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Iron-based waterworks sludge was activated using 0.5-3 mol/L H2SO4 acid to obtain the acid-activated iron-based waterworks sludge (AAIBWS). The sludge treated with 1 mol/L H2SO4 acid was best for phosphorus adsorption and used to carry out batch phosphorus adsorption experiments. The influencing factors including solution pH, contact time and reaction temperature were investigated. The results indicated that the acid environment was favourable for P adsorption. The phosphorus adsorption increased with the rising reaction time and temperature. The pseudo-second-order equation was best to describe the adsorption process among the three kinetic models. The Langmuir isotherm provided a better fit of the data than the Freundlich model. Thermodynamic parameters showed that the phosphorus adsorption on AAIBWS-1 had a spontaneous and endothermic nature.

The severe land subsidence could lead to ground collapse, building damage and a series of disasters. Up to now, the land subsidence has occurred in more than 50 cities in China, which seriously affects the life and production safety of local people and restricts the development of cities. While, Beijing is one of the most serious cities. This paper takes the urban area of Beijing as an example. PS-InSAR technology is used to process 40 scenes of Terra SAR images from 2010 to 2015, and the high-coherence points are selected by fusing the two algorithms of coherence coefficient and amplitude deviation. In order to verify the reliability of the results, the second-level measurement results are compared with the PS-InSAR deformation results, and five leveling points are used to evaluate the accuracy. The results show that: the maximum absolute error between the Leveling results and the InSAR measurement result is 8.87 mm, and the standard error is 3.22 mm, which meets the accuracy requirements. And areas with serious subsidence occur in Changping District, Haidian District, Daxing District, and Chaoyang District; there is no obvious subsidence trend in the central and eastern parts of Dongcheng, Xicheng and Fengtai District, and the surface is relatively stable. The subsidence in Tongzhou and Shunyi District is serious relatively, the subsidence in these two areas is -6 mm/a~-67 mm/a and -11 mm/a~-22 mm/a respectively. Finally, the spatial relationship between fault zones and land subsidence was preliminarily discussed. The results show that, the subsidence of the south of Changping was so serious than others while the Nankou-Sunhe fault zone crossed with Babaoshan and Huangzhuang-Gaoliying fault zone through this area respectively.

The blade vortex evaluation in Francis Turbine under deep part load conditions generates severe pressure ‎fluctuations in the runner. The complex flow in a model turbine is numerically investigated based on a ‎modified Partially Averaged Navier-Stokes method. The main emphasis is focused on revealing the ‎correlation mechanism of blade vortex evolution and energy production. The results indicate that the ‎modified PANS method shows significant advantages in hydro turbine’s simulation than the traditional ‎RANS method. At deep part load conditions, the vorticity formed at the leading edge of the suction ‎surface and the trailing edge of the pressure surface in the blade channels. The stretching term provides ‎the most vorticity increments while the dilation term inhibiting part which only provides a decrement of ‎the vorticity evolution. Based on the entropy production theory, the total entropy production distribution ‎is consisting with the distribution of vorticity. At deep part load condition, direct dissipation and turbulent ‎dissipation provide the most entropy, while at part load condition the proportion of these two-part ‎decreased‎.

With the gradual formation of the space technical system of National Geodetic Datum, the storage management and application services of the geodetic data have been developing rapidly. This paper studies Geodetic data content, characteristics, classification principles and classification methods in the geodetic technology system and initially forms a standard classification system of geodetic data. On the basis of studying the key technical links to the modern Geodetic Datum comprehensive data acquisition, storage, management and service, this paper has tackled the real-time data optimal storage based on DBFS technology. Technical problems such as multi-dimensional data integration and docking of the software, building a safe and standardized management and the geodetic data service system, coordinating the application of network resources, storage resources, computing resources and other soft and hard environment elements, achieving efficient management and service of land, sea and air integrated observation data results, greatly improving the management ability and application service level of Geodetic data, for surveying and mapping. Business operation of the benchmark database provides support and promotes the social application on geodetic results.

