromatic hydrocarbon (PAH) molecules. However, we have previously demonstrated that PAHs with aromatic C--D units are insufficient to account for the missing D. Here we explore if PAHs with aliphatic C--D units could be a reservoir of D. We perform quantum chemical computations of the vibrational spectra of "superdeuterated" PAHs (in which one D and one H share an C atom) and PAHs attached with D-substituted methyl group, and derive the band strengths of the aliphatic C--D stretch (A_4.65). By applying the computationally derived A_4.65 to the observed aliphatic C--D emission at ~4.6--4.8 micron, we find that PAHs with aliphatic C--D units could have tied up a substantial amount of D/H and marginally account for the missing D. The possible routes to generate PAHs with aliphatic C--D units are also discussed., Comment: 41 pages, 24 figures, accepted for publication by ApJS

The exact nature of the 2175 Angstrom extinction bump, the strongest spectroscopic absorption feature superimposed on the interstellar extinction curve, remains unknown ever since its discovery in 1965. Popular candidate carriers for the extinction bump include nano-sized graphitic grains and polycyclic aromatic hydrocarbon (PAH) molecules. To quantitatively evaluate PAHs as a possible carrier, we perform quantum chemical computations for the electronic transitions of 30 compact, pericondensed PAH molecules and their cations as well as anions with a wide range of sizes from 16 to 96 C atoms and a mean size of 43 C atoms. It is found that a mixture of such PAHs, which individually exhibit sharp absorption features, show a smooth and broad absorption band that resembles the 2175 Angstrom interstellar extinction bump. Arising from \pi^{*} --\pi, the width and intensity of the absorption bump for otherwise randomly-selected and uniformly-weighted PAH mixtures, do not vary much with PAH sizes and charge states, whereas the position shifts to longer wavelengths as PAH size increases. While the computed bump position, with the computational uncertainty taken into account, appears to agree with that of the interstellar extinction bump, the computed width is considerably broader than the interstellar bump if the molecules are uniformly weighted. It appears that, to account for the observed bump width, one has to resort to PAH species of specific sizes and structures., Comment: 13 pages, 8 figures, 1 table, accepted for publication in MNRAS

The most striking characteristics of the mysterious 2175 Angstrom extinction bump, the strongest spectroscopic absorption feature seen on the interstellar extinction curve, are the invariant central wavelength and variable bandwidth: its peak position at 2175 Angstrom is remarkably constant while its bandwidth varies from one line of sight to another. However, recent studies of the lines of sight toward a number of Herbig Ae/Be stars have revealed that the extinction bump exhibits substantial shifts from the canonical wavelength of 2175 Angstrom. In this work we revisit these lines of sight and take a physical approach to determine the ultraviolet (UV) extinction curve for each line of sight. It is found that the wavelengths of the derived UV extinction bumps are around 2200 Angstrom and the scatters are considerably smaller than that of the previous study based on the same set of Herbig Ae/Be stars, consistent with the conventional wisdom. Nevertheless, the scatters are still appreciably larger than that associated with the nominal bump position of 2175 Angstrom. This is discussed in the context that Herbig Ae/Be stars are not well-suited for interstellar extinction studies., Comment: 12 pages, 9 figures, 2 tables, accepted for publication in MNRAS

