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Ce-induced effects on the self-assembly of arachidic acid Langmuir monolayers was studied in this work. The monolayers were formed on the liquid subphase in the presence of Ce(III) ions. A new type of structural configuration is found for such monolayers, in which the monolayer maintains its structural ordering despite being compressed beyond the collapse point. Instead of forming 3D aggregates as in the typical collapsed state, the monolayer appears to be corrugated. Grazing incidence X-ray diffraction and X-ray standing waves confirm these findings. The diffraction pattern for the monolayer in a new state is represented by the unclosed diffraction rings with maxima near the sample horizon. This diffraction pattern is quantitatively reproduced in the numerical simulations by assuming the corrugated monolayer. The details of the conditions under which these corrugated Langmuir monolayers were observed and the analysis of the diffraction data are described., Comment: This is an original manuscript consisting of 18 pages, 2 tables and 10 figures. To be submitted for publication in the (IUCr) Journal of Applied Crystallography

In this article, we derive a theoretical formalism that unifies the rigorous coupled wave analysis and the dynamical diffraction theory. Based on this formalism, we design a computational approach for the diffraction calculation for the nanoscale lamellar gratings with an arbitrary line profile shape. In this approach, the gratings line profile is approximated as a polygon. This proves to be convenient since such an approach does not rely on the geometry model of the grating. We test the new approach against other computational theories and a synchrotron scattering experiment., Comment: This is an original manuscript consisting of 15 pages and 8 figures. To be submitted for publication in the Nano Research journal (ISSN: 1998-0000). The experimental and analytical part of this research has been done before Feb 2022

We implemented the Bayesian analysis to the polarised neutron reflectivity data. Reflectivity data from a magnetic TbCo thin film structure was studied using the bundle of a Monte-Carlo Markov-chain algorithm, likelihood estimation, and error modeling. By utilizing the Bayesian analysis, we were able to investigate the uniqueness of the solution beyond reconstructing the magnetic and structure parameters. This approach has demonstrated its expedience as several probable reconstructions were found (the multimodality case) concerning the isotopic composition of the surface cover layer. Such multimodal reconstruction emphasizes the importance of rigorous data analysis instead of the direct data fitting approach, especially in the case of poor statistically conditioned data, typical for neutron reflectivity experiments. The analysis details and the discussion on multimodality are in this article.

Following the recent demonstration of grazing-incidence X-ray fluorescence (GIXRF) based characterization of the 3D atomic distribution of different elements and dimensional parameters of periodic nanoscale structures, this work presents a new computational scheme for the simulation of the angular dependent fluorescence intensities from such periodic 2D and 3D nanoscale structures. The computational scheme is based on the dynamical diffraction theory in many-beam approximation, which allows to derive a semi-analytical solution to the Sherman equation in a linear-algebraic form. The computational scheme has been used to analyze recently published GIXRF data measured on 2D Si3N4 lamellar gratings, as well as on periodically structured 3D Cr nano pillars. Both the dimensional and structural parameters of these nanostructures have been reconstructed by fitting numeric simulations to the experimental GIXRF data. Obtained results show good agreement with nominal parameters used in the manufacturing of the structures, as well as with reconstructed parameters based on the previously published finite element method simulations, in case of the Si3N4 grating.

We present a model independent approach for the reconstruction of the atomic concentration profile in a nanoscale layered structure, as measured using the X-ray fluorescence yield modulated by an X-ray standing wave (XSW). The approach is based on the direct regularized solution of the system of linear equations that characterizes the fluorescence yield. The suggested technique was optimized for, but not limited to, the analysis of periodic layered structures where the XSW is formed under Bragg conditions. The developed approach was applied to the reconstruction of the atomic concentration profiles for LaN/BN multilayers with 50 periods of 35 A thick layers. The object is especially difficult to analyse with traditional methods, as the estimated thickness of the interface region between the constituent materials is comparable to the individual layer thicknesses. However, using the suggested technique it was possible to reconstruct the La atomic profile, showing that the La atoms stay localized within the LaN layers and interfaces and do not diffuse into the BN layer. The atomic distributions were found with an accuracy of 1 A. The analysis of the Kr fluorescence yield showed that Kr atoms originating from the sputter gas are trapped in both the LaN-on-BN and the BN-on-LaN interfaces., Comment: 10 pages, 6 figures. The article presents the latest findings on the application of X-ray Standing Waves (XSW) technique for the analysis of periodic multilayer structures. A novel approach of the data treatment for XSW was proposed. The efficiency of developed approached was illustrated by the analysis of the atomic profiles in LaN/B4C multilayer mirror with a period thickness of 4.3 nm