The 2019 novel coronavirus (2019-nCov) has caused increasing number of infected cases globally. This study was performed to analyze information regarding the transmission route and presence of viral nucleic acids on several clinical samples. Confirmed 2019-nCov-infected cases were identified in Dongyang and were treated according to guidelines for the diagnosis of 2019-nCov infection released by the National Health Commission. Information regarding the contacts that the infected people had was collected to determine whether it caused clustered cases. A series of successive nucleic acid examination of feces, oropharyngeal swabs, and sputum was also performed, and the results were analyzed. A total of 19 confirmed cases of 2019-nCov infection were identified in Dongyang, Zhejiang Province, China. Five cases showed severe symptoms, and the remaining ones showed mild manifestations. Ten cases infected from two asymptomatic individuals were clustered into two groups. Among 14 cases with consecutive nucleic acid test results, four patients showed positive results in feces after their negative conversion in oropharyngeal swabs. Asymptomatic individuals with the virus could cause 2019-nCov clustered cases, and the clustered cases may differ from sporadic cases on age and length of hospitalization. In addition, nucleic acids in feces last longer than those in oropharyngeal swabs.

The features of the landslide geological disaster are wide distribution, variety, high frequency, high intensity, destructive and so on. It has become a natural disaster with harmful and wide range of influence. The technology of ground-based synthetic aperture radar is a novel deformation monitoring technology developed in recent years. The features of the technology are large monitoring area, high accuracy, long distance without contact and so on. In this paper, fast ground-based synthetic aperture radar (Fast-GBSAR) based on frequency modulated continuous wave (FMCW) system is used to collect the data of Ma Liuzui landslide in Chongqing. The device can reduce the atmospheric errors caused by rapidly changing environment. The landslide deformation can be monitored in severe weather conditions (for example, fog) by Fast-GBSAR with acquisition speed up to 5 seconds per time. The data of Ma Liuzui landslide in Chongqing are analyzed in this paper. The result verifies that the device can monitor landslide deformation under severe weather conditions.

We present a new high-efficiency divided chirp-pulse amplification (DCPA) system based on an actively controlled quasi-all-fiber structure. As a proof-of-principle experiment, a two-channel amplification system composed of single-mode ytterbium-doped fiber is constructed. The experimental results show that the degree of linear polarization of ~93% is maintained after recombination and the system efficiency is up to ~95%. In addition, the beam quality (M2 factor) is around 1.2. Moreover, the system can operate stably for a long time without performance degradation. Compared with the traditional spatial DCPA, this system exhibits some advantages, such as improved spatial adjustment, high stability, compact size, and low cost. It is demonstrated that this work paves the way to design a quasi-all-fiber high-performance pulsed laser system.

