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Microplastics (MPs) and pesticides are two classes of environmental pollutants and have become global challenges. MPs could adsorb substantial environmental pollutants, which may affect their transportation, distribution and cause combination toxicity. Therefore, the study of sorption properties and mechanisms is the basis of the ecological risk assessment of co-exposure of pesticides and MPs. In this research, typical triazole fungicide tebuconazole (TEB) is selected as a model pollutant, and its sorption behaviour was investigated by kinetic and isotherm models. Meanwhile, a series of environmental influencing factors, like pH, salinity, and metals were conducted. Results showed that the sorption of TEB on MPs could reach equilibrium at 24 h, and the sorption capacity followed the order of PA (polyamide) > PS (polystyrene) > PP (polypropylene). The pseudo-second-order model was the most appropriate model to describe kinetic data, and the Freundlich model was well fit for PA sorption isotherms, in contrast the Langmuir model is better for PP and PS. Additionally, the pH of the solution, salinity, and metals have an important effect on sorption. Combined with Fourier Transform Infrared Spectroscopy and environmental influencing factors, the sorption mechanisms were mainly electrostatic interaction and hydrogen bond for PA and PP, and hydrophobic force, intermolecular force, and electrostatic force for PS, respectively.

Swelling, mechanical strength, flexibility, and toughness are important parameters in hydrogel preparation for application in the human body. Herein, composite hydrogels were prepared using a mix of Konjac glucomannan (KGM), sodium alginate (SA), and polyvinyl alcohol (PVA) cross-linked by calcium hydroxide. The PVA/KGM/SA composite hydrogel showed a suitable swelling ratio and rate, as well as elasticity and flexibility. In addition, the elongation at break was 660.3%, with a breaking strength of 87.25 kPa and a compression modulus of 1.660 MPa. Rheological studies showed that the composite hydrogel was composed of a multiply cross-linked network involving chemical and physical interactions, thereby affecting the elasticity and flexibility of the gel. Interestingly, the composite gel network was reformed when the temperature decreased. In rabbit models of dry eye, the hydrogel effectively maintained the normal tear meniscus height and increased the low tear meniscus area. The results therefore showed that the PVA/KGM/SA gels not only provide a simple, effective, and safe method for the preparation of hydrogels, but also have potential applications in the treatment of dry eye syndrome.