573 results on '"Vignoles P."'
Search Results
2. The Role of Cultural Heterogeneity in Strengthening the Link Between Family Relationships and Life Satisfaction in 50 Societies
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Li, Liman Man Wai, Lun, Vivian Miu-Chi, Bond, Michael Harris, Yeung, June Chun, Igou, Eric Raymond, Haas, Brian W., Stoyanova, Stanislava, Maricchiolo, Fridanna, Zelenski, John M., Vauclair, Christin-Melanie, Uchida, Yukiko, Poláčková Šolcová, Iva, Sirlopú, David, Park, Joonha, Kosiarczyk, Aleksandra, Kocimska-Zych, Agata, Capaldi, Colin A., Adamovic, Mladen, Akotia, Charity S., Albert, Isabelle, Appoh, Lily, Arevalo, Douglas, Baltin, Arno, Denoux, Patrick, Domínguez-Espinosa, Alejandra, Esteves, Carla Sofia, Gamsakhurdia, Vladimer, Fülöp, Márta, Garðarsdóttir, Ragna B., Gavreliuc, Alin, Boer, Diana, Igbokwe, David O., Işık, İdil, Kascakova, Natalia, Klůzová Kračmárová, Lucie, Kostoula, Olga, Kronberger, Nicole, Kwiatkowska, Anna, Lee, J. Hannah, Liu, Xinhui, Łużniak-Piecha, Magdalena, Malyonova, Arina, Barrientos Marroquin, Pablo Eduardo, Mohorić, Tamara, Mosca, Oriana, Murdock, Elke, Mustaffa, Nur Fariza, Nader, Martin, Nadi, Azar, Okvitawanli, Ayu, van Osch, Yvette, Pavlopoulos, Vassilis, Pavlović, Zoran, Rizwan, Muhammad, Romashov, Vladyslav, Røysamb, Espen, Sargautyte, Ruta, Schwarz, Beate, Selim, Heyla A., Serdarevich, Ursula, Stogianni, Maria, Sun, Chien-Ru, Teyssier, Julien, van Tilburg, Wijnand A. P., Torres, Claudio, Vignoles, Vivian L., Xing, Cai, and Krys, Kuba
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- 2024
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3. A molecular dynamics investigation of laminar pyrocarbons elasticity up to high-temperatures
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Franck Polewczyk, Paul Lafourcade, Nicolas Pineau, Christophe Denoual, Gérard L. Vignoles, and Jean-Marc Leyssale
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Pyrolytic carbon ,Structure ,Texture ,Elasticity ,High temperature ,Molecular dynamics ,Chemistry ,QD1-999 - Abstract
The mechanical properties of anisotropic carbons such as the pyrocarbon (pyC) matrices in C/C composites remain poorly documented, especially at elevated temperatures where these materials find most of their applications. We provide here a comprehensive molecular dynamics investigation of the high temperature – up to 4000 K – elastic behavior of six nanoscale pyC models in the context of fast temperature increases, not allowing for major structural modifications such as graphitization. We show that the structure of the most anisotropic and less disordered carbons, like the rough laminar (RL) pyC, is mostly not affected by annealing at the nanosecond timescale, aside from healing unstable defects like two-coordinated atoms at graphene edges. Conversely, highly disordered and less anisotropic carbons like the smooth laminar (SL) pyC show some significant rearrangements at grain boundaries and the development of some limited microporosity. The elastic constants of all highly anisotropic models moderately decrease with increasing temperature, somehow similarly to what is observed for graphite. Elastic constants of the SL pyC show a stronger decrease at high temperature, due to the decrease in density even though all models retain an important degree of stiffness up to 4000 K.
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- 2024
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4. Paramphistomum daubneyi: characteristics of infection in three lymnaeid species
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Sanabria R., Titi A., Mekroud A., Vignoles P., Dreyfuss G., Rondelaud D., and Romero J.
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Galba truncatula ,Lymnaea neotropica ,Lymnaea viatrix ,Paramphistomum daubneyi ,experimental infection ,metacercaria ,redia ,Infectious and parasitic diseases ,RC109-216 - Abstract
Experimental infections of two South American lymnaeids (Lymnaea neotropica and L. viatrix var. ventricosa) with Paramphistomum daubneyi were carried out to determine if these snail species could sustain larval development of this digenean and, if so, to specify their potential for cercarial production. A French population of Galba truncatula infected and raised according to the same protocol served as controls. In both experiments, prevalence of P. daubneyi infections in snails did not significantly differ from each other. In snail groups evaluated for cercarial shedding (first experiment), a significantly lower number of shed cercariae was noted for L. neotropica, while those from G. truncatula and L. v. ventricosa did not differ significantly from each other. Dissection of infected snails at day 65 post-exposure at 20 °C (second experiment) found significantly lower burdens of P. daubneyi rediae and cercariae in the bodies of L. neotropica than in those of G. truncatula and L. v. ventricosa. Compared to total cercarial production observed in dissected snails, the percentage of cercariae which exited from snails was 75.6% for G. truncatula, 21.6% for L. neotropica, and 91.4% for L. v. ventricosa. This last species seems to be a good candidate for metacercarial production of P. daubneyi.
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- 2012
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5. Local adaptation of the trematode Fasciola hepatica to the snail Galba truncatula
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Dreyfuss G., Vignoles P., and Rondelaud D.
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Fasciola hepatica ,Galba truncatula ,cercaria ,experimental infection ,redia ,river bank ,Infectious and parasitic diseases ,RC109-216 - Abstract
Experimental infections of six riverbank populations of Galba truncatula with Fasciola hepatica were carried out to determine if the poor susceptibility of these populations to this digenean might be due to the scarcity or the absence of natural encounters between these snails and the parasite. The first three populations originated from banks frequented by cattle in the past (riverbank group) whereas the three others were living on islet banks without any known contact with local ruminants (islet group). After their exposure, all snails were placed in their natural habitats from the end of October up to their collection at the beginning of April. Compared to the riverbank group, snails, which died without cercarial shedding clearly predominated in the islet group, while the other infected snails were few in number. Most of these last snails released their cercariae during a single shedding wave. In islet snails dissected after their death, the redial and cercarial burdens were significantly lower than those noted in riverbank G. truncatula. Snails living on these islet banks are thus able to sustain larval development of F. hepatica. The modifications noted in the characteristics of snail infection suggest the existence of an incomplete adaptation between these G. truncatula and the parasite, probably due to the absence of natural contact between host and parasite.
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- 2012
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6. Haplometra cylindracea (Zeder, 1800) (Trematoda: Plagiorchiidae): variation in the dates of cercarial shedding for overwintering Galba truncatula
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Vignoles P., Dreyfuss G., and Rondelaud D.
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cercaria ,cercarial shedding ,Galba truncatula ,Haplometra cylindracea ,natural infection ,Infectious and parasitic diseases ,RC109-216 - Abstract
Natural infections of Galba truncatula with Haplometra cylindracea were followed from 2001 to 2009 to determine if their characteristics were similar when snails came from water collections frequented by Bufo bufo or by frogs and newts for their egg-laying. Snail samples were collected from both types of sites to count shed cercariae for three days and also free cercariae when snails were dissected. In sites only frequented by B. bufo, cercarial shedding occurred earlier than in those colonized by frogs and newts (March instead of April-May). In contrast, the number of cercariae shed during three successive days was significantly higher in May. This variation in the dates of cercarial shedding might be due, either to a synchronism between cercaria-releasing snails and the presence of the definitive host (tadpoles) in water collections, or to an earlier infection of overwintering snails in autumn by H. cylindracea miracidia in the case of toad-frequented sites.
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- 2011
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7. Radix natalensis (Gastropoda: Lymnaeidae), a potential intermediate host of Fasciola hepatica in Egypt
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Dar Y., Djuikwo Teukeng F.F., Vignoles P., Dreyfuss G., and Rondelaud D.
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Fasciola hepatica ,Radix natalensis ,cercaria ,experimental infections ,Egypt ,Infectious and parasitic diseases ,RC109-216 - Abstract
Experimental infections of Egyptian Radix natalensis with French miracidia of Fasciola hepatica were carried out to determine if this snail might act as an intermediate host in the life cycle of this digenean in Egypt. Single exposures of R. natalensis to miracidia (2/snail) and two successive exposures (a total of 4 miracidia/snail) were performed using lymnaeids measuring 1 to 6 mm in height. Live larval forms of F. hepatica were noted in single- and double-exposed snails. In double exposures, a significant increase of snail survival on day 28 post-exposure (at 24 °C) and an decrease in prevalence were noted when the height of snails at exposure was increasing. Cercariae of F. hepatica were shed by these snails (90.7/snail) during a mean patent period of 24.3 days. All snails have released these cercariae during 2-13 waves of shedding. According to these results, R. natalensis can be considered a potential intermediate host of F. hepatica in Egypt.
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- 2010
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8. The redial and cercarial production of a Digenean in the snail host is lower when no cercarial shedding occurs
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Dreyfuss G., Vignoles P., and Rondelaud D.
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Fasciola hepatica ,Galba truncatula ,Paramphistomum daubneyi ,cercaria ,redia ,Infectious and parasitic diseases ,RC109-216 - Abstract
Single- and double-miracidium exposures of Galba truncatula with Fasciola hepatica (two groups) or with Paramphistomum daubneyi (two groups) were carried out under laboratory conditions to compare parasite production in cercaria-shedding snails (CS snails) with that found in snails without emission (NCS snails). Free rediae and cercariae were thus counted in snails from both categories after their dissection at regular intervals (at 24 °C). In the four groups, the numbers of free rediae and free cercariae found at day 75 post-exposure (F. hepatica) or at day 85 (P. daubneyi) were significantly greater in CS snails than in NCS ones. The number of cercariae in NCS subgroups did not show any significant variation from day 45 p.e. to day 75 (F. hepatica, the two groups) or from day 55 to day 85 (P. daubneyi, singlemiracidium infections), while it significantly decreased with increasing time of infection in the double-miracidium infections with P. daubneyi. In NCS snails, the presence of too numerous free cercariae within the snail’s body (the volume of the body allows development only of a given number of rediae) might rapidly block out redial development and intraredial differentiation of other cercariae. The numerical diminution of P. daubneyi cercariae in the NCS snails (double-miracidium group) might probably be due to the lysis of new cercariae just formed, probably in reason of a lack of nutrients available for these larvae within the snail.
