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This study introduces an innovative solution to address the challenges arising from the volatile natural gas market and the growing integration of renewable energy sources within the industrial sector. The research strives to confront this challenge by including renewable methanol (CH3OH) and converting it into methane (CH4), with an intermediate step involving synthesis gas (CO/H2) by using concentrating solar power. This approach provides a sustainable and adaptable solution to reduce dependence on natural gas. The process entails a methanol decomposition reaction at moderate temperatures (<350 °C). Subsequently, the synthesis gas is compressed to 40 bar, stored, and discharged through a methanation process that can be conducted at high temperatures (>500 °C). The resulting methane is used as fuel for gas turbines and can also serve as feedstock in the chemical industry. The simulations were conducted in ASPEN HYSYS and yielded overall system efficiencies exceeding 29% and roundtrip efficiencies of 44%. Through techno-economic optimisation of the reaction conditions, competitive levelized fuel costs (LCOF) of €172/MWh and future LCOE values of €145/MWh were achieved. These findings present an innovative strategy for integrating gas turbine cycles and additional conversion pathways for green methanol.

Past work by the authors has suggested that Solar micro Gas Turbines (SmGTs) can be used cost-effectively to produce electric power and heat for freshwater production through desalination, mainly in off-grid locations. This is further studied in this work, providing an exhaustive modelling procedure and methodology. Additionally, a comprehensive analysis of system performance under both design and part-load conditions is provided along with the complete set of characteristics of the components of the SmGT and the desalination unit. To this end, the SmGT is assessed first, incorporating innovative solutions that enable better off-design performance: Variable Inlet Guide Vanes (VIGVs) in the compressor and Variable Nozzle Guide Vanes (VNGVs) in the turbine. The implementation of these features brings significant advantages in part-load operation, leading to a considerable increase in solar-to-electric efficiency and rangeability, particularly under certain ambient conditions; in particular, using these features yields 5% higher efficiency at the minimum load of the original engine (without variable geometry) and, from this load setting downwards, 15% lower minimum stable load is enabled. Furthermore, a sensitivity analysis to control strategies and ambient conditions has been included, exploring their impact on system performance. The water treatment system is comprised of two elements. A Reverse Osmosis (RO) desalination unit is driven by the electric power produced by the SmGT. Considering the emphasis on flexibility and part-load operation enhancement addressed in this work, a moderate recovery rate is proposed for this unit. The RO unit produces brine with high salt concentration to be partially treated further in a Zero Liquid Discharge (ZLD) unit driven by the exhaust gases of the microturbine (at about 250–300 °C), where the sensible heat of this stream is harvested by the ZLD unit to “dry” and concentrate the effluent. Finally, the potential and the operationa

This study aimed to investigate the combined effects of compression ratio (CR), start of injection angle (SOI) and water injection (WI) on the performance, including NOx emissions, of a modified turbocharged compression ignition engine using H₂ as the primary fuel and diesel solely as a pilot ignition source. WI and H₂ were both injected into the intake manifold just after the charge heat exchanger. Test conditions varied the engine speed from 1500 rpm to 2750 rpm, covering a wide range of the original engine's operating conditions, water mass flow varied from 0 to 0.795 g/cycle and SOI for pilot ignition was studied in the range 10°, 5°, 0° before top dead center. Subsequently, the study examined the combined effect of reducing the engine's CR from 17.5:1 (base) to 13.5:1, in one-point increments, reducing SOI and water addition to further enhance the hydrogen energy share (HES). HES varied from 0 % to 85 % under different engine conditions, and WI and SOI were employed to prevent knocking and ensure that the maximum combustion pressure did not exceed 160 bar. The test results indicate that NOₓ emissions increase with HES, but reducing the CR results in a reduction in NOₓ emissions of approximately 50 %. Additionally, WI further reduces NOₓ emissions by up to 50 %. The experimental evidence demonstrates that combining WI with CR and SOI reduction can effectively lower NOₓ emissions, achieving an efficiency greater than 35 % and therefore approaching the base diesel mode's efficiency. This also reduces the maximum in-cylinder pressure, allowing for an increase in turbocharger pressure and consequently enhancing the engine's specific power. The maximum engine power achieved was 31.6 kW at 2500 rpm (mean effective pressure of 10.1 bar), with a CR of 15.5, SOI at 10°, 1.5 kg/kWh of water, a HES of 81 %, and a minimum NOₓ level of approximately 480 ppm, with a maximum combustion pressure below 120 bar.

Past work by the authors has suggested that Solar micro Gas Turbines (SmGTs) can be used cost-effectively to produce electric power and heat for freshwater production through desalination, mainly in off-grid locations. This is further studied in this work, presenting a detailed description of system performance at design and part-load conditions, as well as the characteristics of the components of the SmGT and the desalination unit. To this end, the SmGT is assessed first, considering techniques that achieve a greater off-design performance such as incorporating Variable Inlet Guide Vanes (VIGVs) at the compressor inlet, and including the sensitivity to control strategies and ambient conditions, exploring their expectedly very negative impact on the SmGT performance. Water treatment system is comprised of two elements. A Reverse Osmosis desalination unit is driven by the electric power produced by the SmGT. This produces brine with high salt concentration to be partially treated further in a Zero Liquid Discharge (ZLD) unit driven by the exhaust gases of the microturbine (at about 250-300ºC), where the sensible heat of this stream is harvested by the ZLD unit to “dry” and concentrate the effluent. Finally, the potential and the operational limitations of the ZLD system are discussed, supplemented by an experimental proof of concept where its feasibility was verified.