Additional size-resolved chemical information is needed before the physicochemical characteristics and sources of airborne particles can be understood; however, this information remains unavailable in most regions of China due to lacking measurement data. In this study, we report observations of various chemical species in size-segregated particle samples that were collected over 1 year in the urban area of Beijing, a megacity that experiences severe haze episodes. In addition to fine particles, high concentrations of coarse particles were measured during the periods of haze. The abundance and chemical compositions of the particles in this study were temporally and spatially variable, with major contributions from organic matter and secondary inorganic aerosols. The contributions of organic matter to the particle mass decreased from 37.9 to 31.2 %, and the total contribution of sulfate, nitrate and ammonium increased from 19.1 to 33.9 % between non-haze and haze days, respectively. Due to heterogeneous reactions and hygroscopic growth, the peak concentrations of the organic carbon, cadmium and sulfate, nitrate, ammonium, chloride and potassium shifted from 0.43 to 0.65 µm on non-haze days to 0.65–1.1 µm on haze days. Although the size distributions of lead and thallium were similar during the observation period, their concentrations increased by a factor of more than 1.5 on haze days compared with non-haze days. We observed that sulfate and ammonium, which have a size range of 0.43–0.65 µm, sulfate and nitrate, which have a size range of 0.65–1.1 µm, calcium, which has a size range of 5.8–9 µm, and the meteorological factors of relative humidity and wind speed were responsible for haze pollution when the visibility was less than 10 km. Source apportionment using Positive Matrix Factorization showed six PM2.1 sources and seven PM2.1–9 common sources: secondary inorganic aerosol (25.1 % for fine particles vs. 9.8 % for coarse particles), coal combustion (17.7 % vs. 7.8 %), biomass burning (11.1 % vs. 11.8 %), industrial pollution (12.1 % vs. 5.1 %), road dust (8.4 % vs. 10.9 %), vehicle emissions (19.6 % for fine particles), mineral dust (22.6 % for coarse particles) and organic aerosol (23.6 % for coarse particles). The contributions of the first four factors and vehicle emissions were higher on haze days than non-haze days, while the reverse is true for road dust and mineral dust. The sources' contribution generally increased as the size decreased, with the exception of mineral dust. However, two peaks were consistently found in the fine and coarse particles. In addition, the sources' contribution varied with the wind direction, with coal and oil combustion products increasing during southern flows. This result suggests that future air pollution control strategies should consider wind patterns, especially during episodes of haze. Furthermore, the findings of this study indicated that the PM2.5-based data set is insufficient for determining source control policies for haze in China and that detailed size-resolved information is needed to characterize the important sources of particulate matter in urban regions and better understand severe haze pollution.

The exchange and migration of basin materials that are carried by pore fluids are the essence of diagenesis, which can alter physical properties of clastic rocks as well as control formation and distribution of favorable reservoirs of petroliferous basins. Diagenetic products and pore fluids, resulting from migration and exchange of basin materials, can be used to deduce those processes. In this study, 300 core samples from 46 wells were collected for preparation of casting thin sections, SEM, BSE, EDS, inclusion analysis, and isotope analysis in Dongying Sag, Bohai Bay Basin, East China. Combined with geochemical characteristics of pore fluids and geological background of the study area, the source and exchange mechanisms of materials in the pore fluids of rift basins were discussed. It was revealed that the material exchange of pore fluids could be divided into five stages. The first stage was the evaporation concentration stage during which mainly Ca2+, Mg2+, and CO32- precipitated as high-Mg calcites. Then came the shale compaction stage, when mainly Ca2+ and CO32- from shale compaction water precipitated as calcites. The third stage was the carboxylic acid dissolution stage featured by predominant dissolution of plagioclases, during which Ca2+ and Na+ entered pore fluids, and Si and Al also entered pore fluids and then migrated as clathrates, ultimately precipitating as kaolinites. The fourth stage was the organic CO2 stage, mainly characterized by the kaolinization of K-feldspar as well as dissolution of metamorphic lithic fragments and carbon cements. During this stage, K+, Fe2+, Mg2+, Ca2+, HCO3-, and CO32- entered pore fluids. The fifth stage was the alkaline fluid stage, during which the cementation of ferro-carbonates and ankerites as well as illitization or chloritization of kaolinites prevailed, leading to the precipitation of K+, Fe2+, Mg2+, Ca2+, and CO32- from pore fluids.