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- 2009
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9. Analysis of CD20 and PD-L1 levels on small extracellular vesicles (sEV) produced by DLBCL cells and EBV-transformed B cells, and potential role in T cell inhibition
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Hussein Akil, Hafidha Bentayeb, Marine Aitamer, Chantal Vignoles, Julie Abraham, Nathalie Gachard, Agnès Olivrie, Anne Guyot, Jessica Gobbo, Jean Feuillard, Hamasseh Shirvani, and Danielle Troutaud
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DLBCL ,Human lymphoblastoid cell lines ,sEV ,Exosomes ,CD20 ,PD-L1 ,Diseases of the blood and blood-forming organs ,RC633-647.5 ,Neoplasms. Tumors. Oncology. Including cancer and carcinogens ,RC254-282 - Abstract
Abstract Increasing evidence supports a role for small extracellular vesicles (sEV, including exosomes) in Diffuse Large B-cell lymphoma (DLBCL) progression and resistance to treatment. CD20 and PD-L1 are found on DLBCL-derived sEV, but little is known about their patient-level heterogeneity. Moreover, the capacity of PD-L1+ sEV to modulate T cells needs to be clarified. Herein we analyzed sEV produced by human DLBCL cell lines and EBV-transformed B cell-lymphoblastoid cell lines (LCLs), a model allowing autologous T cell co-cultures. We determined CD20 and PD-L1 levels on plasma sEV from patient samples vs healthy volunteers (HV). sEV functional relevance was also investigated on CD4+ and CD8+ T cells. sEV derived from all cell lines showed an enrichment of CD20 and a high glycosylated PD-L1 expression when compared to cell lysates. High PD-L1 expression on LCL-derived sEV was associated with higher CD4+ and CD8+ T cell apoptosis. In patients, plasma sEV concentration was higher vs HV. Compared to sEV-CD20 level that seemed higher in patients, PD-L1 level in sEV was not different from those of HV. A high glycosylated PD-L1 level was shown in sEV from both patients and HV plasma samples, that was associated with the same inhibiting effect on activated T cells. We conclude that sEV derived from EBV-transformed B cells realize an immunosuppressive role that involved cell–cell interaction and probably at least PD-L1. Furthermore, our findings suggest the potential of circulating sEV as a source of biomarkers in DLBCL, notably to have information on immunotherapeutic target levels of parental tumor cells.
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- 2024
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10. Unusual snail species involved in the transmission of Fasciola hepatica in watercress beds in central France
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Dreyfuss G., Vignoles P., Abrous M., and Rondelaud D.
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Fasciola hepatica ,Lymnaea ovata ,L. stagnalis ,Paramphistomum daubneyi ,Physa acuta ,Planorbis leucostoma ,France ,parasitic infections ,watercress bed ,Infectious and parasitic diseases ,RC109-216 - Abstract
Four freshwater pulmonate species (Lymnaea ovata, L. stagnalis, Physa acuta, Planorbis leucostoma)were living in several watercress beds known for their relationships with human cases of fasciolosis, whereas L. truncatula was never found. The aims of these studies were to determine the prevalence of natural infections with Fasciola hepatica in snails and to verify if these species might ensure the full larval development of this trematode (with cercarial shedding] when they were experimentally subjected to F. hepatica only, or to co-infections with an other trematode species. Investigations were so carried out in six snail populations living in watercress beds (including three for P. acuta) and in four others originating from three brooks or a pond (as controls). Snails naturally infected with F. hepatica were found in two watercress beds inhabited by L. ovata (prevalence of infection: 1.4 %) and P. leucostoma (0.1 %), respectively. The L. ovata from the watercress bed could be infected at a higher size than those from the control population and the prevalence of this infection was greater in the bed population. Similar findings were noted for L. stagnalis. Despite single or dual infections, the results obtained with the four populations of P. acuta were unsuccessful. In contrast, the co-infections of young P. leucostoma with Paramphistomum daubneyi and F. hepatica resulted in the shedding of some F. hepatica cercariae. According to the authors, the occurrence of fasciolosis in these watercress beds would be the consequence of frequent natural encounters between parasite and snails (L. ovata, L. stagnalis), or of co-infections with P. daubneyi and F. hepatica (P. leucostoma). In watercress beds only colonized by P. acuta, a lymnaeid species would have ensured the larval development of F. hepatica but it would have been eliminated by P. acuta, as this last species was known to be invasive and could colonize open drainage ditches on siliceous soil.
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- 2002
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11. A Hierarchical Bayesian Examination of the Chronological Relationship between the Noaillian and Rayssian Phases of the French Middle Gravettian
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William E. Banks, Anaïs Vignoles, Jessica Lacarrière, André Morala, and Laurent Klaric
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Middle Gravettian ,Noaillian ,Rayssian ,chronology ,hierarchical Bayesian age modeling ,ChronoModel ,Human evolution ,GN281-289 ,Stratigraphy ,QE640-699 - Abstract
Issues of chronology are central to inferences pertaining to relationships between both contemporaneous and successive prehistoric typo-technological entities (i.e., archaeological cultures), culture–environment relationships, and ultimately the mechanisms at play behind cultural changes observed through time in the archaeological record. We refine the chronology of Upper Paleolithic archaeological cultures between 35–18 calibrated kiloanni before the present in present-day France by incorporating recently published radiocarbon data along with new 14C ages that we obtained from several Gravettian archaeological contexts. We present the results of a Bayesian age model that includes these new radiometric data and that, more importantly, separates Gravettian contexts in regions north of the Garonne River into two successive cultural phases: The Northern Noaillian and the Rayssian, respectively. This new age model places the beginning of the Noaillian during Greenland Stadial 5.2. The appearance of contexts containing assemblages associated with the Rayssian lithic technical system occurs immediately prior to the termination of Greenland Interstadial 5.1, and it is present throughout Heinrich Event 3 (GS-5.1) and into the following GI-4 climatic amelioration. Despite the Rayssian’s initial appearance during the brief and relatively weakly expressed Greenland Interstadial 5.1, its duration suggests that Rayssian lithic technology was well-suited to the environmental conditions of Greenland Stadial 5.1.
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- 2024
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12. Does College Level the Playing Field? Socioeconomic Gaps in the Earnings of Similar Graduates: Evidence from South Korea
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Lee, Sangwoo and Vignoles, Anna
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The socioeconomic gap in participation at university is an enduring policy issue in South Korea, as in many other countries. However, less attention has been paid to the socioeconomic gap in the outcomes from tertiary education. This paper addresses this gap in the literature, using the Korean Education and Employment Panel (KEEP) data to investigate the extent to which the wages of Korean graduates who attended similar higher education institutions vary by socioeconomic background. The results show that a degree appears to largely level the playing field, in terms of earnings, between male graduates from poor and rich backgrounds. For females, by contrast, family background is still a strong predictor of earnings, even after allowing for institution attended and discipline of degree. Further, the wage premium for 2-year and 4-year college degrees also varies by family background. Four-year college degrees, contrary to popular belief, do not always attract a higher wage premium than 2-year college degrees, particularly for men from poorer family backgrounds.
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- 2022
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13. Découverte de restes humains néandertaliens à l’abri Tourtoirac (Dordogne)
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Isabelle Crevecoeur, Dominique Armand, Cédric Beauval, Mathieu Bosq, Pauline Dugas, Véronique Laroulandie, Alexandre Michel, Éric Pubert, Daniela Rosso, Aurélien Royer, Anna Rufà Bonache, Erwan Vaissié, Émilie Vigier, Anaïs Luiza Vignoles, Quentin Villeneuve, and Luc Doyon
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History of Civilization ,CB3-482 - Published
- 2023
14. Introduction to a Culturally Sensitive Measure of Well-Being: Combining Life Satisfaction and Interdependent Happiness Across 49 Different Cultures
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Krys, Kuba, Haas, Brian W., Igou, Eric Raymond, Kosiarczyk, Aleksandra, Kocimska-Bortnowska, Agata, Kwiatkowska, Anna, Lun, Vivian Miu-Chi, Maricchiolo, Fridanna, Park, Joonha, Šolcová, Iva Poláčková, Sirlopú, David, Uchida, Yukiko, Vauclair, Christin-Melanie, Vignoles, Vivian L., Zelenski, John M., Adamovic, Mladen, Akotia, Charity S., Albert, Isabelle, Appoh, Lily, Mira, D. M. Arévalo, Baltin, Arno, Denoux, Patrick, Domínguez-Espinosa, Alejandra, Esteves, Carla Sofia, Gamsakhurdia, Vladimer, Fülöp, Márta, Garðarsdóttir, Ragna B., Gavreliuc, Alin, Boer, Diana, Igbokwe, David O., Işık, İdil, Kascakova, Natalia, Klůzová Kráčmarová, Lucie, Kosakowska-Berezecka, Natasza, Kostoula, Olga, Kronberger, Nicole, Lee, J. Hannah, Liu, Xinhui, Łużniak-Piecha, Magdalena, Malyonova, Arina, Barrientos, Pablo Eduardo, Mohorić, Tamara, Mosca, Oriana, Murdock, Elke, Mustaffa, Nur Fariza, Nader, Martin, Nadi, Azar, Okvitawanli, Ayu, van Osch, Yvette, Pavlopoulos, Vassilis, Pavlović, Zoran, Rizwan, Muhammad, Romashov, Vladyslav, Røysamb, Espen, Sargautyte, Ruta, Schwarz, Beate, Selim, Heyla A., Serdarevich, Ursula, Stogianni, Maria, Sun, Chien-Ru, Teyssier, Julien, van Tilburg, Wijnand A. P., Torres, Claudio, Xing, Cai, and Bond, Michael Harris
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- 2023
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15. Understanding Higher Education Access: Inequalities and Early Learning in Low and Lower-Middle-Income Countries
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Ilie, Sonia, Rose, Pauline, and Vignoles, Anna
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Globally, access to higher education has increased, but inequalities by socio-economic background remain. This article explores the relationship between early schooling opportunities (and learning) and progression into higher education in four low and middle-income countries. We analyse data from the Young Lives longitudinal study, following cohorts of young people from age 5 to 22 in four country settings: Ethiopia, Peru, Vietnam and India. We reveal wide variability in higher education participation between the four countries, with a common pattern of a very strong association between early learning and later higher education participation, even after allowing for a range of demographic characteristics. Whilst early learning is important in predicting later higher education participation, we also find that significant barriers to higher education participation remain for low socio-economic status groups, even if they initially show good levels of learning. We track the trajectories of children who have initial good levels of learning, and hence arguably the potential to progress to higher education, and assess the extent to which socio-economic background plays a mediating role in these trajectories. Pupils with initially good levels of learning at primary school age, but who are from poor backgrounds, fall back in terms of their relative attainment during secondary schooling years. This implies that socio-economic status continues to be a barrier to educational attainment throughout these children's lives. We discuss the implications of these findings for policy initiatives aimed at narrowing inequalities in higher education access in poorer countries.