This work focuses on the off-design analysis of a simple recuperative transcritical power cycle working with the CO₂ + C₆F₆ mixture as working fluid. The cycle is air-cooled and proposed for a state-of-the-art concentrated solar plant with solar salts as heat transfer fluid in a hot region, with a cycle minimum and maximum temperature of 51 °C and 550 °C at design conditions. The design of each cycle heat exchanger (primary, recuperator and condenser) is carried out in MATLAB with referenced models and the turbine designed in CFD, providing performance maps adopted by the cycle operating in sliding pressure. The off-design of the cycle is developed with a routine simulating the thermodynamic conditions of the cycle at variable ambient temperature and thermal inputs down to 40 % of the nominal value. The results show that the cycle can efficiently run in a wide range of part load conditions and ambient temperatures, from around 0 °C to over 40 °C, with net electric cycle efficiencies from 45 % to 36 %: according to the control philosophy proposed, the condenser fans are fixed at design speed, while the cycle operates in sliding pressure, when is possible. The results evidence the flexibility and good performances of the proposed system in various operating conditions.

Micro Gas Turbines are on-site generators with the potential to help the transition to a greener economy. However, their deployment into the market did not match the expectations. The Root Cause Analysis (RCA) is the methodology to uncover the highest-level causes before identifying possible solutions. This work applies the traditional approach to problem-solving, which originated as a methodology to find faults in processes. The methodology leads to an in-depth exploration of the problem and the cause–effect relationships within the microturbine and energy market. Specifically, the traditional RCA allowed for a creative and extensive approach. This study highlights the difficulty of targeting the problem from a general perspective with such tools. The process-based tools of the RCA make it challenging to represent such complex systems effectively. In this regard, the authors compare the present methodology with the Theory of Constraints, analysing benefits and obstacles. Eventually, the present methodology systematically isolated several root causes of the problem.

The security of the supply of clean energy resources and the production of renewable fuels for industry are some of the strategies to combat climate change. In this sense, the massive implementation of green fuels that is foreseen forces the industrial park to operate on hydrogen and/or ammonia, methanol and others, with a cost overrun for stakeholders. This work proposes an alternative through a methanol-to-methane conversion system from the intermediate step to synthesis gas. Methanol decomposition is a process that can be produced with solar energy (CSP) at moderate temperatures (<350 °C) and at low cost, whereas methanation is a well-known and industrially mature process that occurs at temperatures < 625 °C. The integration of both processes is employed as a method of solar storage, namely through high-pressure syngas and its discharge for power production in conventional cycles. Recuperative ORC configurations, Rankine steam, and a sCO2 Brayton cycle were integrated; all of them of techno-economic interest, offering round-trip efficiencies higher than 50 % and levelized costs (LCOE) lower than EUR 55/MWh, considering a high-energy methane stream at the outlet. This offers a system that proposes a solution for the massive deployment of methanol as a green hydrogen carrier molecule, where it is capable of cleanly and efficiently storing thermochemical energy and producing high-purity methane at the output, usable in other power cycles, or as an industrial feedstock.

Micro gas turbines are an on-site power and heat generation technology with a small footprint, low gaseous (NOx) and acoustic emissions, low maintenance and high-grade heat. They entered the market at the dawn of the twentieth century; nevertheless, they achieved minimal success and a marginal role in the microgeneration market. Reciprocating internal combustion engines raised considerable barriers hindering their market deployment, and Fuel Cells are also set to compete in this segment. In this scenario, this work presents an analysis of competitiveness grounded in the Theory of Constraints. To this end, a specific Key Performance Indicator has been produced, which combines technical, economic, and operational factors according to the end-user requirement. This indicator is a function of several penalty factors representing technology and market barriers, which aims to yield a unique insight into the most competitive technology for a given application, accounting for the uncertainty deriving from technical and economic elements. This novel methodology is applied to a new potential niche market: Power-to-Hydrogen-to-Power for remote applications. The methodology is applied to an independent rural community in South Wales, for which a backup power system is assessed. Four technologies are considered in the analysis: reciprocating engines, fuel cells and two different microturbines layouts. Finally, this work provides an overview of the possible R&D&I paths necessary to increase the competitiveness of micro gas turbines in certain markets.

Among the portfolio of energy systems for local power generation, Organic Rankine cycles (ORCs) for residential applications are an opportunity for local cogeneration based on synergies with existing thermal heating and storage systems. They can be highly competitive for isolated installations and the refurbishment of existing solar heating installations based on solar domestic hot water. This article evaluates the potential for hybrid solar ORC integration in residential buildings. The analyses focus on the annual yields of a domestic 1 kW ORC cycle to assess the advantages and disadvantages of the variation of demand and the availability of solar resources. The models are developed, integrating TRNSYS and EES to allow a detailed evolution characterisation. Performance and impact of CHP adaptation are considered based on demand, storage volume-collectors area ratio, and production strategies. The analysis is completed with a thermo-economic analysis under different ranges of thermodynamic parameters. Positive IRR results of 8.61% are obtained for the installation located in Seville, Spain, operating the ORC 15% of the year. It also reduces the overheating associated with the lack of heat demand and excess solar irradiation in the solar system for the warm months by 20%.

This work presents an extension of the touch-free flash sintering technique. In the proposed technique, chemical reaction and sintering occur in a single step, without the use of electrodes, in the presence of electric and magnetic fields.We show that a dense, single-phase strontium hexaferrite magnet can be produced from a mixture of commercial carbonate and oxide powders in a single step in a little more than a minute. This new technique implies significant reduction in energy and time consumption (primarily because of ultrafast processing) relative to conventional sintering.

