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As its next step in space exploration, the National Aeronautics and Space Administration (NASA) revealed plans to establish a permanent human presence on Mars. Habitat outfitting, i.e., the technology to provide the crew with the necessary equipment to perform mission tasks as well as a comfortable, safe, and livable habitable volume, has not been fully explored yet. This study proposes that, rather than shipping prefabricated outfitting elements to Mars, habitat outfitting can be realized by in-situ construction using cyanobacteria and fungi as building agents. A synthetic lichen system, composed of diazotrophic cyanobacteria and filamentous fungi, can be created to produce abundant biominerals (CaCO3) and biopolymers, which will glue Martian regolith into consolidated building blocks. These self-growing building blocks can be assembled into various structures, such as floors, walls, partitions, and furniture.

We calculate from first principles the electron-phonon coupling strength in ferromagnetic iron-cobalt Fe$_{1-x}$Co$_x$ alloys for compositions ranging from $x=0$ to $x=0.75$. We find strong, spin-dependent variation of the electron-phonon coupling strength with alloy composition. The minimum of the electron-phonon interaction is found near the composition $x=0.25$. We analyze the variation of the electron-phonon interaction with composition, as a function of electron spin, density of states, electron-phonon matrix elements, and phonon frequencies. Our results are in good qualitative agreement with magnetization dynamics experiments.

A six-night optical turbulence monitoring campaign has been carried at Cerro Paranal observatory in February and March, 2023 to facilitate the development and characterisation of two novel atmospheric site monitoring instruments - the ring-image next generation scintillation sensor (RINGSS) and 24-hour Shack Hartmann image motion monitor (24hSHIMM) in the context of providing optical turbulence monitoring support for upcoming 20-40m telescopes. Alongside these two instruments, the well-characterised Stereo-SCIDAR and 2016-MASS-DIMM were operated throughout the campaign to provide data for comparison. All instruments obtain estimates of optical turbulence profiles through statistical analysis of intensity and wavefront angle-of-arrival fluctuations from observations of stars. Contemporaneous measurements of the integrated turbulence parameters are compared and the ratios, bias, unbiased root mean square error and correlation of results from each instrument assessed. Strong agreement was observed in measurements of seeing, free atmosphere seeing and coherence time. Less correlation is seen for isoplanatic angle, although the median values agree well. Median turbulence parameters are further compared against long-term monitoring data from Paranal instruments. Profiles from the three small-telescope instruments are compared with the 100-layer profile from the stereo-SCIDAR. It is found that the RINGSS and SHIMM offer improved accuracy in characterisation of the vertical optical turbulence profile over the MASS-DIMM. Finally, the first results of continuous optical turbulence monitoring at Paranal are presented which show a strong diurnal variation and predictable trend in the seeing. A value of 2.65" is found for the median daytime seeing., Comment: Accepted in MNRAS

Materials with high thermal conductivity are needed to conduct heat away from hot spots in power electronics and optoelectronic devices. Cubic boron arsenide (c-BAs) has a high thermal conductivity due to its special phonon dispersion relation. Previous experimental studies of c-BAs report a room-temperature thermal conductivity between 1000 and 1300 watts per meter-kelvin. We synthesized high purity c-BAs single crystals with room-temperature thermal conductivity of 1500 watts per meter-kelvin. We observed its thermal conductivity to be proportional to the inverse square of temperature between 300 and 600 kelvin, a stronger dependence than predicted by state-of-the-art theory., Comment: 14 pages, 3 figures

