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The oceanographic conditions of the Southern California Bight (SCB) dictate the distribution and abundance of prey resources and therefore the presence of mobile predators, such as goose-beaked whales (Ziphius cavirostris). Goose-beaked whales are deep-diving odontocetes that spend a majority of their time foraging at depth. Due to their cryptic behavior, little is known about how they respond to seasonal and interannual changes in their environment. This study utilizes passive acoustic data recorded from two sites within the SCB to explore the oceanographic conditions that goose-beaked whales appear to favor. Utilizing optimum multiparameter analysis, modeled temperature and salinity data are used to identify and quantify these source waters: Pacific Subarctic Upper Water (PSUW), Pacific Equatorial Water (PEW), and Eastern North Pacific Central Water (ENPCW). The interannual and seasonal variability in goose-beaked whale presence was related to the variability in El Niño Southern Oscillation events and the fraction and vertical distribution of the three source waters. Goose-beaked whale acoustic presence was highest during the winter and spring and decreased during the late summer and early fall. These seasonal increases occurred at times of increased fractions of PEW in the California Undercurrent and decreased fractions of ENPCW in surface waters. Interannual increases in goose-beaked whale presence occurred during El Niño events. These results establish a baseline understanding of the oceanographic characteristics that correlate with goose-beaked whale presence in the SCB. Furthering our knowledge of this elusive species is key to understanding how anthropogenic activities impact goose-beaked whales.

ABSTRACT Located at the confluence of the Arctic and North Pacific and with Alaska at its heart, the Pacific Arctic Region (PAR) is a unique and interconnected regional climate system. Significant climatic changes in the PAR are described by a novel, mobile monthly Alaska Arctic Front (AAF) index, which is defined by sea level pressure differences between the migratory cores of the Beaufort High and Aleutian Low. Regional climate variability associated with the AAF shows prominent decadal signatures that are driven by the opposing effects of the North Pacific and the Arctic atmospheric pressure fields. Low AAF (negative phase) is dominated by North Pacific forcing, whereas high AAF (positive phase) is dominated by Arctic atmospheric processes. The recent (2011–2021) negative AAF phase, which is associated with the westward displacement of Aleutian Low explaining stronger northward winds and enhanced water transport northward through Bering Strait, is conducive to increased oceanic heat and freshwater content, reduced regional sea ice cover in the PAR, and to the expansion of Pacific species into the Arctic. These factors are all indicators of the Pacification of the Arctic Ocean, a key feature of climate change related to progression of anomalous Pacific water masses and biota into the polar basins. It is not yet clear if or when the recent phase of decadal variability will change and alter the rate of Pacification of the Arctic climate system. [ABSTRACT FROM AUTHOR]

Excessive sediment concentration in water can cause damage to prefabricated concrete channels. This study evaluates the impact of sediment‐laden water flow on the mass loss of concrete after abrasion, incorporating scanning electron microscope‐energy dispersive spectrometer (SEM‐EDS) and X‐ray diffraction (XRD) analyses to assess the effects of four steam‐curing parameters—delay time, heating rate, constant temperature duration, and steam curing temperature—on the abrasion resistance of concrete used in enterprise prefabricated water conveyance channels. The results indicate that the abrasion resistance of concrete for prefabricated channels improves gradually with increases in delay time and constant temperature duration. When the delay time exceeds 3 h and the constant temperature time exceeds 4 h, the concrete's abrasion resistance can reach more than 5 h(g/cm2)−1. Rapid heating rates and excessively high steam curing temperatures adversely affect the concrete's abrasion resistance. However, when the heating rate is controlled within 20°C/h and the steam curing temperature does not exceed 70°C, the concrete's abrasion resistance can achieve more than 5 h(g/cm2)−1. In compliance with the standard DL/T5201‐2021 requirements, it is recommended that concrete with high demands for abrasion resistance should preferentially select steam‐curing parameters within these ranges. [ABSTRACT FROM AUTHOR]

Energy content has long been proposed as a fundamental, integrated, and reliable indicator of the condition of individuals as it reflects past bioenergetics and influences future life‐history traits. There is a direct biochemical link between energy density and body composition described by four main compounds in fish (protein, lipid, ash, and water), with proteins and lipids being the sources of energy. If relationships between water content, or lipid content, and energy density have been well described in relative terms, the absolute mass variations in the proximate composition have been overlooked and thus their interpretation is often equivocal. In our study, based on a large and unique dataset on the proximate composition and energy density of anchovy (Engraulis encrasicolus) and sardine (Sardina pilchardus) from sampling in the Bay of Biscay and the English Channel, we aimed to better explain the patterns between water content and other proximate components or energy density, based on the dynamics of proteins, lipids, and water absolute masses. For the first time, we defined good, intermediate, and poor condition states in wild fish, based on water content, corresponding to the different dynamics of lipids and proteins in the metabolism of individuals. Anchovy and sardine exhibited remarkably similar patterns of variation in the compounds and in the limits between the condition states with respect to water content. Those patterns revealed that water mass remained constant for a given fish size whatever its condition state, and that variability in water content only resulted from the variation in lipid and protein masses. Furthermore, the differential dynamics of proteins and lipids, with only lipids mobilized in the good condition state, only proteins in the poor condition state, and both proteins and lipids in the intermediate condition state, elucidates the nonlinear pattern observed in the relationship between energy density and water content. Overall, our results highlight the importance of monitoring the intraspecific variations in water content to predict the proximate composition and energy content in small pelagic fish and better assess individual and population conditions in changing ecosystems as well as to better parameterize bioenergetic models. [ABSTRACT FROM AUTHOR]

Water must condense into ice clouds in the coldest brown dwarfs and exoplanets. When they form, these icy clouds change the emergent spectra, temperature structure, and albedo of the substellar atmosphere. The properties of clouds are governed by complex microphysics but these complexities are often not captured by the simpler parameterized cloud models used in climate models or retrieval models. Here, we combine microphysical cloud modeling and 1D climate modeling to incorporate insights from microphysical models into a self-consistent, parameterized cloud model. Using the 1D Community Aerosol and Radiation Model for Atmospheres (CARMA), we generate microphysical water clouds and compare their properties with those from the widely used EddySed cloud model for a grid of Y dwarfs. We find that the mass of water condensate in our CARMA water clouds is significantly limited by available condensation nuclei; in models without additional seed particles for clouds added, the atmosphere becomes supersaturated. We incorporate water latent heat release in the convective and radiative parts of the atmosphere and find no significant impact on water-ice cloud formation for typical gas giant compositions. Our analysis reveals the CARMA cloud profiles have a gradual decrease in opacity of approximately 4% per bar below the cloud base. Incorporating this gradual cloud base falloff and a variable f sed parameter allows spectra generated from the parameterized Eddysed model to better match those of the microphysical CARMA model. This work provides recommendations for efficiently generating microphysically informed water clouds for future models of cold substellar objects with H/He atmospheres. [ABSTRACT FROM AUTHOR]

Circulation and water masses in the greater Prydz Bay region were surveyed in the austral summer 2021 (January-March) during the 'Trends in Euphausiids off Mawson, Predators and Oceanography' (TEMPO) experiment, and are described in this paper. The Southern Antarctic Circumpolar Current Front is found in the northern part of the survey area, generally near 63-64°S, whereas the Southern Boundary Front is located between 64 and 65.5°S. The westward flowing Antarctic Slope Front (ASF) is found in the southern part of the survey area near the continental slope on most transects. Highest concentrations of oxygen (> 300 µmol kg-1) are found in shelf waters at stations in Prydz Bay, south of 67°S along 75°E, whereas the lowest oxygen values are found in the Circumpolar Deep Water layer, with an average of roughly 215 µmol kg-1. North of the northern extension of the ASF, surface mixed layers are between 20 and 60m deep. Mixed layers tend to deepen slightly in the northern part of the survey, generally increasing north of 64°S where the ocean has been ice-free the longest. We find evidence of upwelling of waters into the surface layers, based on temperature anomaly, particularly strong along 80°E. Enhanced variability of biogeochemical properties - nutrients, DIC, DO - in the AASW layer is driven by a combination of sea-ice and biological processes. Antarctic Bottom Water, defined as water with neutral density > 28.3 kg m-3, was sampled at all the offshore full-depth stations, with a colder/fresher variety along western transects and a warmer/saltier variety in the east. Newly formed Antarctic Bottom Water - the coldest, freshest, and most recently ventilated - is mostly found in the deep ocean along 65°E, in the base of the Daly Canyon. [ABSTRACT FROM AUTHOR]

The acidification of coastal waters is distinguished from the open ocean because of much stronger synergistic effects between anthropogenic forcing and local biogeochemical processes. However, ocean acidification research is still rather limited in polar coastal oceans. Here, we present a 16 year (2002–2018) observational dataset in the Chukchi Sea during the rapid sea‐ice melting season to determine the long‐term changes in pH and aragonite saturation state (Ωarag). We found that pH and Ωarag significantly declined in the water column with average rates of −0.0095 ± 0.0027 years−1 and −0.0333 ± 0.0098 years−1, respectively, and are 4–6 times faster than those solely due to increasing atmospheric CO2. We attributed the rapid acidification to the increased dissolved inorganic carbon owing to a combination of ice melt‐induced increased atmospheric CO2 invasion and subsurface remineralization induced by a stronger surface biological production as a result of the increased inflow of the nutrient‐rich Pacific water. Plain Language Summary: Anthropogenic CO2 absorbed by the ocean leads to a lower pH and the calcium carbonate saturation state (Ω) and threatens the marine ecosystems state of healthiness via a process called ocean acidification (OA). The Arctic Ocean is particularly sensitive to OA because more CO2 can be dissolved in cold water. This study used the observations collected over 16 years from 2002 to 2018 to estimate long‐term trends of Ωarag and pH in the Chukchi Sea. The results show that rapid acidification occurred in the water column during the rapid sea‐ice melting season from 2002 to 2018, leading to or approaching aragonite undersaturation. The rapid acidification is attributed to the enhanced increasing concentration of dissolved inorganic carbon. While sea ice melt induced uptake of anthropogenic CO2 partly explains the long‐term acidification, the remainder is due to the increased nutrient‐rich Pacific inflow water which promotes the high biological CO2 utilization in the surface waters but leads to stronger subsurface acidification due to the regenerated CO2. We suggest that the acidity in Chukchi Arctic Shelf waters will increase in the future if the increased inflow of Pacific water continues. Key Points: pH and Ωarag declined significantly from 2002 to 2018 during sea‐ice melting season, 4–6 times greater than air CO2 increases‐induced changesThe enhanced acidification in the Chukchi Sea is mainly driven by increased DIC, owing to atmospheric CO2 uptake and biological activityPWW has been in aragonite undersaturation since 2010; other water masses are expected to encounter Ωarag < 1 in 15 years [ABSTRACT FROM AUTHOR]

