Search

The introduction of quantum methods in spectroscopy can provide enhanced performance and technical advantages in the management of noise. We investigate the application of quantum illumination in a pump and probe experiment. Thermal lensing in a suspension of gold nanorods is explored using a classical beam as the pump and the emission from parametric downconversion as the probe. We obtain an insightful description of the behaviour of the suspension under pumping with a method known to provide good noise rejection. Our findings are a further step towards investigating effects of quantum light in complex plasmonic media.

Assessing the presence of chemical, biological, radiological and nuclear threats is a crucial task which is usually dealt with by analyzing the presence of spectral features in a measured absorption profile. The use of quantum light allows to perform these measurements remotely without compromising the measurement accuracy through ghost spectrometry. However, in order to have sufficient signal-to-noise ratio, it is typically required to wait long acquisition times, hence subtracting to the benefits provided by remote sensing. In many instances, though, reconstructing the full spectral lineshape of an object is not needed and the interest lies in discriminating whether a spectrally absorbing object may be present or not. Here we show that this task can be performed fast and accurately through ghost spectrometry by comparing the low resources measurement with a reference. We discuss the experimental results obtained with different samples and complement them with simulations to explore the most common scenarios.

High-performing nanomaterials are paramount for advanced photonic technologies, like sensing, lasing, imaging, data storage, processing, and medical and biological applications. Metal nanoparticles play a key role, because the localized surface plasmonic resonances enhance the linear and nonlinear optical properties of hosting materials, thus increasing the range of applications. The improved optical response results in an enriched and largely unexplored phenomenology. In the present work, we show the formation and interaction of two dispersive shock waves emerging by illuminating an aqueous suspension of gold nanorods with a pulsed laser beam. By analyzing the characteristic undular bores that regularize a shock front in a dispersive material, we were able to distinguish dispersive shock waves of different origins, i.e., electronic and thermal, first coexisting and then interacting to form a double front of equal intensity. The observed scenario agrees with existing literature reporting an electronic and thermal contribution to the nonlinear refractive index of material containing gold nanoparticles. Although a full comprehension of the reported results deserves an analytical description, they already pave the way to using materials containing metal nanoparticles as a platform for studying fundamental extreme nonlinear phenomena and developing novel solutions for sensing and control.

Selective removal of heavy metals from water is a complex topic. We present a theoretical computational approach, supported by experimental evidences, to design a functionalized nanomaterial that is able to selectively capture metallic ions from water in a self-assembling process. A theoretical model is used to map an experimental mixture of Ag nanoparticles and either Co$^{2+}$ or Ni$^{2+}$ onto an additive highly asymmetric attractive Lennard Jones binary mixture. Extensive NVT (constant number of particles, volume, and temperature) Monte Carlo simulations are performed to derive a set of parameters that first induce aggregation among the two species in solution and then affect the morphology of the aggregates. The computational predictions are thus compared with the experimental results. The gathered insights can be used as guidelines for the prediction of an optimal design of a new generation of selective nanoparticles to be used for metallic ion adsorption and hence for maximizing the trapping of ions in an aqueous solution., Comment: This version has been removed by arXiv administrators because the submitted pdf is copyright of the journal, in violation of arXiv policy

The $\beta^-$ based radio-guided surgery overcomes the corresponding $\gamma$ technique in case the background from healthy tissues is relevant. It can be used only in case a radio-tracer marked with $^{90}$Y is available since the current probe prototype was optimized for the emission spectrum of this radio-nuclide. Here we study, with a set of laboratory tests and simulations, the prototype capability in case a different radio-nuclide is chosen among those used in nuclear medicine. As a result we estimate the probe efficiency on electrons and photons as a function of energy and we evaluate the feasibility of a radio-guided surgery exploiting the selected radio-nuclides. We conclude that requiring a 0.1~ml residue to be detected within 1~s by administering 3~MBq/Kg of radio-isotope, the current probe prototype would yield a significant signal in a vast range of values of SUV and TNR in case $^{31}$Si,$^{32}$P, $^{97}$Zr, and $^{188}$Re are used. Conversely, a tuning of the detector would be needed to efficiency use $^{83}$Br, $^{133}$I, and $^{153}$Sm, although they could already be used in case of high SUV or TNR values. Finally, $^{18}$F,$^{67}$Cu, $^{131}$I, and $^{177}$Lu are not useable for radio-guided surgery with the current probe design., Comment: 14 pages, 5 Figs

We present results of an x-ray study of structural properties of semicrystalline polymer films using nanofocused x-ray beam. We applied the x-ray cross-correlation analysis (XCCA) to scattering data from blends of poly(3-hexylthiophene) (P3HT) embedded with gold nanoparticles (AuNPs). Spatially resolved maps of orientational distribution of crystalline domains allow us to distinguish sample regions of predominant face-on morphology,with a continuous transition to edge-on morphology. The average size of crystalline domains was determined to be of the order of 10 nm. As compared to pristine P3HT film, the P3HT/AuNPs blend is characterized by substantial ordering of crystalline domains, which can be induced by Au nanoparticles. The inhomogeneous structure of the polymer film is clearly visualized on the spatially resolved nanoscale 2D maps obtained using XCCA. Our results suggest that the observed changes of the polymer matrix within crystalline regions can be attributed to nanoconfinement in the presence of gold nanoparticles., Comment: 10 pages, 6 figures, 53 references