Since the mid-20th century, nitrogen (N) deposition has shown an increasing trend in the Tibetan Plateau (TP), where alpine ecosystems are sensitive to elevated N deposition. However, the quantitative characterization of N deposition in the TP remains unclear, due in most part to the lack of in situ measurement. Using the Tibetan Observation and Research Platform network, we conducted short-term in situ measurements of major ions (NO3−, Cl−, SO42−, NH4+, Na+, K+, Ca2+, and Mg2+) wet deposition at five remote sites in the TP during 2011–2013. At Southeast Tibet Station, Nam Co Station, Qomolangma Station, Ngari Station, and Muztagh Ata Station, the NH4+–N wet deposition was 0.63, 0.68, 0.92, 0.36, and 1.25 kg N ha−1 yr−1, respectively; the NO3−–N wet deposition was 0.28, 0.24, 0.03, 0.08, and 0.30 kg N ha−1 yr−1, respectively; and the inorganic N wet deposition was 0.91, 0.92, 0.94, 0.44, and 1.55 kg N ha−1 yr−1, respectively. The inorganic N wet deposition mainly occurred in the form of NH4+–N during summer at all sites. Results of enrichment factor analysis and principal component analysis demonstrated that both NH4+–N and NO3−–N wet deposition in the TP were mainly influenced by anthropogenic activities. Backward trajectory analysis showed that the inorganic N deposition at Muztagh Ata Station was mainly transported from central Asia and the Middle East through westerlies. At Southeast Tibet Station, Nam Co Station, Qomolangma Station, and Ngari Station, the inorganic N deposition was mainly contributed by anthropogenic sources in south Asia, and was mainly transported by the Indian monsoon. Combining site-scale in situ measurements of inorganic N wet deposition in this and previous studies, the average wet deposition of atmospheric NH4+–N, NO3−–N, and inorganic N in the TP was estimated to be 1.06, 0.51, and 1.58 kg N ha−1 yr−1, respectively. The average NH4+–N : NO3−–N ratio in precipitation in the TP was approximately 2 : 1. Results from the present study suggest that earlier estimations based on chemical transport model simulations and/or limited field measurements likely overestimated substantially the regional inorganic N wet deposition in the TP. To clarify the total N deposition in the TP more clearly, it is essential to conduct long-term monitoring of both wet and dry deposition of atmospheric N in various climate zones in the TP in the future.

Microbial communities in injected water are expected to have significant influence on those of reservoir strata in long-term water flooding petroleum reservoirs. To investigate the similarities and differences in microbial communities in injected water and reservoir strata, high-throughput sequencing of microbial partial 16S rRNA of the water samples collected from the wellhead and downhole of injection wells, and from production wells in a homogeneous sandstone reservoir and a heterogeneous conglomerate reservoir were performed. The results indicate that a small number of microbial populations are shared between the water samples from the injection and production wells in the sandstone reservoir, whereas a large number of microbial populations are shared in the conglomerate reservoir. The bacterial and archaeal communities in the reservoir strata have high concentrations, which are similar to those in the injected water. However, microbial population abundance exhibited large differences between the water samples from the injection and production wells. The number of shared populations reflects the influence of microbial communities in injected water on those in reservoir strata to some extent, and show strong association with the unique variation of reservoir environments.

The evolution of physical, chemical and optical properties of urban aerosol particles was characterized during an extreme haze episode in Beijing, PRC, from 24 through 31 January 2013 based on in situ measurements. The average mass concentrations of PM1, PM2.5 and PM10 were 99 ± 67 μg m−3 (average ± SD), 188 ± 128 μg m−3 and 265 ± 157 μg m−3, respectively. A significant increase in PM1-2.5 fraction was observed during the most heavily polluted period. The average scattering coefficient at 550 nm was 877 ± 624 Mm−1. An increasing relative amount of coarse particles can be deduced from the variations of backscattering ratios, asymmetry parameter and scattering Ångström exponent. Particle number-size distributions between 14 and 2500 nm diameter showed high number concentrations, particularly in the nucleation mode and accumulation mode. Size-resolved chemical composition of submicron aerosol from a high-resolution time-of-flight aerosol mass spectrometer showed that the mass concentrations of organic, sulfate, nitrate, ammonium and chlorine mainly resided on particles between 500 and 800 nm (vacuum diameter), and nitrate and ammonium contributed greatly to particle growth during the heavily polluted day (28 January). Increasing relative humidity and stable synoptic conditions on 28 January combined with heavy pollution on 28 January, leading to enhanced water uptake by the hygroscopic submicron particles and formation of secondary aerosol, which might be the main reasons for the severity of the haze episode. Light-scattering apportionment showed that organic, sulfate, ammonium nitrate and ammonium chloride compounds contributed to light-scattering fractions of 54, 24, 12 and 10%, respectively. This study indicated that the organic component in submicron aerosol played an important role in visibility degradation during the haze episode in Beijing.