The 2022 Hunga eruption caused unprecedented stratospheric hydration. Aura Microwave Limb Sounder (MLS) measurements show that the stratospheric water vapor mass remains essentially unchanged as of early 2024 and that the Hunga hydration occurred atop a robust (possibly accelerating) moistening trend in the stratosphere. Enhanced by the excess Hunga water vapor, dehydration via polar stratospheric cloud sedimentation in the 2023 Antarctic vortex exceeded climatological values by ∼ ${\sim} $50%. Simple projections based on modeled exponential decay illustrate that the timing of the return to humidity levels that would have been expected absent the Hunga hydration depends on the ongoing stratospheric water vapor trend. With the Hunga hydration compounding an underlying moistening trend, the stratosphere could remain anomalously humid for an extended period. Plain Language Summary: The 2022 Hunga eruption injected an unprecedented amount of water vapor directly into the very dry stratosphere. This abrupt increase in water vapor from Hunga occurred at a time when the stratosphere was already gradually becoming moister. Using measurements from the Microwave Limb Sounder (MLS) on NASA's Aura satellite, we show that stratospheric water vapor remained elevated, essentially unchanged, from the time of the eruption until at least early 2024. MLS data further reveal that, in 2023, one of the main mechanisms for drying the stratosphere—permanent removal of water vapor by formation and settling of ice polar stratospheric cloud particles over Antarctica—was substantially more effective than usual, boosted by the excess water vapor from Hunga. Projections indicate that the return to moisture levels that would have been expected in the absence of the eruption depends on how humid the stratosphere continues to get. Considering the ongoing moistening trend and the water vapor injected by Hunga, the stratosphere could remain unusually humid for a considerable period. Key Points: The stratospheric water vapor mass has remained essentially unchanged since the Hunga hydration through at least early 2024Fueled by excess Hunga water vapor, 2023 Antarctic vortex polar stratospheric cloud dehydration exceeded the climatological mean by ∼50%Given its robust (and potentially accelerating) background moistening trend, the stratosphere could stay anomalously humid for years [ABSTRACT FROM AUTHOR]

To predict ecosystem change in the Arctic Ocean, understanding Arctic phytoplankton phenology is essential. We develop a marine ecosystem model focusing on phytoplankton dynamics and the competition for multiple resources based on knowledge from in situ data obtained in the Chukchi Sea. The model is designed to include the unique ecological characteristics of the Arctic Ocean. To the best of our knowledge, this is the first model successfully simulating the current paradigm for Arctic phytoplankton phenology, including both under‐ice blooms and succession of phytoplankton groups. Sensitivity experiments show that the dominance of diatoms can be sustained by lateral transport of a high‐silicate water mass (Pacific Winter Water). Experiments for future scenarios show that sea ice retreat drives a decrease in large diatoms and an increase in the other relatively small non‐diatom groups. These results suggest that dominant phytoplankton groups can be shifted from diatoms to non‐diatoms under ongoing Arctic Ocean sea ice retreat. Plain Language Summary: Understanding the phytoplankton ecology of the Arctic Ocean is important for predicting ecosystem change as sea ice retreats. We have developed a phytoplankton ecosystem model that describes three different phytoplankton groups, each of which competes for three different nutrients. The model successfully simulates the observed characteristics of the Arctic phytoplankton ecology, such as under‐ice blooms and the growth and decline of the various phytoplankton groups, which was not successfully simulated by previous models. Our results show that horizontal transport of waters with high silicate concentrations play a key role in sustaining silicate‐dependent phytoplankton (diatom) groups. Simulations that explore future sea ice retreat scenarios suggest that the dominant phytoplankton group can be significantly altered by the changing conditions of the Arctic Ocean. Key Points: We develop new ecosystem model for phytoplankton phenology during ice‐covered to open‐water periods using observations from the Chukchi SeaThe model successfully captures the succession of phytoplankton groups reported by previous studies, not resolved by previous modelsThe model predicts that dominant phytoplankton groups can be significantly altered by future sea ice scenarios [ABSTRACT FROM AUTHOR]

Although autotrophic picophytoplankton (APP) is a sensitive component of phytoplankton responding to climate variability, little has been investigated in relatively undisturbed marine systems. This study aimed to assess the monthly dynamics of APP abundances from March 2009 to December 2010 and their association with regional climate variability at the Alfonso Basin station (Gulf of California). APP, the most abundant autotrophic component in the 0–100-m layer, and chlorophyll-a concentration (Chl-a) showed interannual variations associated with climate variability. APP abundance was positively correlated with temperature, salinity, and Chl-a, and significant negative correlations were established between nitrites + nitrates and phosphates. From July 2009 to April 2010, APP-integrated abundance explains at least 48% of the net primary productivity variation, suggesting a positive response to a prolonged influence of surface tropical water mass. According to the depth-integrated (0–100 m) abundance, APP variation was associated with the temporal evolution of Central Pacific El Niño 2009–2010 and multiannual warming that explains the positive trends in satellite sea surface temperature and stratification, and lower nutrient concentrations and N:P ratios values in the upper pycnocline layer at Alfonso Basin. These results highlight the importance of maintaining regional marine observatories. [ABSTRACT FROM AUTHOR]

AbstractThis paper addresses the global issue of water scarcity and the need for sustainable development by exploring eco-friendly desalination technology – solar still. Although solar still has lower productivity compared to conventional fossil-fueled desalination technologies, much research is being conducted to enhance its productivity. Most studies focus solely on optimizing water mass in solar still, neglecting other correlated factors. Hence, this paper presents mathematical modeling and experimental studies on the impact of water mass, initial temperature, and solar insolation on solar still performance in Polish weather conditions. The findings reveal that solar still productivity ranges from 215 mL/m2/day to 5079 mL/m2/day between June and October in Poland. It is observed that solar still productivity decreases with increasing water mass beyond the critical threshold of solar insolation on the glass cover plane, which is 2.676 kWh/m2/day. However, below that threshold, the effect of water mass on the solar still productivity strongly depends on its initial temperature. [ABSTRACT FROM AUTHOR]

Although zooplankton were extensively studied in the North Sea, knowledge about winter zooplankton assemblages is still scarce, despite potential influence of zooplankton overwintering stocks on seasonal plankton succession and productivity. Furthermore, several economically and ecologically important fish species reproduce during winter contributing to the zooplankton community as passive members (eggs) or predators (larvae). To elucidate on winter zooplankton distribution, abundance and composition in the Southern North Sea and Eastern English Channel, we defined assemblages based on mesozoo- and ichthyoplankton data sampled between January and February 2008 using fuzzy-clustering and indicator species. Mesozoo- and ichthyoplankton (eggs+larvae) were integrated in a common analysis by using a spatial grid adapted to the datasets and defined by means of a geostatistical method developed in agronomics. Potential environmental drivers of assemblage distribution were evaluated by means of GLMM and comparison with data from 2022 facilitated insight about the inter-annual representativeness of the assemblages. Five zooplankton assemblages were found varying with regard to total zooplankton abundance, dominant and indicator taxa. Spatial variability of abiotic (dissolved nutrients, salinity, depth, temperature, organic matter in suspension, chlorophyll a), biotic variables (phyto- and microplankton composition), water masses and fish spawning grounds were revealed as potential drivers of assemblage distribution. Assemblages off the Rhine-Scheldt estuary and in the German Bight harbored the biggest zooplankton overwintering stocks that might influence the grazing pressure on phytoplankton spring production. Assemblages off the Rhine-Scheldt estuary and covering the English Channel and the Southern Bight were found to be of high importance for herring and plaice larvae. Although further analyses suggested inter-annual representativeness of the assemblages found (2008 vs 2022), the assessment of further years would be necessary to account for potential inter-annual variability. Future studies could profit from the assessment of microzooplankton facilitating insight in fish larvae feeding potential and zooplankton overwintering strategies. [ABSTRACT FROM AUTHOR]

Mesozooplankton is a key component of the ocean, regulating global processes such as the carbon pump, and ensuring energy transfer from lower to higher trophic levels. Yet, knowledge on mesozooplankton diversity, distribution and connectivity at global scale is still fragmented. To fill this gap, we applied DNA metabarcoding to mesozooplankton samples collected during the Malaspina‐2010 circumnavigation expedition across the Atlantic, Indian and Pacific oceans from the surface to bathypelagic depths. We highlight the still scarce knowledge on global mesozooplankton diversity and identify the Indian Ocean and the deep sea as the oceanic regions with the highest proportion of hidden diversity. We report no consistent alpha‐diversity patterns for mesozooplankton at a global scale, neither across vertical nor horizontal gradients. However, beta‐diversity analysis suggests horizontal and vertical structuring of mesozooplankton communities mostly attributed to turnover and reveals an increase in mesozooplankton beta‐diversity with depth, indicating reduced connectivity at deeper layers. Additionally, we identify a water mass type‐mediated structuring of mesozooplankton bathypelagic communities instead of an oceanic basin‐mediated as observed at upper layers. This suggests limited dispersal at deep ocean layers, most likely due to weaker currents and lower mixing of water mass types, thus reinforcing the importance of oceanic currents and barriers to dispersal in shaping global plankton communities. [ABSTRACT FROM AUTHOR]

