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A influência de condições halomórficas, hidromórficas e sulfato redutoras na mineralogia da fração argila e na geoquímica de três solos de mangue foi estudada no manguezal do rio Iriri. A partir de uma transeção, foram escolhidos três perfis representativos dos solos de mangue da área nos quais foram descritas as condições geoquímicas e sua conseqüência sobre a mineralogia de seus respectivos solos. A análise mineralógica (DRX e EDS) e as condições físico-químicas encontradas revelam a ocorrência de processos de piritização na área de estudo. A assembléia mineralógica está composta tanto por argilominerais alóctones (caulinitas, micas e esmectitas) como por argilominerais autóctones (micas, esmectitas e pirita). A partir de evidências provenientes da DRX e EDS, especula-se a formação de glauconita nestes solos. As condições de halomorfia e hidromorfia determinam valores de Eh e pH sob os quais elementos como Fe2+ e SO encontram-se livres na solução do solo com tendência à estabilidade da pirita (FeS2), favorecendo, portanto, o processo da piritização.

The Kayapó Xicrin do Cateté (Xicrin) indigenous reserve is located within the Amazon forest in Pará (Brazil). The Xicrins have developed a soil classification system that is incorporated in their language and culture. The etymology of their classification system and its logical structure makes it similar and comparable with modern soil classification. The etymology of the Xicrin's language is based on the junction of radicals to form words for different soil names. The name of the soil is formed by the main noun radical "puka", to which adjectives referring to soil morphological attributes are added. Modern classification systems are also based on similar morphological variables, and analytical support for defining boundaries of chemical or physical soil attributes are important only in lower hierarchical levels. Soil scientists have developed a soil classification system that is sensitive for the restrictions and potentialities the soil will show for modern agriculture. The Xicrins classify soils for what is important for their life style, i.e. a harmonic and friendly life with the resources they gain from the forest.

ABSTRACT Kaolinite is the main clay mineral in most soils around the world and has been widely used for industrial purposes. This research aimed to study chemical, morphological and crystallographic characteristics of kaolinite, and establish the origin of kaolinitic samples on Serra do Mar and kaolinitic layers on peatlands, located at Southern Brazil. Samples were collected on different geomorphological positions: two samples at Serra do Mar (kaolinitic saprolite – SAP, and kaolinitic layers - KL); and two cores at the peatland with Sapric Histosols from Quaternary sedimentary basin. Granulometry and total organic carbon (TOC) were determined in soil samples. Kaolinite in silt and clay fractions was studied by chemical extractions, X-ray diffraction (XRD), thermal analysis (DTA/TG), and scanning electron microscopy with energy dispersive spectroscopy – SEM/EDS. Chemical and mineralogical characteristics of kaolinite were divided into two groups, according to the particle size and the location of the deposit in the relief. Silt fraction: i) SAP – genesis mainly derived from mica weathering; ii) peatland, containing pseudomorph crystals smaller than those found in Serra do Mar; Clay fraction: i) Serra do Mar – there was a larger contribution of K-feldspar weathering in the genesis of kaolinite from KL in relation to SAP; ii) peatland – the stronger weathering and the hydromorphic conditions resulted in less neoformed crystalline kaolinites. For both environments, the substitution of Al3+ by Fe3+ into the octahedral sheet led to a reduction in the mineral thickness and also increased the occurrence of structural deformations in clay kaolinite. Kaolinite in peatland is a combination of the following genesis processes: transportation from Serra do Mar (mainly in the silt fraction) and; formation in situ through neogenesis process (dominant in the clay fraction).

O objetivo deste trabalho foi avaliar diferentes métodos de extração e quantificação de alumínio trocável em Organossolos. As amostras foram coletadas em três perfis de turfeira e, então, secas ao ar e passadas em peneira de malha de 2 mm. Foram feitas extrações com KCl 1 mol L-1 , Ca(OAc2) 1 mol L-1 e CuCl2 0,5 mol L-1 . Em seguida, os extratos obtidos por KCl e Ca(OAc2) foram analisados por titulação com NaOH 0,025 mol L-1 e por espectrômetro de absorção atômica com forno de grafite (GF-AAE). Os extratos obtidos por CuCl2 foram analisados por GF-AAE. Na quantificação por GF-AAE, os extratores KCl e Ca(OAc2) tiveram capacidade semelhante de extrair alumínio trocável, enquanto o CuCl2 foi capaz de extrair também o Al reativo. Os elevados teores de alumínio trocável observados na titulação após extração com KCl podem estar relacionados aos elevados teores do íon H+ presente nas amostras. O método indicado para determinação do teor de alumínio trocável em Organossolos é a extração com KCl ou com Ca(OAc2) e, para quantificação, a espectrofotometria de absorção atômica com forno de grafite.