Passively harmonic mode locking (HML) operation had been demonstrated in an erbium-doped fiber laser with a microfiber-based topological insulator (TI) Bi2Te3 saturable absorber (SA). It was found that the pulse train possessed different orders of HML (with a tunable repetition rate from 232 to 390 MHz) due to different incident pump powers. The spectra exhibited typical features of conventional solitons (perfect Gaussian profile with Kelly sidebands) with no continuous wave component. The measured signal-to-noise ratio (SNR) reached 60 dB, whereas the pulse duration was kept around 1.32 ps without significant change. The experimental observation revealed that the microfiber-based TI device could indeed be employed as a high-performance SA for further applications in ultrafast photonics.

Atmospheric deposition is considered to be a major process that removes pollutants from the atmosphere and an important source of nutrients and contaminants for ecosystems. Trace elements (TEs), especially toxic metals deposited on plants and into soil or water, can cause substantial damage to the environment and human health due to their transfer and accumulation in food chains. Despite public concerns, quantitative knowledge of metal deposition from the atmosphere to ecosystems remains scarce. To advance our understanding of the spatiotemporal variations in the magnitudes, pathways, compositions and impacts of atmospherically deposited TEs, precipitation (rain and snow) and dry-deposited particles were collected simultaneously at 10 sites in Northern China from December 2007 to November 2010. The measurements showed that the wet and dry depositions of TEs in the target areas were orders of magnitude higher than previous observations within and outside China, generating great concern over the potential risks. The spatial distribution of the total (wet plus dry) deposition flux was consistent with that of the dry deposition, with a significant decrease from industrial and urban areas to suburban, agricultural and rural sites, while the wet deposition exhibited less spatial variation. In addition, the seasonal variation of wet deposition was also different from that of dry deposition, although they were both governed by the precipitation and emission patterns. For the majority of TEs that exist as coarse particles, dry deposition dominated the total flux at each site. This was not the case for potassium, nickel, arsenic, lead, zinc, cadmium, selenium, silver and thallium, for which the relative importance between wet and dry deposition fluxes varied by site. Whether wet deposition is the major atmospheric cleansing mechanism for the TEs depends on the size distribution of the particles. We found that atmospheric inputs of copper, lead, zinc, cadmium, arsenic and selenium were of the same magnitude as their increases in the topsoil of agricultural systems. At a background forest site in Northern China, the total deposition flux of lead observed in this study (14.1 mg m−2 yr−1) was twice that of the critical load calculated for temperate forest ecosystems in Europe. These findings provide baseline data needed for future targeting policies to protect various ecosystems from long-term heavy metal input via atmospheric deposition.

In January 2013, Beijing experienced several serious haze events. To achieve a better understanding of the characteristics, sources and processes of aerosols during this month, an Aerodyne high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) was deployed at an urban site between 1 January and 1 February 2013 to obtain the size-resolved chemical composition of non-refractory submicron particles (NR-PM1). During this period, the mean measured NR-PM1 mass concentration was 89.3 ± 85.6 μg m−3, and it peaked at 423 μg m−3. Positive matrix factorization (PMF) differentiated the organic aerosol into five components, including a highly oxidized, low-volatility oxygenated organic aerosol (LV-OOA), a less oxidized, semi-volatile oxygenated OA (SV-OOA), a coal combustion OA (CCOA), a cooking-related OA (COA), and a hydrocarbon-like OA (HOA), which on average accounted for 28%, 26%, 15%, 20% and 11% of the total organic mass, respectively. A detailed comparison between the polluted days and unpolluted days found many interesting results. First, the organic fraction was the most important NR-PM1 species during the unpolluted days (58%), while inorganic species were dominant on polluted days (59%). The OA composition also experienced a significant change; it was dominated by primary OA (POA), including COA, HOA and CCOA, on unpolluted days. The contribution of secondary OA (SOA) increased from 35% to 63% between unpolluted and polluted days. Second, meteorological effects played an important role in the heavy pollution in this month and differed significantly between the two types of days. The temperature and relative humidity (RH) were all increased on polluted days and the wind speed and air pressure were decreased. Third, the diurnal variation trend in NR-PM1 species and OA components showed some differences between the two types of days, and the OA was more highly oxidized on polluted days. Fourth, the effects of air masses were significantly different between the two types of days; air was mainly transported from contaminated areas on the polluted days. The comparison also found that the aerosol was more acidic on polluted days. Additionally, the variation trends of the mass concentration and mass fractions of NR-PM1 species and OA components were more dramatic when the NR-PM1 mass loading was at a higher level. The serious pollution observed in this month can be attributed to the synergy of unfavorable meteorological factors, the transport of air masses from high-pollution areas, emission by local sources, and other factors.