Quinolone antibiotics (QNs) contamination in the aquatic environment is a global public health issue considering their resistance and mobility. In this study, a simple, efficient, and sensitive method was developed for the accurate quantification of fifteen QNs in water using automated disk-based solid-phase extraction (SPE) coupled with ultra-performance liquid chromatography–tandem mass spectrometry (UPLC–MS/MS). By utilizing a 3M SDB-XC disk to enrich QNs from a 1000 mL water sample, the detection limits were improved to 0.008–0.055 ng/L due to the satisfactory enrichment factors of 897−1136, but only requiring about 60 min per six samples. The linearity of the method ranged from 0.05 to 100 μg/L for the 15 QNs, with correlation coefficients of 0.9992–0.9999, and the recoveries were in the range of 81–114%, with relative standard deviations of 0.2–13.3% (n = 6). The developed method was applicable for the quantification of trace QNs at low ng/L levels in drinking and environmental waters. The results showed that no QNs were detected in tap water, while three and four QNs were detected in the river water of Zhoushan and the seawater of Daiquyang and Yueqing Bay, East China, respectively, with a total concentration of 1.600–8.511 ng/L and 1.651–16.421 ng/L, respectively. Among the detected QNs, ofloxacin (OFL) was the predominant compound in river water, while enrofloxacin (ENR) was predominant in seawater. The risk quotient (RQ) results revealed that QNs posed a low risk to crustaceans and fish, but a low-to-medium risk to algae, and OFL presented the main ecological risk factor in river water, while ENR and CIP in seawater. Overall, the proposed automated disk-based SPE–UPLC–MS/MS method is highly efficient and sensitive, making it suitable for routine analysis of QNs in drinking and environmental waters. [ABSTRACT FROM AUTHOR]

The pathways and mixing in dense water overflows have been addressed in a range of numerical studies based on the DOME (Dynamics of Overflow Mixing and Entrainment) setup. These studies are motivated by overflows such as the flow of dense and cold water over the ridge between Iceland and Scotland. The main route of this water is through the Faroe-Shetland channel and further through the Faroe Bank Channel. After leaving the Faroe Bank Channel, the dense water continues along the slope along the Iceland-Faroe Ridge. Across this ridge there is also a strong flow of Atlantic water that may affect the pathway and mixing in the dense plume. In the DOME investigations, the slope steepness is assumed to be constant and there is no active background flow in the ambient water masses above the dense plume. With the situation along the Iceland-Faroe Ridge in mind, the setup from the DOME experiment is adjusted to study the effects of i) the slope profile, ii) flows crossing the slope on top of the along-slope flow of dense water, and iii) the topography near the overflow channel of dense water. It is found that the rate of descent is depending on slope steepness, and for a curved slope going from flat on top of a ridge to much steeper away from the ridge, dense water parcels near the ridge top or crest will sink slower than the faster flowing dense water further down along the slope. A cross-flow over the ridge, mimicking the flow of Atlantic water over the Iceland-Faroe Ridge, will force stronger mixing between the dense water and the ambient water above and dense water mixed up into the surface water can be allowed to flow out across the ridge. Furthermore, the dynamical situation along the slope will change and fluid parcels in the deeper part of the plume can experience a faster rate of descent. By removing a barrier in the topography downstream of the overflow channel, dense water can be steered towards the ridge and the starting point of the center of mass of the descending overflow water will be higher up on the slope. [ABSTRACT FROM AUTHOR]

Introducing a novel meta-heuristic optimization algorithm, the Flood Algorithm (FLA) draws inspiration from the intricate movement and flow patterns of water masses during flooding events in river basins. FLA mathematically models key phenomena such as the movement of water toward slopes, flow rates over time, soil permeability effects, and periodic increases and decreases in water levels from precipitation and losses. Leveraging these models, the algorithm guides the movement and evolution of a population of potential solutions toward enhanced optimality. The algorithm endeavors to establish an appropriate correlation between the fundamental aspects of natural flood events and the optimization process. Its formulation and working mechanism are described in detail. It operates in two main phases—a regular movement phase, where the population moves naturally toward current best solutions, and a flooding phase, which introduces random disturbances to increase diversity. New solutions are periodically introduced while weaker ones are removed, mirroring the natural cycles of water levels. FLA's effectiveness is demonstrated through its application on well-known benchmark optimization problems and engineering design problems. Extensive comparisons have been carried out on CEC2005 functions using 16 algorithms in both basic and enhanced modes, as well as on CEC2014 functions with dimensions 30, 50, and 100 using a total of 20 other algorithms. These rigorous studies unequivocally confirm the robustness and strength of the proposed algorithm. Furthermore, the algorithm's performance on 12 constrained engineering problems demonstrates its ability to tackle real-world challenges. The FLA's source code is publicly available at https://www.optim-app.com/projects/fla. [ABSTRACT FROM AUTHOR]

The efficient delivery of nicotine in e-cigarette aerosols depends on the deposition efficiency of these aerosols within the respiratory tract. Accurate prediction of the hygroscopic growth of e-cigarette aerosols is pivotal to understanding their deposition. This study introduces a novel experimental approach to quantify the water activity coefficient, which is a crucial parameter governing the extent of hygroscopic growth in e-cigarette aerosols. Propylene glycol (PG) and vegetable glycerin (VG) are the primary components of e-liquid so that are used as the experimental subjects. Our findings reveal intriguing trends in the behavior of PG and VG mixtures. As relative humidity (RH) increases, these mixtures exhibit elevated equilibrium mass fractions of water accompanied by a decrease in water activity coefficients. Moreover, higher initial PG/VG mass ratios lead to decreased mass fractions of water and increased water activity coefficients. Notably, solution pH also impacts water activity coefficients, with higher pH levels corresponding to increased coefficients. The results reveal the factors which can affect the hygroscopic growth of e-cigarette aerosols, thus contributing to the understanding of the deposition of such aerosols within the respiratory tract. Moreover, the experimental apparatus proposed in this study provides a straightforward and reliable method to obtain hygroscopic parameters of multicomponent solutions. Copyright © 2024 American Association for Aerosol Research [ABSTRACT FROM AUTHOR]

Adjuvants are included in many pesticide spray mixtures to enhance the performance of the applied chemical. Many adjuvants which modify the emulsion or extensional viscosity of the tank‐mixture have been found to offer benefits in drift management, primarily by eliminating or reducing the 'Fine' droplets included in the spray with diameters <100–200 μm that can move off‐target in unfavorable conditions during ground, airblast and aerial pesticide applications. Among wind tunnel and field studies conducted around the world, there is consensus that while some adjuvants are effective for drift management, the performance varies on a case‐by‐case basis, requiring verification for each adjuvant which could be achieved through a programme such as certification based on showing a reduction in Fine droplets and/or a reduction in airborne drift. These can be measured in wind tunnel studies according to international standards. This article provides a review of the current science in this subject area, from the approaches to data collection to a review of existing data and regulatory application for encouraging and rewarding the use of appropriate adjuvants that have been demonstrated to reduce airborne spray drift potential and therefore the size of no‐spray buffer zones appropriate to protect nontarget sensitive areas from drift exposure. Some adjuvants can offer the same reduction in drift as offered by hooded sprayer retrofits. A drift reduction programme based on adjuvant use could include testing candidate adjuvants for their effect on droplet size and reduction in Fine droplets when sprayed through reference nozzles and compared against sprays without the adjuvant. Testing could also be based alternatively on measurements of drift potential on collectors such as monofilament line in wind tunnel or field studies. Once shown to be effective in reducing 'Fines' or spray drift, adjuvants could be certified and then referenced on pesticide labels and/or regulatory or best management practice schemes to encourage their use and offer reductions in use restrictions or no‐spray buffer zone sizes based on drift management. Studies have shown that some adjuvants can reduce pesticide leaching into soils and contamination of groundwater, as well as runoff of active ingredients from plants into the environment. Performance depends on the adjuvant type, the pesticide with which it is used, the soil or plant type, the timing and mass of water input from rainfall and climatic factors. © 2024 The Author(s). Pest Management Science published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry. [ABSTRACT FROM AUTHOR]

The connection of the Southern Ocean and Eastern Equatorial Pacific (EEP) has been used to explain the presence of an old, respired water mass into the Eastern Tropical North Pacific (ETNP) and Eastern North Pacific (ENP) during deglaciation. This water mass and its geochemical properties are transported along the thermocline via subsurface and intermediate circulation. Some questions remain regarding an intermediate water mass with old and less ventilated characteristics in the eastern Pacific because certain sedimentary records of δ13C, δ18O, and Δ14C in benthic foraminifera have failed to prove its presence. The top-down hypothesis has been proposed to explain the absence of this carbon isotopic signal in benthic and its presence in planktonic foraminifera in the EEP. To prove this hypothesis in the ETNP, oxygen and carbon isotopic compositions were determined for Neogloboquadrina dutertrei in a core collected at 700 m depth over the Magdalena margin, Mexico. From these new data, a reconstruction of the water column structure and the change in ocean circulation at the thermocline level during deglaciation was inferred. N. dutertrei δ18O values in the ETNP and those from Globigerina bulloides in the ENP, similar to those of N. dutertrei in the EEP, suggest that the tropical water mass extended as far as 32 °N. Specifically, N. dutertrei δ18O values were more positive in the Heinrich Stadial-1 (HS-1) and Younger Dryas (YD) than the Bolling Allerod-Antarctic Cold Reversal (BA-ACR) and Early Holocene (EH) suggesting the presence of a saline water mass with origin in the EEP. N. dutertrei δ13C depleted values during the HS-1 and YD suggested the presence of a water mass with old and respired carbon. This is consistent with the salinification or "spicy" inferred from δ18O for the ETNP. These isotopic findings in N. dutertrei corroborate the existence of a tropical water mass that probably originated in the Southern Ocean. Additionally, the present data do not support the top-down hypothesis. [ABSTRACT FROM AUTHOR]