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- 2021
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16. The Relationship between Educational Television and Mathematics Capability in Tanzania
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Watson, Joe, Hennessy, Sara, and Vignoles, Anna
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Previous studies have often demonstrated that educational television can have a positive effect on learning outcomes in low-income countries when delivered in controlled settings. However, existing research in low-resource contexts has scarcely considered the association between child outcomes and viewing in usual environments (ie, at their home, a friend's home or a relative's home). This lack of research is striking, as evidence from controlled settings might provide limited information on the effects of normal television exposure. This paper, therefore, investigates the relationship between normal exposure to a popular Tanzania-produced cartoon, "Ubongo Kids" and mathematics capability, as represented by plausible values derived from an item response theory model applied to children's test responses. Cross-sectional investigation of a sample of 38 682 Tanzanian children suggested normal educational television exposure to be significantly associated with mathematics capability, when controlling for age, sex, school enrolment, Kiswahili attainment and household fixed effects. While cross-sectional results are not necessarily causal, the findings in this paper broadly correspond with those from previous designs using repeated observations. What is more, considering association results alongside cost and viewership estimates suggests television-based interventions to be highly cost effective.
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- 2021
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17. School Segregation in Public and Semiprivate Primary Schools in Andalusia
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Prieto-Latorre, Claudia, Marcenaro-Gutierrez, Oscar D., and Vignoles, Anna
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School segregation by socio-economic background is a feature of most education systems and impacts negatively on educational outcomes for poor children. Evidence on this issue is lacking for the Spanish primary education system and in particular the extent to which a) poor and rich students sort into different types of school and b) the extent of segregation within different school types. We measure the level of segregation of students from different socioeconomic backgrounds into public and semiprivate schools and within these two types of school using the Hutchens Index. The analysis is based on data for students attending 5th grade in the largest region in Spain (Andalusia). Our results indicate significant differences in the level of segregation across and within both school types. Students from higher socioeconomic backgrounds are more likely to attend semiprivate schools. This provides evidence of the inequity of providing public funding for semiprivate schools that are then disproportionately attended by wealthier students.
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- 2021
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18. Cultural fit of emotions and subjective well-being: Replicating comparative evidence and extending it to the Mediterranean region
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Alexander Kirchner-Häusler, Jozefien De Leersnyder, Ayse K. Uskul, Fattana Mirzada, Vivian L. Vignoles, Rosa Rodríguez-Bailón, Vanessa A. Castillo, Susan E. Cross, Meral Gezici-Yalçın, Charles Harb, Shenel Husnu, Keiko Ishii, Panagiota Karamaouna, Konstantinos Kafetsios, Evangelia Kateri, Juan Matamoros-Lima, Rania Miniesy, Jinkyung Na, Zafer Özkan, Stefano Pagliaro, Charis Psaltis, Dina Rabie, Manuel Teresi, and Yukiko Uchida
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Fit ,Well-being ,Emotion ,Mediterranean ,Culture ,Psychology ,BF1-990 - Abstract
Greater “emotional fit” with one's cultural group is often associated with positive psychological and relational outcomes. However, the few empirical studies on this link have been limited to the comparison of Anglo-Western, independent, and East Asian, interdependent cultural contexts. In the current paper, we conceptually replicated findings from three studies on the link between emotional fit and well-being in Anglo-Western and East Asian contexts, using different methods and more comprehensive samples. Moreover, we expanded emotional fit research to the understudied Mediterranean region, characterized by an emphasis on “honor” and a distinct blend of independence and interdependence. We collected data from N = 3,097 participants from 12 countries and asked participants to report their emotional experience in 10 hypothetical situations and to rate their well-being in different domains. Our results largely replicated established positive links between emotional fit and well-being in the Anglo-West and East-Asia, as i) experiencing more culturally valued emotions (from which we infer cultural fit) was linked to better general well-being; ii) actual, calculated emotional fit in relationship-focused situations predicted better relational well-being; and iii) only in East Asia calculated emotional fit in culturally central contexts predicted psychological well-being and thriving. Our exploratory analyses on the Mediterranean region showed a non-homogenous pattern: while general well-being was consistently most strongly predicted by the intensity of disengaging emotions, relational and psychological well-being were differentially predicted by calculated emotional fit in relationship-focused situations across different Mediterranean sub-regions. The current work consolidates insights into how our well-being is shaped by the interplay between culture and emotional fit and strengthens evidence that there may be ‘universalism without uniformity’.
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- 2023
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19. CD20 expression, TrkB activation and functional activity of diffuse large B cell lymphoma-derived small extracellular vesicles
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Aitamer, Marine, Akil, Hussein, Vignoles, Chantal, Branchaud, Maud, Abraham, Julie, Gachard, Nathalie, Feuillard, Jean, Jauberteau, Marie-Odile, Shirvani, Hamasseh, Troutaud, Danielle, and Bentayeb, Hafidha
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- 2021
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20. Mathematics Mastery: Primary Evaluation Report
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Education Endowment Foundation (EEF) (United Kingdom), University College London (UCL) (United Kingdom), Institute of Education (IOE), Vignoles, Anna, Jerrim, John, and Cowan, Richard
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The Mathematics Mastery programme is a whole-school approach to teaching mathematics that aims to raise attainment for all pupils and close the attainment gap between pupils from low income families and their peers. The programme aims to deepen pupils' understanding of key mathematical concepts. This evaluation assessed the impact of Mathematics Mastery on pupils in Year 1, after the programme had been implemented in schools for one year. It was intended that schools would also begin to use the programme in Year 2 in the second year of implementation, and continue until the approach was in place across the school. The evaluation used a randomised controlled trial design, with schools randomly allocated to begin the programme in 2012 or 2013. Eighty-three schools from London and the South East participated in the trial, with a total sample of 4,176 pupils. Participating schools received training and resources to support the adoption of the programme which was delivered by the education charity, Ark. The project was one of two evaluations of Mathematics Mastery funded by the Education Endowment Foundation (EEF). Key conclusions include: (1) On average, Year 1 pupils in schools adopting Mathematics Mastery made a small amount more progress than pupils in schools that did not. However, the effect detected was not statistically significant, meaning that it is not possible to rule out chance as an explanation; (2) There is little evidence that the effect of Mathematics Mastery differs between children with different levels of prior achievement; (3) Combining the findings from this study and a second randomised controlled trial of Mathematics Mastery involving Year 7 pupils strengthens the overall evidence for the approach; (4) Given the low per-pupil cost, Mathematics Mastery may represent a cost-effective change for primary schools to consider; and (5) It would be worthwhile to track the medium and long-term impact of the approach, in part to assess the degree to which the test used in this evaluation is predictive of general mathematics attainment and performance in high-stakes tests. [For the Secondary Evaluation Report, see ED581187. For the Overarching Summary Report, see ED581180.]
- Published
- 2015
21. Mathematics Mastery: Overarching Summary Report
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Education Endowment Foundation (EEF) (United Kingdom), University College London (UCL) (United Kingdom), Institute of Education (IOE), Jerrim, John, and Vignoles, Anna
- Abstract
The Mathematics Mastery programme is a whole-school approach to teaching mathematics that aims to raise attainment for all pupils and close the attainment gap between pupils from low income families and their peers. The programme aims to deepen pupils' conceptual understanding of key mathematical concepts. This summary is based on two randomised controlled trials of Mathematics Mastery funded by the Education Endowment Foundation. The first evaluation assessed the impact of the programme on pupils in Year 1. 83 schools from London and the South East participated in the trial, with a total sample of 4,176 pupils. The second assessed the impact of the programme on pupils in Year 7. 44 schools from London and the South East participated in the trial, with a total sample of 5,938 pupils. Both evaluations assessed the programme's impact in its first year of adoption. In subsequent years it was intended that schools would begin to use the approach with older year groups until it was in place across all year groups. The education charity, Ark, provided participating schools with training and resources to support the adoption of the programme. Key conclusions include: (1) This summary is based on findings from two randomised controlled trials conducted in English schools between 2011 and 2014; (2) On average, pupils in schools adopting Mathematics Mastery made a small amount more progress than pupils in schools that did not. The effect detected was statistically significant, which means that it is likely that that improvement was caused by the programme; (3) It is unclear whether the programme had a different impact on pupils eligible for free school meals, or on pupils with higher or lower attainment; (4) Given the low per-pupil cost, Mathematics Mastery may represent a cost-effective change for schools to consider; and (5) The evaluations assessed the impact of the programme in its first year of adoption. It would be worthwhile to track the medium and long-term impact of the approach. [For the Primary Evaluation Report, see ED581183. For the Secondary Evaluation Report, see ED581187.]
