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Controlling the adverse effects of global warming on human communities requires reducing carbon dioxide emissions and developing clean energy resources. Fossil fuel overuse damages the environment and raises sustainability concerns. As a resource-rich element, cobalt oxide hybrids have attracted considerable attention as low-priced and eco-friendly electrocatalysts. Alkaline solutions disperse Co 3 O 4 easily despite its highly stable nature, which arises from the reverse spinel structures of Co. Metal oxides, nickel foam, polymeric frameworks, and carbon nanotubes have been successfully served to combine with the Co 3 O 4 constructions for improving the electrocatalytic performance. To date, no comprehensive study has systematically investigated the relation between the cobalt oxide hybrid's physicochemical-electronic aspects and its catalytic features. This review mainly focuses on material design, fabrication, morphology, structural characteristics, and electroactivity, considering the critical factors towards practical applications. The economic impacts of the constructions and their expected contribution to large-scale utilizations are also demonstrated. Moreover, this research discusses the synergistic effects of crucial electrochemical parameters on sustainable energy production over the Co 3 O 4 -based hybrids. Finally, some beneficial conclusive suggestions are made based on emerging factors for real-world application. Future research in the field aiming at developing sustainable and clean energy production technologies can effectively benefit from the findings of this report., (© 2024 The Chemical Society of Japan and Wiley-VCH GmbH.)

In order to prepare self-standing and flexible slow neutron reflectors made of graphite fluoride (GF) with high contents of (C 2 F) n structural phase, graphite foils of different thicknesses were used as starting materials for gas (F 2 )/solid fluorination. The maximal interlayer distance of GF was obtained with this phase thanks to the stacking sequence FCCF/FCCF; this is mandatory for the efficient reflection of slow neutrons. 71 and 77% of the (C 2 F) n phase were achieved for graphite foils with thicknesses of 1.0 and 0.1 mm, respectively. The interlayer distances were 8.6 Å as expected. The fluorination conditions (static mode, a long duration of 24 h, annealing in pure F 2 gas for 24 h, and temperatures in the 390-460 °C range) were adapted to large pieces of graphite foils (7 × 7 cm 2 ) in order to both avoid exfoliation and achieve a homogeneous dispersion of fluorine atoms. This process was also efficient for thinner (0.01 mm thick) graphitized graphene oxide foil. 56% of the (C 2 F) n phase and an interlayer of 8.6 Å were achieved for this foil when fluorination was performed at 430 °C. Whatever the nature and the thickness of the foil, their flexibilities are maintained.

Researchers are increasingly focusing on using biomass waste for green synthesis of nanostructured materials since green reducing, capping, stabilizing and orientation agents play a significant role in final application. Wheat peel extract contains a rich source of reducing and structure orienting agents that are not utilized for morphological transformation of NiO nanostructures. Our study focuses on the role of wheat peel extract in morphological transformation during the synthesis of NiO nanostructures as well as in non-enzymatic electrochemical urea sensing. It was observed that the morphological transformation of NiO flakes into nanoplatelets took place in the presence of wheat peel extract during the preparation of NiO nanostructures and that both the lateral size and thickness of the nanostructures were significantly reduced. Wheat peel extract was also found to reduce the optical band gap of NiO. A NiO nanostructure prepared with 5 mL of wheat peel extract (sample 2) was highly efficient for the detection of urea without the use of urease enzyme. It has been demonstrated that the induced modification of NiO nanoplatelets through the use of structure-orienting agents in the wheat peel has enhanced their electrochemical performance. A linear range of 0.1 mM to 13 mM was achieved with a detection limit of 0.003 mM in the proposed urea sensor. The performance of the presented non-enzymatic urea sensor was evaluated in terms of selectivity, stability, reproducibility, and practical application, and the results were highly satisfactory. As a result of the high surface active sites on sample 2, the low charge transfer resistance, as well as the high exposure to the surface active sites of wheat peel extract, sample 2 demonstrated enhanced performance. The wheat peel extract could be used for the green synthesis of a wide range of nanostructured materials, particularly metal/metal oxides for various electrochemical applications., Competing Interests: Authors have no conflict of interest in the presented research work., (This journal is © The Royal Society of Chemistry.)

