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The optically trapped ensembles of atoms provide a versatile platform for storing and coherent manipulation of quantum information. However, efficient realization of quantum information processing requires long-lived quantum states protected from the decoherence e.g. via spontaneous emission. Here, we theoretically study collective dipolar oscillations in finite planar arrays of quantum emitters in free space and analyze mechanisms that govern the emergence of strongly subradiant collective states. We demonstrate that the external coupling between the collective states associated with the symmetry of the array and with the quasi-flat dispersion of the corresponding infinite lattice plays a crucial role in the boost of their radiative lifetime. We show that among different regular arrangements of the atoms the square atomic arrays support eigenstates with minimal radiative losses ∝Ntot−5 $\propto {N}_{\text{tot}}^{-5}$ scaled with the total number of atoms N tot.

Suppressing the spontaneous emission in quantum emitters ensembles (atoms) is one of the topical problems in quantum optics and quantum technology. While many approaches are based on utilizing the subradiance effect in ordered quantum emitters arrays, the ensemble configurations providing the minimal spontaneous emission rate are yet unknown. In this work, we employ the differential evolution algorithm to identify the optimal configurations of a few atomic ensembles that support quantum states with maximal radiative lifetime. We demonstrate that atoms tend to assemble mostly in quasi-regular structures with specific geometry, which strongly depends on the minimally allowed interatomic distance r min . While the discovered specific non-radiative realizations of small ensembles cannot be immediately predicted, there is particular correspondence to the non-radiative states in the atomic lattices. In particular, we have found that states inheriting their properties either from the bound states in the continuum or band edge states of infinite lattices dominate across a wide range of r min values. Additionally, we show that for small interatomic distances, the linear arrays with modulated spacing have the smallest radiative losses exponentially decreasing as the size of the ensemble increases. [ABSTRACT FROM AUTHOR]

New hybrid materials based on Ag nanoparticles stabilized by a polyaminopropylalkoxysiloxane hyperbranched polymer matrix were prepared. The Ag nanoparticles were synthesized in 2-propanol by metal vapor synthesis (MVS) and incorporated into the polymer matrix using metal-containing organosol. MVS is based on the interaction of extremely reactive atomic metals formed by evaporation in high vacuum (10−4–10−5 Torr) with organic substances during their co-condensation on the cooled walls of a reaction vessel. Polyaminopropylsiloxanes with hyperbranched molecular architectures were obtained in the process of heterofunctional polycondensation of the corresponding AB2-type monosodiumoxoorganodialkoxysilanes derived from the commercially available aminopropyltrialkoxysilanes. The nanocomposites were characterized using transmission (TEM) and scanning (SEM) electron microscopy, X-ray photoelectron spectroscopy (XPS), powder X-ray diffraction (PXRD) and Fourier-transform infrared spectroscopy (FTIR). TEM images show that Ag nanoparticles stabilized in the polymer matrix have an average size of 5.3 nm. In the Ag-containing composite, the metal nanoparticles have a "core-shell" structure, in which the "core" and "shell" represent the M0 and Mδ+ states, respectively. Nanocomposites based on silver nanoparticles stabilized with amine-containing polyorganosiloxane polymers showed antimicrobial activity against Bacillus subtilis and Escherichia coli. [ABSTRACT FROM AUTHOR]

Chromatin insulators are special regulatory elements involved in modulation of enhancer-promoter interactions. The best studied insulators in Drosophila require Suppressor of Hairy Wing [Su(Hw)], Modifier of mdg4 [Mod(mdg4)] and centrosomal 190 kDa (CP190) proteins to be functional. These insulator proteins are colocalized in nuclear speckles named insulator bodies. Here, we demonstrate that post-translational modification of insulator proteins by small ubiquitin-like modifier (SUMO) and intact CP190 protein is crucial for insulator body formation. Inactivation of SUMO binding sites in Mod(mdg4)-67.2 leads to the inability of the mutant protein and Su(Hw) to be assembled into insulator bodies. In vivo functional tests show that a smaller amount of intact Mod(mdg4)-67.2, compared with the mutant protein, is required to restore the normal activity of the Su(Hw) insulator. However, high expression of mutant Mod(mdg4)-67.2 completely rescues the insulator activity, indicating that sumoylation is not necessary for enhancer blocking. These results suggest that insulator bodies function as a depot of sumoylated proteins that are involved in insulation and can facilitate insulator complex formation, but are nonessential for insulator action. [ABSTRACT FROM AUTHOR]

Au/Al2O3 and Ni/Al2O3 prepared by deposition-precipitation and impregnation methods, respectively, and Au–Ni/Al2O3 prepared by impregnation of the Au/Al2O3 system with nickel have been studied by physicochemical methods. The catalysts were tested in allylbenzene isomerization at 443 K. The isomerization on Au/Al2O3 proceeds with a rather low rate, while monometallic Ni/Al2O3 is inactive. Unlike monometallic catalysts, Au–Ni/Al2O3 demonstrates a strong synergetic effect: the isomerization rate on the bimetallic sample exceeds the sum of the rates over the individual metals by an order of magnitude. The catalysts structure was estimated by XPS, DRIFT, and XAS techniques. It was revealed that nickel in Au–Ni/Al2O3 and Ni/Al2O3 exist as Ni2+ cations with the coordination state close to that in the precursor, gold in Au/Al2O3 exist as Au0 nanoclusters, whereas the Au0 nanoclusters co-exist with Au3+ cations in the bimetallic Au–Ni/Al2O3 sample. Reasons of the synergetic catalytic effect for Au–Ni/Al2O3 are discussed in terms of the formation of new positively charged Au catalytic centers. [ABSTRACT FROM AUTHOR]