The isotopic composition of barium ^[sup 138]Ba) has emerged as a powerful tracer of deep-ocean circulation, water mass provenance, and the oceanic Ba cycle. Although the δ[sup 138]Ba of water masses is primarily controlled by the balance between pelagic barite precipitation and Ba resupply from ocean circulation, questions remain regarding the isotopic offset associated with pelagic barite formation and how the resultant Ba isotope compositions are transmitted through the water column to marine sediments. To address these questions, we conducted a time series study of dissolved, particulate, and sedimentary Ba chemistry in the Gulf of Aqaba (GOA), in the northern Red Sea, from January 2015 to April 2016. These data span significant seasonal changes in hydrography, primary productivity, and aerosol deposition, revealing three principal findings. First, the dissolved Ba chemistry of the GOA is vertically uniform across the time series, largely reflecting water mass advection from the Red Sea, with mean dissolved Ba concentrations of 47.9 ± 4.7 nmol kg[sup -1] and mean δ[sup 13ί]^ = +0.55%" ± 0.07%" (±2 SD, n = 18). Second, despite significant variations in particulate matter composition and flux, the δ[sup 138]Ba of sinking particulate Ba maintained a consistent isotope composition across different depths and over time at +0.09% ± 0.06% (n = 26). Consequently, these data imply a consistent Ba isotope offset of -0.46% ± 0.10% (±2 SD) between sinking particulates and seawater. This offset is similar to those determined in previous studies and indicates that it applies to particulates formed across diverse environmental conditions. Third, barite-containing sediment samples deposited in the GOA exhibit δ[sup 13ί]^ = +0.34% ± 0.03%, which is offset by approximately +0.2% relative to sinking particles. While the specific mechanism driving this offset remains unresolved, our results highlight the importance of performing site-specific proxy validations and exercising careful site selection when applying novel paleoceanographic proxies. [ABSTRACT FROM AUTHOR]

Introduction: In the Southern Ocean, the large-scale distribution of zooplankton, including their abundance and community composition from the epipelagic to the upper bathypelagic layers, remains poorly understood. This gap in knowledge limits our comprehension of their ecological and biogeochemical roles. Methods: To better understand their community structure, depth-stratified zooplankton samples were collected from 0 to 1500 m during four summers in the East-Pacific and Indian sectors of the Southern Ocean. In addition, analysis of environmental drivers including temperature, salinity, dissolved oxygen, and chlorophyll a concentration, as well as water masses was conducted. Results: Our study indicates that zooplankton diversity may be similar between the two sectors, while zooplankton abundance was higher in the East-Pacific sector during different sampling months and years. Moreover, zooplankton abundance decreased with depth in both sectors. Based on cluster analysis, zooplankton communities were generally divided by either the epipelagic or the deeper layers' communities. In both sectors, the epipelagic layer was dominated by cyclopoid copepods, such as Oithona similis and Oncaea curvata, as well as calanoid copepods including Calanoides acutus, Rhincalanus gigas, and Ctenocalanus citer, while copepods and other taxa including Chaetognatha, Amphipoda, and Ostracoda, were important contributors to the deep layer communities. Discussion: Our analysis revealed that water masses, combined with their physical characteristics such as specific temperature and salinity ranges and depth, along with biological factors such as chlorophyll a concentration, might be the most important drivers for structuring zooplankton communities from epipelagic to upper bathypelagic layer. [ABSTRACT FROM AUTHOR]

Near‐surface wind fields in the Prydz Bay and Amery Ice Shelf region of East Antarctica play a crucial role in the formation and variability of Antarctic Bottom Water, a cold, dense water mass that sinks and spreads across the deep ocean basins influencing ocean circulation and modulating earth's climate system. This study investigates the primary modes of variability of these wind fields using the self‐organizing map (SOM) method and data from the latest version of the European Centre for Medium‐Range Weather Forecasts (ECMWF) ReAnalyses (ERA5), spanning four decades from 1979 to 2020. While the wind field climatology, characterized by small seasonal variation, is dominated by katabatic and large‐scale forcing, the spatial patterns of the primary variability modes are mainly influenced by synoptic system activities. The overall trend in annual wind speed anomalies is positive across the study region, with the exception of the southwestern part and central Prydz Bay. However, significant trends are observed in only two out of nine SOM nodes (nodes 4 and 9), which collectively explain less than 30% of the averaged trends over the region. The interannual variability in the seasonal occurrences of certain nodes is linked to several well‐known climate modes, including the El Niño–Southern Oscillation, the Southern Annular Mode and Zonal Wavenumber 3. Our results provide a reference for forecasting the occurrence frequency of specific patterns, which could help mitigate the impact of extreme wind events through improved forecasting. [ABSTRACT FROM AUTHOR]

The role of mixing between layers of different densities is key to how the ocean works and interacts with other components of the Earth's system. Correctly accounting for its effect in numerical simulations is therefore of utmost importance. However, numerical models are still plagued with spurious sources of mixing, originating mostly from the vertical advection schemes in the case of fixed-coordinate models. As the number of phenomena explicitly resolved by models increases, so does the amplitude of resolved vertical motions and the amount of spurious numerical mixing, and regional models are no exception to this. This paper provides a clear illustration of this phenomenon in the context of simulating the south-east Asian (SEA) seas along with a simple way to reduce its impact. This region is known for its particularly strong internal tides and the fundamental role they play in the dynamic of the region. Using the Symphonie ocean model, simulations including and excluding tides and using a pseudo-third-order upwind advection scheme on the vertical are compared to several reference datasets, and the impact on water masses is assessed. The high diffusivity of this advection scheme is demonstrated along with the importance of accounting for tidal mixing for a correct representation of water masses. Simultaneously, we present an improvement in this advection scheme to make it more suitable for use in the vertical. Simulations with the new formulation are added for comparison. We conclude that the use of a higher-order numerical diffusion operator greatly improves the overall performance of the model. [ABSTRACT FROM AUTHOR]

Arctic fjords, being transitional areas between glacier‐covered land and the ocean, are characterized by strong environmental gradients. The seasonal melting of glaciers generates strong turbidity and primary production antagonist gradients, which can affect benthic habitats. Two sampling campaigns were carried out in Kongsfjorden (Svalbard, Arctic Ocean) in May and August 2021 to investigate seasonal changes in benthic foraminifera spatial distribution and ecosystem functioning along a longitudinal transect of 10 km from the Kronebreen tidewater glacier front. Concurrently, organic matter quantity and biochemical composition, sediment grain size, and physical parameters of the water masses were investigated as possible driving factors of benthic ecosystem responses. In a previous study, three statistically determined foraminiferal biozonations (glacier proximal, medial, and distal) were observed on the basis of their species content within the closest 10 km from the glacier front, presenting similar assemblages in both seasons. Our results indicate that foraminiferal distribution at the local scale is mainly driven by physical and geochemical gradients induced by melting waters and sediment discharges from the tidewater glacier occurring during summer. Due to the climate change, the melting season is expected to last longer and increasing global temperature will much probably accelerate the melting processes. Our findings strongly support the use of foraminifera as bioindicators to monitor the effects of ongoing climate change on the benthic ecosystems of Arctic fjords and, accessorily, as proxies for reconstructing glacier front positions in the recent past. [ABSTRACT FROM AUTHOR]

Pacific Winter Water (PWW) with high dissolved inorganic carbon (DIC) is the key water mass in which subsurface acidification occurs in the western Arctic Ocean. To investigate and partition carbon sources added to PWW across the Chukchi shelf to the adjacent Canada Basin, we investigated the distributions of DIC and its stable isotope (δ13C‐DIC) with other hydrographic and biogeochemical parameters during the Mirai cruise in the late summer of 2021. Using a four‐end‐member mixing model, we deciphered the water masses and separated DIC changes induced by biological processes from those induced by conservative mixing. We demonstrated that DIC dynamics in PWW were mainly controlled by the biological decomposition of organic carbon (OC). A mass balance model analysis of DIC and δ13C‐DIC suggested that the apparent δ13C signature of the respired organic carbon (δ13COCx) within PWW was −22.2‰ ± 1.1‰ on the shelf and −25.6‰ ± 1.6‰ in the basin. Therefore, we concluded that marine‐origin OC was the dominant carbon source that was decomposed in the Chukchi shelf bottom water, while respired terrestrial‐origin carbon made a major contribution to DIC pool in the basin PWW. We proposed that terrestrial OC from the Chukchi and Beaufort coastal seas could be an important carbon source, which was associated with winter water formation on the shelves and influenced by Beaufort Gyre state shift and circulation changes. This unconventional finding has important ramifications for the prediction of the future state of ocean acidification in the western Arctic Ocean. [ABSTRACT FROM AUTHOR]