The so-called "unidentified infrared emission" (UIE) features at 3.3, 6.2, 7.7, 8.6, and 11.3 micron ubiquitously seen in a wide variety of astrophysical regions are generally attributed to polycyclic aromatic hydrocarbon (PAH) molecules. Astronomical PAHs often have an aliphatic component (e.g., aliphatic sidegroups like methyl --CH3 may be attached as functional groups to PAHs) as revealed by the detection in many UIE sources of the aliphatic C--H stretching feature at 3.4 micron. With its unprecedented sensitivity, unprecedented spatial resolution and high spectral resolution, the James Webb Space Telescope (JWST) holds great promise for evolutionizing the studies of aliphatics and aromatics in the universe. To facilitate analyzing JWST observations, we present a theoretical framework for determining the aliphatic fractions (\eta_ali) of PAHs, the fractions of C atoms in aliphatic units, from the emission intensity ratios of the 3.4 micron feature to the 3.3 micron feature. To demonstrate the effectiveness of this framework, we compile the 3.3 and 3.4 micron UIE data obtained in the pre-JWST era for an as complete as possible sample, and then apply the framework to these pre-JWST data. We derive a median aliphatic fraction of <\eta_ali>=5.4\% and find that the aliphatic fractions are the highest in protoplanetary nebulae illuminated by cool stars lacking ultraviolet radiation. Nevertheless, the "hardness" of stellar photons is not the only factor affecting the PAH aliphaticity, other factors such as the starlight intensity may also play an important role., Comment: 30 pages, 15 figures, accepted for publication by ApJS

The High Energy X-ray telescope (HE) on-board the Hard X-ray Modulation Telescope (\textit{Insight}-HXMT) can serve as a wide Field of View (FOV) gamma-ray monitor with high time resolution ($\mu$s) and large effective area (up to thousands cm$^2$). We developed a pipeline to search for Gamma-Ray Bursts (GRBs), using the traditional signal-to-noise ratio (SNR) method for blind search and the coherent search method for targeted search. By taking into account the location and spectrum of the burst and the detector response, the targeted coherent search is more powerful to unveil weak and sub-threshold bursts, especially those in temporal coincidence with Gravitational Wave (GW) events. Based on the original method in literature, we further improved the coherent search to filter out false triggers caused by spikes in light curves, which are commonly seen in gamma-ray instruments (e.g. \textit{Fermi}/GBM, \textit{POLAR}). We show that our improved targeted coherent search method could eliminate almost all false triggers caused by spikes. Based on the first two years of \textit{Insight}-HXMT/HE data, our targeted search recovered 40 GRBs, which were detected by either \textit{Swift}/BAT or \textit{Fermi}/GBM but too weak to be found in our blind search. With this coherent search pipeline, the GRB detection sensitivity of \textit{Insight}-HXMT/HE is increased to about 1.5E-08 erg/cm$^2$ (200 keV$-$3 MeV). We also used this targeted coherent method to search \textit{Insight}-HXMT/HE data for electromagnetic (EM) counterparts of LIGO-Virgo GW events (including O2 and O3a runs). However, we did not find any significant burst associated with GW events., Comment: 12 pages, 14 figures, 5 tables; accepted for publication in MNRAS

We studied the harmonics of the millihertz quasi-periodic oscillations (mHz QPOs) in the neutron-star low-mass X-ray binary 4U 1636-53 using the Rossi X-ray Timing Explorer observations. We detected the harmonics of the mHz QPOs in 73 data intervals, with most of them in the transitional spectra state. We found that the ratio between the rms amplitude of the harmonic and that of the fundamental remains constant in a wide range of the fundamental frequency. More importantly, we studied, for the first time, the rms amplitude of the harmonics vs. energy in 4U 1636-53 in the 2-5 keV range. We found that the rms amplitude of both the harmonic and the fundamental shows a decreasing trend as the energy increases, which is different from the behaviors reported in QPOs in certain black hole systems. Furthermore, our results suggest that not all observations with mHz QPOs have the harmonic component, although the reason behind this is still unclear., Comment: 17 pages, 10 figures, accepted by ApJ