The ability to measure uric acid (UA) non-enzymatically in human blood has been demonstrated through the use of a simple and efficient electrochemical method. A phytochemical extract from radish white peel extract improved the electrocatalytic performance of nickel-cobalt bimetallic oxide (NiCo 2 O 4 ) during a hydrothermal process through abundant surface holes of oxides, an alteration of morphology, an excellent crystal quality, and increased Co(III) and Ni(II) chemical states. The surface structure, morphology, crystalline quality, and chemical composition were determined using a variety of analytical techniques, including powder X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HR-TEM), and X-ray photoelectron spectroscopy (XPS). The electrochemical characterization by CV revealed a linear range of UA from 0.1 mM to 8 mM, with a detection limit of 0.005 mM and a limit of quantification (LOQ) of 0.008 mM. A study of the sensitivity of NiCo 2 O 4 nanostructures modified on the surface to UA detection with amperometry has revealed a linear range from 0.1 mM to 4 mM for detection. High stability, repeatability, and selectivity were associated with the enhanced electrochemical performance of non-enzymatic UA sensing. A significant contribution to the full outperforming sensing characterization can be attributed to the tailoring of surface properties of NiCo 2 O 4 nanostructures. EIS analysis revealed a low charge-transfer resistance of 114,970 Ohms that offered NiCo 2 O 4 nanostructures prepared with 5 mL of radish white peel extract, confirming an enhanced performance of the presented non-enzymatic UA sensor. As well as testing the practicality of the UA sensor, blood samples from human beings were also tested for UA. Due to its high sensitivity, stability, selectivity, repeatability, and simplicity, the developed non-enzymatic UA sensor is ideal for monitoring UA for a wide range of concentrations in biological matrixes.

Recently, the nanostructured nickel-cobalt bimetallic oxide (NiCo 2 O 4 ) material with high electrochemical activity has received intensive attention. Beside this, the biomass assisted synthesis of NiCo 2 O 4 is gaining popularity due to its advantageous features such as being low cost, simplicity, minimal use of toxic chemicals, and environment-friendly and ecofriendly nature. The electrochemical activity of spinel NiCo 2 O 4 is associated with its mixed metal oxidation states. Therefore, much attention has been paid to the crystal quality, morphology and tunable surface chemistry of NiCo 2 O 4 nanostructures. In this study, we have used citrus lemon juice consisting of a variety of chemical compounds having the properties of a stabilizing agent, capping agent and chelating agent. Moreover, the presence of several acidic chemical compounds in citrus lemon juice changed the pH of the growth solution and consequently we observed surface modified and structural changes that were found to be very effective for the development of energy conversion and energy storage systems. These naturally occurring compounds in citrus lemon juice played a dynamic role in transforming the nanorod morphology of NiCo 2 O 4 into small and well-packed nanoparticles. Hence, the prepared NiCo 2 O 4 nanostructures exhibited a new surface-oriented nanoparticle morphology, high concentration of defects on the surface (especially oxygen vacancies), sufficient ionic diffusion and reaction of electrolytic ions, enhanced electrical conductivity, and favorable reaction kinetics at the interface. The electrocatalytic properties of the NiCo 2 O 4 nanostructures were studied in oxygen evolution reaction (OER) at a low overpotential of 250 mV for 10 mA cm -2 , Tafel slope of 98 mV dec -1 , and durability of 40 h. Moreover, an asymmetric supercapacitor was produced and the obtained results indicated a high specific capacitance of ( C s ) of 1519.19 F g -1 , and energy density of 33.08 W h kg -1 at 0.8 A g -1 . The enhanced electrochemical performance could be attributed to the favorable structural changes, surface modification, and surface crystal facet exposure due to the use of citrus lemon juice. The proposed method of transformation of nanorod to nanoparticles could be used for the design of a new generation of efficient electrocatalyst materials for energy storage and conversion uses., Competing Interests: Authors declare no conflict of interest in this research work., (This journal is © The Royal Society of Chemistry.)