This paper deals with the integration of a Power-to-Power Energy Storage System (P2P-ESS) based on a hydrogen driven micro gas turbine (mGT) for an off-grid application with a continuous demand of 30 kWe for three European cities: Palermo, Frankfurt, and Newcastle. In the first part of the analysis, the results show that the latitude of the location is a very strong driver in determining the size of the system (hence footprint) and the amount of seasonal storage. The rated capacity of the PV plant and electrolyzer are 37%/41% and 58%/64% higher in Frankfurt and Newcastle, respectively, as compared to the original design for Palermo. And not only this, but seasonal storage also increases largely from 3125 kg H2 to 5023 and 5920 kg H2. As a consequence of this, LCOE takes values of 0.86 €/kWh, 1.26 €/kWh, and 1.5 €/kWh for the three cities, respectively, whilst round-trip efficiency is approximately 15.7% for the three designs at the 3 cities. Finally, with the aim to reduce the footprint and rating of the different systems, a final assessment of the system hybridised with battery storage shows a 20% LCOE reduction and a 10% higher round-trip efficiency.

Micro gas turbines are an on-site power and heat generation technology with a small footprint, low gaseous (NOx) and acoustic emissions, low maintenance and high-grade heat. They entered the market at the dawn of the twentieth century; nevertheless, they achieved minimal success and a marginal role in the microgeneration market. Reciprocating internal combustion engines raised considerable barriers hindering their market deployment, and Fuel Cells are also set to compete in this segment. In this scenario, this work presents an analysis of competitiveness grounded in the Theory of Constraints. To this end, a specific Key Performance Indicator has been produced, which combines technical, economic, and operational factors according to the end-user requirement. This indicator is a function of several penalty factors representing technology and market barriers, which aims to yield a unique insight into the most competitive technology for a given application, accounting for the uncertainty deriving from technical and economic elements. This novel methodology is applied to a new potential niche market: Power-to-Hydrogen-to-Power for remote applications. The methodology is applied to an independent rural community in South Wales, for which a backup power system is assessed. Four technologies are considered in the analysis: reciprocating engines, fuel cells and two different microturbines layouts. Finally, this work provides an overview of the possible R&D&I paths necessary to increase the competitiveness of micro gas turbines in certain markets.

Thermal energy storage systems are an emerging option for efficient energy conversion and storage, especially if they can concentrate solar energy. This work studies a flexibleCH₃OH-to-CH₄ conversion system from intermediate conversion to synthesis gas. The design is based on a combination of processes already tested experimentally and applied in industry. The concept we develop integrates the decomposition of CH₃OH and methanation processes, providing different pathways for energy use, such as natural gas, direct heat, and power supply, or storage in chemical bonds. This flexibility in adapting the operation of the system to different energy availability and energy needs makes the concept appealing for changeable application. Thermal efficiencies of 39% are possible for the CH₃OH decomposition phase and of 26% for the overall system for CH₄ production. Thus, from the high energy density of CH₃OH, levelized storage costs of €134.8/MWh can be obtained, which is lower than systems based on molten salts. These results should spur interest in further advances for the proposed flexible concept.

The SCARABEUS project investigates the use of CO₂–based mixtures as working fluid in power cycles for nextgeneration Concentrated Solar Power plants. These fluids exhibit a critical temperature higher than pure CO₂, enabling dry condensation of the working fluid even at the high ambient temperatures typical of sites with a high solar radiation. As a consequence, the SCARABEUS power cycle achieves higher thermal efficiency than standard sCO₂ cycles, whose performance deteriorates significantly with ambient temperature. In any case, the actual feasibility of this concept is still to be confirmed by a complete techno-economic assessment. To that purpose, it is critical to accurately estimate the power consumption of the Heat Rejection Unit (HRU), which is one of the most important parasitic loads of the system. Bearing all this in mind, this manuscript presents the design of a horizontal, direct air-cooled condenser (ACC). The bundle geometry proposed is comprised of seven tubes in three passes, with a staggered arrangement. The complete thermal model, developed in MatLab, has been already disclosed by the SCARABEUS consortium in a previous paper, and validated both experimentally in a dedicated test rig and against results obtained by the commercial software Xace®. The novelty in the present manuscript lies in the integration of this thermal model of the tubes with a complete design and integration tool of the whole heat rejection sub-system, including the design of a rotoronly axial fan and supporting frame. The impact of several design parameters (i.e., air temperature rise, acceptable hot pressure drops, tube length) is studied, taking into account auxiliary power consumption, footprint and cycle efficiency as main figures of merit. Two candidate mixtures are taken into account, identified in previous works by the same authors (85%CO₂-15%C6F6 and 80%CO₂-20%SO₂), and a pure sCO₂ case is also considered for the sake of comparison. The results show that, for a given g

Micro Gas Turbines are small devices for on-site power and heat generation. Their high maintainability and fuel flexibility make them a suitable technology for transitioning to a greener economy. However, their commercialisation did not match the stakeholders’ expectations. The authors applied the Theory of Constraints – a methodology for the continuous improvement of systems – to the MGT industry introducing a structured and rigorous representation. The constraint – i.e. Root Cause – Analysis identified which entities sustain the cause–effect chain, eventually generating the Undesired Effects. The system constraints link to the specificity and effectiveness of commercialisation strategies and product innovation in agreement with evolutionary market theories. Moreover, the Theory of Constraints emphasises the presence of reinforcement loops that make targeting entities like high product costs ineffective. The missing piece to complete the puzzle is solving a logic block representing the product’s market competitiveness depending on economic and technical factors. This study suggests that combining market-driven innovation and commercialisation is likely the only long-term solution to the lack of commercial success of the technology. However, the work also highlights limitations in the proposed methodology and solutions. To tackle these, the authors suggest and introduce numerical frameworks based on the Theory of Constraint.

