1. Stability and Elasticity of Ultrathin Sphere-Patterned Block Copolymer Films
- Author
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Qiao, Le, Vega, Daniel A., and Schmid, Friederike
- Subjects
Condensed Matter - Soft Condensed Matter ,Physics - Chemical Physics ,Physics - Computational Physics - Abstract
Sphere-patterned ultrathin block copolymers films are potentially interesting for a variety of applications in nanotechnology. We use self-consistent field theory to investigate the elastic response of sphere monolayer films with respect to in-plane shear, in-plane extension and compression deformations, and with respect to bending. The relations between the in-plane elastic moduli is roughly compatible with the expectations for two-dimensional elastic systems with hexagonal symmetry, with one notable exception: The pure shear and the simple shear moduli differ from each other by roughly 20%. Even more importantly, the bending constants are found to be negative, indicating that free-standing block copolymer membranes made of only sphere mono-layer are inherently unstable above the glass transition. Our results are discussed in view of experimental findings.
- Published
- 2024
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