The electrochemical performance of NiCo 2 O 4 with urea precursors was evaluated in order to develop a non-enzymatic urea sensor. In this study, NiCo 2 O 4 nanostructures were synthesized hydrothermally at different concentrations of urea and characterized using scanning electron microscopy and X-ray diffraction. Nanostructures of NiCo 2 O 4 exhibit a nanorod-like morphology and a cubic phase crystal structure. Urea can be detected with high sensitivity through NiCo 2 O 4 nanostructures driven by urea precursors under alkaline conditions. A low limit of detection of 0.05 and an analytical range of 0.1 mM to 10 mM urea are provided. The concentration of 006 mM was determined by cyclic voltammetry. Chronoamperometry was used to determine the linear range in the range of 0.1 mM to 8 mM. Several analytical parameters were assessed, including selectivity, stability, and repeatability. NiCo 2 O 4 nanostructures can also be used to detect urea in various biological samples in a practical manner.

To cope with environmental pollution caused by toxic emissions into water streams, high-performance photocatalysts based on ZnO semiconductor materials are urgently needed. In this study, ZnO nanostructures are synthesized using leafy spinach extract using a biogenic approach. By using phytochemicals contained in spinach, ZnO nanorods are transformed into large clusters assembled with nanosheets with visible porous structures. Through X-ray diffraction, it has been demonstrated that leafy spinach extract prepared with ZnO is hexagonal in structure. Surface properties of ZnO were altered by using 10 mL, 20 mL, 30 mL, and 40 mL quantities of leafy spinach extract. The size of ZnO crystallites is typically 14 nanometers. In the presence of sunlight, ZnO nanostructures mineralized methylene blue. Studies investigated photocatalyst doses, dye concentrations, pH effects on dye solutions, and scavengers. The ZnO nanostructures prepared with 40 mL of leafy spinach extract outperformed the degradation efficiency of 99.9% for the MB since hydroxyl radicals were primarily responsible for degradation. During degradation, first-order kinetics were observed. Leafy spinach extract could be used to develop novel photocatalysts for the production of solar hydrogen and environmental hydrogen.

To determine urea accurately in clinical samples, food samples, dairy products, and agricultural samples, a new analytical method is required, and non-enzymatic methods are preferred due to their low cost and ease of use. In this study, bitter gourd peel biomass waste is utilized to modify and structurally transform nickel oxide (NiO) nanostructures during the low-temperature aqueous chemical growth method. As a result of the high concentration of phytochemicals, the surface was highly sensitive to urea oxidation under alkaline conditions of 0.1 M NaOH. We investigated the structure and shape of NiO nanostructures using powder X-ray diffraction (XRD) and scanning electron microscopy (SEM). In spite of their flake-like morphology and excellent crystal quality, NiO nanostructures exhibited cubic phases. An investigation of the effects of bitter gourd juice demonstrated that a large volume of juice produced thin flakes measuring 100 to 200 nanometers in diameter. We are able to detect urea concentrations between 1-9 mM with a detection limit of 0.02 mM using our urea sensor. Additionally, the stability, reproducibility, repeatability, and selectivity of the sensor were examined. A variety of real samples, including milk, blood, urine, wheat flour, and curd, were used to test the non-enzymatic urea sensors. These real samples demonstrated the potential of the electrode device for measuring urea in a routine manner. It is noteworthy that bitter gourd contains phytochemicals that are capable of altering surfaces and activating catalytic reactions. In this way, new materials can be developed for a wide range of applications, including biomedicine, energy production, and environmental protection.