With the increasing volatility in natural gas markets and the need for residential heat, research for alternative fuels is necessary for several regions. This paper presents a high-duration thermochemical energy storage system (TCES) based on methanol, evaluating its integration with district heating networks, offering a renewable solar-based storage solution and low-temperature heat generation from the exothermic discharge reaction heat. The system eliminates greenhouse gas emissions by using concentrated solar thermal energy to decompose methanol into synthesis gas. Applying the optimised operational thermodynamic parameters, it is possible to satisfy the thermal demand of 892 households in Spain through 12 MW of concentrated solar energy supported by 10 hours of energy storage. Storage efficiencies exceeding 30% and chemical conversion efficiencies exceeding 65% have been demonstrated, resulting in a combined efficiency of 55% for the heating network and methanol TCES. The results show a levelized cost of storage (LCOS) highly competitive with other storage systems (<100 €/MWh), given the simplicity and flexibility of the proposed system.

Heating decarbonisation through electrification is a difficult challenge due to the considerable increase in peak power demand. This research proposes a novel modelling approach that utilises easily accessible national-level data to identify the required heat storage volume in buildings to decrease peak power demand and maximises carbon reductions associated with electrified heating technologies through smart demand-side response. The approach assesses the optimal shifting of heat pump operation to meet thermal heating demand according to different heat storage capacities in buildings, which are defined in relation to the time (in hours) in which the heating demand can be provided directly from the heat battery, without heat pump operation. Ten scenarios (S) are analysed: two baselines (S1–S2) and eight load shifting strategies (S3–S10) based on hourly and daily demand-side responses. Moreover, they are compared with a reference scenario (S0), with heating currently based on fossil fuels. The approach was demonstrated in two different regions, Spain and the United Kingdom. The optimal heat storage capacity was found on the order of 12 and 24 h of heating demand in both countries, reducing additional power capacity by 30–37% and 40–46%, respectively. However, the environmental benefits of heat storage alternatives were similar to the baseline scenario due to higher energy consumption and marginal power generation based on fossil fuels. It was also found that load shifting capability below 4 h presents limited benefits, reducing additional power capacity by 10% at the national scale. The results highlight the importance of integrated heat storage technologies with the electrification of heat in highly gas-dependent regions. They can mitigate the need for an additional fossil-based dispatchable generation to meet high peak demand. The modelling approach provides a high-level strategy with regional specificity that, due to common datasets, can be easily replicated globa

This work presents a tool for developing competencies in sustainability, focusing on evaluating the environmental impact and carbon footprint in schools. The tool is based on sustainability indicators and follows a methodology derived from the ClimAct and ECF4CLIM projects. It is conceived as a support for the users and the schools to identify and evaluate the relative impact of different actions and measures, to engage them in a sustainable pathway to low-carbon schools supporting their decision-making at the different levels of users. The areas are transport, waste, green procurement, green spaces, energy, water, and indoor air quality. The tool aims to support users and schools in identifying and evaluating the impact of various actions and measures, facilitating decision-making for a sustainable and low-carbon school environment. To quantify sustainability performance, Key Performance Indicators (KPIs) have been established for each area. The results from schools that tested the tool revealed low scores in green procurement (0.59/5) and water (2.03/5), while achieving higher scores in green spaces (3.46/5) and indoor air quality (3.92/5). These findings highlight the areas where improvement is needed and provide a basis for targeted interventions. Developed on the PowerApps platform, supported by Microsoft, the tool allows access to users of different ages and knowledge levels. It has been successfully tested in six schools in Andalusia, Spain, obtaining relevant results in the seven sustainable areas defined. Based on the results, this tool will be used within co-creation and co-implementation processes for more sustainable schools and competencies acquisition by the participants.

Micro Gas Turbines are small devices for on-site power and heat generation. Their high maintainability and fuel flexibility make them a suitable technology for transitioning to a greener economy. However, their commercialisation did not match the stakeholders’ expectations. The authors applied the Theory of Constraints – a methodology for the continuous improvement of systems – to the MGT industry introducing a structured and rigorous representation. The constraint – i.e. Root Cause – Analysis identified which entities sustain the cause–effect chain, eventually generating the Undesired Effects. The system constraints link to the specificity and effectiveness of commercialisation strategies and product innovation in agreement with evolutionary market theories. Moreover, the Theory of Constraints emphasises the presence of reinforcement loops that make targeting entities like high product costs ineffective. The missing piece to complete the puzzle is solving a logic block representing the product’s market competitiveness depending on economic and technical factors. This study suggests that combining market-driven innovation and commercialisation is likely the only long-term solution to the lack of commercial success of the technology. However, the work also highlights limitations in the proposed methodology and solutions. To tackle these, the authors suggest and introduce numerical frameworks based on the Theory of Constraint.

The current context of the climate emergency highlights the need for the decarbonization of the energy sector by replacing current fossil fuels with renewable energy sources. In this regard, concentrating solar power (CSP) technology represents a commercially proven alternative. However, these types of plants are associated with high production costs and difficulties in controlling production during temporary variations in solar resource availability. In order to minimize these drawbacks, this study proposes the hybridization of CSP technology with direct biomass combustion, with the particularity of an innovative process scheme that does not correspond to traditional series or parallel configurations. This paper focuses on the techno-economic evaluation of this novel configuration in a small-scale power plant. To achieve this, both solar resource and biomass production, which are dependent on the selected location, were analyzed. Additionally, the plant was characterized from both technical and economic perspectives. The obtained results allowed for the characterization of the Levelized Cost of Energy (LCOE) based on various parameters such as the size of the solar field and biomass boilers, as well as limitations on biomass consumption.