Observationally, the interstellar gas-phase abundance of deuterium (D) is considerably depleted and the missing D atoms are often postulated to have been locked up into carbonaceous solids and polycyclic aromatic hydrocarbon (PAH) molecules. An accurate knowledge of the fractional amount of D (relative to H) tied up in carbon dust and PAHs has important cosmological implications since D originated exclusively from the Big Bang and the present-day D abundance, after accounting for the astration it has experienced during the Galactic evolution, provides essential clues to the primordial nucleosynthesis and the cosmological parameters. To quantitatively explore the extent to which PAHs could possibly accommodate the observed D depletion, we have previously quantum-chemically computed the infrared vibrational spectra of mono-deuterated PAHs and derived the mean intrinsic band strengths of the 3.3 $\mu$m C--H stretch (A$_{3.3}$) and the 4.4 $\mu$m C--D stretch (A$_{4.4}$). Here we extend our previous work to multi-deuterated PAH species of different deuterations, sizes and structures. We find that both the intrinsic band strengths A$_{3.3}$ and A$_{4.4}$ and their ratios A$_{4.4}$/A$_{3.3}$ not only show little variations among PAHs of different deuterations, sizes and structures, they are also closely similar to that of mono-deuterated PAHs. Therefore, a PAH deuteration level (i.e., the fraction of peripheral atoms attached to C atoms in the form of D) of ~2.4% previously estimated from the observed 4.4 $\mu$m to 3.3 $\mu$m band ratio based on the A$_{4.4}$/A$_{3.3}$ ratio of mono-deuterated PAHs is robust., Comment: 36 pages, 17 figures, 6 tables; accepted for publication in The Astrophysical Journal Supplement Series

Deuterium (D) is one of the light elements created in the big bang. As the Galaxy evolves, the D/H abundance in the interstellar medium (ISM) decreases from its primordial value due to "astration". However, the observed gas-phase D/H abundances of some interstellar sightlines are substantially lower than the expected reduction by astration alone. The missing D could have been depleted onto polycyclic aromatic hydrocarbon (PAH) molecules which are ubiquitous and abundant in interstellar regions. To quantitatively explore the hypothesis of PAHs as a possible reservoir of interstellar D, we compute quantum-chemically the infrared vibrational spectra of mono-deuterated PAHs (and their cations) of various sizes. We find that, as expected, when H in PAHs is replaced by D, the C-H stretching and bending modes at 3.3, 8.6 and 11.3 $\mu$m respectively shift to longer wavelengths at $\sim$4.4, 11.4 and 15.4 $\mu$m by a factor of $\sim$$\sqrt{13/7}$, the difference in reduced mass between the C-H and C-D oscillators. We derive from the computed spectra the mean intrinsic strengths of the 3.3 $\mu$m C-H stretch and 4.4 $\mu$m C--D stretch to be $\langle A_{3.3} \rangle \sim 13.4$ km/mol and $\langle A_{4.4} \rangle \sim 7.4$ km/mol for neutral deuterated PAHs which would dominate the interstellar 3.3 and 4.4 $\mu$m emission. By comparing the computationally-derived mean ratio of $\langle A_{4.4}/A_{3.3} \rangle \sim 0.56$ for neutral PAHs with the mean ratio of the observed intensities of $\langle (I_{4.4}/I_{3.3})_{\rm obs} \rangle \sim 0.019$, we estimate the degree of deuteration (i.e., the fraction of peripheral atoms attached to C in the form of D) to be ~2.4\%, corresponding to a D-enrichment of a factor of ~1200 with respect to the interstellar D/H abundance., Comment: 29 pages, 13 figures, 5 tables; accepted for publication in The Astrophysical Journal Supplement Series