The surface tailored metal oxide nanostructures for the development of non-enzymatic sensors are highly demanded, but it is a big task due to the wide range of complexities during the growth process. The presented study focused on the surface modification of the heterogeneous morphology of cobalt oxide (Co 3 O 4 ) prepared by the hydrothermal method. Further surface modification was conducted with the use of sodium citrate as a reducing and surface modifying agent for the Co 3 O 4 nanostructures through the high density of oxygenated terminal groups from the citrate ions. The citrate ions enabled a significant surface modification of the Co 3 O 4 nanostructures, which further improved the electrochemical properties of the Co 3 O 4 material toward the design of the non-enzymatic ascorbic acid sensor in a phosphate buffer solution of pH 7.4. The morphology and crystal arrays of the Co 3 O 4 nanostructures were studied by scanning electron microscopy (SEM) and powder X-ray diffraction (XRD) techniques. These physical characterizations showed the highly tailored surface features of Co 3 O 4 nanostructures and a significant impact on the crystal properties. The electrochemical activity of Co 3 O 4 was studied by chronoamperometry, linear sweep voltammetry, and cyclic voltammetry (CV) for the detection of ascorbic acid. The linear range of the proposed sensor was measured from 0.5 mM to 6.5 mM and a low limit of detection of 0.001 mM was also estimated. The presented Co 3 O 4 nanostructures exhibited significant surface roughness and surface area, consequently playing a vital role toward the selective, sensitive, and stable detection of ascorbic acid. The use of a low cost surface modifying agent such as sodium citrate could be of great interest for the surface roughness and high surface area of nanostructured materials for the improved electrochemical properties for the biomedical, energy storage, and conversion systems.

In this study, we have prepared cobalt selenide (CoSe 2 ) due to its useful aspects from a catalysis point of view such as abundant active sites from Se edges, and significant stability in alkaline conditions. CoSe 2 , however, has yet to prove its functionality, so we doped palladium oxide (PdO) onto CoSe 2 nanostructures using ultraviolet (UV) light, resulting in an efficient and stable water oxidation composite. The crystal arrays, morphology, and chemical composition of the surface were studied using a variety of characterization techniques, including X-ray diffraction (XRD), scanning electron microscopy (SEM), high resolution transmission electron microscopy (HRTEM), X-ray photoelectron spectroscopy (XPS), and Fourier transform infrared (FTIR) spectroscopy. It was also demonstrated that the composite systems were heterogeneous in their morphology, undergoing a shift in their diffraction patterns, suffering from a variety of metal oxidation states and surface defects. The water oxidation was verified by a low overpotential of 260 mV at a current density of 20 mA cm -2 with a Tafel Slope value of 57 mV dec -1 . The presence of multi metal oxidation states, rich surface edges of Se and favorable charge transport played a leading role towards water oxidation with a low energy demand. Furthermore, 48 h of durability is associated with the composite system. With the use of PdO and CoSe 2 , new, low efficiency, simple electrocatalysts for water catalysis have been developed, enabling the development of practical energy conversion and storage systems. This is an excellent alternative approach for fostering growth in the field., Competing Interests: All authors declare no conflict of interest in this research work., (This journal is © The Royal Society of Chemistry.)

In this study, chloride (Cl−) ions were successfully doped into ZnO nanostructures by the solvothermal method. The effect of various Cl− concentrations on the photocatalytic activity of ZnO towards the photodegradation of methylene blue (MB) under the illumination of ultraviolet light was studied. The as-prepared Cl−-doped ZnO nanostructures were analyzed in terms of morphology, structure, composition and optical properties. XRD data revealed an average crystallite size of 23 nm, and the XRD patterns were assigned to the wurtzite structure of ZnO even after doping with Cl−. Importantly, the optical band gap of various Cl ion-doped ZnO nanostructures was successively reduced from 3.42 to 3.16 eV. The photodegradation efficiency of various Cl− ion-doped ZnO nanostructures was studied for MB in aqueous solution, and the relative performance of each Cl ion-doped ZnO sample was as follows: 20% Cl−-doped ZnO > 15% Cl−-doped ZnO > 10% Cl−-doped ZnO > 5% Cl−-doped ZnO > pristine ZnO. Furthermore, the correlation of the pH of the MB solution and each Cl ion dopant concentration was also investigated. The combined results of varying dopant levels and the effect of the pH of the MB solution on the photodegradation process verified the crucial role of Cl− ions in activating the degradation kinetics of MB. Therefore, these newly developed photocatalysts could be considered as alternative materials for practical applications such as wastewater treatment.

