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The availability of system comprising multiple cluster nodes in the case of CMF was studied.Firstly,contraposing to the system with two cluster nodes,two CTMC models for the step-by-step recovery mechanism and uniform resetting one were proposed respectively.Furthermore,the conclusion on the priority and inferiority comparison for related plans of different mechanisms was derived thereby.Moreover,its correctness was simulated and validated by stochastic reward nets tool.Additionally,the availability of system with n（n>2） cluster nodes was discussed.

Comprehensive Summary: Nitrenes, as neutral monovalent nitrogen‐centered molecular species, can insert into various bond or remove nitrogen atoms from amines. Nitrene assisted single‐atom skeletal editing, discovered decades ago, provides an efficient approach for the precise alteration of cyclic skeletons. In this review, we briefly summarize early studies on skeletal editing of cyclic frameworks involving nitrene species, and introduce several recent important advances systematically. [ABSTRACT FROM AUTHOR]

One of the primary candidate materials used in 650°C ultra-supercritical (USC) thermal power plant units is a novel thick grade of heat-resistant steel, 08Cr9W3Co3VNbCuBN (G115), for which China has complete intellectual property rights. In this study, G115 steel with a 115 mm thick wall was successfully welded using gas tungsten arc welding (GTAW) + shielded metal arc welding (SWAM), which was a significant step toward achieving its application in large-diameter boiler tubes. The influence of the welding process on the microstructure and mechanical properties of the G115 welded joint after post-weld heat treatment (PWHT) at 770°C for 11 h was investigated. The findings demonstrate that the weld zone (WZ) after PWHT was composed of martensite and ferrite, and M23C6 was the precipitate. The average hardness of WZ was 273.1 HV, and the average impact toughness was above 39J, which was sufficient for actual production applications. It offered the necessary theoretical foundation for the practical development of thick-walled G115 heat-resistant alloy steel during welding. [ABSTRACT FROM AUTHOR]

A Cu/CPA co‐catalytic system has been developed for achieving the direct hydrophosphinylation of alkynes with phosphine oxides in delivering novel axially chiral phosphorus‐containing alkenes in high yields and excellent enantioselectivities (up to 99 % yield and 99 % ee). DFT calculations were performed to elucidate the reaction pathway and the origin of enantiocontrol. This streamlined and modular methodology establishes a new platform for the design and application of new axially chiral styrene‐phosphine ligands. [ABSTRACT FROM AUTHOR]