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The spatial distribution of molecules in AGB circumstellar envelopes is regulated by different processes. In the outer layers all molecules are destroyed due to the interaction with interstellar ultraviolet photons. Here we aim to characterize in a coherent and uniform way the radial extent of three molecules (SiO, CS, and SiS) in envelopes around AGB stars of O- and C-rich character, and to study their dependence with mass loss rate. To that purpose, we used the Yebes 40m and IRAM 30m telescopes to observe 7 M-type and 7 C-type AGB envelopes covering a wide range of mass loss rates (1e-7 - 1e-5 Msun/yr) in lines of SiO, CS, and SiS spanning a range of upper level energies of 2-130 K. We carried out excitation and radiative transfer calculations over a wide parameter space to characterize the molecular abundance and radial extent. A chi2 analysis indicates that the abundance is well constrained while the radial extent is more difficult to constrain. The radial extent increases with increasing envelope density, in agreement with previous observational findings. At high envelope densities, Mdot/vexp > 1e-6 (Msun/yr)/(km/s), the radial extent of SiO, CS, and SiS are similar, while at low envelope densities, Mdot/vexp < 1e-7 (Msun/yr)/(km/s), the radial extent differ among the three molecules, in agreement with theoretical expectations based on destruction due to photodissociation. At low envelope densities we find a sequence of increasing radial extent, SiS -> CS -> SiO. We also find a tentative dependence of the radial extent with the chemical type (O- or C-rich) of the star for SiO and CS. Interferometric observations and further investigation of the photodissociation of SiO, CS, and SiS should allow to clarify the situation on the relative photodissociation radius of SiO, CS, and SiS in AGB envelopes and the dependence with envelope density and C/O ratio., Comment: Accepted for publication in A&A. Abstract abridged

Polarisation observations of masers in the circumstellar envelopes (CSEs) around Asymptotic Giant Branch (AGB) stars have revealed strong magnetic fields. However, masers probe only specific lines-of-sight through the CSE. Non-masing molecular line polarisation observation can more directly reveal the large scale magnetic field morphology and hence probe the effect of the magnetic field on AGB mass-loss and the shaping of the AGB wind. Observations and models of CSE molecular line polarisation can now be used to describe the magnetic field morphology and estimate its strength throughout the entire CSE. We use observations taken with ALMA of molecular line polarisation in the envelope of two AGB stars (CW~Leo and R~Leo). We model the observations using the multi-dimensional polarised radiative transfer tool PORTAL. We find linearly polarised emission, with maximum fractional polarisation on the order of a few percent, in several molecular lines towards both stars. We can explain the observed differences in polarisation structure between the different molecular lines by alignment of the molecules by a combination of the Goldreich-Kylafis effect and radiative alignment effects. We specifically show that the polarisation of CO traces the morphology of the magnetic field. Competition between the alignment mechanisms allows us to describe the behaviour of the magnetic field strength with radius throughout the circumstellar envelope of CW~Leo. The magnetic field strength derived using this method is inconsistent with the magnetic field strength derived using a structure function analysis of the CO polarisation and the strength previously derived using CN Zeeman observations. In contrast with CW~Leo, the magnetic field in the outer envelope of R~Leo appears to be advected outwards by the stellar wind. {abridged abstract}, Comment: 23 pages, 21 figures, accepted for publication in A&A

Red supergiant stars (RSGs, Minit = 10-40Msun) are known to eject large amounts of material, as much as half of their initial mass during this evolutionary phase. However, the processes powering the mass ejection in low- and intermediate-mass stars do not work for RSGs and the mechanism that drives the ejection remains unknown. Different mechanisms have been proposed as responsible for this mass ejection but so far little is known about the actual processes taking place in these objects. Here we present high angular resolution interferometric ALMA maps of VY CMa continuum and molecular emission, which resolve the structure of the ejecta with unprecedented detail. The study of the molecular emission from the ejecta around evolved stars has been shown to be an essential tool in determining the characteristics of the mass loss ejections. Our aim is thus to use the information provided by these observations to understand the ejections undergone by VY CMa and to determine their possible origins. We inspected the kinematics of molecular emission observed. We obtained position-velocity diagrams and reconstructed the 3D structure of the gas traced by the different species. It allowed us to study the morphology and kinematics of the gas traced by the different species surrounding VY CMa. Two types of ejecta are clearly observed: extended, irregular, and vast ejecta surrounding the star that are carved by localized fast outflows. The structure of the outflows is found to be particularly flat. We present a 3D reconstruction of these outflows and proof of the carving. This indicates that two different mass loss processes take place in this massive star. We tentatively propose the physical cause for the formation of both types of structures. These results provide essential information on the mass loss processes of RSGs and thus of their further evolution., Comment: 13 pages, 10 figures