In this study, we have investigated the role of natural dead sea sponge (DSS, Porifera) as a three-dimensional (3D) porous host substrate for the immobilization of nanostructured ZnO material towards the development of ZnO based floating photocatalysts for efficient removal of methylene blue (MB) dye under the illumination of sunlight. After photodegradation, the treated water after dye degradation contains several pathogens, different disinfectants or chemical reagents that are essentially used. This is not the case for DSS as it can naturally kill any pathogens during the wastewater treatment process. To explore these functions, ZnO nanosheets were incorporated onto DSS via hydrothermal protocol and the as prepared ZnO/DSS hybrid material exhibited approximately ∼100% degradation efficiency for the removal of MB. Importantly, the degradation kinetics associated with the fabricated ZnO/DSS was remarkably accelerated as evidenced by the high values of degradation reaction rate constants (3.35 × 10 -2 min -1 ). The outperformance of ZnO/DSS could be attributed to the adsorption caused by its 3D porous structure together with the high rapid oxidation of MB. Furthermore, the high charge separation of electron-hole pairs, natural porosity, and abundant catalytic sites offered by the hybrid ZnO/DSS floating photocatalyst have enabled quantitative (∼100%) degradation efficiency for MB. Finally, the excellent reusability results confirm the feasibility of using natural ZnO/DSS-based photocatalyst for practical solution of wastewater treatment and other environmental problems., (© 2022 IOP Publishing Ltd.)

In this study, we synthesized hybrid systems based on manganese oxide@zinc oxide (Mn 3 O 4 @ZnO), using sol gel and hydrothermal methods. The hybrid materials exhibited hierarchical morphologies and structures characterized by the hexagonal phase of ZnO and the tetragonal phase of Mn 3 O 4 . The hybrid materials were tested for degradation of methylene blue (MB), methyl orange (MO), and malachite green (MG) under ultraviolet (UV) light illumination. The aim of this work was to observe the effect of various amounts of Mn 3 O 4 in enhancing the photocatalytic properties of ZnO-based hybrid structures towards the degradation of MB, MO and MG. The ZnO photocatalyst showed better performance with an increasing amount of Mn 3 O 4 , and the degradation efficiency for the hybrid material containing the maximum amount of Mn 3 O 4 was found to be 94.59%, 89.99%, and 97.40% for MB, MO and MG, respectively. The improvement in the performance of hybrid materials can be attributed to the high charge separation rate of electron-hole pairs, the co-catalytic role, the large number of catalytic sites, and the synergy for the production of high quantities of oxidizing radicals. The performance obtained from the various Mn 3 O 4 @ZnO hybrid materials suggest that Mn 3 O 4 can be considered an effective co-catalyst for a wide range of photocatalytic materials such as titanium dioxide, tin oxide, and carbon-based materials, in developing practical hybrid photocatalysts for the degradation of dyes and for wastewater treatment.