Superhydrogenated polycyclic aromatic hydrocarbons (PAHs) may be present in H-rich and ultraviolet-poor benign regions. The addition of excess H atoms to PAHs converts the aromatic bonds into aliphatic bonds, the strongest of which falls near 3.4 $\mu$m. Therefore, superhydrogenated PAHs are often hypothesized as a carrier of the 3.4 $\mu$m emission feature which typically accompanies the stronger 3.3 $\mu$m aromatic C--H stretching feature. To assess this hypothesis, we use density function theory to compute the IR vibrational spectra of superhydrogenated PAHs and their ions of various sizes (ranging from benzene, naphthalene to perylene and coronene) and of various degrees of hydrogenation (ranging from minimal hydrogenation to heavy hydrogenation). For each molecule, we derive the intrinsic oscillator strengths of the 3.3 $\mu$m aromatic C--H stretch ($A_{3.3}$) and the 3.4 $\mu$m aliphatic C--H stretch ($A_{3.4}$). By comparing the computationally-derived mean ratio of $\langle A_{3.4}/A_{3.3}\rangle\sim1.98$ with the mean ratio of the observed intensities $\langle I_{3.4}/I_{3.3}\rangle\sim0.12$, we find that the degree of superhydrogenation --- the fraction of C atoms attached with excess H atoms --- is only $\sim2.2\%$ for neutral PAHs which predominantly emit the 3.3 and 3.4 $\mu$m features. We also determine for each molecule the intrinsic band strengths of the 6.2 $\mu$m aromatic C--C stretch ($A_{6.2}$) and the 6.85 $\mu$m aliphatic C--H deformation ($A_{6.85}$). We derive the degree of superhydrogenation from the mean ratio of the observed intensities $\langle I_{6.85}/I_{6.2}\rangle\sim0.10$ and $\langle A_{6.85}/A_{6.2}\rangle\sim1.53$ for neutrals and $\langle A_{6.85}/A_{6.2}\rangle\sim1.23$ for cations to be $\lesssim 3.1\%$ for neutrals and $\lesssim 8.6\%$ for cations. We conclude that astrophysical PAHs are primarily aromatic and are only marginally superhydrogenated., Comment: 49 pages, 26 figures; accepted for publication in The Astrophysical Journal Supplement Series

Interstellar graphene could be present in the interstellar medium (ISM), resulting from the photochemical processing of polycyclic aromatic hydrocarbon (PAH) molecules and/or collisional fragmentation of graphitic particles. Indeed, by comparing the observed ultraviolet (UV) extinction and infrared (IR) emission of the diffuse ISM with that predicted for graphene, as much as $\sim$ 2% of the total interstellar carbon could have been locked up in graphene without violating the observational constraints. While the possible detection of planar C$_{24}$, a small piece of a graphene sheet, has been reported towards several Galactic and extragalactic planetary nebulae, graphene has not yet been detected in interstellar environments. In this work, we search for the characteristic IR features of C$_{24}$ at $\sim$ 6.6, 9.8, 20 $\mu m$ toward Sgr B2, a high-mass star formation region, and find a candidate target toward R.A. (J2000) = $267^{\circ}.05855$ and Decl. (J2000) = $-28^{\circ}.01479$ in Sgr B2 whose Spitzer/IRS spectra exhibit three bands peaking at $\sim$ 6.637, 9.853 and 20.050 $\mu m$ which appear to be coincident with that of C$_{24}$. Possible features of C$_{60}$ are also seen in this region. The candidate region is a warm dust environment heated by massive stars or star clusters, associated with a WISE spot (a tracer of star-formation activity), close to the HII region candidate IRAS 17450-2759, and is surrounded by seven young stellar object candidates within $\sim$ 5$^{\prime}$, suggesting that the creation and/or excitation of C$_{24}$ could be related to star formation activities., Comment: 10 pages in total, 4 figures, 3 tables. Accepted for publication in RAA

PtBi2 with a layered trigonal crystal structure was recently reported to exhibit an unconventional large linear magnetoresistance, while the mechanism involved is still elusive. Using high resolution angle-resolved photoemission spectroscopy, we present a systematic study on its bulk and surface electronic structure. Through careful comparison with first-principle calculations, our experiment distinguishes the low-lying bulk bands from entangled surface states, allowing the estimation of the real stoichiometry of samples. We find significant electron doping in PtBi2, implying a substantial Bi deficiency induced disorder therein. We discover a Dirac-cone-like surface state on the boundary of the Brillouin zone, which is identified as an accidental Dirac band without topological protection. Our findings exclude quantum-limit-induced linear band dispersion as the cause of the unconventional large linear magnetoresistance., Comment: 5 pages, 5 figures

