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Motile liquid crystal (LC) colloids show peculiar behavior due to the high sensitivity to external stimuli driven by the LC elastic and surface effects. However, few studies focus on harnessing the LC phase transitions to propel colloidal inclusions by the nematic-isotropic (NI) interface. We engineer a quasi-2D active system consisting of solid micron-sized light-absorbent platelets immersed in a thermotropic nematic LC. The platelets self-propel in the presence of light while self-inducing a localized NI phase transition. The sample's temperature, light intensity, and confinement determine three different regimes: a 2D large regime where the platelet-isotropic phase bubble is static and the NI interface remains stable; a compact motile-2D regime where the NI interface lies closer to the platelet's contour; and a motile-3D-confinement regime characterized by the emergence of multipolar configurations of the LC. We perform continuum-theory simulations that predict stationary platelet-LC states when confined in 3D. Our study in an intrinsically far-from-equilibrium landscape is crucial for designing simple synthetic systems that contribute to our understanding of harnessing liquid crystals' phase transitions to propel colloidal inclusions and trigger tunable topological reconfigurations leading to photonic responses., Comment: 29 pages main text. 5 figures main text. Supporting Information included at the end

The development of synthetic microswimmers has advanced our understanding of the fundamental self-propelled mechanisms of living systems. However, there are scarce studies at the microscale within highly structured anisotropic media, such as bacteria or cellular receptors that swim in concentrated solutions of filamentous proteins or lipids with viscoelastic properties. Synthetic liquid crystals (LCs) have the potential to serve as biomimetic surrogates to study the structure and dynamics of living systems. Nevertheless, studies on thermotropic LCs have mainly focused on electro and magneto-phoretic effects, with a few others on diffusiophoresis or light-driven distortions of the LC nematic director. To the best of our knowledge, here we report self-thermophoretic experiments on thermotropic LCs for the first time. Our system consists of 2D confined Janus particles in 5CB with homeotropic anchoring on the particle and LC cell surfaces. The Janus particles include a conductive titanium coating that, upon exposure to an LED source, is heated and induces a local steady nematic-isotropic phase transition, leading to the self-propulsion of the particles orthogonally to the LC director. The trajectories of the Janus particles were tracked at different intensities of the applied light. A model is developed to describe the mean-squared displacement of a Janus particle suspended in a nematic LC. The model assumes that the Janus particle feels the LC as a continuum with the anisotropic viscosity of the bulk nematic phase. Moreover, the viscoelasticity of the LC is also considered. The model describes the experimental data well, and the fitting parameter related to the magnitude of the swimming force increases with the intensity of the applied light. Moreover, our approach represents an important step for developing a platform for highly structured anisotropic active materials., Comment: 15 pages, 6 figures

The optical properties of liquid crystals serve as the basis for display, diagnostic, and sensing technologies. Such properties are generally controlled by relying on electric fields. In this work, we investigate the effects of microfluidic flows and acoustic fields on the molecular orientation and the corresponding optical response of nematic liquid crystals. Several previously unknown structures are identified, which are rationalized in terms of a state diagram as a function of the strengths of the flow and the acoustic field. The new structures are interpreted by relying on calculations with a free energy functional expressed in terms of the tensorial order parameter, using continuum theory simulations in the Landau-de Gennes framework. Taken together, the findings presented here offer promise for the development of new systems based on combinations of sound, flow, and confinement.

Solar grade silicon (SoG-Si) is a key material for the development of crystalline silicon photovoltaics (PV), which is expected to reach the tera-watt level in the next years and around 50TW in 2050. Upgraded metallurgical grade silicon (UMG-Si) has already demonstrated to be a viable alternative to standard polysilicon in terms of cost and quality. This study presents the life cycle assessment (LCA) of UMG obtained by the FerroSolar process. Moreover, it shows the environmental impacts of PV modules and electricity generation based on this material. For this, an exhaustive review of the life cycle inventory (LCI) of PV value chain, from metallurgical grade silicon (MG-Si) down to electricity generation, has been carried out updating inputs for all processes. The Balance of System (BoS) has also been updated with real state of the art data for a fixed open ground large PV site (100 MW). Two different electricity mixes, with low and high carbon intensities, have been considered. The results reveal that for PV electricity generation using UMG instead of polysilicon leads to an overall reduction of Climate change (CC) emissions of over 20%, along with an improvement of the Energy Payback Time (EPBT) of 25%, achieving significantly low values, 12 gCO2eq / kWhe and 0.52 years, respectively. Moreover, it is shown that UMG silicon feedstock is not the main contributor to the carbon and energy footprint of the produced electricity, leaving the first place to PV module manufacturing., Comment: Main: 32 pages, 9 figures, 3 tables. Supplementary Material: 24 pages, 2 figures, 25 tables

Upgraded metallurgical grade silicon (UMG-Si) for photovoltaic (PV) solar applications has been manufactured through the metallurgical route by means of the process developed by Ferrosolar. In an ambitious mass production test, performed in commercial solar cells and modules production lines, the silicon was proven to be appropriate for photovoltaics applications (Fornies et al., 2019 Mass production test of solar cells and modules made of 100% umg silicon. 20.76% record efficiency. Energies 12), reaching, in a conventional production line, up to 20.76% of solar cell efficiency with multicrystalline cells made of 100% UMG silicon. In this paper we present more results from the mentioned massive test. Defect engineering is being applied to improve the bulk lifetime of the UMG wafers and to guide in the identification of the limiting defects in the material. Moreover, the modules produced with 100% UMG silicon solar cells were installed together with the modules produced in the same production line with polysilicon material to assess the degradation of the UMG silicon when compared to polysilicon. After 24 months of outdoor PV generation, the degradation, in terms of Performance Ratio at 25C (25PR) diminution, has been the same for both types of modules. Additionally, a Life Cycle Assessment (LCA) has been performed for this UMG silicon and state-of-the-art Siemens polysilicon to compare the environmental impact of both silicon feedstocks. The results presented in this paper; chemical analysis of wafers, defect engineering, low degradation, average efficiency and environmental assessment, lead to a complete study of UMG silicon, confirming its potential to be used as raw material for PV applications., Comment: 17 pages, 13 figures. Accepted in Solar Energy