The present study demonstrates the crucial role of agave americana extract in enhancing the optical properties of zinc oxide (ZnO) through thermal treatment method. Various analytical and surface science techniques have been used to identify the morphology, crystalline structure, chemical composition, and optical properties, including scanning electron microscopy, x-ray diffraction, high resolution transmission electron microscopy (HRTEM), x-ray spectroscopy (EDS) and UV-visible spectroscopy techniques. The physical studies revealed the transformation of ZnO nanorods into nanosheets upon addition of an optimized amount of agave americana extract, which induced large amount of amorphous carbon deposited onto ZnO nanostructures as confirmed by HRTEM analysis. The use of increasing amount of americana extract has significantly reduced the average crystallite size of ZnO nanostructures. The resultant hybrid system of C@ZnO has produced a significant effect on the ultraviolet light-assisted photodegradation of malachite green (MG) dye. The photocatalyst dose was fixed at 10 mg for each study whereas the amount of agave americana extract and MG dye concentration are varied. The functionality of hybrid system was greatly enhanced when the amount of agave americana extract increased while dye concentration kept at lower level. Ultimately, almost 100% degradation efficiency was achieved via the prepared hybrid material, revealing combined contribution from synergy, stabilization of ZnO due to excess of carbon together with the high charge separation rate. The obtained results suggest that the driving role of agave americana extract for surface modification of photocatalyst can be considered for other nanostructured photocatalysts., (© 2022 IOP Publishing Ltd.)

The present study is focused on yogurt as a simple, inexpensive, abundant, and green source for the preparation of luminescent carbon material for enhancing the photodegradation of methylene blue (MB). It introduces an ecological and sustainable approach for the large-scale production of carbon material using the direct thermal annealing of yogurt in a muffle furnace. The size of the as-prepared carbon material is about 200-300 nm, with average particle size distribution of 355 nm. The material exhibits clear luminescence under illumination with ultraviolet light. The synthesized carbon material shows an outstanding degradation functionality of MB under the irradiation of ultraviolet (UV) light in aqueous media. Various dye degradation parameters such as initial dye concentration, catalyst dose, pH of dye solution, and scavenger effects have been investigated. The optimum MB concentration was found to be 2.3 × 10 -5 M with a degradation efficiency of 94.8%. The degradation was highly enhanced at pH 11 with a degradation efficiency of 98.11%. The degradation of MB under highly alkaline conditions was mainly governed by the high amount of hydroxyl radicals. Furthermore, the scavenger study confirmed that the hydroxyl radicals were mainly involved in the degradation process. The degradation kinetics of MB followed first order kinetics with large values of rate constant. The reusability was also studied to ensure the stability of the as-prepared carbon material during the degradation of MB. The preparation of carbon materials with efficient photosensitivity for the degradation of organic dyes from yogurt shows a green and innovative methodology. Therefore, it can be of great interest for future studies related to energy and environmental applications., Competing Interests: Authors declare no conflict of interest in this research work., (This journal is © The Royal Society of Chemistry.)

Metal-organic frameworks (MOFs) have been recently explored as crystalline solids for conversion into amorphous phases demonstrating non-specific mechanical, catalytic, and optical properties. The real-time control of such structural transformations and their outcomes still remain a challenge. Here, we use in situ high-resolution transmission electron microscopy with 0.01 s time resolution to explore non-thermal (electron induced) amorphization of a MOF single crystal, followed by transformation into an amorphous nanomaterial. By comparing a series of M -BTC ( M : Fe 3+ , Co 3+ , Co 2+ , Ni 2+ , and Cu 2+ ; BTC: 1,3,5-benzentricarboxylic acid), we demonstrate that the topology of a metal cluster of the parent MOFs determines the rate of formation and the chemistry of the resulting phases containing an intact ligand and metal or metal oxide nanoparticles. Confocal Raman and photoluminescence spectroscopies further confirm the integrity of the BTC ligand and coordination bond breaking, while high-resolution imaging with chemical and structural analysis over time allows for tracking the dynamics of solid-to-solid transformations. The revealed relationship between the initial and resulting structures and the stability of the obtained phase and its photoluminescence over time contribute to the design of new amorphous MOF-based optical nanomaterials.

