1. Probing scalar coupling differences via long-lived singlet states.
- Author
-
DeVience, Stephen J., Walsworth, Ronald L., and Rosen, Matthew S.
- Subjects
- *
SINGLET state (Quantum mechanics) , *DECOHERENCE (Quantum mechanics) , *NUCLEAR spin , *DIPOLE-dipole interactions , *PHENYLALANINE , *GLUTAMIC acid - Abstract
We probe small scalar coupling differences via the coherent interactions between two nuclear spin singlet states in organic molecules. We show that the spin-lock induced crossing (SLIC) technique enables the coherent transfer of singlet order between one spin pair and another. The transfer is mediated by the difference in syn and anti vicinal or long-range J couplings among the spins. By measuring the transfer rate, we calculate a J coupling difference of 8 ± 2 mHz in phenylalanine–glycine–glycine and 2.57 ± 0.04 Hz in glutamate. We also characterize a coherence between two singlet states in glutamate, which may enable the creation of a long-lived quantum memory. [ABSTRACT FROM AUTHOR]
- Published
- 2016
- Full Text
- View/download PDF