Global warming has accelerated the iodine cycle in the Arctic Ocean, amplifying its significance in the global iodine cycle. However, some intricacies of the iodine cycle in the Arctic marine environment remain unclear. In this study, we present concentrations of stable- and radio-iodine (127I and 129I) in total iodine, iodide (I–), and iodate (IO 3 –) in seawater from the Beaufort, Chukchi, and Bering Seas. Results show a wide range of 129I/127I ratios of total iodine (3.2 × 10–12–9.3 × 10–9), indicating that the total 129I/127I ratio is a valuable fingerprint for identifying water masses and comprehending mixing processes. Iodine loss in surface seawater was quantitatively assessed using 129I, revealing that Arctic rivers substantially contribute to the emission of iodine into the atmosphere from the Arctic and subarctic seas. Our redox simulation in the Arctic intermediate layer shows the concentrations and 129I/127I ratios of I– and IO 3 – during its migration and provides the first evidence of an IO 3 – reduction process masked by the I– oxidation in the intermediate Arctic Ocean. Oxidation and reduction processes in the intermediate Arctic Ocean were characterized by extremely slow rates, at 0.95–2.41 and 0.26 ± 0.13 nM/year, respectively. Our findings demonstrate the effectiveness of anthropogenic 129I in tracking iodine cycling in the Arctic marine environment. [ABSTRACT FROM AUTHOR]

In order to ensure the safety of the tunnel approaching the fault and prevent water inrush disasters, and then take reasonable protective measures, a fault-tunnel-surrounding rock is established by using a three-dimensional (3D) discrete element numerical analysis method, which takes into account the fluid-structure coupling effect. Based on the method of control variables, the catastrophe information characteristics of displacement and water pressure of the surrounding rock of the tunnel face and the corresponding characteristics of changes before the occurrence of water inrush disasters were studied under different fault water pressures during the excavation of the tunnel approaching the water-rich fault. The results show that, during excavation at the same step, displacement and its magnitude in the surrounding rock escalate as fault water pressure increases. The maximum pressure of the water in the surrounding rock is also constantly increasing. As tunnel excavation progresses, at constant fault water pressure, longer excavation distances result in greater axial displacement of the surrounding rock mass and increased water pressure at corresponding positions within the surrounding rock, leading to higher magnitude increases. As excavation proceeds, the displacement and water pressure in the surrounding rock and the increase of its amplitude continue to increase. Pre-reinforcement grouting techniques and pipe umbrella support systems that are very effective protective measures can be determined by a comprehensive approach integrating advanced geological forecasting methods, real-time water pressure detection, and the analysis of stress-strain and seepage pressure field variations in the surrounding rock mass. [ABSTRACT FROM AUTHOR]

The cartographic landscape analysis of Lake Doshne employs geographic landscape methods, GIS cartographic modeling, and geo-ecological analysis. This study includes hydrochemical analysis of the lake's water mass, focusing on saline blocks, tropho-saprobiological indicators, and specific toxic action indicators. Three geological sections of anthropogenic and pre-Quaternary complexes, along with a geological–lithological transverse profile of the lake basin, were developed. Additionally, a geographical landscape model of the lake's natural aquatic complex was presented, distinguishing littoral–sublittoral and profundal aquatic sub-tracts and five types of aquafacies with landscape metric assessments. This approach enables a comprehensive analysis and the creation of cartographic models that can serve as a basis for lake cadastre and optimization of the ecological and landscape conditions in local territories. [ABSTRACT FROM AUTHOR]

Experimental investigations into the characterization of vortices in hyperbolic funnels have shown efficient aeration properties. Certain regimes of vortices have been observed to exhibit high gas dissolution rates. This phenomenon has prompted inquiries into the underlying physical mechanisms at both micro and macroscopic scales. The present study employs computational fluid dynamics to numerically analyze the flow field organization inside these vortices, aiming to elucidate the observed high gas transfer rates. Transient simulations are performed on a three-dimensional radially structured hexahedral mesh, utilizing a multiphase Euler–Euler approach-based volume of fluid method for modeling, along with shear stress transport turbulence modeling based on k − ω equations with curvature correction. The evaluation of the two vortex regimes was conducted in terms of hydraulic retention time, water volume in the reactor, air–water interfacial area, and bulk mixing. Instabilities resembling Taylor vortices observed in Taylor–Couette flow systems emerge in the secondary flow field of these vortical structures, facilitating turbulent mixing. A qualitative analysis of the strength of these instabilities in terms of average vorticity per unit mass of water explains the high gas transfer efficiency. Despite high gas transfer rates, water exiting the funnel remains undersaturated under given operating conditions due to the short hydraulic retention time. [ABSTRACT FROM AUTHOR]

An experimental investigation is performed on the heat transfer performance through free single jet impingement technique using TiO2-water nanofluid (NF). An experimental set-up has been fabricated to analyze the performance of convective heat transfer coefficient of three samples of TiO2-water nanofluid with TiO2 nano particle content of 0.1, 0.15, and 0.2% by mass in distilled water and compared their results with water. The effects of varying nano particles mass fractions, Reynolds number and nozzle-to-plate height on heat transfer performances of jet impingement of nanofluid have been discussed. The experimental outcomes reflected that there is improvement in heat transfer coefficient with increase in Reynolds number (Re), nanoparticle concentration and nozzle-to-plate height. The highest heat transfer is obtained for nozzle-to-plate height of 15 mm at Reynolds number 6600 at 0.15 mass% TiO2-water nanofluid. [ABSTRACT FROM AUTHOR]

Hybrid cements combine clinker with large amount of supplementary cementitious materials while utilizing hydration and alkali activation processes. This paper summarizes shrinkage and creep properties of industrially produced H-cement, containing only 20% of Portland clinker. In comparison with a reference cement CEM II/B-S 32.5 R, autogenous shrinkage is smaller after 7 days, and drying shrinkage is similar at similar times. A different capillary system of H-cement leads to faster water mass loss during drying. Basic and total creep of concrete remains in the standard deviation of B4 and EC2 creep models. The results demonstrate that shrinkage and creep properties of concrete made from H-cement have similar behavior as conventional structural concrete or high-volume fly ash concrete. [ABSTRACT FROM AUTHOR]

To investigate the quasistatic pressure load characteristics of an explosion in a confined cabin in a water mist environment, explosion tests were conducted under different explosive and water mist masses. The concentration of water mist, droplet diameter, and quasistatic pressure inside the cabin were measured. On the basis of the theoretical model of quasistatic pressure in adiabatic ideal gas cabins, a theoretical model of the quasistatic pressure in a confined cabin in a water mist environment was established. On the basis of experimental data and theoretical models, an empirical formula was proposed for the peak quasistatic pressure of implosion in a water mist environment. A model for a cabin explosion in a water mist environment was established, and the load characteristics of a cabin explosion under high water mist concentrations were analyzed. The relevant research results contribute to the prediction of the quasistatic pressure of explosions in a confined cabin in a water mist environment. [ABSTRACT FROM AUTHOR]

The deep glacial trough and hinterland of the Denman Glacier (East Antarctica) makes the area around the Shackleton ice shelf sensitive to ice loss due to warmer deep water intruding onto the continental shelf in the near future. In addition, the configuration of the ocean currents offshore is an important factor in priming the local and regional vulnerability to warm water intrusions. Here, we use reflection seismic data sets from the Bruce Rise offshore the Denman‐Shackleton region to investigate the Cenozoic history of the ocean bottom current configurations offshore and their influence on the Cenozoic sedimentation patterns of the Denman‐Shackleton region. On the Bruce Rise, sediment drift building, and erosional features indicate three distinct ocean current configurations, (a) the production of dense shelf waters in times of a smaller East Antarctic Ice Sheet (EAIS), (b) periods dominated by a strong Antarctic Slope Current (ASC) and (c) periods with a weak ASC. During the early establishment of the EAIS, the Denman‐Shackleton area contributed to the production of Antarctic Bottom Water, a process which stabilizes the regional ice sheet. With a growing icesheet, the ASC strengthened representing an effective barrier between the continental shelf and the warmer water masses of the deeper ocean during most of the times of an extended EAIS. The transition in the paleoceanographic setting from a strong, erosive ASC, toward a weak ASC increases the vulnerability of the Denman‐Shackleton continental shelf to deep water intrusions as we are observing today. Plain Language Summary: Today, warm salty water flows across the continental shelf of the Denman‐Shackleton region in East Antarctica, causing increased melting and the retreat of the local ice sheet. We are investigating based on the sediment archive, how likely these intrusions have been in the geological past. Our analysis shows, that most likely, the Denman‐Shackleton region has not experienced warm water intrusions for the majority of the Antarctic glaciation. During the early presence of the icesheet, the region contributed to the production of Antarctic bottom water, the globally dominating bottom water mass, a process which is not observed since and blocks intruding warm waters. With the transition to colder climates, the strength of the westward flowing ocean currents along the continental slope are managing the barrier between the cold shelf waters and the warmer waters of the deep sea. With a weakening of the current, the intrusion of warm waters onto the continental shelf become more common. This highlights, that the Denman/Shackleton region underwent a complete reversal of the ocean bottom current system throughout the history of the Antarctic ice sheet from the export of denser shelf waters to an increased potential of frequent warm waters on the continental shelf. Key Points: The Denman‐Shackleton region contributes to Antarctic bottom water formation during the early Antarctic glaciationThe Denman‐Shackleton region's ocean current behavior changed dramatically during the late CenozoicExploration of sediment drift building on the Bruce Rise as record of pre‐conditioning for warm water intrusions in the Shackleton region [ABSTRACT FROM AUTHOR]

