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Planar-heterojunction perovskite solar cells (PSCs) have experienced rapid evolution in recent years because of the low-temperature processing, suitable alignment, and high mobility of the tin oxide buried contact layer. However, improper SnO2 surface states and poor crystallinity of the top perovskite films are still the main obstacles for the planar PSCs in which performance always lags behind their mesoporous counterparts. Herein, a new buried contact is reported by introducing graphitic carbon nitride (g-C3N4) into the commonly used SnO2 which performs outstanding transmittance, conductivity, and surface states for a high-quality electron-transporting layer. Moreover, the vertical composition and crystallinity of the top perovskite film are manipulated by rich amino groups on the edge of the g-C3N4 nanosheets which induce the prenucleation of the lead-rich species at the buried interface. Benefiting from the high-quality buried contacts and the optimized perovskite layers, the resultant PSCs achieve a champion efficiency of 21.5% with all photovoltaic parameters enhanced in comparison with their control counterparts (

In order to analyze and study the causes of thermowell fracture and make scientific and reasonable selection of thermowell type，the comprehensive failure analysis of thermowell fracture was carried out by scanning electron microscopy combined with energy spectrometer，Xray diffractometer and other surface analysis methods，and the vibration of the casing was simulated and calculated.Results showed that corrosion product film was formed on the fracture surface of thermowell，and fatigue striation was observed.From the calculation results，it could be found that the vibration frequency of the thermowell under the action of steam exceeded its own natural frequency，and far exceeded the safety coefficient.Furthermore，the comprehensive analysis showed that the corrosion fatigue and other main causes under the comprehensive actions of variable working conditions led to the environment sensitive fracture of thermowell.

The Hall-Petch relationship, according to which the strength of a metal increases as the grain size decreases, has been reported to break down at a critical grain size of around 10 to 15 nanometres1,2. As the grain size decreases beyond this point, the dominant mechanism of deformation switches from a dislocation-mediated process to grain boundary sliding, leading to material softening. In one previous approach, stabilization of grain boundaries through relaxation and molybdenum segregation was used to prevent this softening effect in nickel-molybdenum alloys with grain sizes below 10 nanometres3. Here we track in situ the yield stress and deformation texturing of pure nickel samples of various average grain sizes using a diamond anvil cell coupled with radial X-ray diffraction. Our high-pressure experiments reveal continuous strengthening in samples with grain sizes from 200 nanometres down to 3 nanometres, with the strengthening enhanced (rather than reduced) at grain sizes smaller than 20 nanometres. We achieve a yield strength of approximately 4.2 gigapascals in our 3-nanometre-grain-size samples, ten times stronger than that of a commercial nickel material. A maximum flow stress of 10.2 gigapascals is obtained in nickel of grain size 3 nanometres for the pressure range studied here. We see similar patterns of compression strengthening in gold and palladium samples down to the smallest grain sizes. Simulations and transmission electron microscopy reveal that the high strength observed in nickel of grain size 3 nanometres is caused by the superposition of strengthening mechanisms: both partial and full dislocation hardening plus suppression of grain boundary plasticity. These insights contribute to the ongoing search for ultrastrong metals via materials engineering.

Sheet metal forming limit diagram (FLD) is a comprehensive index used to evaluate sheet metal formability. In this paper, the forming limit curves of GH605 sheet materials with 0.2 mm and 2.5 mm thickness under three different heat treatment conditions were obtained by numerical simulation of bulging. Then, the simulated forming limit results of the three materials with 0.2 mm thickness were compared with the experimental results. The results show that the simulated FLDs can be in good agreement with the experimental FLDs. The influences of work hardening index (n value) and anisotropy index (r value) on the forming limit are analysed from the view of material property difference. The comprehensive simulated and experimental results show that the formability of the sheets after the two kinds of solution treatment is significantly better than that of the annealed sheets. The forming limit curve increases with the increase of n value and r value, and the influence of n value on the forming limit curve is more significant than that of r value. The forming limit diagram established by numerical simulation can provide a theoretical basis for material development and process selection.

In order to study the effect of hole extrusion strengthening process on the fatigue performance of Ti2AlNb alloy, a simulation analysis model of residual stress of hole strengthening process was established. The distribution law of surface residual stress and strengthening mechanism after hole extrusion process were discussed. In this work, the hole extrusion experiments were carried out. The high temperature and low cycle fatigue performance of the compressed and un-compressed specimens were tested respectively. Meanwhile, the microstructure characteristics of the fatigue fracture of the two specimens were compared. The results show that the hole extrusion process can produce a strong residual compressive stress layer around the small hole, which effectively delays and inhibits the initiation and propagation of fatigue cracks, and significantly improves the high temperature and low cycle fatigue performance of Ti2AlNb specimens.