The ozone weekend effect (OWE) was first investigated in the metropolitan area of Beijing–Tianjin–Hebei (BTH), China, using in situ measurements from the Atmospheric Environment Monitoring Network from July 2009 to August 2011. The results indicate that there is an obvious weekly periodical variation in the surface ozone concentration. There is a lower ozone concentration from Wednesday to Friday (weekday) and a higher concentration from Saturday to Monday (weekend) at all the locations of the study. NOx also displays a weekly cycle, with the maximum level occurring on weekdays and the minimum level on weekends, especially later on Sunday night and early Monday morning. This pattern may be responsible for the higher concentration of ozone on weekends. Additionally, the vertical variations in O3 and NOx from the 8 m, 47 m, 120 m and 280 m observation platforms on the 325 m Beijing meteorological tower displayed obvious weekly cycles that corresponded to the surface results. A smaller decrease in volatile organic compounds (VOCs; using CO as a proxy) and much lower NOx concentrations on the weekend may lead to higher VOC / NOx ratio, which can enhance the ozone production efficiency in VOC-limited regime areas. Additionally, a clear weekly cycle in the fine aerosol concentration was observed, with maximum values occurring on weekdays and minimum values occurring on weekends. Higher concentrations of aerosol on weekdays can reduce the UV radiation flux by scattering or absorbing, which leads to a decrease in the ozone production efficiency. A significant weekly cycle in UV radiation, consistent with the aerosol concentration, was discovered at the Beijing meteorological tower site (BJT), validating the assumption. A comprehensive understanding of the ozone weekend effect in the BTH area can provide deep insights into controlling photochemical pollution.

Atmospheric sulfur (S) deposition via precipitation, particles and gases was investigated at ten sites in Northern China. Measurements were performed continuously between December 2007 and November 2010. The total S deposition flux in the target area ranged from 35.0 to 100.7 kg S ha−1 yr−1, noticeably higher than the values documented in Europe, North America, and East Asia. The ten-site, 3-yr average total S deposition was 64.8 kg S ha−1 yr−1, with 68% attributed to dry deposition (mainly SO2) and the rest to wet deposition. Consequently, the spatial distribution of the total flux was consistent to that of dry deposition, that is, higher values were observed at industrial and urban sites than at agricultural and rural sites. However, the seasonal variation in the total S deposition was not obvious across the entire year because of opposite seasonal trends in wet and dry deposition. It was found that the wet deposition, without significant spatial and interannual differences, was influenced by the volume of precipitation, the air-column concentrations of S compounds and in-cloud scavenging. Similar to the wet deposition, the dry-deposited sulfate was also less dependent on the surface concentration. Nevertheless, the regional differences in SO2 dry deposition were mostly explained by the ambient concentration, which is closely associated with local emissions. As expected, the spatial pattern of total S deposition resembled that of the emission inventory, indicating the dramatic anthropogenic imprints on the regional S budget. Although at most of the study sites the "acid equivalents" deposition of S was comparable to that of nitrogen (N), the importance of S in the acidification risks was more pronounced at the industrial sites. The ten-site, 3-yr mean total "acid equivalents" deposition of S and N was estimated to be 8.4 (range: 4.2–11.6) keq ha−1 yr−1, which exceeds the critical loads for natural ecosystems in Northern China. Taking these findings and our previous studies together, a multi-pollutant perspective and joint mitigation strategies to abate SO2 and NH3 simultaneously in the target area are recommended to protect natural ecosystems from excess acid deposition.