Pd site doping effect on superconductivity was investigated in quasi-one-dimensional superconductor Nb2(Pd1-xRx)0.76S5 (R=Ir, Ag) by measuring resistivity, magnetic susceptibility and Hall effect. It was found that superconducting transition temperature (Tc) is firstly slightly enhanced by partial substitution of Pd with Ir and then it is suppressed gradually as Ir content increases further. Meanwhile Ag substitution quickly suppresses the system to a nonsuperconducting ground state. Hall effect measurements indicate the variations of charge carrier density caused by Ir or Ag doping. The established phase diagram implies that the charge carrier density (or the band filling) could be one of the crucial controlling factors to determine Tc in this system., Comment: 5 pages, 5 figures. EPL in press

The unidentified infrared emission (UIE) features at 3.3, 6.2, 7.7, 8.6, and 11.3 micrometer, commonly attributed to polycyclic aromatic hydrocarbon (PAH) molecules, have been recently ascribed to mixed aromatic/aliphatic organic nanoparticles. More recently, an upper limit of <9% on the aliphatic fraction (i.e., the fraction of carbon atoms in aliphatic form) of the UIE carriers based on the observed intensities of the 3.4 and 3.3 micrometer emission features by attributing them to aliphatic and aromatic C-H stretching modes, respectively, and assuming A_34./A_3.3~0.68 derived from a small set of aliphatic and aromatic compounds, where A_3.4 and A_3.3 are respectively the band strengths of the 3.4 micrometer aliphatic and 3.3 micrometer aromatic C-H bonds. To improve the estimate of the aliphatic fraction of the UIE carriers, here we analyze 35 UIE sources which exhibit both the 3.3 and 3.4 micrometer C-H features and determine I_3.4/I_3.3, the ratio of the power emitted from the 3.4 micrometer feature to that from the 3.3 micrometer feature. We derive the median ratio to be ~ 0.12. We employ density functional theory and second-order perturbation theory to compute A_3.4/A_3.3 for a range of methyl-substituted PAHs. The resulting A_3.4/A_3.3 ratio well exceeds 1.4, with an average ratio of ~1.76. By attributing the 3.4 micrometer feature exclusively to aliphatic C-H stretch (i.e., neglecting anharmonicity and superhydrogenation), we derive the fraction of C atoms in aliphatic form to be ~2%. We therefore conclude that the UIE emitters are predominantly aromatic., Comment: 14 pages, 5 figures, 1 table; accepted for publication in The Astrophysical Journal

We perform a survey of the Cr, Mn and Fe-K emission lines in young supernova remnants (SNRs) with the Japanese X-ray astronomy satellite {\sl Suzaku}. The Cr and/or Mn emission lines are detected in 3C\,397 and 0519-69.0 for the first time. We also confirm the detection of these lines in Kepler, W49B, N103B and Cas A. We derive the line parameters (i.e., the line centroid energy, flux and equivalent width [EW]) for these six sources and perform a correlation analysis for the line center energies of Cr, Mn and Fe. Also included in the correlation analysis are Tycho and G344.7-0.1 for which the Cr, Mn and Fe-K line parameters were available in the literature through {\sl Suzaku} observations. We find that the line center energies of Cr correlates very well with that of Fe and that of Mn. This confirms our previous findings that the Cr, Mn and Fe are spatially co-located, share a similar ionization state, and have a common origin in the supernova nucleo-synthesis. We find that the ratio of the EW of the Cr emission line to that of Fe ($\EWR\equiv \EWCr/\EWFe$) provides useful constraints on the SNR progenitors and on the SN explosion mechanisms: for SNRs with $\EWR > 2%$, a type Ia origin is favored (e.g., N103B, G344.7-0.1, 3C\,397 and 0519-69.0); for SNRs with $\EWR < 2%$, they could be of either core-collpase origin or carbon-deflagration Ia origin., Comment: 17 pages, 5 figures, accepted for publication in the Astrophysical Journal