We present ALMA continuum and molecular line emission maps at $\sim$1 mm of OH 231.8, a well studied bipolar nebula around an AGB star. The excellent angular resolution of our maps ($\sim$20 mas) allows us to scrutinise the central nebular regions of OH 231.8, which hold the clues to unravel how this iconic object assembled its complex nebular architecture. We report, for the first time in this object and others of its kind, the discovery of a rotating circumbinary disk selectively traced by NaCl, KCl, and H$_2$O emission lines. This represents the first detection of KCl in an oxygen-rich AGB circumstellar envelope. The rotating disk, of radius $\sim$30 au, lies at the base of a young bipolar wind traced by SiO and SiS emission, which also presents signs of rotation at its base. The NaCl equatorial structure is characterised by a mean rotation velocity of $\sim$4 km s$^{-1}$ and extremely low expansion speeds, $\sim$3 km s$^{-1}$. The outflow has a predominantly expansive kinematics characterised by a constant radial velocity gradient of $\sim$65 km s$^{-1}$ arcsec$^{-1}$ at its base. Beyond $r$$\sim$350 au, the gas in the outflow continues radially flowing at a constant terminal speed of $\sim$16 km s$^{-1}$. Our continuum maps reveal a spatially resolved dust disk-like structure perpendicular to the outflow, with the NaCl, KCl and H$_2$O emission arising from the disk's surface layers. Within the disk, we also identify an unresolved point continuum source, which likely represents the central Mira-type star QX Pup enshrouded by a $\sim$3 $R_{\star}$ component of hot ($\sim$1400 K) freshly formed dust. The point source is slightly off-centered from the disk centroid, enabling us for the first time to place constraints to the orbital separation and period of the central binary system, $a$$\sim$20 au and $P_{\rm orb}$$\sim$55 yr, respectively. (abridged)., Comment: 30 pages, 18 figures. Accepted for publication in Astronomy & Astrophysics (on 19/06/2022)

The nucleosynthesis production of fluorine (F) is still a matter of debate. Asymptotic giant branch (AGB) stars are one of the main candidates for F production. However, their contribution to the total F budget is not fully known due to the lack of observations. In this paper, we report the detection of AlF line emission, one of the two main carriers of F in the gas-phase in the outflow of evolved stars, towards five nearby oxygen-rich AGB stars, $o$ Ceti, R Leo, IK Tau, R Dor, and W Hya. From spatially resolved observations, we estimated the AlF emitting region with a radius $\sim11R_{\star}$ for $o$ Ceti and $\sim9R_{\star}$ for R Leo. From population diagram analysis, we report the AlF column densities of $\sim 5.8\times10^{15}$ cm$^{-2}$ and $\sim 3\times10^{15}$ cm$^{-2}$ for $o$ Ceti and R Leo, respectively, within these regions. For $o$ Ceti, we used the C$^{18}$O ($v=0$, $J=3-2$) observations to estimate the H$_2$ column density of the emitting region. We found a fractional abundance of $f_{\rm AlF/H_2}\sim(2.5\pm1.7)\times10^{-8}$. This gives a lower limit on the F budget in $o$ Ceti and is compatible with the solar F budget $f_{\rm F/H_2}=(5\pm2)\times10^{-8}$. For R Leo, a fractional abundance $f_{\rm AlF/H_2}=(1.2\pm0.5)\times10^{-8}$ is estimated. For other sources, we cannot precisely determine the emitting region based on the available data. Assuming an emitting region with a radius of $\sim 11R_{\star}$ and the rotational temperatures derived for $o$ Ceti and R Leo, we crudely approximated the AlF column density to be $\sim(1.2-1.5)\times10^{15}$ cm$^{-2}$ in W Hya, $\sim(2.5-3.0)\times10^{14}$ cm$^{-2}$ in R Dor, and $\sim(0.6-1.0)\times10^{16}$ cm$^{-2}$ in IK Tau. These result in fractional abundances within a range of $f_{\rm AlF/H_2}\sim(0.1-4)\times10^{-8}$ in W Hya, R Dor, and IK Tau., Comment: 11 pages, 9 figures