Emissions of reactive nitrogen (N) species can affect surrounding ecosystems via atmospheric deposition. However, few long-term and multi-site measurements have focused on both the wet and the dry deposition of individual N species in large areas of Northern China. Thus, the magnitude of atmospheric deposition of various N species in Northern China remains uncertain. In this study, the wet and dry atmospheric deposition of different N species was investigated during a three-year observation campaign at ten selected sites in Northern China. The results indicate that N deposition levels in Northern China were high with a ten-site, three-year average of 60.6 kg N ha−1 yr−1. The deposition levels showed spatial and temporal variation in the range of 28.5–100.4 kg N ha−1 yr−1. Of the annual total deposition, 40% was deposited via precipitation, and the remaining 60% was comprised of dry-deposited forms. Compared with gaseous N species, particulate N species were not the major contributor of dry-deposited N; they contributed approximately 10% to the total flux. On an annual basis, oxidized species accounted for 21% of total N deposition, thereby implying that other forms of gaseous N, such as NH3, comprised a dominant portion of the total flux. The contribution of NO3− to N deposition was enhanced in certain urban and industrial areas, possibly due to the fossil fuse combustion. As expected, the total N deposition in Northern China was significantly larger than the values reported by national scale monitoring networks in Europe, North America and East Asia because of high rates of wet deposition and gaseous NH3 dry deposition. Taken together, these findings show that NH3 emissions should be abated to mitigate high N deposition and associated potential impacts on ecosystems in Northern China. The present results improve our understanding of spatio-temporal variations of magnitudes, pathways and species of deposited N in the target areas, and are important not only to inform conservation and regulatory bodies but also to initiate further detailed studies. Uncertainties among current observations underscore the need to quantify the impact of vegetation on dry deposition and to refine the simulation of dry deposition velocity.

To assess contribution of multiple environmental factors to carbon exchanges between the atmosphere and forest soils, four old-growth forests referred to as boreal coniferous forest, temperate needle-broadleaved mixed forest, subtropical evergreen broadleaved forest and tropical monsoon rain forest were selected along eastern China. In each old-growth forest, soil CO2 and CH4 fluxes were measured from 2003 to 2005 applying the static opaque chamber and gas chromatography technique. Soil temperature and moisture at the 10 cm depth were simultaneously measured with the greenhouse gas measurements. Inorganic N (NH4+-N and NO3−-N) in the 0–10 cm was determined monthly. From north to south, annual mean CO2 emission ranged from 18.09 ± 0.22 to 35.40 ± 2.24 Mg CO2 ha−1 yr−1 and annual mean CH4 uptake ranged from 0.04 ± 0.11 to 5.15 ± 0.96 kg CH4 ha−1 yr−1 in the four old-growth forests. Soil CO2 flux in the old-growth forests was mainly driven by soil temperature, followed by soil moisture and NO3−-N. Temperature sensitivity (Q10) of soil CO2 flux was lower at lower latitudes with high temperature and more precipitation, probably because of less soil organic carbon (SOC). Soil NO3− accumulation caused by environmental change was often accompanied by an increase in soil CO2 emission. In addition, soil CH4 uptake decreased with an increase in soil moisture. The response of soil CH4 flux to temperature was dependent upon the optimal value of soil temperature in each forest. Soil NH4+-N consumption tended to promote soil CH4 uptake in the old-growth forests, whereas soil NO3−-N accumulation was not conducive to CH4 oxidation in anaerobic condition. These results indicate that soil mineral N dynamics largely affects the soil gas fluxes of CO2 and CH4 in the old-growth forests, along with climate conditions.