We propose that a non-thermal X-ray arc inside the remnant of Tycho's supernova (SN) represents the interaction between the SN ejecta and the companion star's envelope lost in the impact of the explosion. The X-ray emission of the remnant further shows an apparent shadow casted by the arc in the opposite direction of the explosion site, consistent with the blocking of the SN ejecta by the envelope. This scenario supports the single degenerate binary origin of Tycho's SN. The properties of the X-ray arc, together with the previous detection of the companion candidate and its space velocity by Ruiz-Lapuente et al. (2004) and Hern\'{a}ndez et al.(2009), enables us to further infer 1) the progenitor binary has a period of 4.9$^{+5.3}_{-3.0}$ days, 2) the companion gained a kick velocity of 42$\pm$30 km s$^{-1}$, and 3) the stripped envelope mass is about 0.0016($\leq0.0083$) $M_{\sun}$. However, we notice that the nature of the companion candidate is still under debate, and the above parameters need to be revised according to the actual properties of the companion candidate. Further work to measure the proper motion of the arc and to check the capability of the interaction to emit the amount of X-rays observed from the arc is also needed to validate the current scenario., Comment: 17 pages with 4 figures included, accepted to ApJ

We present new results of the HESS J1731-347/SNR G353.6-0.7 system from XMM-NEWTOM and Suzaku X-ray observations, and Delinha CO observations. We discover extended hard X-rays coincident with the bright, extended TeV source HESS J1731-347 and the shell of the radio SNR. We find that spatially-resolved X-ray spectra can generally be characterized by an absorbed power-law model, with photon-index of ~ 2, typical of non-thermal emission. A bright X-ray compact source, XMMS J173203-344518, is also detected near the center of the SNR. We find no evidence of a radio counterpart or an extended X-ray morphology for this source, making it unlikely to be a pulsar wind nebular (PWN). The spectrum of the source can be well fitted by an absorbed blackbody with a temperature of ~ 0.5 keV plus a power-law tail with a photon-index of ~ 5, reminiscent of the X-ray emission of a magnetar. CO observations toward the inner part of the HESS source reveal a bright cloud component at -20+/-4 km s^{-1}, which is likely located at the same distance of ~ 3.2 kpc as the SNR. Based on the probable association between the X-ray and $\gamma$-ray emissions and likely association between the CO cloud and the SNR, we argue that the extended TeV emission originates from the interaction between the SNR shock and the adjacent CO clouds rather than from a PWN., Comment: 9 pages, 4 figs, 2 tables. To appear in ApJ, 2010, ApJ, in press

We performed a Cr-K emission line survey in young supernova remnants (SNRs) with the Chandra archival data. Our sample includes W49B, Cas A, Tycho and Kepler. We confirmed the existence of the Cr line in W49B and discovered this emission line in the other three SNRs. The line center energies, equivalent widths (EWs) and fluxes of the Cr lines are given. The Cr in Cas A is in a high ionization state while that in Tycho and Kepler is in a much lower one. We find a good positive correlation between Cr and Fe line center energies, suggesting a common origin of Cr and Fe in the nucleosynthesis, which is consistent with the theoretical predictions. We propose that the EW ratio between Cr and Fe can be used as a supplementary constraint on the progenitors' properties and the explosion mechanism., Comment: 20 pages, 6 figures, accepted by ApJ

Using the data acquired in the Time To Spill (TTS) mode for long gamma-ray bursts (GRBs) collected by the Burst and Transient Source Experiment on board the Compton Gamma Ray Observatory (BATSE/CGRO), we have carefully measured spectral lags in time between the low (25-55 keV) and high (110-320 keV) energy bands of individual pulses contained in 64 multi-peak GRBs. We find that the temporal lead by higher-energy gamma-ray photons (i.e., positive lags) is the norm in this selected sample set of long GRBs. While relatively few in number, some pulses of several long GRBs do show negative lags. This distribution of spectral lags in long GRBs is in contrast to that in short GRBs. This apparent difference poses challenges and constraints on the physical mechanism(s) of producing long and short GRBs. The relation between the pulse peak count rates and the spectral lags is also examined. Observationally, there seems to be no clear evidence for systematic spectral lag-luminosity connection for pulses within a given long GRB., Comment: 20 pages, 4 figures