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In this paper, we present a new experimental apparatus for the measurement of the detection efficiency of free-space single-photon detectors based on the substitution method. For the first time, we extend the analysis to account for the wavelength dependence introduced by the transmissivity of the optical window in front of the detector's active area. Our method involves measuring the detector's response at different wavelengths and comparing it to a calibrated reference detector. This allows us to accurately quantify the efficiency variations due to the optical window's transmissivity. The results provide a comprehensive understanding of the wavelength-dependent efficiency, which is crucial for optimizing the performance of single-photon detectors in various applications, including quantum communication and photonics research. This characterization technique offers a significant advancement in the precision and reliability of single-photon detection efficiency measurements.

The impact of noise sources in real-world implementations of Twin-Field Quantum Key Distribution (TF-QKD) protocols is investigated, focusing on phase noise from photon sources and connecting fibers. This work emphasizes the role of laser quality, network topology, fiber length, arm balance, and detector performance in determining key rates. Remarkably, it reveals that the leading TF-QKD protocols are similarly affected by phase noise despite different mechanisms. This study demonstrates duty cycle improvements of over a factor of two through narrow-linewidth lasers and phase-control techniques, highlighting the potential synergy with high-precision time/frequency distribution services. Ultrastable lasers, evolving toward integration and miniaturization, offer promise for agile TF-QKD implementations on existing networks. Properly addressing phase noise and practical constraints allows for consistent key rate predictions, protocol selection, and layout design, crucial for establishing secure long-haul links for the Quantum Communication Infrastructures under development in several countries., Comment: 20 pages, 8 figures, 3 tables. Post-print version

Bell inequalities are one of the cornerstones of quantum foundations, and fundamental tools for quantum technologies. Recently, the scientific community worldwide has put a lot of effort towards them, which culminated with loophole-free experiments. Nonetheless, none of the experimental tests so far was able to extract information on the full inequality from each entangled pair, since the wave function collapse forbids performing, on the same quantum state, all the measurements needed for evaluating the entire Bell parameter. We present here the first single-pair Bell inequality test, able to obtain a Bell parameter value for every entangled pair detected. This is made possible by exploiting sequential weak measurements, allowing to measure non-commuting observables in sequence on the same state, on each entangled particle. Such an approach not only grants unprecedented measurement capability, but also removes the need to choose between different measurement bases, intrinsically eliminating the freedom-of-choice loophole and stretching the concept of counterfactual-definiteness (since it allows measuring in the otherwise not-chosen bases). We also demonstrate how, after the Bell parameter measurement, the pair under test still presents a noteworthy amount of entanglement, providing evidence of the absence of (complete) wave function collapse and allowing to exploit this quantum resource for further protocols., Comment: 14 pages, 3 figures

We propose and experimentally demonstrate a general method allowing us to unravel microscopic noise events that affect a continuous quantum variable. Such unraveling is achieved by frequent measurements of a discrete variable coupled to the continuous one. The experimental realization involves photons traversing a noisy channel. There, their polarization, whose coupling to the photons spatial wavepacket is subjected to stochastic noise, is frequently measured in the quantum Zeno regime. The measurements not only preserve the polarization state, but also enable the recording of the full noise statistics from the spatially-resolved detection of the photons emerging from the channel. This method proves the possibility of employing photons as quantum noise sensors and robust carriers of information., Comment: 6 pages, 3 figures

We show that, by utilising temporal quantum correlations as expressed by pseudo-density operators (PDOs), it is possible to recover formally the standard quantum dynamical evolution as a sequence of teleportations in time. We demonstrate that any completely positive evolution can be formally reconstructed by teleportation with different temporally correlated states. This provides a different interpretation of maximally correlated PDOs, as resources to induce quantum time-evolution. Furthermore, we note that the possibility of this protocol stems from the strict formal correspondence between spatial and temporal entanglement in quantum theory. We proceed to demonstrate experimentally this correspondence, by showing a multipartite violation of generalised temporal and spatial Bell inequalities and verifying agreement with theoretical predictions to a high degree of accuracy, in high-quality photon qubits., Comment: preprint

We experimentally demonstrate, for the first time, noise diagnostics by repeated quantum measurements. Specifically, we establish the ability of a single photon, subjected to random polarisation noise, to diagnose non-Markovian temporal correlations of such a noise process. In the frequency domain, these noise correlations correspond to colored noise spectra, as opposed to the ones related to Markovian, white noise. Both the noise spectrum and its corresponding temporal correlations are diagnosed by probing the photon by means of frequent, (partially-)selective polarisation measurements. Our main result is the experimental demonstration that noise with positive temporal correlations corresponds to our single photon undergoing a dynamical regime enabled by the quantum Zeno effect (QZE), while noise characterized by negative (anti-) correlations corresponds to regimes associated with the anti-Zeno effect (AZE). This demonstration opens the way to a new kind of noise spectroscopy based on QZE and AZE in photon (or other single-particle) state probing.

Quantum mechanics allows the distribution of intrinsically secure encryption keys by optical means. Twin-field quantum key distribution is the most promising technique for its implementation on long-distance fibers, but requires stabilizing the optical length of the communication channels between parties. In proof-of-principle experiments based on spooled fibers, this was achieved by interleaving the quantum communication with periodical adjustment frames. In this approach, longer duty cycles for the key streaming come at the cost of a looser control of channel length, and a successful key-transfer using this technique in a real world remains a significant challenge. Using interferometry techniques derived from frequency metrology, we developed a solution for the simultaneous key streaming and channel length control, and demonstrate it on a 206 km field-deployed fiber with 65 dB loss. Our technique reduces the quantum-bit-error-rate contributed by channel length variations to <1%, representing an effective solution for real-world quantum communications.

Recently, the fast development of quantum technologies led to the need for tools allowing the characterization of quantum resources. In particular, the ability to estimate non-classical aspects, e.g. entanglement and quantum discord, in two-qubit systems, is relevant to optimise the performance of quantum information processes. Here we present an experiment in which the amount of entanglement and discord are measured exploiting different estimators. Among them, some will prove to be optimal, i.e., able to reach the ultimate precision bound allowed by quantum mechanics. These estimation techniques have been tested with a specific family of states ranging from nearly pure Bell states to completely mixed states. This work represents a significant step in the development of reliable metrological tools for quantum technologies.