From the point of view of vehicle maintenance, one of the most important systems of urban buses is the cooling system. These vehicles run typically more than 80,000 km per year, and the radiator of the system gets fouled due to dust and dirt of the cooling air, which produces an increase in water temperature. This situation forces to stop the vehicle and perform washing of the radiator. This study is focused on the development of a model of the cooling system of urban buses based on an artificial neural network (ANN), which is used for system diagnosis and engine surveillance. Data are gathered from the CAN-bus system of every bus, which have allowed the development of a dynamic ANN that fits the cooling dynamics.

Closed supercritical and transcritical power cycles operating on Carbon Dioxide have proven to be a promising technology for power generation and, as such, they are being researched by numerous international projects today. Despite the advantageous features of these cycles enabling very high efficiencies in intermediate temperature applications, the major shortcoming of the technology is a strong dependence on ambient temperature; in order to perform compression near the CO2 critical point (31ºC), low ambient temperatures are needed. This is particularly challenging in Concentrated Solar Power applications, typically found in hot, semi-arid locations. To overcome this limitation, the SCARABEUS project explores the idea of blending raw carbon dioxide with small amounts of certain dopants in order to shift the critical temperature of the resulting working fluid to higher values, hence enabling gaseous compression near the critical point or even liquid compression regardless of a high ambient temperature. Different dopants have been studied within the project so far (i.e. C6F6, TiCl4 and SO2) but the final selection will have to account for trade-offs between thermodynamic performance, economic metrics and system reliability. Bearing all this in mind, the present paper deals with the development of a non-physics-based model using Artificial Neural Networks (ANN), developed using Matlab’s Deep Learning Toolbox, to enable SCARABEUS system optimisation without running the detailed – and extremely time consuming – thermal models, developed with Thermoflex and Matlab software. In the first part of the paper, the candidate dopants and cycle layouts are presented and discussed, and a thorough description of the ANN training methodology is provided, along with all the main assumptions and hypothesis made. In the second part of the manuscript, results confirms that the ANN is a reliable tool capable of successfully reproducing the detailed Thermoflex model, estimating the cycle

The project develops the concept and implementation of Industry 4.0 for small- and medium-sized companies, which is currently lacking in the industrial sector. The aim is to obtain a methodology or procedure to facilitate the conversion of medium-sized industrial manufacturing companies into “digital factory” working models, in accordance with Industry 4.0.

The potential of supercritical Carbon Dioxide power cycles to supersede subcritical steam turbine technology in Concentrated Solar Power applications is widely acknowledged. Some differential features of the former are higher efficiency at similar temperatures (in the range from 600 to 750ºC), smaller footprint, higher flexibility and lower cost. Several theoretical and experimental R&D projects are currently working on aspects such as component development (turbomachinery and heat exchangers), system integration into the solar subsystem (receiver and thermal energy storage system), operability, materials… Nevertheless, whilst progress is being made at a very high pace, there is still a great deal of uncertainty regarding how much sCO2 technology will be able to reduce the cost of solar thermal electricity with respect to contemporary CSP technology. This is mostly caused by the sensitivity of cycle performance to ambient temperature, bringing about a large efficiency drop when this temperature exceeds 35ºC. The root cause for this performance drop is the unfeasibility of compression near the critical point, where the very high density of the fluid reduces density and, therefore, compression work. The SCARABEUS project is based on the addition of certain dopants to carbon dioxide in order to yield a working mixture with higher critical pressure and temperature. As a consequence of these modified critical properties of the fluid, compression near the critical point is enabled even at ambient temperatures as high as 40-45ºC. Moreover, at these high temperatures, condensation and compression in liquid state are still possible. The characteristics of the new working fluids have been proved to enable thermal efficiencies higher than 50% for minimum cycle temperatures as high as 60ºC, hence boosting the performance of CSP plants well beyond of the capabilities of systems based on steam turbines. This implies a substantial reduction of the cost of the plant. Nevertheless

This manuscript investigates the supercritical carbon dioxide (sCO2) power cycle employed in the power block of concentrated solar power (CSP) plants—solar tower—as an alternative for solar desalination, developed with either distillation or reverse osmosis. This concept is investigated as a possible up-scaling of the SOLMIDEFF project, originally based on a hot-air micro gas turbine combined with a solar dish collector. For the upscaled concept, five different sCO2 cycles are considered, chosen amongst the best-performing configurations proposed in the literature for CSP applications, and modelled with Thermoflex software. The influence of ambient conditions is studied, considering two minimum cycle temperatures (35 °C and 50 °C), corresponding to Santa Cruz de Tenerife and Abu Dhabi, respectively. The results show that the low temperatures at the inlet of the heat rejection unit compromise the viability of distillation technologies. On the other hand, the high thermal efficiency achieved by these cycles, especially with the recompression and partial cooling layouts, reduces the specific energy consumption when combined with reverse osmosis (RO), below that of photovoltaic (PV)+RO. Feed-water preheating is explored as a solution to further reduce energy consumption, concluding that its actual interest is not clear and strongly depends on the location considered and the corresponding water quality standards.