- Published
- 2015
22. Personal Life Satisfaction as a Measure of Societal Happiness is an Individualistic Presumption: Evidence from Fifty Countries
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Krys, Kuba, Park, Joonha, Kocimska-Zych, Agata, Kosiarczyk, Aleksandra, Selim, Heyla A., Wojtczuk-Turek, Agnieszka, Haas, Brian W., Uchida, Yukiko, Torres, Claudio, Capaldi, Colin A., Bond, Michael Harris, Zelenski, John M., Lun, Vivian Miu-Chi, Maricchiolo, Fridanna, Vauclair, Christin-Melanie, Poláčková Šolcová, Iva, Sirlopú, David, Xing, Cai, Vignoles, Vivian L., van Tilburg, Wijnand A. P., Teyssier, Julien, Sun, Chien-Ru, Stoyanova, Stanislava, Serdarevich, Ursula, Schwarz, Beate, Sargautyte, Ruta, Røysamb, Espen, Romashov, Vladyslav, Rizwan, Muhammad, Pavlović, Zoran, Pavlopoulos, Vassilis, van Osch, Yvette, Okvitawanli, Ayu, Nadi, Azar, Nader, Martin, Nur Fariza, Mustaffa, Mosca, Oriana, Mohorić, Tamara, Barrientos, Pablo Eduardo, Malyonova, Arina, Liu, Xinhui, Lee, J. Hannah, Kwiatkowska, Anna, Kronberger, Nicole, Klůzová Kračmárová, Lucie, Kascakova, Natalia, Işık, İdil, Igou, Eric R., Igbokwe, David O., Hanke-Boer, Diana, Gavreliuc, Alin, Garðarsdóttir, Ragna B., Fülöp, Márta, Gamsakhurdia, Vladimer, Esteves, Carla Sofia, Domínguez-Espinosa, Alejandra, Denoux, Patrick, Charkviani, Salome, Baltin, Arno, Mira, Arévalo D. M., Appoh, Lily, Albert, Isabelle, Akotia, Charity S., and Adamovic, Mladen
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- 2021
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23. Advances in ceramic composites: manufacture, performances and applications
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Dietmar Koch, Elisabeth Opila, and Gerard Vignoles
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Clay industries. Ceramics. Glass ,TP785-869 - Published
- 2022
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24. Physical processes causing the formation of penitentes
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Claudin, P., Jarry, H., Vignoles, G., Plapp, M., and Andreotti, B.
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Condensed Matter - Soft Condensed Matter - Abstract
Snow penitentes form in sublimation conditions by differential ablation. Here we investigate the physical processes at the initial stage of penitente growth and perform the linear stability analysis of a flat surface submitted to the solar heat flux. We show that these patterns do not simply result from the self-illumination of the surface --a scale-free process-- but are primarily controlled by vapor diffusion and heat conduction. The wavelength at which snow penitentes emerge is derived and discussed. We found that it is controlled by aerodynamic mixing of vapor above the ice surface., Comment: 11 pages, 10 figures
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- 2015
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25. Methodological Lessons on Measuring Quality Teaching in Southern Contexts, with a Focus on India and Pakistan
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Aslam, Monazza, Malik, Rabea, Rawal, Shenila, Rose, Pauline, Vignoles, Anna, and Whitaker, Lydia
- Abstract
Quantifying the impact of teaching quality on pupil learning, and understanding what teacher characteristics or practices are likely to improve student achievement, are pressing research questions in all countries. Empirical evidence also needs to be context specific since different education systems are likely to have different facilitators and barriers to good teaching. Existing evidence, largely from the US, suggests a number of strong research designs that enable researchers to model the impact of teaching on pupil achievement. However, operationalising these models in more resource-constrained contexts is challenging. In this paper we describe our attempt to model the impact of teachers and their practices on pupil achievement using the quantitative data generated for this research (household and school surveys with a teacher survey and an attempt to assess teacher knowledge). We describe the challenges when trying to implement this approach in the Indian and Pakistan context and the methodological adaptions needed. We reflect on the strengths and weaknesses of our approach. We note that existing literature tends to provide relatively minimal descriptions of the specific research design and instruments used to model teacher quality and hence provides a partial picture of methodological considerations. In this paper we contribute a detailed and frank account of developing a workable research design and the challenges we encountered.
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- 2019
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26. Do Government Schools Improve Learning for Poor Students? Evidence from Rural Pakistan
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Aslam, Monazza, Malik, Rabea, Rawal, Shenila, Rose, Pauline, and Vignoles, Anna
- Abstract
Pakistan's Punjab province has witnessed numerous education reforms in recent years. Many of these reforms have been aimed at improving the well-documented low levels of learning by focusing on improving teaching quality. The rhetoric suggests that government schools, particularly those in rural areas with a more disadvantaged pupil base, are especially ineffective at imparting learning. This paper seeks to investigate whether children in rural Punjab are learning literacy and numeracy over the course of a year, and if so, are some pupils progressing more than others. Using recently collected data, it finds that children in our sample are making progress. Variation in progress is found to be greater within schools rather than across them. The competence and qualifications of a teacher also makes a significant difference to a child's academic progress. The paper further finds differential progress for rich and poor students within schools, suggesting an important role for education policy to put in place targeted support towards those from disadvantaged backgrounds to ensure improvements in their learning keep pace with their peers.
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- 2019
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27. School Choice in England: Evidence from National Administrative Data
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Burgess, Simon, Greaves, Ellen, and Vignoles, Anna
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We study school choice in England using a new dataset containing the choices of all parents seeking a school place in state secondary schools. We provide new empirical evidence to inform how the school choice market functions, including the number of choices made, whether the nearest school is the first choice and the probability of an offer from the first choice school. These indicators show that school choice is actively used by many households in England. We use the rich data available to describe how choices vary by pupil, school and neighbourhood characteristics and how school choice is used differently by different groups and in different parts of the country. For the first time, we are able to present national data on how the school choices made by parents vary according to pupils' ethnic group and across urban and rural areas. We show, contrary to some existing literature that has relied on smaller and less representative samples of parents and pupils, that school choices do not vary significantly by social background. We show that parents pro-actively use the choice system and present new evidence on the extent to which the current school admissions criteria that prioritise distance penalise poorer families.
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- 2019
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28. Just a phase? Mapping the transition of behavioural problems from childhood to adolescence
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Bathelt, Joe, Vignoles, Anna, and Astle, Duncan E.
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- 2021
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29. Is it really 'panic buying'? Public perceptions and experiences of extra buying at the onset of the COVID-19 pandemic.
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Evangelos Ntontis, Sara Vestergren, Patricio Saavedra, Fergus Neville, Klara Jurstakova, Chris Cocking, Siugmin Lay, John Drury, Clifford Stott, Stephen Reicher, and Vivian L Vignoles
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Medicine ,Science - Abstract
Shopping behaviour in response to extreme events is often characterized as "panic buying" which connotes irrationality and loss of control. However, "panic buying" has been criticized for attributing shopping behaviour to people's alleged psychological frailty while ignoring other psychological and structural factors that might be at play. We report a qualitative exploration of the experiences and understandings of shopping behaviour of members of the public at the onset of the COVID-19 pandemic. Through a thematic analysis of semi-structured interviews with 23 participants, we developed three themes. The first theme addresses people's understandings of "panic buying". When participants referred to "panic buying" they meant observed product shortages (rather than the underlying psychological processes that can lead to such behaviours), preparedness behaviours, or emotions such as fear and worry. The second theme focuses on the influence of the media and other people's behaviour in shaping subsequent shopping behaviours. The third theme addresses the meaningful motivations behind increased shopping, which participants described in terms of preparedness; some participants reported increased shopping behaviours as a response to other people stockpiling, to reduce their trips to supermarkets, or to prepare for product shortages and longer stays at home. Overall, despite frequently using the term 'panic', the irrationalist connotations of "panic buying" were largely absent from participants' accounts. Thus, "panic buying" is not a useful concept and should not be used as it constructs expected responses to threat as irrational or pathological. It can also facilitate such behaviours, creating a self-fulfilling prophecy.
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- 2022
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30. Post-16 Educational Choices and Institutional Value Added at Key Stage 5. CEE DP 124
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London School of Economics & Political Science, Centre for the Economics of Education, Crawford, Claire, Meschi, Elena, and Vignoles, Anna
- Abstract
In the UK there has historically been a clear demarcation between the academic and vocational routes through education post-16. Generally vocational study is taken either on a part time basis or full time at Further Education (FE) colleges. Students who want to take academic qualifications such as A levels have the option to enrol in a school sixth form, a Sixth Form College or a general FE college. The FE route is therefore an important one through the educational system for both vocational and academic students alike. This research investigates which types of students choose to study at these different institutions and whether this choice matters for the achievement of educational outcomes. In this report the authors determine first what types of student stay on in education past the age of 16 and which types of student enrol in different types of post-16 institution. They then ask whether post-16 institutions matter to pupils' final key stage 5 achievement and specifically whether FE colleges contribute differently to the gain in pupil attainment for those taking A levels as compared to sixth form based provision (in schools or colleges). In this paper the authors assume that the decision process regarding the person's choice of post compulsory education course (if any) is sequential. They conclude the following: (1) Different types of pupils choose to enrol in FE and sixth form based provision; and (2) The following types of pupils are more likely to enrol in sixth form based provision: (1) More advantaged/high achieving pupils; (2) Pupils in a school with a 6th form; (3) Pupils in the most advantaged schools; (4) Pupils in a single sex school; (5) Pupils in a school with a lower pupil teacher ratio; and (6) Pupils in comprehensive or community schools. The authors conclude from Part 1 of their report, that general FE college enrolment is determined by pupils' prior attainment but also by their family background and their parents' attitude towards education. As FE attendance is socially graded, this is likely to impact on pupil performance at Key Stage 5 as well. These results clearly illustrate that there is significant selection of pupils into FE provision and that this will tend to bias results if it is not fully accounted for. The authors conclude from Parts 2 and 3 of this report that those in general FE colleges, whether doing A levels or other types of Key Stage 5 qualifications, do more poorly in terms of their education attainment than those who opt for sixth form based provision. This result only holds for students who are higher achieving at GCSE level. Furthermore, they only considered students who took either A levels or other level 3 qualifications in FE colleges. FE colleges often take students who have not attained level 2 qualifications and this important role is not considered in their analysis. The authors also need to be cautious. Their models do allow for a substantial array of factors that influence pupils' choice of post 16 institution and that also influence pupil attainment, such as pupils' socio-economic background. Yet they need to remain aware that despite the richness of their models, this result may still reflect the fact that those who attend FE colleges are more educationally disadvantaged in ways that they do not account for in their model. Appended are: (1) Summarising descriptive statistics; (2) The determinants of remaining in full time education and choice of post-16 provision by gender; (3) Separate models by institution types- Dependent variable: KS5 average score A-level only); (4) Test of balance between observables in the two groups (treated and nontreated); and (5) The relationship between post 16 institution and participation in higher education. (Contains 25 tables, 4 figures, and 37 footnotes.)
