Search

The performance and phase-separated microstructures of epoxy asphalt binders greatly depend on the concentration of epoxy resin or bitumen. In this paper, the effect of the epoxy resin (ER) concentration (10–90%) on the viscosity, thermo-mechanical properties, and phase-separated morphology of warm-mix epoxy asphalt binders (WEABs) was investigated using the Brookfield rotational viscometer, differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA) and laser scanning confocal microscopy (LSCM). Due to the high reactivity of epoxy resin, the viscosity of WEABs increases with time. Furthermore, the initial viscosity of WEABs decreases with the ER concentration. Depending on the ER concentration, the viscosity–time behavior of WEABs is divided into three stages: slow (10–40%), fast (50–80%), and extremely slow (90%). In the slow stage, the viscosity slightly increases with the ER concentration, while the fast stage shows an opposite trend. DSC and DMA results reveal that WEABs with 10–80% ER exhibit two glass transition temperatures (Tgs) for cured epoxy resin and bitumen. Moreover, the Tgs of epoxy resin and bitumen increase with the ER concentration. However, WEAB with 90 % ER has only one Tg. LSCM observation shows that phase separation occurs in all WEABs. For WEABs containing 10–40% ER, spherical epoxy particles act as the discontinuous phase and disperse in the continuous bitumen phase. However, in WEABs with 50–90% ER, phase inversion takes place. Contrarily, bitumen particles disperse in the continuous epoxy phase. The damping properties of WEABs with the continuous epoxy phases increase with the ER concentration, while the crosslinking density shows an opposite trend. The occurrence of phase inversion results in a sharp increase in the tensile strength of WEABs. For WEABs with the continuous epoxy phases, the elongation at break increases with the ER concentration. The toughness first increases and then decreases with the ER concentration. A maximum toughness value shows at 70% ER. [ABSTRACT FROM AUTHOR]

Waterborne polyurethane asphalt emulsion (WPUA) is an environmentally friendly bituminous material, whose performance is highly dependent on the phase structure of the continuous phase. In this paper, WPUAs in the vicinity of phase inversion were prepared using waterborne polyurethane (WPU) and asphalt emulsion. The chemical structures, thermal stability, dynamic mechanical properties, phase-separated morphology and mechanical performance of WPUAs were studied. Fourier-transform infrared (FTIR) spectra revealed that there are no –NCO bonds in either the pure WPU or WPUAs. Moreover, the preparation of WPUA is a physical process. The addition of WPU weakens the thermal stability of asphalt emulsion. WPU improves the storage modulus of asphalt emulsion at lower and higher temperatures. The glass transition temperatures of the WPUA films are higher than that of the pure WPU film. When the WPU concentration increases from 30 wt% to 40 wt%, phase inversion occurs; that is, the continuous phase shifts from asphalt to WPU. The WPUA films have lower tensile strength and toughness than the pure WPU film. However, the elongations at break of the WPUA films are higher than that of the pure WPU film. Both the tensile strength and toughness of the WPUA films increase with the WPU concentration. Due to the occurrence of phase inversion, the elongation at break, tensile strength and toughness of the WPUA film containing 30 wt% WPU are increased by 29%, 250% and 369%, respectively, compared to the film with 40 wt% WPU. [ABSTRACT FROM AUTHOR]

To investigate the effect of silica sand particle size and epoxy resin content on the performance of silica sand permeable brick based on hydrogenated bisphenol A type epoxy resin. The content of epoxy resin was controlled to be 2%, 4%, 6% and 8% of the mass of silica sand, and the mesh size of silica sand was 35, 50 and 70 mesh, respectively. The strength, water permeability, water retention, water filtration and anti-slip properties of the prepared silica sand permeable tiles were tested. The test results showed that when the particle size of silica sand was 50 mesh and the content of epoxy resin was 4% of the mass of silica sand, the silica sand permeable brick had the best compressive, flexural and anti-slip properties, and the water permeability rate could reach 1.5mL/(min⋅cm²), water retention rate 0.068g/cm³ and water filtration rate 90.2%. [ABSTRACT FROM AUTHOR]

The COVID-19 pandemic engenders unemployment risks globally and locally. Reflectively engaging in Beck's risk society debates, this paper critically reviews the discursive effects of „risks" when employed by the government in debates about unemployment insurance since the 1997 sovereignty handover. We break down the concept of risk into four layers: moral risk, financial risk, socio-economic risk and political risk and bring to light the contradictory outcomes that colour the nuanced attitudes among the state, the NGOs and the affected subjects. [ABSTRACT FROM AUTHOR]