Aims: We aim to determine the abundances of SiO, CS, SiS, SO, and SO$_2$ in a large sample of oxygen-rich AGB envelopes covering a wide range of mass loss rates to investigate the potential role that these molecules could play in the formation of dust in these environments. Methods:We surveyed a sample of 30 oxygen-rich AGB stars in the $\lambda$ 2 mm band using the IRAM 30m telescope. We performed excitation and radiative transfer calculations based on the LVG method to model the observed lines of the molecules and to derive their fractional abundances in the observed envelopes. Results:We detected SiO in all 30 targeted envelopes, as well as CS, SiS, SO, and SO$_2$ in 18, 13, 26, and 19 sources, respectively. Remarkably, SiS is not detected in any envelope with a mass loss rate below $10^{-6}$ M$_{\odot}$ yr$^{-1}$, whereas it is detected in all envelopes with mass loss rates above that threshold. From a comparison with a previous, similar study on C-rich sources, it becomes evident that the fractional abundances of CS and SiS show a marked differentiation between C-rich and O-rich sources, being two orders of magnitude and one order of magnitude more abundant in C-rich sources, respectively, while the fractional abundance of SiO turns out to be insensitive to the C/O ratio. The abundance of SiO in O-rich envelopes behaves similarly to C-rich sources, that is, the denser the envelope the lower its abundance. A similar trend, albeit less clear than for SiO, is observed for SO in O-rich sources. Conclusions: The marked dependence of CS and SiS abundances on the C/O ratio indicates that these two molecules form more efficiently in C- than O-rich envelopes. The decline in the abundance of SiO with increasing envelope density and the tentative one for SO indicate that SiO and possibly SO act as gas-phase precursors of dust in circumstellar envelopes around O-rich AGB stars., Comment: 22 pages, 3 figures, Accepted for publications in Astronomy & Astrophysics

The study of the gas in the envelopes surrounding asymptotic giant branch (AGB) stars through observations in the millimetre wavelength range provides information about the history and nature of these molecular factories. Here we present ALMA observations at subarsecond resolution, complemented with IRAM-30m data, of several lines of SiO, SiS, and CS towards the best-studied AGB circumstellar envelope, IRC+10216. We aim to characterise their spatial distribution and determine their fractional abundances mainly through radiative transfer and chemical modelling. The three species display extended emission with several enhanced emission shells. CS displays the most extended distribution reaching distances up to approximately 20''. SiS and SiO emission have similar sizes of approximately 11'', but SiS emission is slightly more compact. We have estimated fractional abundances relative to H$_2$, which on average are equal to f(SiO)$\sim$10$^{-7}$, f(SiS)$\sim$10$^{-6}$, and f(CS)$\sim$10$^{-6}$ up to the photo-dissociation region. The observations and analysis presented here show evidence that the circumstellar material displays clear deviations from an homogeneous spherical wind, with clumps and low density shells that may allow UV photons from the interstellar medium (ISM) to penetrate deep into the envelope, shifting the photo-dissociation radius inwards. Our chemical model predicts photo-dissociation radii compatible with those derived from the observations, although it is unable to predict abundance variations from the starting radius of the calculations ($\sim$10$R_{*}$), which may reflect the simplicity of the model. We conclude that the spatial distribution of the gas proves the episodic and variable nature of the mass loss mechanism of IRC+10216, on timescales of hundreds of years., Comment: 21 pages, 24 figures. Accepted for publication in A&A