- Published
- 2011
31. The Determinants of Non-Cognitive and Cognitive Schooling Outcomes. Report to the Department of Children, Schools and Families. CEE Special Report 004
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London School of Economics & Political Science, Centre for the Economics of Education, Vignoles, Anna, and Meschi, Elena
- Abstract
The Centre for the Economics of Education was asked to investigate the factors that influence a range of children's academic and non-academic outcomes, including their enjoyment of school, whether they take unauthorised absence from school and whether they feel they are bullied. The study also investigated whether schools can influence these non-academic outcomes. The study makes use of the Longitudinal Study of Young People in England, which is a survey of young people in secondary school that collects information on bullying, truancy and many other factors in each child's life. The data is linked to information on each child's academic achievement, enabling this study to investigate the inter-relationship between a pupil's academic performance and non academic outcomes. Pupils who enjoy school more at age 14 have, perhaps unsurprisingly, higher academic achievement by age 16. Equally, children who have higher achievement at age 11 go on to enjoy school more at age 16 though this is a not a strong relationship. In other words enjoyment of school and academic achievement are clearly linked. Pupils who were bullied or who took unauthorised absence at age 14 had significantly lower educational achievement at GCSE. Pupils who experienced bullying at age 14 were also much more likely to experience bullying at age 16. Therefore early negative outcomes, such as being bullied, suggest the child is at risk of having later negative experiences at age 16. Conversely, pupils who participate in positive extra-curricular activities, such as clubs, were also found to have better academic achievement later in their schooling. High achievers at school, i.e. pupils who do well academically at age 14, were also no more likely to be bullied at age 16 than other children. The report also investigated the impact of schools on some of these non-academic outcomes between 14-16 and found little evidence that schools currently have different impacts on pupil's enjoyment of school, nor whether they take unauthorised absence, nor their likelihood of being bullied. In other words, which school a pupil attends is likely to have small or no effect on their wider well-being. This does not mean that schools do not have the potential to impact on these factors but rather that currently there are not large differences across schools in these outcomes once socio-economic factors have been taken into account. The report concludes that non-academic factors, such as a pupil's enjoyment of school, are inextricably linked to pupils' academic achievement. We need to be aware of these relationships when considering policies to improve pupil achievement. The report also provides some useful risk indicators of future low pupil academic achievement. For example, some factors, such as being bullied or taking unauthorised absence, predict low future academic achievement. Again this can be used by schools and policy-makers to identify pupils at risk of low attainment. This research report was written before the new UK Government took office on 11 May 2010. As a result the content may not reflect current Government policy. This research will be of use to officials and ministers in helping to shape the future direction of policy and Departmental strategy. Appended are: (1) Appendix 1: Descriptive statistics; (2) Fixed or Random Effect; (3) Robustness Checks; (4) Correlation between fixed effects from the different models; and (5) Instrumental Variables estimates. (Contains 13 tables, 6 figures and 24 footnotes.)
- Published
- 2010
32. Access, Choice and Participation in Higher Education. CEE DP 101
- Author
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London School of Economics & Political Science, Centre for the Economics of Education, Gibbons, Stephen, and Vignoles, Anna
- Abstract
Commuting or re-location costs could be an in important influence on students' university choices and might even deter some from going to university. The barriers presented by these costs may be high for lower-income students, and students for whom there are cultural incentives to remain in or close to the parental home. If this is the case, then the geographical accessibility of universities has an important bearing on differences in higher education choices for different income and ethnic groups, and, in turn, on their earnings and life chances. Existing evidence has shown that university places are not evenly spatially distributed in Britain. Research has also found that "non-traditional" students--those from backgrounds in which higher-education participation is emerging--cite the location of institutions as a factor affecting their decision to go in to higher education. However, it is easy to make the mistake of attributing behaviour to ethnicity, gender or income when these behaviours are really due to other differences, like academic achievement, or home location which will have strong bearing on if and where students go to university. In fact, there is no large scale, systematic evidence for the UK that shows that proximity to a university really matters for higher education participation or choice amongst universities, or that it matters more for specific ethnic or income groups. The authors' research looks at these questions using administrative data on the population of school leavers and university entrants in England. These data allow the authors to link the choices of students from different ethnic and income backgrounds to distances between home and university, whilst accounting for schooling, neighbourhood and other background characteristics. Their key findings are: (1) Universities are not evenly distributed around the country but 90% of locations have three institutions and 4000 first degree places within 100km; (2) Non-white ethnic groups and low-income students actually live closer to their nearest three higher education institutions and closer to their nearest three high-quality research institutions than their white and high-income counterparts. These facts suggest that disparities in geographical access are unlikely to be a source of disadvantage to ethnic minorities and poor students; (3) Home-to-university distance has only a tiny influence on the probability of participation in higher education, relative to achievement and other background factors. Their statistical models imply that doubling the distance to the nearest institution would reduce the probability of white female participation by at most 4.5% in relative terms--reducing the probability of participation at the mean from 28.4% to 27.1%. For males, the effect is only half that, but there are no systematic differences by ethnic or income group; (4) In contrast, distance is the strongest factor influencing university choice amongst those who participate. The probability that a student attends a specific university decreases by 8%-15% with each 10% increase in home-to-university distance. This distance cost is observed for all ethnic and income groups, but is highest for Pakistani and Bangladeshi girls and low income students, and lowest for Black students and those from Professional backgrounds; and (5) The influence of distance on choice of institution could make a difference to the type of higher education received by different demographic groups. This is a moot point for ethnic minorities, who have high participation rates at "elite" research intensive universities relative to whites, but provides a potential explanation for lower participation rates amongst women and low income groups in top ranked research universities. The findings therefore offer no support for the idea that improving the accessibility of higher education institutions is an effective route to raising participation. However, targeting the accessibility of higher-quality institutions could increase uptake of high quality HE places amongst suitably qualified students from lower-occupational status backgrounds. Such policies might include action to reduce the role of distance (distance learning) but also policies to encourage higher status institutions to undertake outreach activities further afield. In any case, the authors find no evidence to suggest that such a policy need be gender or ethnically targeted. One further important spatial implication from this work is that the type and quality of higher education in which students enroll is in part governed by the type and quality of local institutions, which in turn partly determines the skill composition of the local population. Given this, the local mix of institution types and quality could have a strong bearing on the quality and composition of the local human capital stock. (Contains 11 tables, 4 figures and 23 footnotes.)
- Published
- 2009
33. Building the Foundations for Measuring Learning Gain in Higher Education: A Conceptual Framework and Measurement Instrument
- Author
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Vermunt, Jan D., Ilie, Sonia, and Vignoles, Anna
- Abstract
In this paper, we set out the first step towards the measurement of learning gain in higher education by putting forward a conceptual framework for understanding learning gain that is relevant across disciplines. We then introduce the operationalisation of this conceptual framework into a new set of measurement tools. With the use of data from a large-scale survey of 11 English universities and over 4,500 students, we test the reliability and validity of the measurement instrument empirically. We find support in the data for the reliability of most of the measurement scales we put forward, as well as for the validity of the conceptual framework. Based on these results, we reflect on the conceptual framework and associated measurement tools in the context of at-scale deployment and the potential implications for policy and practice in higher education.
- Published
- 2018
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34. Do Financial Education Interventions for Women from Poor Households Impact Their Financial Behaviors? Experimental Evidence from India
- Author
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Bhutoria, Aditi and Vignoles, Anna
- Abstract
Policymakers have invested significant resources in financial education to improve financial literacy of the poor, reduce bad financial decision-making, and increase take-up of financial services and products. Yet, there is limited evidence on the effectiveness of such interventions, especially in developing countries. This paper provides evidence from a clustered randomized controlled trial (RCT) where a relatively light financial education program (one day of training) was offered to a large sample of women (n = 1,281) from poor households in informal community settings. The educational intervention was a significant departure from the more costly traditional classroom-style adult education interventions. It was based on simple "rules of thumb" and used a goal-oriented and action-focused approach, targeted at changing behaviors. We find evidence of modest, positive treatment effects for some outcomes including an increase in personal savings, achieved at a relatively low cost of training per participant.