Using the Boltzmann transport equation (BTE), we study the evolution of nonequilibrium carrier distributions in simple ($sp$) metals, assumed to have been instantaneously excited by an ultrafast laser pulse with photon energy $h \nu$. The mathematical structure of the BTE scattering integrals reveals that $h \nu$ is a natural energy scale for describing the dynamics. Normalizing all energy quantities by $h \nu$ leads to a set of three unitless parameters -- $\beta / \delta$, $\gamma$, and $\alpha$ -- that control the relaxation dynamics: $\beta / \delta$ is the normalized ratio of electron-phonon to electron-electron scattering strengths, $\gamma$ is the normalized phonon (lattice) temperature, and $\alpha$ is the normalized absorbed energy density. Using this theory, we systematically investigate relaxation times for the high-energy part of the distribution ($\tau_H$), energy transfer to the phonon subsystem ($\tau_E$), and intracarrier thermalization ($\tau_{th}$). In the linear region of response (valid when $\alpha$ is sufficiently small), we offer heuristic descriptions of each of these relaxation times as functions of $\beta / \delta$ and $\gamma$. Our results as a function of excitation level $\alpha$ show that many ultrafast experimental investigations lie in a transition region between low excitation (where the relaxation times are independent of $\alpha$) and high excitation (where the two-temperature model of carrier dynamics is valid). Approximate boundaries that separate these three regions are described by simple expressions involving the normalized parameters of our model., Comment: 26 pages, 11 figures, and Supplemental Material. arXiv admin note: substantial text overlap with arXiv:2210.09422

Extractant design in liquid-liquid extraction (LLE) is a research frontier of metal ion separations that typically focuses on the direct extractant-metal interactions. However, a more detailed understanding of energetic drivers of separations beyond primary metal coordination is often lacking, including the role of solvent in the extractant phase. In this work, we propose a new mechanism for enhancing metal-complexant energetics with nanostructured solvents. Using molecular dynamics simulations with umbrella sampling, we find that the organic solvent can reshape the energetics of the extractant's intramolecular conformational landscape. We calculate free energy profiles of different conformations of a representative bidentate extractant, n-octyl(phenyl)-N,N-diisobutyl carbamoyl methyl phosphinoxide (CMPO), in four different solvents: dodecane, tributyl phosphate (TBP), and dry and wet ionic liquid (IL) 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([EMIM][Tf_2N]). By promoting reorganization of the extractant molecule into its binding conformation, our findings reveal how particular solvents can ameliorate this unfavorable step of the metal separation process. In particular, the charge alternating nanodomains formed in ILs substantially reduce the free energy penalty associated with extractant reorganization. Importantly, using alchemical free energy calculations, we find that this stabilization persists even when we explicitly include the extracted cation. These findings provide insight into the energic drivers of metal ion separations and potentially suggest a new approach to designing effective separations using a molecular-level understanding of solvent effects.

The inverse Faraday effect is an opto-magnetic phenomenon that describes the ability of circularly polarized light to induce magnetism in solids. The capability of light to control magnetic order in solid state materials and devices is of interest for a variety of applications, such as magnetic recording, quantum computation and spintronic technologies. However, significant gaps in understanding about the effect persist, such as what material properties govern the magnitude of the effect in metals. In this work, we report time-resolved measurements of the specular inverse Faraday effect in non-magnetic metals, i.e., the magneto-optic Kerr effect induced by circularly polarized light. We measure this specular inverse Faraday effect in Cu, Pd, Pt, W, Ta, and Au at a laser wavelength of 783 nm. For Ta and W, we investigate both {\alpha} and \{beta} phases. We observe that excitation of these metals with circularly polarized light induces significant circular dichroism. This nonlinear magneto-optical response to circularly polarized light is an order of magnitude larger in {\alpha}-W than other metals, e.g., Pt, Au, and is greater than nearly all other reported values for IFE in other materials. Our results benchmark the range of IFE that can be observed in non-magnetic metals and provide insight into what material properties govern the inverse Faraday effect in metals.