The South Scotia Ridge, in the Atlantic sector of the Southern Ocean, is a key region for water mass modification. It is the location of the Weddell‐Scotia Confluence, an area of reduced stratification which separates the Weddell Gyre to the south and the Antarctic Circumpolar Current to the north, and which receives input of shelf waters from the tip of the Antarctic Peninsula. To elucidate the transformations over the ridge, we focus on one of its largest seamounts, Discovery Bank, which has previously been observed as hosting a stratified Taylor column that retains water for months to years, during which time water masses are entrained from north and south of the Weddell Front and steadily mixed. Data from ship‐deployed sensors and autonomous platforms are analyzed to quantify and understand the diapycnal mixing, heat fluxes and water mass transformations over the bank. Ocean glider and free‐profiling drifting float data show that the mid‐depth temperature maximum of the Circumpolar Deep Water (CDW) is eroded between the northern and southern sides of the bank, while diapycnal diffusivity is enhanced by up to an order‐of‐magnitude over its steeply sloping portions. This is accompanied by heat fluxes from the CDW layer being increased by up to a factor of six, which may contribute to a reduction in mid‐depth stratification. Tidal model analysis shows that the southern side of the bank hosts strong barotropic to baroclinic energy conversion (>150 N m−2), emphasizing the role of internal tides in modulating water mass transformations in the Confluence. Plain Language Summary: The Weddell‐Scotia Confluence region, in the South Atlantic sector of the Southern Ocean, is a zone where ocean waters from the Antarctic Circumpolar Current to the north, the Weddell Sea to the south, and the Antarctic Peninsula to the west, come together and interact. In this paper, observations from a research ship, an autonomous underwater glider, and free‐drifting ocean floats are used to characterize the mixing between these different sources of water, and to understand what impact this mixing has on the downstream vertical structure of the water column. The results show that an anticlockwise circulation of waters occurs around a large underwater seamount in the region, causing the waters there to be trapped for months to years. In addition, interaction with the steeply sloping undersea topography generates particularly strong mixing between these different waters through the action of tides, which helps to sustain the characteristic low vertical density gradients present in the region. These processes have important implications for both the movement of mid‐depth waters south into the circulation of the Weddell Sea, and likely also for the supply of nutrients to the productive surface layer of the ocean. Key Points: New observations reveal enhanced mixing rates and mid‐depth heat fluxes over one of the largest seamounts of the South Scotia RidgeThis enhanced mixing may help to sustain the mid‐depth stratification minimum found in the Weddell Scotia ConfluenceResults from a tidal model show high rates of barotropic to baroclinic tidal energy conversion over steeply sloping parts of the bank [ABSTRACT FROM AUTHOR]

The Labrador Shelf is integral to the North Atlantic Ocean's climate system, exerting a significant influence on both regional and global scales. This study examines continuous, high‐temporal resolution hydrographic profiles collected by two Argo floats located on the Labrador Shelf. Our focus centers on the subsurface changes. Among observed seasonal variations, the most pronounced and consistent change is a marked temperature increase during autumn in the Cold Intermediate Layer, which is also confirmed in an eddy resolving global reanalysis data set. Contrary to previous studies that attributed this warming to the autumnal deepening of the mixed layer, our analysis indicates that the warming extends to underneath the deepest mixed layer. Thus, mixed layer development cannot account for the observed warming in the deeper layer. On the other hand, analysis of velocity fields from reanalysis data set reveals active onshore intrusions at several locations, with a section at 58°N emerging as the northernmost hotspot. Budget analysis further indicates that the dominant factor driving autumn warming at Section 58°N is cross‐isobath advection that is associated with the intrusion of slope waters onto the shelf. Subsequently, the positive temperature anomaly at Section 58°N and other enhanced intrusion locations are transported downstream through along‐isobath currents, resulting in lagged yet intensified warming at lower latitudes. Our findings underscore the essential role of cross‐isobath intrusion, in combination with along‐isobath movements in governing seasonal temperature variability in the deep layer of the Labrador Shelf. Incorporating this mechanism is crucial for accurately hindcasting and forecasting bottom environmental conditions in the region. Plain Language Summary: The Cold Intermediate Layer (CIL) is a cold and relatively fresh water overlying the Labrador Shelf, capped by a thin, seasonal, warmer layer in summer. Observations and reanalysis data set reveal that the water mass becomes significantly warmer in autumn. Previous studies attributed the warming to the deepening of the heated summer upper layers in fall, or the downstream transport of upstream waters. Here, we demonstrate that warming in the deep CIL layer is initially driven by enhanced onshore velocity carrying warmer slope water to the shelf. Subsequently, the positive temperature anomaly at higher latitude is transported downstream through along‐isobath currents, resulting in lagged yet intensified warming at lower latitudes. This study reveals the essential role of cross‐shelf exchange in modulating seasonal temperature variability under the surface on the Labrador Shelf. Key Points: The subsurface water along the Labrador Shelf undergoes pronounced autumn warmingThe autumn warming of the subsurface water is triggered by enhanced onshore intrusionLagged yet intensified warming at the southern shelf result from the along‐shelf spread and accumulation of onshore‐intruded warm water [ABSTRACT FROM AUTHOR]

pH is a key index in ocean biogeochemical and acidification research. However, there remains a limited understanding of the spatial patterns and drivers of pH across different coastal oceans. In this study, we present the distribution of spectrophotometric pHT (in total proton scale) from a synoptic summer cruise in 2018. We examine the processes controlling pHT along the U.S. East Coast, covering the South Atlantic Bight (SAB), Mid‐Atlantic Bight (MAB), and Gulf of Maine (GoM). Our findings reveal a continuous low pHT band associated with the oxygen minimum and CO2 maximum zone along the slope of the entire east coast, extending from the bottom layer (∼1,000 m) in the SAB to the middle layer (300–500 m) in the MAB and GoM. We also identified unique low pHT features in each subregion, including an onshore upwelling of the low pHT slope water in the SAB, a seasonal low pHT feature on the bottom of the MAB shelf associated with the Cold Pool water, and an inflow of low pHT slope water to the bottom of the GoM. Our findings suggest that net biological production plays a prominent role in regulating sea‐surface pHT, driving it away from the air‐sea equilibrated pHT and mitigating the pHT decrease caused by the anthropogenic carbon dioxide (CO2) uptake. Furthermore, net biological respiration dominates the interior pHT distributions. Our analysis provides new insights and establishes a foundation for interpreting future pH changes in response to processes such as water masses shifting, ocean warming, and anthropogenic carbon uptake in coastal oceans. Plain Language Summary: Given that pH is a crucial index for assessing ocean acidification, understanding pH distribution patterns and its controlling factors in coastal oceans is essential. This study investigates pH from a summer 2018 cruise along the entire U.S. East Coast. We found that the surface‐water pH deviates from the atmospheric equilibrium, primarily due to net biological production. Subsurface pH patterns are also mainly controlled by biological factors. Along the slope, a continuous low pH band is associated with the oxygen minimum zone, extending from the bottom in the SAB to the middle depth in the MAB and GoM. On the shelf, each subregion has unique subsurface low pH features, including a shoreward upwelling of the low pH slope water in the SAB, a seasonal low pH feature in the MAB Cold Pool, and an inflow of low pH slope water in the bottom of GoM. This research provides new insights into the processes controlling pH distribution and lays a foundation for interpreting current and future pH decadal trends in the context of climate change. Key Points: The subsurface pH minimum layer extends from the slope bottom in the south to the middle layer of the slope in the northEach subregion has a distinct low‐pH feature, including onshore upwelling, Cold Pool water, and Gulf bottom waterSurface pH deviates from air‐sea gas equilibrium due to net biological production, while interior ocean pH is dominated by respiration [ABSTRACT FROM AUTHOR]

Global marine anthropogenic CO2 inventories have traditionally emphasized the North Atlantic's role in the carbon cycle, while Southern hemisphere processes are less understood. The South Subtropical Convergence (SSTC) in the South Atlantic, a juncture of distinct nutrient‐rich waters, offers a valuable study area for discerning the potential impacts of climate change on the ocean's biological carbon pump (Csoft). Using discrete observations from GLODAPv2.2022 and BGC‐Argo at 40°S in the Atlantic Ocean from 1972 to 2023, an increase in dissolved inorganic carbon (DIC) of +1.44 ± 0.11 μmol kg−1 yr−1 in surface waters was observed. While anthropogenic CO2 played a role, variations in the contribution of Csoft were observed. Discrepancies emerged in assessing Csoft based on the tracers employed: when using AOU, Csoft(AOU) recorded an increase of +0.20 ± 0.03 μmol kg−1 yr−1, while using nitrate as the reference, Csoft(NO3) displayed an increase of +0.85 ± 0.07 μmol kg−1 yr−1. Key processes such as water mass composition shifts, changes in oxygenation, remineralization in the Southern Ocean, and the challenges they pose in accurately representing the evolving Csoft are discussed. These findings highlight that while global studies primarily attribute DIC increase to anthropogenic CO2, observations at 40°S reveal an intensified biological carbon pump, showing that regional DIC changes are more complex than previously thought and emphasizing the need for better parameterizations to compute the BCP in the marine carbon budget. Plain Language Summary: The South Atlantic Ocean at 40°S has experienced changes in dissolved inorganic carbon (DIC) over the years, affecting its carbon composition. This study running from 1972 to 2023 showcased an increase in the DIC down to 2,000 m deep. While anthropogenic CO2 has traditionally been seen as the major contributor, the biological carbon pump's activity, influenced by various ocean processes, emerged as a significant driver. Specifically, factors such as photosynthesis, organic matter remineralization, sea ice movements, and freshwater influx from melting ice play pivotal roles in dictating oxygen and nitrate levels, both crucial components to predict the biological carbon pump's contribution to DIC. Our findings emphasize that this enhanced biological pump might contribute as much as human‐made CO2 to DIC in certain ocean regions. If unchecked, these changes could recalibrate ocean carbon budgets and predictions with potential shifts in water mass compositions, demanding more vigilant future monitoring. Key Points: The South Subtropical Convergence (SSTC) at 40°S in the Atlantic Ocean shows an intensified biological carbon pump, amidst uncertaintiesDiscrepancies in trends between oxygen utilization and nitrate concentrations provide two distinct estimates of the biological carbon pumpLocal and far‐field processes affect remineralization at 40°S, but their relative contributions cannot yet be precisely quantified [ABSTRACT FROM AUTHOR]

