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Purpose: This study aimed to investigate the correlation between preoperative pain catastrophizing and social support, and acute post-surgical pain in patients who underwent knee arthroplasty. The study also aimed to determine whether social support moderates the role of pain catastrophizing psychologically in acute post-surgical pain after knee arthroplasty. Patients and Methods: This study recruited participants to survey a tertiary hospital in Dalian, China, between November 2022 and October 2023. Participants completed pain catastrophizing scales and social support reevaluated scales one day (T1) before they were confirmed to undergo knee arthroplasty, and finished the Numeric Rating Scale at 24h (T2), 48h (T3), and 72h (T4) postoperatively. Pearson correlation analyses were used to explore the relationship between social support, pain catastrophizing, and acute post-surgical pain, hierarchical regression analysis was used to test the moderating role of social support between pain catastrophizing and acute post-surgical pain. Results: This study recruited 178 knee arthroplasty patients. The results of the t-test or one-way ANOVA indicated that there were statistically significant differences in gender, age, education, occupation, disease duration, whether the knee replacement was performed for the first time, preoperative pain scores, and operation time in patients with knee arthroplasty (P < 0.05). The correlation analysis of social support, pain catastrophization, and acute post-surgical pain in knee arthroplasty patients showed that social support was negatively correlated with acute post-surgical pain (r=− 0.584, P< 0.01), and pain catastrophizing was positively correlated with postoperative acute pain (r=0.601, P< 0.01); The hierarchical regression analysis revealed that social support had a significant moderating effect on the relationship between pain catastrophizing and acute post-surgical pain (ΔR2=0.606, P< 0.05). Conclusion: The acute post-surgical pain of knee arthroplasty patients was affected by gender, age, education, occupation, disease duration, whether the knee arthroplasty was performed for the first time, preoperative pain scores, and operation time. Acute Post-surgical pain in patients with knee arthroplasty was affected by social support and pain catastrophizing, and social support had a moderating effect on the relationship between pain catastrophizing and acute post-surgical pain. [ABSTRACT FROM AUTHOR]

Reinforced concrete structures play a pivotal role in island and reef engineering projects. Given the resource constraints typical of island regions, substituting traditional manufactured sand aggregate with reef limestone not only reduces reliance on river sand but also addresses the issue of disposing of waste reef limestone slag generated during excavation. However, the performance characteristics of reef limestone concrete, particularly its bond strength with reinforcing steel, warrant further investigation. This is particularly true for the bond–slip behavior of the reinforcement. This study aims to elucidate the effects of various parameters on the bond performance between steel and reef limestone concrete through central pullout tests. These parameters include the type and diameter of the reinforcement, bond length, and loading rate. The investigation encompasses the analysis of load–slip curves, bond failure modes, and variations in bond stress. Additionally, using the Abaqus software, a numerical simulation was conducted to analyze the mesoscopic stress characteristics, thereby revealing the mechanisms of bond formation and failure modes between steel reinforcement and reef limestone concrete. The results indicate that the bond–slip curve for reef limestone concrete reinforced with ribbed rebars and Glass Fiber-Reinforced Polymer (GFRP) rebars can be broadly categorized into four phases: minor slip, slip, decline, and residual, with the residual phase exhibiting a wave-like pattern. The predominant failure modes in reef limestone concrete are either pulling out or splitting. The bond stress in reef limestone concrete decreases with an increase in rebar diameter and bond length; conversely, it increases with the loading rate, although the ultimate slip decreases. The mesoscopic failure characteristics of reinforced reef limestone concrete, as simulated in Abaqus, are consistent with the experimental outcomes. [ABSTRACT FROM AUTHOR]

Based on the traditional black tea processing technology, the hot air withering process was used to replace the traditional indoor natural withering process on the basis of the traditional black tea processing technology. The effects of four hot air withering processes of 35 °, 45 °, 55 ° and 65 ° on the quality of summer and autumn black tea were studied and analyzed from three aspects of sensory quality, taste quality and aroma quality. The results show that compared with 25 ° traditional indoor natural withering black tea, the comprehensive sensory quality of black tea processed by 45 ° hot air withering process was better. The color of dry tea was dark brown and moist, the soup color was red and bright, the taste was mellow and refreshing, and the quality characteristics was sweet aroma. At the same time, the contents of tea polyphenols, gallic acid, EGCG, theaflavins, thearubigins and the ratio of the sum contents of theaflavins and thearubigins to the content of theabrownins (TFRB) significantly increased (P<0.05), while the content of soluble sugar decreased significantly (P<0.05). The types of aroma quality components increased, among which alcohols accounted for the highest proportion (70.47%), and the relative contents of alcohols, ketones and esters increased significantly (P<0.05), while pyrroles and aldehydes decreased significantly (P < 0.05). And the aroma components with flower and fruit aroma such as trans-3-hexenol, 2,3-dihydro-2,2,6-trimethylbenzaldehyde and α-ionone were detected. This shows that hot air withering with appropriate temperature is conducive to improving the quality of black tea, which can be applied to the production practice of improving the quality of black tea in summer and autumn. [ABSTRACT FROM AUTHOR]

The hypercubic family of interconnection networks, encompassing the hypercube and its derivatives and variants, has a wide range of applications in parallel processing. Various problems in general complex networks can be addressed by choosing a hypercubic network as a skeleton. In this paper, we provide insight into why hypercubic networks are suitable as network skeletons and discuss a mapping scheme to take advantage of the symmetry of such networks for developing efficient algorithms.

The widely discussed single‐atom catalysts (SACs) are regarded as a kind of attractive material for sulfate radical‐based advanced oxidation processes (SR‐AOPs) owing to their maximum atomic utilization efficiency and outstanding stability. Currently, metal–organic frameworks (MOFs) have appeared as prospective precursors for building SACs due to extensive chelating sites, functional adjustability, and structural tunability. However, there are few critical and systematic reviews about the application of MOF‐derived SACs in SR‐AOPs, especially in‐depth analysis of the mechanisms. Therefore, this review seeks to offer a thorough summary of the development of MOF‐derived SACs in SR‐AOPs. First, the unique advantages of MOFs as derivative precursors for SACs are discussed thoroughly. Afterward, the current synthesis strategies are elaborated categorically to unveil the formation process of single atoms and their coordination environments. Notably, the roles of different reaction sites including the generation of reactive species and mediating electron transfer are further analyzed to explain mechanisms comprehensively. Thereafter, the characterization techniques and theoretical calculations for mechanisms studies are also highlighted. Eventually, critical insights into present challenges and future developments are proposed, which are expected to enhance the catalytic efficiency of MOF‐derived SACs in SR‐AOPs. [ABSTRACT FROM AUTHOR]