The scarcity of comprehensive characterizations of soils associated to gentle summit depressions of the Northeastern Brazilian Coastal Plains justifies this work, which had as objective to provide basic information for the more diverse agricultural and non-agricultural uses. For that, representative soils (Spodosols or similar soils) from these environments were selected in Alagoas, Sergipe and Bahia states. This approach included characterization of morphological, mineralogical and micromorphological properties of the soil profiles, employing standard procedures. The morphological characterization corroborated the effect of the podzolization process during the formation of these soils. The mineralogy of the clay fraction of these soils was basically composed of kaolinite and quartz, which, associated to the very sandy texture, helped in the understanding of the obtained data. The soil micromorphological study, besides confirming the field morphology, mainly in regard to the strong cementation, aggregated value to the work in terms of the secure identification of the clay illuviation process (non-identified in the field), in association with the dominant podzolization process.A carência de caracterizações abrangentes de solos associados às depressões suaves de topo dos Tabuleiros Costeiros do nordeste brasileiro justifica este trabalho, o qual objetivou fornecer informações básicas para as mais diversas finalidades agrícolas e não-agrícolas. Para tal, foram selecionados solos representativos (Espodossolos ou solos afins) desses ambientes nos estados de Alagoas, Sergipe e Bahia. A abordagem utilizada englobou a caracterização de atributos morfológicos, mineralógicos e micromorfológicos de perfis dos solos, empregando-se metodologia padronizada. A caracterização morfológica corroborou o efeito do processo de podzolização na formação desses solos. A mineralogia da fração argila desses solos foi composta basicamente por caulinita e quartzo, o que, ao lado da textura muito arenosa, ajudou na compreensão dos dados obtidos. O estudo micromorfológico do solo, além de confirmar a morfologia de campo, particularmente no tocante à forte cimentação, agregou valor ao trabalho em termos da identificação inequívoca do processo de argiluviação (não identificada no campo) em associação ao processo dominante de podzolização.

In tropical forests, the environmental heterogeneity can provide niche partitioning at local scales and determine the diversity and plant species distribution. Thus, this study aimed to investigate the variations of tree species structure and distribution in response to relief and soil profile features in a portion of the largest remnant of Brazilian Atlantic rain forest. All trees ³ 5 cm diameter at breast height were recorded in two 0.99 ha plots. Topographic survey and a soil characterization were accomplished in both plots. Topsoil samples (0-20 cm) were taken from 88 quadrats and analyzed for chemical and particle size properties. Differences for both diversity and tree density were identified among three kinds of soils. A canonical correspondence analysis (CCA) indicated that the specific abundance varied among the three kinds of soils mapped: a shallow Udept - Orthent / Aquent gradient, probably due to differences in soil drainage. Nutrient content was less likely to affect tree species composition and distribution than relief, pH, Al3+, and soil texture. Some species were randomly distributed and did not show restriction to relief and soil properties. However, preferences in niche occupation detected in this study, derived from the catenary environments found, rise up as an important explanation for the high tree species diversity in tropical forests.

Smectitic clay minerals are frequently identified in mangrove soils, but there is little information about their types and origins. Besides their importance in the agronomical and geotechnical areas, smectites play an important environmental role by adsorbing nutrients, organic pollutants and heavy metals. Smectites found in mangrove soils can be of marine or continental detrital origin, or of neoformation origin. Thus, the objective of this study was to identify the types of smectites present in the State of São Paulo mangrove soils (Brazil), and to relate them to their possible origins. Soil samples were taken in five mangroves along the State of Sao Paulo State coast line. The mineral composition of the clay fraction was identified by X-ray Diffractometry (XRD) applying the Greene-Kelly test and by Fourier transform infrared spectroscopy (FTIR). Highlighting the peaks in the 3,560 cm-1 band and in the region near 798 and 820 cm-1, there was a predominance of nontronite in the soil at the Sítio Grande River, Pai Matos Island, Caranguejo Island and Itapanhaú River mangroves, and possibly a lower concentration of ferric montmorillonite in the Escuro River mangrove. Since the continental sediments in these environments are very poor in smectite, the origin of these minerals in the mangrove soils studied is related to sedimentation left by past marine transgressions, to neoformation processes, or yet to a combination of both origins.Minerais de argila esmectíticos são freqüentemente identificados em solos de manguezais, mas são escassas as informações sobre os tipos encontrados e suas origens. A despeito da importância para a agronomia e geotecnia, as esmectitas desempenham também importante papel no âmbito ambiental, atuando na adsorção de nutrientes, poluentes orgânicos e metais pesados. Esmectitas em solos de manguezais podem ser de origem detrítica, marinha ou continental, e também de neoformação. Assim, este estudo objetivou identificar os tipos de esmectitas presentes em solos de manguezais do Estado de São Paulo e relacioná-los com suas possíveis origens. Para tanto, foram amostrados solos de cinco manguezais distribuídos ao longo do litoral paulista, cuja identificação dos constituintes mineralógicos da fração argila foi realizada por difratometria de raios X (DRX) com aplicação do teste de Greene-Kelly e por espectroscopia no infravermelho com transformada de Fourier (FTIR). Destacando os picos na banda de 3.560 cm-1 e na região próxima a 798 e 820 cm-1, verificou-se o predomínio de nontronita nos solos dos manguezais do Rio Sítio Grande, Ilha de Pai Matos, Ilha do Caranguejo e Rio Itapanhaú e, possivelmente menor participação de montmorilonita férrica no manguezal do Rio Escuro. Como os sedimentos continentais destes ambientes são muito pobres em esmectitas, a origem destes minerais nos solos dos manguezais estudados está relacionada à sedimentação deixada pelas transgressões marinhas pretéritas ou aos processos de neoformação ou, ainda, com uma combinação de ambas origens.

