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Covalent organic frameworks (COFs) are crystalline organic porous polymers that can be precisely integrated by building blocks to achieve pre‐designed composition, components, and functions, making them a powerful platform for the development of molecular devices in the field of electrocatalysis. The precise control of channel/dopant positions and highly ordered network structures of COFs provide an ideal material system for the applications of advanced electrocatalysis. In this paper, the topological structure design and synthesis methods of COFs are reviewed in detail, and their design principles are deeply analyzed. In addition, the applications of COFs and their derivatives in the field of electrocatalysis are systematically summarized and the optimization strategies are proposed. Finally, the application prospects of COFs and their derivatives in electrocatalysis and the challenges that may be encountered in the future are prospected, providing helpful guidance for future research. [ABSTRACT FROM AUTHOR]

Covalent organic frameworks (COFs) are porous organic materials with well‐defined and uniform structure. The material is an excellent candidate as a solid adsorbent for iodine adsorption. In the present study, we report the synthesis of COF with porphyrin moiety, TF‐TA‐COF, by solvothermal reaction, which was characterized by XRD, solid‐state 13C NMR, IR, TGA, and nitrogen adsorption‐desorption analysis. TF‐TA‐COF showed a high specific surface area of 443 m2 g−1, and exhibited good adsorption performance for iodine vapor, with an adsorption capacity of 2.74 g g−1. XPS and Raman spectrum indicated that a hybrid of physisorption and chemisorption took place between host COF and iodine molecules. The electric properties of iodine‐loaded TF‐TA‐COF were also studied. After doped with iodine, the conductivity of the material increased by more than 5 orders of magnitude. The photoconductivity of I2‐doped COF was also studied and TF‐TA‐COF showed doping‐enhanced photocurrent generation. [ABSTRACT FROM AUTHOR]

In this study, laboratory experiments were conducted to investigate the influence of changes in storm wave height and water level on beach response in a medium-scale wave flume. A schematic storm was simulated (rising, apex, and waning phases). A non-intrusive photogrammetric method was used to collect high-resolution and synchronous data regarding the free surface water elevation and bed level, from which shoreline location, sandbar position, cross-shore sediment transport rates, and nonlinear wave parameters were derived. The cross-shore sediment transport was in agreement with previous laboratory measurements, including the monotonous exchange from foreshore erosion to shoaling zone accretion in most stages of the storm simulation. The surf zone was the main region supplying sediment for beach morphology modification and sandbar generation. The degree of storm erosion was not completely determined by the largest wave height and water level or the cumulative wave power of the apex phase. The largest gradients of the wave parameter sequence change occurred in the rising phase, and this was the main factor generating efficient beachface erosion. It induced an increase in sandbar size, accompanied by the cross-shore motion of maximum velocity amplitude, more violent disturbances of wave nonlinearity, and increased surf zone erosion, with these factors increasing beach instability and leading to more severe storm erosion. The large wave height and water level resulted in shoreline retreat, with a more significant swash zone erosion under a higher runup. The offshore sediment transport turned toward the onshore direction as the original large sandbar deteriorated under the decreasing wave parameter sequence in the waning phase. [ABSTRACT FROM AUTHOR]