In this study, we have used cotton silk as a source of abundant hydroxyl groups for the fast nucleation/growth of cobalt oxide (Co 3 O 4 ) nanowires via a hydrothermal method. The crystal planes of the Co 3 O 4 nanowires well matched the cubic phase. The as-synthesized Co 3 O 4 nanowires mainly contained cobalt and oxygen elements and were found to be highly sensitive towards uric acid in 0.01 M phosphate buffer solution at pH 7.4. Importantly, the Co 3 O 4 nanowires exhibited a large surface area, which was heavily utilized during the immobilization of the enzyme uricase via a physical adsorption method. The potentiometric response of the uricase-immobilizing Co 3 O 4 nanowires was measured in the presence of uric acid (UA) against a silver/silver chloride (Ag/AgCl) reference electrode. The newly fabricated uric acid biosensor possessed a low limit of detection of 1.0 ± 0.2 nM with a wide linear range of 5 nM to 10 mM and sensitivity of 30.6 mV dec -1 . Additionally, several related parameters of the developed uric acid biosensor were investigated, such as the repeatability, reproducibility, storage stability, selectivity, and dynamic response time, and these were found to be satisfactory. The good performance of the Co 3 O 4 nanowires was verified based on the fast charge-transfer kinetics, as confirmed via electrochemical impedance spectroscopy. The successful practical use of the uric acid biosensor was demonstrated based on the recovery method. The observed performance of the uricase-immobilizing Co 3 O 4 nanowires revealed that they could be considered as a promising and alternative tool for the detection of uric acid under both in vitro and in vivo conditions. Also, the use of cotton silk as a source of abundant hydroxyl groups may be considered for the remarkably fast nucleation/growth of other metal-oxide nanostructures, thereby facilitating the fabrication of functional electrochemical devices, such as batteries, water-splitting devices, and supercapacitors., Competing Interests: The authors declare that there are no conflicts of interest related to this research work., (This journal is © The Royal Society of Chemistry.)

Activation is commonly used to improve the surface and porosity of different kinds of carbon nanomaterials: activated carbon, carbon nanotubes, graphene, and carbon black. In this study, both physical and chemical activations are applied to graphene oxide by using CO 2 and KOH-based approaches, respectively. The structural and the chemical properties of the prepared activated graphene are deeply characterized by means of scanning electron microscopy, Raman spectroscopy, Fourier transform infrared spectroscopy, X-ray photoelectron spectrometry and nitrogen adsorption. Temperature activation is shown to be a key parameter leading to enhanced CO 2 adsorption capacity of the graphene oxide-based materials. The specific surface area is increased from 219.3 m 2 g -1 for starting graphene oxide to 762.5 and 1060.5 m 2 g -1 after physical and chemical activation, respectively. The performance of CO 2 adsorption is gradually enhanced with the activation temperature for both approaches: for the best performances of a factor of 6.5 and 9 for physical and chemical activation, respectively. The measured CO 2 capacities are of 27.2 mg g -1 and 38.9 mg g -1 for the physically and chemically activated graphene, respectively, at 25 °C and 1 bar.

Nanofluids which consist of nanoparticles added to conventional fluids (or base fluids) are considered as promising heat transfer fluids. Compared to metal, metal oxide nanoparticles and carbon nanotubes, graphene with its extremely high intrinsic thermal conductivity became the best candidate to design nanofluids. Such nanofluids have the potential to be highly-efficient heat transfer fluid by reducing loss of heat and increasing cooling rates. Over the last ten years, graphene-based nanofluids have shown significant thermal conductivity enhancements, however due to the numerous and interlinked parameters to consider, optimisation of their efficiency is still challenging. The present review article analyses and discusses the reported thermal conductivity in term of performance with respect to the amount of the used graphene to develop the prepared nanofluids. The enhancement of thermal conductivity must meet the minimal graphene amount due to its production cost and because graphene nanoparticles induces high viscosity in the nanofluid leading to higher energy consumption for the heat transfer systems. Unprecedented in the literature, this work proposes a simple approach to quantitatively compare the enhancement of the thermal conductivity of the nanofluids. The thermal conductivity performance parameter introduced could be applied to all nanofluid families and may become a reference tool in the nanofluid community. Such tool will help to determine the optimal preparation conditions without compromising the superior thermal performances., (Copyright © 2021 Elsevier B.V. All rights reserved.)