This paper investigates the interest and potential of using working fluids based on Carbon and Sulphur Dioxide mixtures (CO2-SO2) in a transcritical Recompression cycle. In order to assess the actual thermodynamic potential of the concept proposed, the influence of dopant (SO2) content is assessed for two different turbine inlet temperatures (550 °C and 700 °C). The results obtained are compared with other CO2 mixtures already proposed in literature (CO2-C6F6 and CO2--TiCl4) and for two alternative cycle layouts (Recuperated Rankine and Precompression). The results pf the analysis reveal that, at high ambient temperature, the Recompression cycle operating on CO2-SO2, with Sulphur Dioxide content between 20% and 30%(v), is a very interesting option for Concentrated Solar Power plants, able to achieve thermal efficiencies of approx. 45% and 51% at 550 °C and 700 °C respectively. At a minimum cycle temperature of 50 °C, the proposed configuration leads to thermal efficiency gains of 6% and 2% with respect to the Brayton and Recompression cycles working on pure CO2. This performance enhancement of the Recompression cycle with CO2-SO2 is comparable to or higher than that enabled by other CO2 mixtures proposed in literature, but with significantly higher specific work (smaller footprint) and temperature rise across the solar receiver (lower installation costs).

The widespread use of renewable energy requires the support of high-capacity energy storage systems. This work proposes a thermochemical energy storage system for concentrated solar power plants based on the reversible hydration/dehydration process of the calcium hydroxide. It is a single fluidised bed reactor concept with alternating dehydration-hydration processes, charging and discharging alternating reactions, with superheated steam as fluidising agent. The system has been modelled using Aspen Plus™, including equilibrium data and hydrodynamic performance of the reactor. The model has been used to evaluate the effect of different parameters of the reactor, such as geometry, average particle size, or inlet streams conditions, on the performance of the reactor and the system. The thermal integration of the system was optimised using pinch analysis. For the proposed layouts, round-trip efficiencies values of 68 % are obtained. The economic analyses show specific investment costs between 4170 $/kWe and 3250 $/kWe for plants in the range of 31 MW to 45 MW, which are competitive with those expected for plants with storage of molten salts in this power range. LCOE values between 67 $/MWh and 83 $/MWh were obtained. The analyses show how these values highly depend on the fresh material replacement requirements related to the deactivation of the material and operational strategies. The results show the interest in further developments of this concept for concentrated solar power plants.

Large-scale thermochemical energy storage (TCES) is gaining relevance as an alternative to current thermal energy storage systems in Concentrated Solar Power plants. Among the different systems, the reversible reaction between CaO and CO2 stands out due to the wide availability and low cost of the raw material: limestone. Direct solar absorption of the storage media would improve the efficiency of solar-to-thermal energy storage due to reduced thermal transfer barriers, but the solar optical absorption of CaCO3 is poor. In this work, we propose the use of a Ca-rich calcarenite sedimentary rock so-called albero as an alternative to limestone. We demonstrate that this reddish material exhibits an average solar absorptance that is approximately ten times larger than limestone. Moreover, the multicycle carbonation/calcination performance under different experimental conditions has been studied by thermogravimetry, and similar values to those exhibited for limestone have been obtained. Besides, the material is cheap (6 €/ton), and simulations showed that the use of this material would significantly improve the overall CaL-CSP efficiency at the industrial level.

Throughout the last decades the developments on desalination field have been focused on energy consumption and costs reduction. However, water recovery and brine disposal are becoming a matter of concern to desalination industry. In this work, a Zero Liquid Discharge (ZLD) unit coupled with a Solar Micro Gas Turbine (SMGT) system is presented to address, among others, the challenges of mining industry in remote areas, in particular, fossil fuel dependence, water availability and pollution derived from effluents disposal. As a way to assess the feasibility of the proposal, a techno-economic analysis of the application in two Southern American regions (Chile and Ecuador) of photovoltaic modules, wind turbines and Solar Micro Gas Turbines is performed. Afterwards, the main novel feature of the new system—i.e., the ZLD unit—is described and a sensitivity analysis on its functioning whilst coupled with the SMGT is carried out. The aim is to propose a preliminary design of the ZLD process. The selection of the optimal ratio between exhaust gases and brine mass flow rates is analyzed, as well as variation in inlet salinity and temperatures. Furthermore, the water which could be recovered from effluents, at the same time that the heat of exhaust gases from SMGT is harvested, is quantified. Lastly, according to the results obtained, a preliminary design of a 10 kWe rated power SMGT system, coupled to Reverse Osmosis (RO) and ZLD units, is proposed.

The combination of alternate fuels, such as biodiesel, and low-temperature combustion (LTC) constitutes a promising solution to reduce pollutant emission and to avoid dependence on fossil fuels. However, this concept requires additional research to optimise LTC of biodiesel over wider operating ranges, specifically including the implementation of numerical models to assist in the development of these engines. In this work, an experimental analysis was carried out assessing both thermal performance and emissions derived from the LTC of diesel/biodiesel blends with late direct injection. Furthermore, this analysis allowed implementing a predictive tool to characterise in-cylinder pressure trace under this operation strategy. This model was coupled with an empirical law to simulate heat release during the combustion process. Least squares method was applied to fit this empirical law to experimental data involving different conditions in terms of percentages of rapeseed biodiesel in the fuel blend, rotational speed, fuel/air equivalence ratio and percentages of external exhaust gas recirculation. To build the predictive model, a multiple regression methodology was used to correlate the law parameters with the operating conditions. Finally, a validation process based on the simulation of in-cylinder pressure trace was developed, revealing that the predictions agreed well with the experimental data. This suggests that the proposed model is able to satisfactorily predict the LTC of diesel/biodiesel blends within the test range.

