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Five new difluoroboron complexes with 4-pyridyl-β-diketones were synthesized and their structures were confirmed by elemental analysis, IR, 1H NMR, ESI-MS and UV–vis spectroscopy. Their photoluminescence behavior was studied in DMF solution and solid state. The quantum yields (Φu) of complexes 2a–2e in DMF solution were measured relative to quinine sulfate and their lifetime values (τ) were calculated according to the luminescence decay curves in the solid state. From these data, the difluoroboron complexes exhibited the excellent photoluminescence properties. Especially, the complexes 2d and 2e displayed the stronger photoluminescence intensity, much higher quantum yield and longer lifetime value as compared to complexes 2a, 2b and 2c. The results indicate that the substituents at the 4-position on benzene ring have a significant impacts on the photoluminescence properties of the difluoroboron complexes.

The cloud computing market is composed by many cloud service providers, It is a key problem about how to choose and to determine the appropriate the competitiveness partners between the major cloud service providers. For this problem we propose a optimization algorithm based on graph theory solution. First we should clearly consider the factors in choosing the partner's .On this basis we establish the mathematical model of the cloud service provider partners. How to select the tender of cloud service providers in the problem, the paper gives the optimization algorithm based on graph theory, last we give an example to verify the effectiveness of the algorithm.

Five pyridyl-β-diketones were synthesized by Claisen condensation of ethyl nicotinate with various aryl methyl ketones in benzene in the presence of sodium amide as the base, and then reacted with boron trifluoride diethyl etherate in dichloromethane to afford some new boron difluoride pyridyl-β-diketonate derivatives. The compounds obtained were characterized using FTIR, (1)H NMR, elemental analysis and mass spectrometry. Their optical properties were studied in DMF by UV-vis absorption and fluorescence spectroscopy. The results showed that these boron complexes exhibited intense fluorescence in the blue-green region (420-490 nm) under UV radiation with a relatively high quantum yield. Especially, compounds 4b and 5b displayed much higher quantum yield as compared to compounds 1b, 2b and 3b.

Some new 3,5-diaryl-1H-pyrazoles were prepared from aryl methyl ketones via Claisen condensation with aromatic esters and followed by cyclization with hydrazine monohydrate. Their structures were confirmed by IR, 1H NMR spectroscopy, mass spectrometry and elemental analysis. The X-ray structure for 3(5)-(4-tert-butylphenyl)-5(3)-(4-methoxyphenyl)-1H-pyrazole (2b) was presented. The results show that compound 2b exists as tautomers I and II, and its molecules are connected by the N–H···N intermolecular hydrogen bonds to form cyclic dimers consisting of the tautomers I and II.

A complex of Cu(II) with 1-(6-hydroxynaphthalen-2-yl) butane-1,3-dione (HNBD) was synthesized and characterized by elemental analysis, IR, UV and TG-DTA techniques. IR spectra as well as UV-visible absorption measurements indicated that Cu(II) ion was coordinated to the HNBD ligand. The TG-DTA curves showed that the thermal decomposition for Cu(II) complex was a three-steps process. At first, the complex had a mass loss of water molecules at temperature below 134°C, then the thermal decomposition of the anhydrous complex was a two-stage process, which corresponded to the loss of two naphthol molecules and the oxidative decomposition of other organic fragments of ligand. The final decomposition product of the complex was CuO.

The polyoxometalate complexes of ciprofloxacin with HnXW12O40(X=B, Si, P) were prepared from ciprofloxacin hydrochloride and HnXW12O40·nH2O (X=B, Si, P) in aqueous solution, and characterized by elemental analysis, IR spectra and TG-DTA. The IR spectrum confirmed the presence of Keggin-type anion of heteropoly acids and the characteristic functional group of ciprofloxacin after the polyoxometalate complexes are formed. The TG/DTA curves showed that their thermal decomposition was a more-steps process consisting of simultaneous processes involving also Keggin anion. The residue of decomposition is a mixture of WO3and B2O3, SiO2or P2O5, confirmed by X-ray diffraction and IR spectroscopy. And the possible thermal decomposition mechanisms of the complexes are proposed.

Claisen condensation of ethyl isonicotinate with different acetophenones gave the corresponding pyridyl-ß-diketones, while the treatment with hydrazine hydrate yielded 3,5-disubstituted-1H-pyrazoles, which then converted 1,3,5-trisubstituted-pyrazole derivatives containing a pyridyl moiety by N-acylation with acyl chloride. The structures of all newly synthesized compounds are established by FTIR, ¹H NMR, mass spectroscopy and elemental analysis, and in the case of compound 2e, analyzed by single-crystal X-ray diffraction further. The anti-microbial activities of the title compounds have been tested by disc diffusion method against Escherichia coli, Staphylococcus aureus, Pyricularia oryzae and Rhizoctnia solani. The results showed that compounds 3c and 4c exhibited good inhibitory activity against all the tested organisms.

To explore the levels of serum GP73 in patients with fatty liver disease.The sera GP73 were determined by ELISA in 178 patients with fatty liver disease and 100 healthy controls.Serum GP73 levels were significantly increased in patients with various fatty liver diseases(70.62 +/- 60.60 ng/ml), compared with those of control population (35.61 +/- 12.22 ng/ml). In patients with alcoholic fatty liver disease, acute liver injury, chronic hepatitis B, and non-alcoholic fatty liver disease, their serum GP73 concentration were 81.86 +/- 47.82 ng/ml, 82.77 +/- 77.73 ng/ml, 63.84 +/- 50.62 ng/ml, and 65.75 +/- 62.20 ng/ml, respectively. But no significant difference was found between these groups (P0.05). In 68 patients with For = 1.0 (71.46 +/- 66.48 ng/ml), 75 patients with For = 2.0 (69.58 +/- 62.31 ng/ml), and 34 patients with F3-F4 (71.65 +/- 43.89 ng/ml), there were also no marked differences was observed between these fatty groups (F = 0.02, P = 0.98).Serum GP73 levels were increased in patients with different liver diseases, but its concentrations were seems not related with degree of fatty injury.