We report on the detection of calcium isocyanide, CaNC, in the carbon-rich evolved star IRC+10216. We derived a column density for this species of (2.0$\pm$0.5)$\times$10$^{11}$ cm$^{-2}$. Based on the observed line profiles and the modelling of its emission through the envelope, the molecule has to be produced in the intermediate and outer layers of the circumstellar envelope where other metal-isocyanides have previously been found in this source. The abundance ratio of CaNC relative to MgNC and FeCN is $\simeq$1/60 and $\simeq$1, respectively. We searched for the species CaF, CaCl, CaC, CaCCH, and CaCH$_3$ for which accurate frequency predictions are available. Only upper limits have been obtained for these molecules., Comment: 5 pages, 2 figures, accepted for publication in A&A

We report the detection and investigate the properties of high-excitation lambda-doubling line emission of hydroxyl (OH) detected towards three asymptotic giant branch (AGB) stars (W Hya, R Dor, and IK Tau) using ALMA. The OH lines are produced very close to the central stars and seem optically thin and with no maser effect. We analyse the molecular excitation using population diagrams and find rotational temperatures of $\sim 2500$ K and column densities of $\sim 10^{19}$ cm$^{-2}$ for both W Hya and R Dor. For W Hya, we observe emission from vibrationally excited H2O arising from the same region as the OH emission. Moreover, CO $v = 1; J = 3 - 2$ emission also shows a brightness peak in the same region. Considering optically thin emission and the rotational temperature derived for OH, we find a CO column density $\sim 15$ times higher than that of OH, within an area of ($92 \times 84$) mas$^2$ centred on the OH emission peak. These results should be considered tentative because of the simple methods employed. The observed OH line frequencies differ significantly from the predicted transition frequencies in the literature, and provide the possibility of using OH lines observed in AGB stars to improve the accuracy of the Hamiltonian used for the OH molecule. We predict stronger OH lambda-doubling lines at millimetre wavelengths than those we detected. These lines will be a good probe of shocked gas in the extended atmosphere and are possibly even suitable as probes of the magnetic field in the atmospheres of close-by AGB stars through the Zeeman effect., Comment: Published in Astronomy and Astrophysics Letters

We present new interferometer molecular observations of R Leo taken at 1.2 mm with the Atacama Large Millimeter Array with an angular resolution up to ~0.026 arcsec. These observations permit us to resolve the innermost envelope of this star revealing the existence of a complex structure that involves extended continuum emission and molecular emission showing a non-radial gas velocity distribution. This molecular emission displays prominent red-shifted absorptions located right in front to the star typical of material infall and lateral gas motions compatible with the presence of a torus-like structure., Comment: 5 pages, 3 figures, 1 table; accepted for publication in A&A

We present continuum and molecular line emission ALMA observations of OH 231.8+4.2, a well studied bipolar nebula around an asymptotic giant branch (AGB) star. The high angular resolution (~0.2-0.3 arcsec) and sensitivity of our ALMA maps provide the most detailed and accurate description of the overall nebular structure and kinematics of this object to date. We have identified a number of outflow components previously unknown. Species studied in this work include 12CO, 13CO, CS, SO, SO2, OCS, SiO, SiS, H3O+, Na37Cl, and CH3OH. The molecules Na37Cl and CH3OH are first detections in OH 231.8+4.2, with CH3OH being also a first detection in an AGB star. Our ALMA maps bring to light the totally unexpected position of the mass-losing AGB star (QX Pup) relative to the large-scale outflow. QX Pup is enshrouded within a compact (<60 AU) parcel of dust and gas (clump S) in expansion (V~5-7 km/s) that is displaced by 0.6arcsec to the south of the dense equatorial region (or waist) where the bipolar lobes join. Our SiO maps disclose a compact bipolar outflow that emerges from QX Pup's vicinity. This outflow is oriented similarly to the large-scale nebula but the expansion velocities are about ten times lower (~35 km/s). We deduce short kinematical ages for the SiO outflow, ranging from ~50-80 yr, in regions within ~150 AU, to ~400-500 yr at the lobe tips (~3500 AU). Adjacent to the SiO outflow, we identify a small-scale hourglass-shaped structure (mini-hourglass) that is probably made of compressed ambient material formed as the SiO outflow penetrates the dense, central regions of the nebula. The lobes and the equatorial waist of the mini-hourglass are both radially expanding with a constant velocity gradient. The mini-waist is characterized by extremely low velocities, down to ~1 km/s at ~150 AU, which tentatively suggest the presence of a stable structure. (abridged)