We report an investigation of the bulk optical, bulk acoustic, and surface acoustic phonons in thin films of turbostratic boron nitride (t-BN) and cubic boron nitride (c-BN) grown on B-doped polycrystalline and single-crystalline diamond (001) and (111) substrates. The characteristics of different types of phonons were determined using Raman and Brillouin-Mandelstam light scattering spectroscopies. The atomic structure of the films was determined using high-resolution transmission electron microscopy (HRTEM) and correlated with the Raman and Brillouin-Mandelstam spectroscopy data. The HRTEM analysis revealed that the cubic boron nitride thin films consisted of a mixture of c-BN and t-BN phases, with c-BN being the dominant phase. It was found that while visible Raman spectroscopy provided information for characterizing the t-BN phase, it faced challenges in differentiating the c-BN phase either due to the presence of high-density defects or the overlapping of the Raman features with those from the B-doped diamond substrates. In contrast, Brillouin-Mandelstam spectroscopy clearly distinguishes the bulk longitudinal and surface acoustic phonons of the c-BN thin films grown on diamond substrates. Additionally, the angle-dependent surface Brillouin-Mandelstam scattering data show the peaks associated with the Rayleigh surface acoustic waves, which have higher phase velocities in c-BN films on diamond (111) substrates. These findings provide valuable insights into the phonon characteristics of the c-BN and diamond interfaces and have important implications for the thermal management of electronic devices based on ultra-wide-band-gap materials., Comment: 27 pages; 4 figures

Characterisation of atmospheric optical turbulence is crucial for the design and operation of modern ground-based optical telescopes. In particular, the effective application of adaptive optics correction on large and extremely large telescopes relies on a detailed knowledge of the prevailing atmospheric conditions, including the vertical profile of the optical turbulence strength and the atmospheric coherence timescale. The Differential Image Motion Monitor (DIMM) has been employed as a facility seeing monitor at many astronomical observing sites across the world for several decades, providing a reliable estimate of the seeing angle. Here we present the Shack-Hartmann Image Motion Monitor (SHIMM), which is a development of the DIMM instrument, in that it exploits differential image motion measurements of bright target stars. However, the SHIMM employs a Shack-Hartmann wavefront sensor in place of the two-hole aperture mask utilised by the DIMM. This allows the SHIMM to provide an estimate of the seeing, unbiased by shot noise or scintillation effects. The SHIMM also produces a low-resolution (three-layer) measure of the vertical turbulence profile, as well as an estimate of the coherence timescale. The SHIMM is designed as a low-cost, portable, instrument. It is comprised of off-the-shelf components so that it is easy to duplicate and well-suited for comparisons of atmospheric conditions within and between different observing sites. Here, the SHIMM design and methodology for estimating key atmospheric parameters will be presented, as well as initial field test results with comparisons to the Stereo-SCIDAR instrument., Comment: Published in MNRAS

PCANet and its variants provided good accuracy results for classification tasks. However, despite the importance of network depth in achieving good classification accuracy, these networks were trained with a maximum of nine layers. In this paper, we introduce a residual compensation convolutional network, which is the first PCANet-like network trained with hundreds of layers while improving classification accuracy. The design of the proposed network consists of several convolutional layers, each followed by post-processing steps and a classifier. To correct the classification errors and significantly increase the network's depth, we train each layer with new labels derived from the residual information of all its preceding layers. This learning mechanism is accomplished by traversing the network's layers in a single forward pass without backpropagation or gradient computations. Our experiments on four distinct classification benchmarks (MNIST, CIFAR-10, CIFAR-100, and TinyImageNet) show that our deep network outperforms all existing PCANet-like networks and is competitive with several traditional gradient-based models.

We report what is believed to be the first example of fully continuous, 24-hour vertical monitoring of atmospheric optical turbulence. This is achieved using a novel instrument, the 24-hour Shack-Hartmann Image Motion Monitor (24hSHIMM). Optical turbulence is a fundamental limitation for applications such as free-space optical communications, where it limits the achievable bandwidth, and ground-based optical astronomy, restricting the observational precision. Knowledge of the turbulence enables us to select the best sites, design optical instrumentation and optimise the operation of ground-based optical systems. The 24hSHIMM estimates the vertical optical turbulence coherence length, time, angle and Rytov variance from the measurement of a four-layer vertical turbulence profile and a wind speed profile retrieved from meteorological forecasts. To illustrate our advance we show the values of these parameters recorded during a 35-hour, continuous demonstration of the instrument. Due to its portability and ability to work in stronger turbulence, the 24hSHIMM can also operate in urban locations, providing the field with a truly continuous, versatile turbulence monitor for all but the most demanding of applications., Comment: Accepted in Optics Express