- Published
- 2018
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35. Parents' Basic Skills and Children Cognitive Outcomes. CEE DP 104
- Author
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London School of Economics & Political Science, Centre for the Economics of Education, de Coulon, Augustin, Meschi, Elena, and Vignoles, Anna
- Abstract
A large proportion of the UK adult population has very poor literacy and/or numeracy skills (see the 1999 Moser Report, the 2003 "Skills for Life" Survey and the 2006 Leitch report). In 1999, the Moser report found that approximately 20% of adults in England had severe literacy difficulties, whilst around 40% had some numeracy problems. Having a population with a large proportion of people with poor literacy and numeracy is harmful both to the low-skilled individuals themselves (who face a higher probability of being unemployed, having an unstable job and lower wages) and to firms (that increasingly need a better skilled workforce). The evidence to support the economic value of basic skills is now extensive (see section 2). There are however, potential indirect benefits from basic skills, which have been less frequently addressed in the literature. This paper addresses the important question of how parents' basic skills relate to the early cognitive development of their children (at age 3-6). This question is important as early cognitive ability is a key determinant of subsequent schooling, wages, and other socio-economic outcomes (Heckman, 1995; Murnane "et al.", 1995; Feinstein and Duckworth, 2006). Further, there are significant cognitive achievement gaps between children from various socioeconomic groups: these gaps emerge early i.e. before starting school (Cunha and Heckman, 2007) and increase as children age (Carneiro and Heckman, 2004; Feinstein, 2003). Understanding the inter-generational transmission of skills is therefore important from both a distributional and an efficiency perspective, and indeed a number of recent papers have investigated the contribution of parents to the early formation of their children's cognitive skill (Todd and Wolpin, 2007, Cunha and Heckman, 2007). The novelty of this paper is that the authors distinguish the separate contribution of parents' literacy and numeracy skills in adulthood (at age 34) on their children's cognitive test scores, as distinct from the role of other factors including parental ability, education and socio-economic status. The authors use the British Cohort Study (BCS) data set, in which rich information on parents is combined with early test scores for their children. The authors use numeracy and literacy tests of parents at age 34 and relate them to cognitive tests of their children taken pre-school at ages 3 to 6. They are able to control for a vast array of family and individual characteristics, including parents' early years (parents have been surveyed 7 times since their birth in 1970) and socio-economic background. The authors find that parents' basic skills in literacy and numeracy at age 34 have a positive significant effect on their children's test scores, over and above the positive effects of parental education and ability. Appended are: (1) Variable Description; (2) OLS estimates using the same sample size for all the regressions; (3) Strength and Difficulties Scale; and (4) SURE regressions of cognitive and non cognitive outcomes for school age children. (Contains 8 tables and 17 footnotes.)
- Published
- 2008
36. An Analysis of the Benefit of NVQ2 Qualifications Acquired at Age 26-34. CEE DP 106
- Author
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London School of Economics & Political Science, Centre for the Economics of Education, De Coulon, Augustin, and Vignoles, Anna
- Abstract
The purpose of this report is to determine the extent to which NVQ2 qualifications, when acquired in a person's late twenties and early thirties, encourage progression on to other learning and/or lead to other beneficial changes in a person's economic circumstances. The project will provide evidence to help inform the Department about whether NVQ2 qualifications are likely to contribute to individuals' productivity and to assist in attempts to improve qualification design and delivery. The report will also provide evidence on the likely effects of the historical policy emphasis on reaching level 2. One issue of pressing policy importance is to explain why the wage returns to NVQ2 qualifications appear to be minimal (Dearden et al. 2000; McIntosh 2002 and Dearden et al. 2004). Although this question has been addressed in a number of different academic studies, we will provide up to date information on the extent to which NVQ2 specifically, when acquired in mid career, can provide wage (and employment) benefits. For the analysis, we use quantitative analysis methods applied to the rich data from the British Cohort Study (1970) data (BCS). The specific research questions we will be able to address are: (1) What are the characteristics of individuals who acquire NVQ2 qualifications in their twenties and thirties? In particular can we describe these individuals in terms of their prior ability, gender, ethnicity, other education and parental background?; (2) Do those who acquire NVQ2 qualifications in their twenties and thirties experience wage gains or employment changes subsequently? Is there any lag in the effect of NVQ2 on wages or employment?; (3) How does the acquisition of NVQ2 qualifications specifically compare, in terms of learning, wage and employment outcomes, as compared to the acquisition of other level 2 qualifications?; and (4) Are individuals who acquire NVQ2 qualifications before the age of 30 more likely to go on to subsequent spells of learning (either accredited or non-accredited learning), as compared to a) individuals who have undertaken other forms of level 2 learning; and b) those who have undertaken no adult learning? The report is structured as follows. We start in section 2 by very briefly summarizing previous research evidence on this issue. We then describe the data and methods used in section 3. In section 4 we investigate the characteristics of individuals who acquire a NVQ2 between the ages of 26 and 34. We will also explore the extent to which there has been any trend change in the acquisition of NVQ2 over the period 1996-2004 for this particular cohort (BCS participants have been interviewed in 1996, 2000 and 2004). Normally we would expect a lower incidence of lifelong learning as individuals get older. However, as various policies have been introduced over the period, this may have increased the likelihood of lifelong learning and we can (descriptively) determine whether there has been any change in the incidence of this form of lifelong learning for this cohort. In section 5 we will then examine the relationship between acquiring an NVQ2 and subsequent changes in both wages and employment. In section 6 we will explore the extent to which acquiring an NVQ2 leads individuals to engage in more learning/ qualification acquisition in subsequent periods. Section 7 concludes. (Contains 17 tables and 13 footnotes.) [Additional funding for this paper was provided by the Department for Innovation, Universities & Skills.]
- Published
- 2008
37. The Value of Basic Skills in the British Labour Market. CEE DP 77
- Author
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London School of Economics & Political Science, Centre for the Economics of Education, Marcenaro-Gutierrez, Oscar, Vignoles, Anna, and De Coulon, Augustin
- Abstract
In this paper we evaluate the labour market value of basic skills in the UK, focusing on the wage and employment returns to having better literacy and numeracy skills. We draw on literacy and numeracy assessments undertaken by all cohort members of the UK 1970 British Cohort Study. The data used are very rich and allow us to account for potential ability bias, including as they do early childhood assessments of ability. We find that the literacy and numeracy effects on earnings are over and above any general effect on earnings from a person being more cognitively able. We also assess whether the value of basic skills, in terms of wage returns, has increased over time, using a cross cohort analysis based on the 1958 National Child Development Study cohort and the 1970 British Cohort Study. Our results show that literacy and numeracy skills retained their high value in the labour market over the period 1995-2004, despite numerous policy attempts to increase the supply of basic skills during this period. Appended are: (1) UK Classifications of levels of literacy and numeracy; (2) British Cohort Study 1970--2004 sweep at age 34; (3) Means and Standard errors of the preferred BCS sample (N=3131); and (4) Full specification for Table 2 (main text): The relationship between age 34 basic skills and earnings: men and women. (Contains 12 tables and 31 footnotes.)
- Published
- 2007
38. Higher Education Academic Salaries in the UK. CEE DP 75
- Author
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London School of Economics & Political Science, Centre for the Economics of Education, Collins, Mark, Vignoles, Anna, and Walker, James
- Abstract
The recent industrial action taken by the Association of University Teachers (AUT) has given the issue of academic pay high prominence in the UK press. There appears to be a remarkable consensus that higher education academic salaries are too low, relative to other groups of workers in the UK, and that this is leading to an academic "brain drain". There is concern that this in turn will result in lower quality higher education, as universities fail to attract the "brightest and the best". To rise above the rhetoric, there is a pressing need for robust evidence on relative academic salaries. In this paper, we compare the salaries of Higher Education teaching professionals in the United Kingdom with those of other comparable professionals. We offer evidence on relative salaries in HE academia over the last decade or so and we compare academic salaries to a range of different comparator groups, including some specific occupational groupings that one might view as more similar, in terms of unobserved characteristics, to academics. We then consider the extent to which the gap between the earnings of HE academics and that of other occupations is attributable to differences in the characteristics of academics, for example the fact that they are more highly educated on average, or to differences in the price paid for a given set of characteristics. We conclude that HE teaching professionals earn somewhat lower earnings than most public sector graduates and do particularly poorly compared to most other comparable professionals; they also work longer hours than most. In particular, academic earnings compare poorly to those in the legal professions, consultants physicians and dental practitioners (across both the public and private sectors). On the other hand, there are groups of public sector workers that do worse than HE academics, and in particular FE academics earn significantly less. Technical Information is appended. (Contains 7 tables and 2 footnotes.)
- Published
- 2007
39. Rippled nanocarbons from periodic arrangements of reordered bivacancies in graphene or SWCNTs
- Author
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Leyssale, Jean-Marc, Vignoles, G érard L., and Villesuzanne, Antoine
- Subjects
Condensed Matter - Materials Science - Abstract
We report on various nanocarbons formed from a unique structural pattern containing two pentagons, three hexagons and two heptagons, resulting from local rearrange- ments around a divacancy in pristine graphene or nanotubes. This defect can be inserted in sheets or tubes either individually or as extended defect lines. Sheets or tubes containing only this defect as a pattern can also be obtained. These fully defective sheets, and most of the tubes, present a very pronounced rippled (wavy) structure and their energies are lower than other structures based on pentagons and heptagons published so far. Another particularity of these rippled carbon sheets is their ability to fold themselves into a two-dimensional porous network of inter- connected tubes upon heat treatment as shown by hybrid Monte Carlo simulations. Finally, contrary to the common belief that pentagon/heptagon based structures are metallic, this work shows that this defect pattern should give rise to semi-metallic conduction.