Lipid remodeling, the modification of cell membrane chemistry via structural rearrangements within the lipid pool of an organism, is a common physiological response amongst all domains of life to alleviate environmental stress and maintain cellular homeostasis. Whereas culture experiments and environmental studies of phytoplankton have demonstrated the plasticity of lipids in response to specific abiotic stressors, few analyses have explored the impacts of multi-environmental stressors at the community-level scale. Here, we study changes in the pool of intact polar lipids (IPLs) of a phytoplanktonic community exposed to multi-environmental stressors during a ∼ 2-month-long mesocosm experiment deployed in the eastern tropical South Pacific off the coast of Callao, Peru. We investigate lipid remodeling of IPLs in response to changing nutrient stoichiometries, temperature, pH, and light availability in surface and subsurface water masses with contrasting redox potentials, using multiple linear regressions, classification and regression trees, and random forest analyses. We observe proportional increases in certain glycolipids (namely mono- and diglycosyldiacylglycerol – MGDG and DGDG, respectively) associated with higher temperatures and oxic conditions, consistent with previous observations of their utility to compensate for thermal stress and their degradation under oxygen stress. N-bearing (i.e., betaine lipids and phosphatidylethanolamine – BLs and PE) and non-N-bearing (i.e., MGDG; phosphatidylglycerol, PG; and sulfoquinovosyldiacylglycerol, SQDG) IPLs are anti-correlated and have strong positive correlations with nitrogen-replete and nitrogen-depleted conditions, respectively, which suggests a substitution mechanism for N-bearing IPLs under nitrogen limitation. Reduced CO 2 (aq) availability and increased pH levels are associated with greater proportions of DGDG and SQDG IPLs, possibly in response to the lower concentration of CO 2 (aq) and the overall lower availability of inorganic carbon for fixation. A higher production of MGDG in surface waters corresponds well with its established photoprotective and antioxidant mechanisms in thylakoid membranes. The observed statistical relationships between IPL distributions, physicochemical parameters, and the composition of the phytoplankton community suggest evidence of lipid remodeling in response to environmental stressors. These physiological responses may allow phytoplankton to reallocate resources from structural or extrachloroplastic membrane lipids (i.e., phospholipids and betaine lipids) under high-growth conditions to thylakoid and/or plastid membrane lipids (i.e., glycolipids and certain phosphatidylglycerols) under growth-limiting conditions. Further investigation of the exact mechanisms controlling the observed trends in lipid distributions is necessary to better understand how membrane reorganization under multi-environmental stressors can affect the pools of cellular C, N, P, and S, as well as their fluxes to higher trophic levels in marine environments subjected to increasing environmental pressure. Our results suggest that future studies addressing the biogeochemical consequences of climate change in the eastern tropical South Pacific Ocean must take into consideration the impacts of lipid remodeling in phytoplankton. [ABSTRACT FROM AUTHOR]

The Gulf of St. Lawrence (GSL), along with the St. Lawrence Estuary, is the largest estuarine system in North America. It is a biologically productive sea and an important fishing ground in Canada. The objectives of this study are to determine how climate changes will affect primary production in the GSL and on the eastern Scotian Shelf, and to determine the drivers of the changes. We use a regional ocean model forced with downscaled output of the Max-Planck Institute Earth System Model to study the changes in net primary production under the climate change scenario of Representative Concentration Pathway 8.5 (RCP8.5). Results reveal a projected 13.4% decrease in annual primary production across the GSL system over the next 70 years. This decline primarily stems from reduced nutrient concentrations in the upper layer, despite the increase in nutrients supplied by rivers. Enhanced freshwater influx and ocean surface warming contribute to heightened stratification, that in turn reduce the vertical nutrient fluxes from deeper layers. This mechanism affects the upwelling of nutrient-rich water at the head of the Laurentian Channel in the Lower St. Lawrence Estuary, leading to a 22% reduction in the vertical nitrate flux in the future. Additionally, nutrient concentrations in the water masses entering the GSL at the Strait of Belle Isle and at Cabot Strait are also reduced. Due to declining sea-ice concentration, the phytoplankton bloom is expected to occur between 9 and 23 days earlier under a warmer climate, and last for up to 24 days longer, depending on the GSL subregions, compared to the historical period (2001-2020). Biological productivity at higher trophic levels, and thus fisheries productivity, could be negatively impacted under the RCP8.5 climate change scenario. [ABSTRACT FROM AUTHOR]

Introduction: Cold-water coral reefs form complex benthic habitats, supporting thousands of species. The broadscale environmental tolerances of reef-forming species such as Lophelia pertusa are well studied, but small-scale differences between different reef settings have received little attention so far. The controlling factors of thriving cold-water coral reefs and how these habitats differ in terms of framework extent, coral colony morphology, and associated fauna could reveal how these benthic ecosystems formand expand. Information on the natural range of environmental fluctuations could provide a better understanding of the resilience of such ecosystems towards environmental changes. Our study aimed to elaborate small-scale forces on local hydrodynamics and oceanographic parameters at two geographically close but contrasting reef sites in mid-Norway. Methods: We investigated natural fluctuations and the seasonal variability of environmental conditions of an inshore and an offshore Lophelia-dominated reef over an annual cycle by time series monitoring of physical properties by benthic landers and water sampling for biogeochemical variables using CTD casts. Results and discussion: The flow fields at the extensive reef on the offshore Sula Ridge and a bank reef at Nord-Leksa in a fjord-system differed regarding both short-term and seasonal levels. The inshore flow field was strong and tidally driven, whereas the offshore flow field was slower with large seasonal variability. The local flow regimes and the seasonal atmospheric forcing could explain the observed seasonality of the hydrographic variables and the observed inter-annual variability in biogeochemical variables. Comparison with a flow model showed that the natural short-term and seasonal variability are driven by small-scale forcing that is not represented in model analyses. These results suggest that local hydrodynamics together with sea-floor topography control the reef extent and the morphology of cold-water coral colonies. [ABSTRACT FROM AUTHOR]

The Arctic is one of the regions under the most dramatic climate change. Global warming has led to elevated freshwater inflow into the western Arctic Ocean and significantly altered nutrient structure and biogeochemical cycling. In this work, inorganic dissolved nutrients in the Chukchi Plateau (CP) and adjacent regions were investigated to further understand their characteristics and influencing factors. Results showed that relatively high nutrient concentrations occurred in the water masses with salinity >32 psu, especially there was a nutrient-rich layer influenced by Winter Pacific Water in the water column (15.10±1.96, 2.23±0.26, and 23.46±6.64 µmol/L for DIN, PO4 3- and Si(OH)4, respectively). Contrarily, lower nutrient concentrations occurred in the mixing water of the upper layer (1.76±1.04, 1.15±0.16 and 3.76±2.29 µmol/L for DIN, PO4 3- and Si(OH)4, respectively) with a low DIN/P ratio (1.44±0.59), suggesting DIN has become the potentially biological limiting factor. Furthermore, the freshening and deepening of the upper layer driven by the Beaufort Gyre has hindered the nutrient transport from underlying layer into the upper layer. A maximum chla was observed at 36-75 m water depth, and the phytoplankton biomass decreased from the western to the eastern CP, accompanied by a decreased contribution of micro-sized chla but an increased contribution of small-sized chla (74.0±0.1%). The phytoplankton resource use efficiency for DIN was estimated as (3.2±4.6)×10-3, which was primarily influenced by the physicochemical parameters of water and also largely regulated by the size structure of phytoplankton. [ABSTRACT FROM AUTHOR]

To understand the influence of the Fukushima accident on the Northwest Pacific, the distributions and transportations of 134Cs and 137Cs in the seawater in the Northwest Pacific in May and September 2015 were studied. The data showed that the Fukushima-derived 134Cs and 137Cs at some stations can still be distinguished from background level ~ 4 years later. On the whole, the activities of 137Cs and 134Cs in seawater were decreasing from May to Sep 2015. But the increased inventories and the surface activities of 137Cs imply that there has ever been an extra 137Cs from offshore water transported to this study area (from 31° N to 27° N, 145° E to 152.5° E) in May 2015. The average activities of 137Cs in subtropical gyre area in south of KE were the highest and the least were to the east of Luzon Strait in 2015. In vertical direction, 137Cs in subtropical gyre area were mainly distributed at 100 ~ 500 m layer and 137Cs only at 500 m layer in this area showed an increasing trend from May to Sep 2015 which reflects more 137Cs were still penetrating to deeper layer of 500 m from upper water. But they were almost not found below 1000 m layer. It was associated with the subsurface transport of radiocesiums by Northwest Pacific Mode Water (NPMW) and the diffusion of mesoscale eddy. Different distribution characteristics of 137Cs existed between north of KE and south of KE. The low-temperature-low-salinity water mass likely to be the first Oyashio Intrusion was the main factor that resulted in higher 137Cs appearing at the upper 100 m layers in north of KE. [ABSTRACT FROM AUTHOR]