The Earth's turbulent atmosphere results in speckled and blurred images of astronomical objects when observed by ground based visible and near-infrared telescopes. Adaptive optics (AO) systems are employed to reduce these atmospheric effects by using wavefront sensors (WFS) and deformable mirrors. Some AO systems are not fast enough to correct for strong, fast, high turbulence wind layers leading to the wind butterfly effect, or wind-driven halo, reducing contrast capabilities in coronagraphic images. Estimating the effective wind speed of the atmosphere allows us to calculate the atmospheric coherence time. This is not only an important parameter to understand for site characterization but could be used to help remove the wind butterfly in post processing. Here we present a method for estimating the atmospheric effective wind speed from spatio-temporal covariance maps generated from pseudo open-loop (POL) WFS data. POL WFS data is used as it aims to reconstruct the full wavefront information when operating in closed-loop. The covariance maps show how different atmospheric turbulent layers traverse the telescope. Our method successfully recovered the effective wind speed from simulated WFS data generated with the soapy python library. The simulated atmospheric turbulence profiles consist of two turbulent layers of ranging strengths and velocities. The method has also been applied to Gemini Planet Imager (GPI) AO WFS data. This gives insight into how the effective wind speed can affect the wind-driven halo seen in the AO image point spread function. In this paper, we will present results from simulated and GPI WFS data., Comment: 7 pages, 6 figures

A semiempirical theory for the excitation and subsequent relaxation of nonthermal electrons is described. The theory, which is applicable to ultrafast-laser excited metals, is based on the Boltzmann transport equation for the carrier distribution function $f(\epsilon,t)$ and includes electron-phonon, electron-electron, and electron-photon scattering integrals in forms that explicitly depend on the electronic density of states. Electron-phonon coupling is treated by extending the theory of Allen [Phys. Rev. Lett. 59, 1460 (1987)] to include highly-excited nonthermal electron distributions, and is used to determine the energy transfer rate between a nonthermal electron subsystem and a thermal phonon subsystem. Electron-electron scattering is treated with a simple energy-conserving electron-electron scattering integral. The electron-photon integral assumes photon absorption is phonon assisted. We apply the theory to analyze prior ultrafast thermionic emission, two-color photoemission, and electronic inelastic light (Raman) scattering experiments on Au. These analyses show that getting the details of $f(\epsilon,t)$ is necessary for proper interpretation of each experiment. Together, the photoemission and Raman-scattering analyses indicate an electron excited 1 eV above the Fermi level has an electron-electron scattering time in the range of 25 to 55 fs., Comment: 26 pages, 5 figures; 1 page Supplemental Material

We report the results of the investigation of bulk and surface acoustic phonons in the undoped and boron-doped single-crystal diamond films using the Brillouin-Mandelstam light scattering spectroscopy. The evolution of the optical phonons in the same set of samples was monitored with Raman spectroscopy. It was found that the frequency and the group velocity of acoustic phonons decrease non-monotonically with the increasing boron doping concentration, revealing pronounced phonon softening. The change in the velocity of the shear horizontal and the high-frequency pseudo-longitudinal acoustic phonons in the degenerately doped diamond, as compared to the undoped diamond, was as large as ~15% and ~12%, respectively. As a result of boron doping, the velocity of the bulk longitudinal and transverse acoustic phonons decreased correspondingly. The frequency of the optical phonons was unaffected at low boron concentration but experienced a strong decrease at the high doping level. The density-functional-theory calculations of the phonon band structure for the pristine and highly-doped sample confirm the phonon softening as a result of boron doping in diamond. The obtained results have important implications for thermal transport in heavily doped diamond, which is a promising material for ultra-wide-band-gap electronics., Comment: 27 pages; 5 figures