Calcium looping is a promising thermochemical energy storage process to be integrated into concentrating solar power plants. This work develops for the first time a comprehensive life cycle assessment of the calcium looping integration in solar plants to assess the potential of the technology from an environmental perspective. Two representative integrations are analysed, representing daily (hot) and seasonal (cold) storage designs. Similar performance environmental impacts are observed in both, with slightly better results for the seasonal storage case due to the simplified energy storage integration. The results show the moderate environmental impact of calcium looping thermochemical energy storage technology, resulting in lower equivalent carbon dioxide emissions 24 kg/MWh) than other energy storage options such as molten salt-based solar facilities (40 kg/MWh). Plant construction involves a higher energy demand for the process, whilst the operation and maintenance on the plant represent a moderate impact due to the low environmental impact of limestone, the unique raw material of the process, and the lower water consumption compared to typical concentrating solar power plants. Besides, the energy required for the system is first time analysed, obtaining an energy payback time of 2.2 years and 2.5 years depending on the storage strategy design.

This paper investigates the interest and potential of using working fluids based on Carbon and Sulphur Dioxide mixtures (CO2-SO2) in a transcritical Recompression cycle. In order to assess the actual thermodynamic potential of the concept proposed, the influence of dopant (SO2) content is assessed for two different turbine inlet temperatures (550 °C and 700 °C). The results obtained are compared with other CO2 mixtures already proposed in literature (CO2-C6F6 and CO2--TiCl4) and for two alternative cycle layouts (Recuperated Rankine and Precompression). The results pf the analysis reveal that, at high ambient temperature, the Recompression cycle operating on CO2-SO2, with Sulphur Dioxide content between 20% and 30%(v), is a very interesting option for Concentrated Solar Power plants, able to achieve thermal efficiencies of approx. 45% and 51% at 550 °C and 700 °C respectively. At a minimum cycle temperature of 50 °C, the proposed configuration leads to thermal efficiency gains of 6% and 2% with respect to the Brayton and Recompression cycles working on pure CO2. This performance enhancement of the Recompression cycle with CO2-SO2 is comparable to or higher than that enabled by other CO2 mixtures proposed in literature, but with significantly higher specific work (smaller footprint) and temperature rise across the solar receiver (lower installation costs).

This work explores the use of open-pore, inert ceramic foams with different pore sizes as particle abatement systems in small biomass combustion systems. Porous foams made of silicon carbide with pore sizes 10 to 60 pores-per-inch were installed in an in-house designed combustion unit operated with wood pellets. Their effects on the temperature distribution inside the chamber, particulate and gases emissions were studied using different airflow rates in the reaction-limited regime (low equivalence ratio) to minimise stoichiometric factors. The influence of pore size, foam position with respect to the flame and space velocity were assessed. The confinement of the flame with inert foams was found to substantially modify the temperature distribution in the combustion chamber, improve the air-fuel mixture, and favour the thermal decomposition of the pellet, leading to a reduction in particulate emissions when compared to free-flame combustion at the same experimental conditions. In general, the amount of particulate matter was found to decrease by up to one order of magnitude as the pore size of the foam was reduced, while the temperature gradient in the combustion chamber was increased. Nitrogen oxides and carbon dioxide emissions were essentially unchanged, irrespectively of the pore size of the foam. It is expected that these values will be improved with longer residence times, as happens in operations with reduced excess air ratios. These results suggest that it is possible to control pollutants derived from domestic heating within the most restrictive current regulations on particulate emissions by integrating flame confinement designs with better operating practices and efficient abatement systems.

Interest in energy poverty has increased in recent years and has made it possible to define the lack of energy resources in households and the importance of energy as a right. The research carried out in this work shows the importance it acquires in the current context, where a large part of the population lives confined to their homes due to the global COVID-19 pandemic and has to face higher energy costs, which affects their health and safety. This paper focuses on showing the need to study and take action on energy-poor households in Andalusia, which has been identified as one of the Spanish communities with the highest level of energy poverty. To this end, the main indicators are calculated for Andalusia. The research is transdisciplinary and has been developed by the Aura team of the University of Seville, which participates in the Solar Decathlon university competition. A high degree of energy vulnerability is concluded, with all the main indicators exceeding the national average. Finally, the conclusions section shows the need to modify the current methodology that defines vulnerable households and develop local databases in territories where the factors that affect energy vulnerability are homogeneous and evolving towards decentralised studies.

The present study aimed to provide an in-depth assessment of the commuting patterns of scholar communities of southwestern European countries and to identify measures to improve their sustainable performance regarding mobility. The adopted methodology characterised the mobility pattern of students as a sustainability indicator and the availability of related infrastructures and local public transport network. Data were gathered by qualitative (behavioural questionnaires) and quantitative (technical audits) approaches, based on measurable indicators (key performance indicators and scores (ranging between 0–5)). Overall, French schools showed the best sustainable performance regarding mobility (2.0) and Gibraltar had the lowest (1.2). The existence of bike parking and electric car charging points were the main weaknesses founds (with their related mean scores being 0.6 and 0.2, respectively). The score associated with annual CO2 emissions due to students’ mobility had the best performance, where all countries managed to obtain an average of 3.1. The global score, which assessed the sustainable performance of scholar communities regarding mobility, had a mean value of 1.5 for all studied countries, which highlights the potential for improvement of the studied schools, mainly targeting the public transport network optimisation and the enhancement of scholar infrastructures concerning bicycle parking and electric cars.

