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Abstract Orbit determination of probes visiting Solar System bodies is currently the main source of our knowledge about their internal structure, inferred from the estimate of their gravity field and rotational state. Nongravitational forces acting on the spacecraft need to be accurately included in the dynamical modeling (either explicitly or in the form of empirical parameters) not to degrade the solution and its geophysical interpretation. In this study, we present our recovery of NASA GRAIL orbits and our lunar gravity field solutions up to degree and order 350. We propose a systematic approach to select an optimal parametrization with empirical accelerations and pseudo‐stochastic pulses, by checking their impact against orbit overlaps or, in the case of GRAIL, the very precise inter‐satellite link. We discuss how parametrization choices may differ depending on whether the goal is limited to orbit reconstruction or if it also includes the solution of gravity field coefficients. We validate our setup for planetary geodesy by iterating extended lunar gravity field solutions from pre‐GRAIL gravity fields, and we discuss the impact of empirical parametrization on the interpretation of gravity solutions and of their error bars.

Polycyclic aromatic compounds (PACs) and metals are important contaminants in road runoff. Vital mitigation measures against aquatic contamination from road runoff include the use of sedimentation ponds. However, it has been demonstrated that ecosystems in sedimentation ponds might be affected by road runoff. Sediments from six natural ponds and 27 sedimentation ponds were investigated to determine the environmental risk of contaminants. The amount of traffic on the respective roads associated with the sedimentation ponds was correlated with the environmental concentrations. Quantification included seven metals, the 16 US Environmental Protection Agency polycyclic aromatic hydrocarbons, alkylated PACs, dibenzothiophene, benzo[e]pyrene, and perylene. The environmental risk was assessed according to the European Union Water Framework Directive guidelines. Sedimentation ponds had a higher level of contaminants than natural ponds, and environmental risks were dominated by the concentration of PACs. Alkylated PACs contributed to the environmental risk posed by PACs and should be included in future monitoring. Only Cu and Zn were measured at concentrations above the environmental quality standards (EQSs), while 13 PACs exceeded the EQS. Sediment concentrations of Cu, Zn, and most PACs correlated significantly with the amount of traffic. The sources of PACs were determined by source apportionment ratios between PACs. Alkylation and pyrogenic indices showed that sources in natural ponds were of mostly pyrogenic origin, whereas in sedimentation ponds they were predominantly petrogenic. Asphalt was the probable main source of PACs. A hierarchical clustering technique was used to investigate both the environmental risks and the pattern of PACs in the ponds and revealed that a few sedimentation ponds were not protecting the environment as intended because the upper sediment layers had not been regularly dredged. Environ Toxicol Chem 2022;41:1838-1850. © 2022 The Authors. Environmental Toxicology and Chemistry published by Wiley Periodicals LLC on behalf of SETAC., (© 2022 The Authors. Environmental Toxicology and Chemistry published by Wiley Periodicals LLC on behalf of SETAC.)

We introduce a methodology to study the possible matter flows of an ecosystem defined by observational biomass data and realistic biological constraints. The flows belong to a polyhedron in a multi dimensional space that may make statistical exploration difficult in practice; instead, we propose to solve a convex optimization problem. Seven criteria based on ecological network indices have been selected to be used as convex goal functions. Numerical results show that the method is fast and can be used for large systems. Minimum flow solutions are analyzed using flow decomposition in paths and circuits. Their consistency is also tested by introducing a system of differential equations for the biomasses and examining the stability of the biomass fixed point. The method is illustrated and explained throughout the text on an ecosystem toy model. It is also applied to realistic food models., (© 2021. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

Road runoff carries a mixture of contaminants that threatens the quality of natural water bodies and the health of aquatic organisms. The use of sedimentation ponds is a nature-based solution for the treatment of road runoff. This study assessed the concentration of polycyclic aromatic hydrocarbons (PAHs) and their alkylated homologues in sediment from seven highway sedimentation ponds and three natural urban ponds. In addition, the study explored the bioaccumulation of PAHs in dragonfly nymphs (Anisoptera). Finally, biota-sediment accumulation factors (BSAFs) were estimated. The results revealed a significant difference in the concentrations of 16 priority PAHs in sediment, with overall higher levels in sedimentation ponds (2,911 µg/kg on average) compared to natural urban ponds (606 µg/kg on average). PAH levels increased substantially once alkylated homologues were considered, with alkylated comprising between 42 and 87% of the total PAH in sediment samples. These results demonstrate the importance of alkylated forms in the environmental assessment of PAHs. The bioaccumulation assessment indicates that dragonfly nymphs bioaccumulate PAHs to a certain degree. It is not clear, however, whether they metabolize PAHs. BSAF results ranged from approx. 0.006 to 10 and indicate that BSAFs can be a powerful tool to determine the functionality of sedimentation ponds.