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2. Synthesis of 6- oxa -Spiro[4.5]decane Derivatives by Merging Ring-Opening of Benzo[ c ]oxepines and Formal 1,2-Oxygen Migration.

Author

Du YD, Ma LL, Wu CY, Wu RH, Yu ZC, Zhou Y, Yang DS, Wu YD, Wang JG, and Wu AX

Abstract

A facile one-pot synthetic method has been developed for constructing 6- oxa -spiro[4.5]decane skeletons by merging the ring-opening of benzo[ c ]oxepines and formal 1,2-oxygen migration reactions. More than 30 examples of the 6- oxa -spiro[4.5]decane derivatives have been synthesized under transition-metal-free conditions.

Published
2024
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