- Published
- 2012
- Full Text
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40. Using Rate of Return Analyses to Understand Sector Skill Needs. CEE DP 70
- Author
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London School of Economics & Political Science, Centre for the Economics of Education, Powdthavee, Nattavudh, and Vignoles, Anna
- Abstract
Policy-makers in almost all countries agree on one thing: namely on the importance of education and skills to ensuring future economic prosperity. A fruitful line of research has focused on determining the impact that acquiring education or training has on an individual's labour market productivity and earning prospects: this is known as rate of return analysis. The Centre for the Economics of Education (CEE) has undertaken extensive research in this area and provided evidence on the returns to a variety of qualifications in the UK (CEE Discussion Papers 4, 6, 35 and 47). The CEE has also investigated specific issues such as the return to basic skills (CEE DP 3), returns to the marginal learner (CEE DP 45), returns to NVQ2 (CEE DP 46), the returns to qualifications acquired in adulthood (CEE DPs 19 and 39) and the returns to training (CEE DP 36). In addition the CEE has researched the range of methodological issues pertaining to rate of return analysis (see CEE DP 5 and 16). In this paper the authors summarise current understanding on the returns to qualifications, focusing specifically on differences in the economic values of qualifications by sector. First they explain what they mean by rate of return analysis in section 2. In section 3 they then discuss how rates of return estimates might be useful for policy-makers, and in particular how those who are trying to understand and meet the skill needs of different sectors of the economy might use such information. In section 4 they describe how rates of return are actually calculated in practice, before going on to summarise the evidence base. They start with a discussion of aggregate supply and demand in section 5, before focusing on the rate of return to specific qualifications and types of education in section 6. They conclude with an analysis of what the empirical evidence implies for policy-makers working on sector skills issues (section 7). A complex picture emerges from the evidence base: (1) In the UK there has been a massive expansion in the supply of qualified labour; (2) Qualifications that are supposedly tailored to employers' skill needs, such as NVQs, are actually valued less highly in the labour market; (3) Newer vocational qualifications (particularly NVQ2) yield a zero or minimal return in the labour market, although they do increase an individual's likelihood of being in employment; (4) The return to lower level vocational qualifications varies substantially across sectors; (5) NVQ qualifications yield a respectably high return if they are acquired through a modern apprenticeship; (6) Rapid expansion of the supply of graduates has resulted in much more variation in graduate outcomes; (7) Much of the apparent fall in the return to a degree for very new graduates is concentrated specifically on graduates who fail to get graduate level jobs; (8) There is substantial variation in returns across different degree subjects, and by implication across different sectors of the economy; and (9) In particular, the return to arts and humanities degrees for very recent graduates appears to have fallen to zero. Additional tables are appended. (Contains 7 figures, 10 tables and 14 footnotes.) [Additional funding was provided by the Sector Skills Development Agency.]
- Published
- 2006
41. What Should an Index of School Segregation Measure? CEE DP 60
- Author
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London School of Economics & Political Science, Centre for the Economics of Education, Allen, Rebecca, and Vignoles, Anna
- Abstract
The paper aims to make a methodological contribution to the education segregation literature, providing a critique of previous measures of segregation used in the literature, as well as suggesting an alternative approach to measuring school segregation. It also provides new empirical evidence on changes in the extent of socio-economic segregation (measured by free school meals (FSM) entitlement) in English schools during the last fifteen years. Specifically, the paper examines Gorard "et al.'s" (2000a, 2003) finding that FSM segregation between schools fell significantly in the years following the 1988 Education Reform Act. Using Annual Schools Census data from 1989 to 2004, the paper challenges the magnitude of their findings, suggesting that the method used by Gorard et al. actually overstates the size of the fall in segregation by 100%. Our results show evidence of an increase in the index of dissimilarity in many Local Authorities, especially in London, although in the South-East as a whole we note that it falls. We also observe higher segregation in LEAs with higher proportions of pupils at voluntary-aided schools. We cannot confirm however, whether this is a causal relationship. It is not necessarily the case that the rise in the segregation index in these Local Authorities is attributable to the behaviour of VA schools. Much of this paper is a critique of previous methods used to measure segregation in schools. For example, we suggest that the GS index is not the optimal way of measuring changes in school segregation for the following reasons: (1) GS is not bounded by 0 and 1: the upper boundary varies according to FSM eligibility, so GS is better described as an "indicator" rather than an index of segregation; (2) GS is not symmetric, meaning that it is capable of showing that FSM segregation is rising and NONFSM segregation is falling simultaneously; and (3) GS is actually systematically variant to changes in overall FSM eligibility, except in the most stringent and unlikely of circumstances (the strict proportionate change in FSM); therefore we can properly describe it as composition variant. It had a tendency to fall as FSM eligibility rises, regardless of the change in the unevenness of school's shares of FSM and NONFSM pupils. In this paper we make the case for a segregation curve approach to measuring segregation and use one exemplar index, the index of Dissimilarity, to re-evaluate the extent of school segregation in England over the last fifteen years. What can we conclude? (1) There was no pervasive increase in segregation over the period; (2) There are a number of potential explanations for this. For example, it may be that de facto school choice did not in fact increase during this period due to capacity constraints; (3) The analysis does however provide clear evidence of an increase in segregation, as measured by the index of dissimilarity, in many Local Authorities, particularly in London. The index is also higher in LEAs with higher proportions of pupils educated at voluntary-aided schools, although this relationship is not necessarily causal; (4) We have not been able evaluate the causal impact of policies that give schools increased control over their own admissions on segregation, however we have found an association between LEAs with higher proportions of pupils in schools that control their own admissions or have explicit select by ability and the level of FSM segregation. We suggest that the level of measured segregation be carefully monitored over time, as the proportion of schools that are LEA community schools continues to fall; and (5) We note that pupil numbers in secondary schools will fall from 2005. It will be important that measures are taken to improve the ability of disadvantaged pupils to take up free places in the schools of their choice, otherwise the spare capacity in the system may well result in rising levels of segregation and in particular a concentration of disadvantaged pupils in some schools operating in deprived areas. We conclude that deciding how best to measure segregation is complex, combining fundamentally normative judgements about what exactly one intends to measure, with more technical judgements about the appropriate properties of the chosen measure. We believe that we have made a good case for a specific approach, being open about the normative judgements we have made to reach our conclusion. We have chosen to criticise one alternative approach to measuring segregation, GS, examining its properties in detail. Further research is certainly needed to subject alternative methods of measuring school segregation, such as multilevel modelling or the isolation index, to the same level of scrutiny. (Contains 6 tables, 13 figures and 12 footnotes.)
- Published
- 2006
42. Education Policy in the UK. CEE DP 57
- Author
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London School of Economics & Political Science, Centre for the Economics of Education, Machin, Stephen, and Vignoles, Anna
- Abstract
Throughout the post-war period there have been many attempts to reform the UK education system, often with an explicit intention to try and make it more productive. The list of education policy reforms that have been attempted over the last 50 years is quite extensive, and recently the UK (and in particular England and Wales) has introduced many innovative market-oriented reforms to its education system, in an attempt to raise standards. The most striking recent reform is that parents have increasingly been given much more choice in terms of the school attended by their children, and schools have been forced to be more accountable. Other notable reforms include a nationally prescribed curriculum, vigorous attempts to raise participation in post-compulsory schooling and the introduction of tuition fees for higher education. In this article the authors describe a number of the more important educational reforms that have been introduced in the UK during the last twenty years or so, and where possible they provide evidence of their impact. However, in the UK, although economists and others are increasingly able to inform policy-makers on the impact and efficacy of specific policy interventions, the evaluation of specific policies in a rigorous manner unfortunately remains relatively unusual. This is mainly because the design of policy interventions is often such that they are not amenable to economic evaluation. Here the authors highlight what one can view as robust findings on each policy intervention, and point to where more evidence is needed. (Contains 4 tables, 2 figures and 5 footnotes.)
- Published
- 2006
43. The Heterogeneous Effect of Selection in Secondary Schools: Understanding the Changing Role of Ability. CEE DP 52
- Author
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London School of Economics & Political Science, Centre for the Economics of Education, Galindo-Rueda, Fernando, and Vignoles, Anna
- Abstract
There has been a substantial rise in British education levels in recent decades, and new empirical evidence suggests that less able but wealthier children have benefited most from this expansion, at least during the 1970s and 1980s. There are many potential explanations for this trend. For example, during this period, the UK's highly selective "grammar school" system was largely dismantled. It is possible that reducing the extent of selection by ability in the UK education system may have altered the relationship between ability, family background and educational achievement, reducing the impact of ability on achievement and increasing the impact of family income and other family background factors. We test this hypothesis using data from the UK in the 1970s. Whilst the impact of the UK grammar system is of course of enormous historical interest, this issue also has significant policy relevance today. Certainly selection remains a topical issue. In the UK and indeed in the US, there have been recent policy initiatives that have attempted to explicitly or implicitly increase selection in the school system. Furthermore, in some parts of the UK, grammar schools remain an important feature of the education system. In this paper we explore and quantify the relationships between early cognitive ability, family background and school selection on the one hand, and educational achievement on the other, focusing particularly on the effects of selective schooling on different groups of students. For example, we assess the impact of selection on higher and lower ability pupils. Our results indicate that the most able pupils in the selective school system did do somewhat better than those of similar ability in mixed ability school systems. Thus the grammar system was advantageous for the most able pupils in the system, i.e. highly able students who managed to get into grammar schools. On the other hand, lower ability pupils did not do systematically better or worse in the selective school system. Many commentators have argued that the "comprehensive experiment" failed in England and Wales, reducing standards and educational achievement. To some extent our findings support this. The shift to mixed ability schooling did reduce the educational achievement of the most able. From an historical perspective, our results also suggest that the dismantling of the UK selective school system played some part in ensuring that the subsequent expansion of the education system disproportionately benefited less able (but wealthier) students. In terms of the current policy agenda, our evidence is potentially comforting to those who endorse increased selection in the education system, suggesting that the most able might benefit from a more selective system and that the negative impact of selection on the rest of the school population is likely to be small. However, the new forms of selection being introduced into the education system today are very different from the UK grammar school system of the 1960s. Furthermore, there are myriad other differences between the current UK education system and that of forty years ago, in terms of pupil characteristics, school standards, school enrolment patterns, curricula developments etc. All these other factors will also impact on pupil achievement, and interact with any selection that might be introduced into the system. Further research on current forms of selection is therefore urgently needed. Appended are: (1) Probability of attending a school in selective system conditional on comprehensive school density; and (2) Reduced form effects of local authority share in non-comprehensive schools. (Contains 11 tables and 24 footnotes.)
- Published
- 2005
44. The school policy, social, and physical environment and change in adolescent physical activity: An exploratory analysis using the LASSO.