The case of the deepwater redfish (Sebastes mentella) in the Gulf of St. Lawrence (GSL) is a compelling example of drastic fluctuations in annual recruitment strength, characteristic of spasmodic stocks. After three decades of low abundance, the emergence of three consecutive strong year classes in 2011–2013 resulted in an unprecedented increase in biomass. In spasmodic stocks such as GSL redfish, strong year classes sustain both the biomass and catch for decades. Therefore, understanding the growth dynamics of these cohorts is essential. In the present study, we reconstructed the annual growth rates of redfish using otolith increment‐based annual chronology and investigated the drivers of growth variation in redfish strong year classes of the early 2010s and early 1980s. Stock biomass was identified as the main extrinsic driver of redfish growth, suggesting intense competition for food at high conspecific density. Warming of deep waters in the GSL, where adult redfish settle, positively correlated with individual growth. However, recent warming of the cold intermediate layer showed a negative correlation with redfish growth, likely related to the shrinking of the habitat this water mass provides for various redfish cold‐water prey rather than to a direct effect of temperature. Reconstruction of redfish annual growth trajectories from birth to capture emphasized the importance of carryover effects in the growth potential of strong year classes. This work provided an important first outlook of the factors driving growth variation in GSL redfish spasmodic stock and explored midterm consequences of density‐dependent pressures on biological parameters of the population. [ABSTRACT FROM AUTHOR]

This work aimed to characterize a dedicated phantom for assessing the dose near metal implants for radiotherapy with photons and protons. A dosimetry audit phantom was redesigned to position a Gafchromic EBT-3 film within a bisected titanium pedicle screw (6.5 mm diameter). The mass density and the water equivalent thickness (WET) of the phantom material were determined. The phantom was irradiated using a photon arc and a horizontal proton beam in combination with a couch rotation of 20°, with three repeated measurements each. Treatment plans utilizing a single field covering the screw and the EBT-3 film were optimized to deliver a physical dose of 2 Gy using a collapsed cone and Monte Carlo dose engine for photons and protons, respectively. The mass density and the WET of the phantom were determined as (1.033 ± 0.010) gcm-3 and (1.022 ± 0.013), respectively. Ionisation chamber measurements agreed within 1% (photons) and 0.5% (protons) with the calculated dose values. Relative photon dosimetry measurements using EBT-3 films revealed an agreement between measured and calculated horizontal profiles within the confidence interval for areas beyond 5 mm from the center. For photon plans, significant deviations of more than 10% were found at the interfaces between phantom material and screw. The proton measurements showed a gradual decrease of 3% across both profiles. In contrast to photon plans, no dose increase was measured within the screw, but significant dose fluctuations (>5%) in the beam's exit region. This study showed that the behavior of dose engine is affected by metal implants and thus dosimetric measurements are highly recommended. The presented phantom can serve as foundation for dedicated end-2-end phantoms. [ABSTRACT FROM AUTHOR]

We propose interpreting the vertical structure of waters not only in space but also over time, taking into account the continuous variability of the ocean and the independence of temperature and salinity parameters. This approach allows us to consider, in real conditions, the entire spectrum of short- and long-term extrema of both characteristics, either separately or together at the same depth. Vertical distributions of temperature and salinity transform separately and independently of each other under the influence of heat and freshwater budgets, which change at different time scales. Each of the parameters has its own active layers with corresponding time scales. Changes in the signs of heat and freshwater budgets and subsequent changes in the characteristics of the surface layer cause the appearance and disappearance of separate extrema of temperature and salinity in the water column. Using a salinity field as an example, we have shown that each of the extrema, in their vertical distribution from the near-surface to the intermediate depths, is a temporary phenomenon with various lifetime scales and is located at the lower boundary of the corresponding active layers. In some areas of the ocean, temperature and salinity extrema exist together at the same depth. Volumes of water with such characteristics and explicit boundaries should be considered water masses. [ABSTRACT FROM AUTHOR]

The Indonesian seas, with their complex passages and vigorous mixing, constitute the only route and are critical in regulating Pacific–Indian Ocean interchange, air–sea interaction, and global climate events. Previous research employing remote sensing and numerical simulations strongly suggested that this mixing is tidally driven and localized in narrow channels and straits, with only a few direct observations to validate it. The current study offers the first comprehensive temporal microstructure observations in the south of Lombok Strait with a radius of 0.05° and centered on 115.54oE and 9.02oS. Fifteen days of tidal mixing observations measured potential temperature and density, salinity, and turbulent energy dissipation rate. The results revealed significant mixing and verified the remotely sensed technique. The south Lombok temporal and depth averaged of the turbulent kinetic energy dissipation rate, and the diapycnal diffusivity from 20 to 250 m are ε = 4.15 ± 15.9) × 10–6 W kg–1 and K ρ = (1.44 ± 10.7) × 10–2 m2s–1, respectively. This K ρ is up to 104 times larger than the Banda Sea [ K ρ = (9.2 ± 0.55) × 10–6 m2s–1] (Alford et al. Geophys Res Lett 26:2741–2744, 1999) or the "open ocean" K ρ = 0.03 × 10–4 m2s−1 within 2° of the equator to (0.4–0.5) × 10–4 m2s−1 at 50°–70° (Kunze et al. J Phys Oceanogr 36:1553–1576, 2006). Therefore, nonlinear interactions between internal tides, tidally induced mixing, and ITF plays a critical role regulating water mass transformation and have strong implications to longer-term variations and change of Pacific–Indian Ocean water circulation and climate. [ABSTRACT FROM AUTHOR]

The Atlantic inventory of anthropogenic carbon (Cant) and its changes between 1990 and 2020 are investigated by applying the transit time distribution (TTD) method to anthropogenic tracer data. In contrast to previous TTD applications, here we take into account the admixture of old waters free of anthropogenic tracers. The greatest difference from other methods based on direct carbon observations is the higher Cant storage in the deep ocean. Estimations of the decadal Cant increase based on direct carbon observations yield in general a smaller share of Cant storage in the North Atlantic and a larger share in the South Atlantic compared to our results. Changes in oceanic circulation and/or ventilation have significant impacts on the Cant inventory on the regional scale. The enhanced upwelling of older water in the Southern Ocean and the variability in the convection depth in the Labrador Sea lead to deviations in the inferred Cant increase between 1990 and 2020 from the rate equivalent to a steady-state ocean. For the total Atlantic Cant inventory, however, decadal ventilation variability of individual water masses partially compensates for each other. In addition, its impact on the Cant storage is small due to the much higher flushing time for the whole Atlantic of the order of hundreds of years. The total Cant inventory increases from 43.0 ± 7.3 Pg C in 1990 to 68.2 ± 10.8 Pg C in 2020, almost in unison with the rising CO2 in the atmosphere. So far, ventilation changes have impacted the Cant concentrations only on the regional scale, especially in the subpolar North Atlantic and the Southern Ocean. [ABSTRACT FROM AUTHOR]

The ocean has absorbed anthropogenic carbon dioxide (Canthro) from the atmosphere and played an important role in mitigating global warming. However, how much Canthro is accumulated in coastal oceans and where it comes from have rarely been addressed with observational data. Here, we use a high-quality carbonate dataset (1996-2018) in the U.S. East Coast to address these questions. Our work shows that the offshore slope waters have the highest Canthro accumulation changes (ΔCanthro) consistent with water mass age and properties. From offshore to nearshore, ΔCanthro decreases with salinity to near zero in the subsurface, indicating no net increase in the export of Canthro from estuaries and wetlands. Excesses over the conservative mixing baseline also reveal an uptake of Canthro from the atmosphere within the shelf. Our analysis suggests that the continental shelf exports most of its absorbed Canthro from the atmosphere to the open ocean and acts as an essential pathway for global ocean Canthro storage and acidification. [ABSTRACT FROM AUTHOR]

The Permian Capitanian-Changhsingian black shale formed in intra-platform basins are the major source rocks in Southwest China. However, the depositional conditions and organic matter accumulation of these black shales are not well understood. In this study, geochemical characteristics comprise TOC, major, trace and REEs from sixty-two samples from the studied outcrop in Northern Nanpanjiang Basin, Southwest China are systematically investigated to determine silicon source, paleo-ocean productivity, and paleo-redox conditions to reveal their influence on organic matter enrichment under 3rd-order sequence. The Capitanian-Changhsingian black shale in the study area is the result of the combined effects of active extensional activity, high paleoproductivity maintained by volcanic activity, and dysoxic and anoxic conditions represented by biological extinction events. There are differences in the factors controlling organic matter accumulation in black shale at different stages. The controlling factors for the organic enrichment during Capitanian (SQ2) are the rapidly deepening water mass of extensional rifts and the high productivity induced by volcanic ash in the igneous provinces, as well as the global anoxic event represented by "negative carbon isotope shift." The controlling factors during Changhsingian are the deepening of water mass under the reactivation of extensional rifts, resulting in a dysoxic environment, and the high productivity maintained by volcanic activity in South China. The Wuchiapingian black shale was formed under dysoxic conditions under the stagnation of extensional activity, and intermittent volcanic activity in South China maintained the high paleo-productivity level of the Wuchiapingian stage. [ABSTRACT FROM AUTHOR]

AbstractLifestyle changes, such as poor eating habits and a reduction in physical exercise, have impaired human lipid profiles. Statins are widely used to treat dyslipidemias, of which rosuvastatin shows greater improvement in the lipid profile and may be used since childhood. This study aimed to assess the hepatic effects when male mice were given 0.9% saline solution or doses of rosuvastatin of 1.5 or 5.5 mg/kg/day from postnatal day (PND) 23 until PND 80. Body mass gain and water and food consumption were monitored during the treatment. Mice were euthanized on PND 80 when blood was collected for serum obtainment, and several organs were collected and weighed. Serum was used for evaluating lipid profiles and markers of hepatic injuries. The liver was assessed for histopathological, morphometric, and stereological changes. There was a temporary reduction in body mass gain and water and food consumption in the rosuvastatin-exposed groups. Both rosuvastatin-treated groups exhibited reduced total cholesterol levels and showed signs of hepatic tissue adaptation in response to prolonged exposure, such as sinusoidal dilation, inflammatory infiltrates, and cell death of hepatocytes. These results are considered side effects of the treatment and may indicate a hepatic adaptation to the chronic exposure. [ABSTRACT FROM AUTHOR]