1. New phenomena in FMR and EPR studies of amorphous oxide films and their crystallization
- Author
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Hongru Zhai, Y.Z. Miao, Ming-Hui Lu, Benxi Gu, and H.Y. Zhang
- Subjects
Materials science ,Annealing (metallurgy) ,Analytical chemistry ,Sputter deposition ,Condensed Matter Physics ,Ferromagnetic resonance ,Electronic, Optical and Magnetic Materials ,Amorphous solid ,law.invention ,law ,visual_art ,visual_art.visual_art_medium ,Ceramic ,Thin film ,Crystallization ,Electron paramagnetic resonance - Abstract
(BiDy) 3 Fe 5 O 12 films were made in the amorphous state by rf magnetron sputtering from a sintered Bi 2 Dy 1 Fe 5 O 12 ceramic target onto quartz substrates and studied by X-ray diffraction. The films were annealed at temperatures ranging from 500 to 700°C for 1 h in air and also at 650°C for different periods of time from 5 to 60 min. X-ray diffraction was used to determined the phase components of the samples. In the X-ray patterns, the amorphous films had two diffuse broad maxima in X-ray diffraction patterns centred at the double diffraction angles 2 θ =31° and 52°, respectively. The films crystallized at 650°C and all the crystallized samples have a single phase of garnet. The FMR linewidth increased with the decreases in annealing temperature and annealing time. No FMR and EPR of Fe 3+ were observed in the amorphous films even though they contained large amounts of Fe 3+ ions, while the EPR of Fe 3+ was observed in slide glass with the same gain.
- Published
- 1995
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