- Author
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Campbell Foubister, Esther M F van Sluijs, Anna Vignoles, Paul Wilkinson, Edward C F Wilson, Caroline H D Croxson, Helen Elizabeth Brown, and Kirsten Corder
- Subjects
Medicine ,Science - Abstract
PurposeWe examined the association between the school policy, social and physical environment and change in adolescent physical activity (PA) and explored how sex and socioeconomic status modified potential associations.MethodsData from the GoActive study were used for these analyses. Participants were adolescents (n = 1765, mean age±SD 13.2±0.4y) from the East of England, UK. Change in longitudinal accelerometer assessed moderate-to-vigorous physical activity (MVPA) was the outcome. School policy, social and physical environment features (n = 267) were exposures. The least absolute shrinkage and selection operator variable selection method (LASSO) was used to determine exposures most relevant to the outcome. Exposures selected by the LASSO were added to a multiple linear regression model with estimates of change in min/day of MVPA per 1-unit change in each exposure reported. Post-hoc analyses, exploring associations between change in variables selected by the LASSO and change in MVPA, were undertaken to further explain findings.FindingsNo school policy or physical environment features were selected by the LASSO as predictors of change in MVPA. The LASSO selected two school social environment variables (participants asking a friend to do physical activity; friend asking a participant to do physical activity) as potential predictors of change in MVPA but no significant associations were found in subsequent linear regression models for all participants (β [95%CI] -1.01 [-2.73;0.71] and 0.65 [-2.17;0.87] min/day respectively). In the post-hoc analyses, for every unit increase in change in participants asking a friend to do PA and change in a friend asking participants to do PA, an increase in MVPA of 2.78 (1.55;4.02) and 1.80 (0.48;3.11) min/day was predicted respectively.ConclusionsThe school social environment is associated with PA during adolescence. Further exploration of how friendships during adolescence may be leveraged to support effective PA promotion in schools is warranted.
- Published
- 2021
- Full Text
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45. Revisiting Free School Meal Eligibility as a Proxy for Pupil Socio-Economic Deprivation
- Author
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Ilie, Sonia, Sutherland, Alex, and Vignoles, Anna
- Abstract
Whether someone has ever had free school meal (FSM) eligibility over a six-year period is the measure of socio-economic disadvantage currently used in the English school system. It is used to monitor the socio-economic gap in achievement in the education system, to identify particular children at risk of low achievement and to direct funding to particular children and schools. In this paper we assess how well this measure predicts pupil attainment in secondary school in comparison to other measures of socio-economic background known to influence pupil attainment, such as parental education or income. We ask whether the FSM measure is an adequate proxy for a pupil's socio-economic disadvantage in an educational context. To do this we draw on the Longitudinal Study of Young People in England and matched administrative data. We find that the FSM eligibility measure correlates highly with other measures of socio-economic disadvantage, however it does not identify all children living in what would be deemed deprived households. We then compare the extent to which the FSM eligibility measure predicts educational achievement relative to other measures of deprivation and find that its predictive power is only marginally lower than many richer survey measures. This provides some reassurance on its use in policy.
- Published
- 2017
- Full Text
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46. Private Schooling and Labour Market Outcomes
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Green, Francis, Henseke, Golo, and Vignoles, Anna
- Abstract
Though a relative small part of the school sector, private schools have an important role in British society, and there are policy concerns about their negative effect on social mobility. Other studies show that individuals who have attended a private school go on to have higher levels of educational achievement, are more likely to secure a high-status occupation and also have higher wages. In this article we contribute new evidence on the magnitude of the wage premium, and address a puzzle found in previous studies: how to explain the direct pay premium whereby privately educated male workers have higher wages even than their similarly educated peers. It is commonly conjectured that the broader curriculum that private schools are able to deliver, coupled with the peer pressures of a partially segregated section of society, help to inculcate cultural capital, including some key "non-cognitive" attributes. We focus here on leadership, organisational participation and an acceptance of hard work. We find that privately educated workers are in jobs that require significantly greater leadership skills, offer greater organisational participation and require greater work intensity. These associations are partially mediated by educational achievement. Collectively these factors contribute little, however, to explaining the direct pay premium. Rather, a more promising account arises from the finding that inclusion of a variable for industry reduces the private school premium to an insignificant amount, which is consistent with selective sorting of privately educated workers into high-paying industries.
- Published
- 2017
- Full Text
- View/download PDF
47. When and Why Do Initially High-Achieving Poor Children Fall Behind?
- Author
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Crawford, Claire, Macmillan, Lindsey, and Vignoles, Anna
- Abstract
In this paper, we examine the trajectories of initially higher- and lower-achieving children from lower and higher socio-economic status families from primary school through to university in England for the first time. We also explore what explains these trajectories. This enables us to provide new insights into when and why the performance of children with similar initial achievement diverges on the basis of their socio-economic background. Our results indicate that pupils from poor backgrounds who are higher achievers in primary school fall behind their better-off but lower-achieving peers during secondary school. This suggests that secondary school may be a critical period to intervene to prevent poor children from falling behind their richer peers. Our analysis suggests that there is less divergence in performance between pupils from different socio-economic backgrounds who attend the same schools. This result is particularly strong for children with low initial achievement. While we remain cautious about the implications of these findings, they provide suggestive evidence that schools (or the sorting of pupils into schools) play an important role in explaining why the test scores of richer and poorer children diverge over time.
- Published
- 2017
- Full Text
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48. An Efficient and Accurate Formalism for the Treatment of Large Amplitude Intramolecular Motion
- Author
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Reinisch, Guillaume, Miki, Kenji, Vignoles, Gérard L, Wong, Bryan M, and Simmons, Chris S
- Subjects
Theoretical and Computational Chemistry ,Biochemistry and Cell Biology ,Computer Software ,Chemical Physics - Abstract
We propose a general approach to describe large amplitude motions (LAM) with multiple degrees of freedom (DOF) in molecules or reaction intermediates, which is useful for the computation of thermochemical or kinetic data. The kinetic part of the LAM Lagrangian is derived using a Z-matrix internal coordinate representation within a new numerical procedure. This derivation is exact for a classical system, and the uncertainties on the prediction of observable quantities largely arise from uncertainties on the LAM potential energy surface (PES) itself. In order to rigorously account for these uncertainties, we present an approach based on Bayesian theory to infer a parametrized physical model of the PES using ab initio calculations. This framework allows for quantification of uncertainties associated with a PES model as well as the forward propagation of these uncertainties to the quantity of interest. A selection and generalization of some treatments accounting for the coupling of the LAM with other internal or external DOF are also presented. Finally, we discuss and validate the approach with two applications: the calculation of the partition function of 1,3-butadiene and the calculation of the high-pressure reaction rate of the CH(3) + H → CH(4) recombination.
- Published
- 2012
49. Digitization and image-based structure-properties relationship evaluation of a porous gold micro-electrode
- Author
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A. Baux, G. Couégnat, G.L. Vignoles, D. Lasseux, A. Kuhn, C. Carucci, N. Mano, and T.D. Le
- Subjects
Porous material ,FIB-SEM ,Digitization ,Defects ,Pore network ,Materials of engineering and construction. Mechanics of materials ,TA401-492 - Abstract
The advantage of using porous materials for biofuel cells and biosensors is their very large internal surface area (where electron exchange takes place) compared to the overall material volume, yielding much larger current densities than on a bare solid electrode of the same size. However, limitations occur because of mass transfer resistance through the pores. We describe here a bottom-up approach to optimize the design of such materials, through the analysis and modeling of their porous structure. Electrodes prepared by replicating stacked Langmuir-Blodgett films, with 1-μm diameter interconnected spherical pores, were studied. Since pore window dimensions are around 100 nm, Focused Ion Beam-Scanning Electron Microscopy (FIB-SEM) has been performed to obtain a 3D reconstruction of the porous medium. Then, a determination of the geometrical characteristics has been achieved through image analysis. The structure of the sphere packing, the shape and size of the connections between spheres, the distances between spheres, the sphere diameters and the specific surface area have been analyzed. The porous medium is close to a face-centered cubic arrangement of spherical pores, but several deviations from ideality are present: missing pores (point defects), stacking errors (dislocations), and incomplete connection between spheres (only 50% of the ideal sphere connections are present). The consequence of such defects on transport is studied through image-based simulations of mass diffusion in the actual porous medium and in similar ideal media.
- Published
- 2020
- Full Text
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50. Chemical Supercritical Fluid Infiltration of Pyrocarbon with Thermal Gradients: Deposition Kinetics and Multiphysics Modeling
- Author
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Gerard L. Vignoles, Gaëtan Talué, Quentin Badey, Alain Guette, René Pailler, Yann Le Petitcorps, and Laurence Maillé
- Subjects
process modeling ,heat and mass transfer ,supercritical fluid ,infiltration front ,chemical vapor infiltration (CVI) ,ceramic-matrix composites (CMCs) ,Technology ,Science - Abstract
The chemical supercritical fluid infiltration process is a recent variation of the chemical vapor infiltration (CVI) process that allows rapid and efficient manufacturing of ceramic-matrix composites (CMCs), albeit still needing optimization. This article proposes a quantitative assessment of the process dynamics through experiments and modeling. The kinetics of carbon deposition were determined through two sets of experiments: CVD on a single filament at pressures between 10 and 50 bar and infiltration at pressures ranging between 50 and 120 bar. The CVI experiments were conducted under important thermal gradients and were interpreted using a model-based reconstitution of these gradients. We found that (i) the kinetic law has to incorporate the potential effect of the reverse reaction (i.e., etching of C by H2); (ii) the activation energy and pre-exponential factor both decrease with pressure up to 50 bar, then remain roughly constant, and (iii) although the apparent activation energy is modest, a favorable situation occurs in which an infiltration front builds up and travels from the hottest to the coldest part of the preform due to the presence of sufficient heat flux. A numerical simulation of the process, based on the solution of momentum, heat, and mass balance equations, fed with appropriate laws for the effective transfer properties of the porous medium and their evolution with infiltration progress, was performed and validated by comparing the simulated and actual infiltration profiles.
- Published
- 2022
- Full Text
- View/download PDF
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