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Fertilizer manufacturing is an energy-intensive process that is done in a select number of facilities across the world. We performed a literature review of methods that are being pursued in the emerging field of sustainable fertilizer manufacturing and analyzed the results of one such sustainably sourced fertilizer process. The results of our testing on a rooftop garden showed that the production of tomatoes was similar to the control and commercial fertilizer scenarios in that the total weight of tomatoes per plant was 16% higher, and the weight per tomato was 68% more than the control (tap water). We hope that this type of research will continue to be performed and expanded so that we can adopt a more sustainable method of fertilizer manufacturing in our pursuit of net positive environmental benefits.

The valorization of waste, by creating economic value while limiting environmental impact, can have an essential role in sustainable development. Particularly, polymeric waste such as biomass and plastics can be used for the production of green hydrogen as a carbon-free energy carrier through the use of nonthermal plasma powered by renewable, potentially surplus, electricity. In this study, a Streamer Dielectric-Barrier Discharge (SDBD) reactor is designed and built to extract hydrogen and carbon co-products from cellulose and low-density polyethylene (LDPE) as model feedstocks of biomass and plastic waste, respectively. Spectroscopic and electrical diagnostics, together with modeling, are used to estimate representative plasma properties, namely electron and excitation temperatures, number density, and power consumption. Cellulose and LDPE are plasma-treated for different treatment times to characterize the evolution of the hydrogen production process. Gas products are analyzed using gas chromatography to determine the mean hydrogen production rate, production efficiency, hydrogen yield, selectivity, and energy cost. The results show that the maximum hydrogen production efficiency for cellulose is 0.8 mol/kWh, which is approximately double that for LDPE. Furthermore, the energy cost of hydrogen production from cellulose is 600 kWh/kg of H2, half that of LDPE. Solid products are examined via scanning electron microscopy, revealing the distinct morphological structure of the two feedstocks treated, as well as by elemental composition analysis. The results demonstrate that SDBD plasma is effective at producing hydrogen from cellulose and LDPE at near atmospheric pressure and relatively low-temperature conditions in rapid-response and compact processes.