Microaggregates that characterize ferralic soils have been hypothesized to have physical, geochemical and/or biological origins. Despite of many studies, the hierarchy between these processes that form microaggregates has seldom been reported. The objective of this work was to study the genesis of microaggregates in a sequence of Ferralic Nitisols developed on Quaternary red clayey sediments and diabase in Piracicaba (SP), Brazil. This issue was tackled by combining optical microscopy, image analysis, scanning electron microscopy and elemental iron quantifications by X-ray fluorescence. Micromorphological investigations showed three different types of microaggregates: (i) oval microaggregates with well sorted quartz grains in their interior; (ii) oval microaggregates without or with poorly sorted quartz grains in their interior; and (iii) dense polyedric microaggregates. These morphological evidences, together with the elemental iron determinations and scanning electron microscopy, revealed the contribution of more than one process for microaggregate formation: (i) the mechanical action of the mesofauna would form the first type of microaggregates (ii) geochemical and biological processes would form the second type and (iii) the fissuration of the soil matrix by expansion and compression processes would form the third type.Os microagregados, característicos do horizonte B latossólico, podem ser formados a partir de processos físicos, geoquímicos e biológicos. Apesar da quantidade de trabalhos realizados sobre este tema, poucos tem discutido a hierarquia entre os processos que formam estes microagregados. O objetivo deste trabalho foi estudar a gênese dos microagregados numa seqüência de solos localizada em Piracicaba (SP), Brasil. Os solos foram classificados como Nitossolos Vermelhos Eutroférricos latossólicos e desenvolvem-se a partir de sedimentos argilosos vermelhos do Quaternário e diabásio. Para atingir o objetivo deste trabalho foram utilizadas técnicas de microscopia ótica, análise de imagens, microscopia eletrônica de varredura e quantificações elementares de ferro através de fluorescência de raio-X. As investigações micromorfológicas mostraram a presença de três tipos de microagregados: (i) microagregados ovais com grãos de quartzo bem selecionados no seu interior; (ii) microagregados ovais sem grãos de quartzo ou grãos de quartzo mal selecionados no seu interior; e (iii) microagregados poliédricos densos. Estas evidencias morfológicas junto com os dados elementares de ferro e a microscopia eletrônica de varredura mostraram a contribuição de mais de um processo na formação dos microagregados: (i) a ação mecânica da mesofauna seria responsável pela formação do primeiro tipo de microagregados; (ii) processos geoquímicos e biológicos estariam formando o segundo tipo de microagregados; e (iii) a fissuração da matriz do solo por processos de contração e expansão formariam o terceiro tipo de microagregados.

Numa sequência de solos sobre diabásio localizada no campus da USP em Piracicaba a formação de ferri-argilãs e os processos de adensamento foram estudados. Foram realizados estudos morfológicos, micromorfológicos, de microscopia eletrônica de varredura e microanálise em amostras retiradas de três trincheiras localizadas nesta sequência. A presença de ferri-argilãs de iluviação foi observada nos horizontes B textural e na alterita principalmente preenchendo a porosidade mamelonar, policôncava e fissural provocando o adensamento dos mesmos. Evidências de hidromorfia temporária sugeriram que este processo estaria provocando a desestabilização das ligações ferro-argila facilitando assim a mobilização e redistribuição do ferro e da argila.The formation of ferriargillans and densing processes were studied on a soil sequence over diabase situated in Piracicaba (SP) Brazil. Morphological, micromorphological, scanning electron microscopic and microanalytical studies were performed on samples taken from three trenches within the sequence. The presence of illuvial ferriargillans was observed mainly in the argillic B horizons and the saprolite, which filled the mamelonar, polyconcave and planar voids which led to their densing. Evidence of temporary hydromorphy suggested that this process would affect the stability of the iron oxide-clay interactions which would promote the mobilization and redistribution of iron and clay.

The minerals of the clay fraction in estuarine plains are mainly detrital, being a mixture of marine and continental sediments, but can also be authigenic. Because of the importance of mangrove ecosystems in tropical estuarine areas and the relatively few existing studies of the mineralogical composition of soils in these environments, the aim of this study was to determine the mineralogical assemblage and identify potential contrasts along the coast of the State of Sao Paulo. Soils from 11 mangroves distributed along the coastal plain of the State of Sao Paulo were sampled at depths of 0 to 20 and 60 to 80 cm, and samples of suspended sediments from the Ribeira do Iguape River were collected for analysis. Mineralogical analyses were performed on the clay and silt fractions by x-ray diffraction (XRD) and transmission electron microscopy, and flesh soil samples were analyzed by scanning electron microscopy-energy dispersive spectrometry and suspended sediments by XRD. The silt fraction contained quartz, feldspars, gibbsite, kaolinite, illite, and vermiculite, and the clay fraction contained smectite, kaolinite, illite, gibbsite, quartz, and feldspars. Locally, vermiculite, biotite, anatase, halloysite, and goethite may occur because of recent transport of sediments to the system. Pyrite was identified in fresh samples. The allochthonous minerals found either were terrestrial and transported by rivers or had originated from the continental platform by past transgressive events. We suggest that the neoformation of smectite and kaolinite occurs in mangrove soils. Different geomorphological settings along the Sao Paulo coast appear to regulate mineral distribution in mangrove soils. Abbreviations: IGUA, Caranguejo Island; ITA, Itapanhau River; PM, Pal Matos Island; RE, Escuro River; RF, Fazenda River; XRD, x-ray diffraction.

Pore-water and solid-phase analysis was undertaken to study the effects of different environmental conditions on redox processes in mangrove soils on the southern coast of Brazil. Three Rhizophora mangle (L.) mangrove forests were studied in different physiographic positions--riverine, fringe, and basin forest--and substrate compositions. Our results indicate different geochemical conditions in soils from different physiographic positions. In the fringe soils, the low acid-volatile sulfide and pyrite Fe contents, associated with high values of [Fe.sup.2+] in pore water, indicate oxic and suboxic conditions in surface layers (0-10 cm). Below this depth, anoxic conditions prevail and sulfate reduction becomes the dominant process of organic matter decay, as indicated by higher concentrations of dissolved H[S.sup.-] and pyrite Fe. In the basin forest, long periods of tidal flooding and low rates of litter export maintained anoxic conditions and high organic matter contents, necessary for anoxic respiration to take place, as shown by the low [Fe.sup.2+] and H[S.sup.-] concentrations in pore water, along with high degree of Fe pyritization values and high concentrations of pyrite Fe. In the riverine soils, the lowest concentrations of pyrite Fe and the highest concentrations of H[S.sup.-] in pore water were obtained in response to low availability of reactive Fe (0-10cm, 31.8 [+ or -] 8.0 mmol [kg.sup.-1]; 20-30 cm, 43.2 [+ or -] 32.3 mmol [kg.sup.-1]) due to its sandy texture, which limits pyrite synthesis. Our results indicate that the participation and intensity, of each process may vary within different physiographic positions because of the effects on the frequency and duration of tidal flooding and soil composition. Our results also show that R. mangle is present on substrates with different geochemical conditions (oxic, suboxic, and anoxic). Abbreviations: AVS, acid-volatile sulfide; BRS, bacterial reduction of sulfate; DOP, degree of Fe pyritization; TOC, total organic carbon.

Wetlands near urban centers may be more isolated areas and can be chosen for the disposal of bodies or used as a crime scene. The predominant soils in these areas usually have a high content of organic matter (OM), classified as Histosols. Soil organic matter (SOM) is composed of many different compounds that can be identified by pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS). The study aimed to use Py-GC/MS to classify small amounts of organic soil in a forensic context. We sampled Histosols from five representative sites of Curitiba, Brazil. The molecular composition of the samples was determined by byPy-GC/MS. The factor analysis was carried out, and the factor scores showed a clear differentiation between the sites. Compounds indicative of relatively fresh plant material was separated from more recalcitrant and charred material. Py-GC/MS has the potential to be a useful tool to study the composition of SOM in Histosols to track the trace sample collected from a crime suspect. • 188 organic compounds were quantified by Py-GC/MS. • Compounds indicative of relatively fresh plant material showed high positive loadings. • Total aromatic compounds varied between 11 and 46%. • Py-GC/MS has potential to be a useful tool in forensic studies of organic soils. [ABSTRACT FROM AUTHOR]