Heating decarbonisation through electrification requires the development of novel heat batteries. They should be suitable for the specific application and match the operation conditions of domestic renewable energy sources. Supercooled liquids, often considered a drawback of phase change materials, are among the most promising technologies supporting heating decarbonisation. Although some studies have shed light on stable supercooling, the fundamentals and stability remain open problems not always accompanied by relevant experimental investigations. This research critically analyses the physic and chemistry of sodium acetate (SA, NaCH3COO) aqueous solution, a low-cost, non-toxic, and abundant compound with stable supercooling for long-term heat storage. It has an appropriate phase change temperature for high-density heat storage using heat pumps or solar thermal technologies in residential applications. The existing discrepancies in literature are critically discussed through a systematic experimental evaluation, providing novel insights into efficient material design and appropriate boundary conditions for reliable material use in long-term heat batteries. Despite previous studies showing that the thermal reliability and stability of sodium acetate aqueous solution as a supercooled liquid for heat storage cannot be guaranteed, this study demonstrates that through an appropriate encapsulation and sealing method, the peritectic composition of sodium acetate solution (p-SA 58 wt%) can be used as a supercooled liquid for long-term heat storage with a stable melting temperature of 57 °C, appropriate for domestic heat technologies. It is demonstrated that energy storage efficiency can be maintained under cycling, with a constant latent heat storage capacity of 245 kJ/kg and a volumetric storage density of 314 MJ/m3. It was confirmed that the material should achieve a fully-melted state for stable supercooling. Finally, local cooling and retaining seed crystals through hi

The SCARABEUS project, funded by the European Commission, is currently investigating the potential gains brought about by the utilization of carbon dioxide mixtures in supercritical power cycles of Concentrated Solar Power plants, in lieu of the common Rankine cycles based on steam turbines or even pure carbon dioxide cycles. The analysis has already confirmed that it is possible to attain thermal efficiencies higher than 51% when ambient temperatures exceed 40°C, which is unheard of when conventional technology or standard CO₂ technology is used. Additionally, this extraordinary performance is achieved with simpler cycle layouts, therefore with lower capital costs. The additives considered include organic and inorganic compounds which are added to the raw carbon dioxide in a variable proportion, depending on the composition of the additive and on ambient temperature. Regardless, it is important to assess whether or not there is an additional environmental advantage in terms of carbon dioxide and other potential hazards brought about by the new chemicals in the system. This is presented in this paper where the results obtained so far by the consortium for the carbon footprint from a Life Cycle perspective are discussed. Along with the assumptions and methodology, the results are compared for three reference plants: state-of-the-art CSP plant based on steam turbines, innovative CSP plant using pure supercritical CO₂ technology, and the SCARABEUS concept using supercritical CO₂ mixtures. The results are promising as they suggest that it is possible to reduce the carbon footprint of a 110 MWe CSP plant to be significantly less than 27kgCO₂/MWh from the fifth assessment report of the Intergovernmental Panel on Climate Change (IPCC AR5).

The present paper explores the utilisation of dopants to increase the critical temperature of Carbon Dioxide (sCO2) as a solution towards maintaining the high thermal efficiencies of sCO2 cycles even when ambient temperatures compromise their feasibility. To this end, the impact of adopting CO2-based mixtures on the performance of power blocks representative of Concentrated Solar Power plants is explored, considering two possible dopants: hexafluorobenzene (C6F6) and titanium tetrachloride (TiCl4). The analysis is applied to a well-known cycle -Recuperated Rankine- and a less common layout -Precompression-. The latter is found capable of fully exploiting the interesting features of these non-conventional working fluids, enabling thermal efficiencies up to 2.3% higher than the simple recuperative configuration. Different scenarios for maximum cycle pressure (250–300 bar), turbine inlet temperature (550–700 °C) and working fluid composition (10–25% molar fraction of dopant) are considered. The results in this work show that CO2-blends with 15–25%(v) of the cited dopants enable efficiencies well in excess of 50% for minimum cycle temperatures as high as 50 °C. To verify this potential gain, the most representative pure sCO2 cycles have been optimised at two minimum cycle temperatures (32 °C and 50°C), proving the superiority of the proposed blended technology in high ambient temperature applications.

Supercritical Carbon Dioxide (sCO2) power cycles have been proposed for Concentrated Solar Power (CSP) applications as a means to increase the performance and reduce the cost of state-of-the-art CSP systems. Nevertheless, the sensitivity of sCO2 systems to the usually hot ambient temperatures found in solar sites compromises the actual thermodynamic and economic gains that were originally anticipated by researchers of this innovative power cycle. In order to exploit the actual potential of sCO2 cycles, the utilization of dopants to shift the (pseudo)critical temperature of the working fluid to higher values is proposed here as a solution towards enabling exactly the same features of supercritical CO2 cycles even when ambient temperatures compromise the feasibility of the latter technology. To this end, this work explores the impact of adopting a CO2-based working mixture on the performance of a CSP power block, considering hexafluorobenzene (C6F6) and titanium tetrachloride (TiCl4) as possible dopants. Different cycle options and operating conditions are studied (250-300 bar and 550-700ºC) as well as molar fractions ranging between 10 and 25%. The results in this work confirm that CO2 blends with 15-25%(v) of the cited dopants enable efficiencies that are well in excess of 50% for minimum cycle temperatures as high as 50 or even 55ºC. It is also confirmed that, for these cycles, turbine inlet temperature and pressure hardly have any effect on the characteristics of the cycle that yields the best performance possible. In this regard, the last part of this work also shows that cycle layout should be an additional degree of freedom in the optimisation process inasmuch as the best performing layout changes depending on boundary conditions.

Olive oil industry is one of the most important industries in the world. Currently, the land devoted to olive-tree cultivation around the world is ca. 11 106 ha, which produces more than 20 106 t olives per year. Most of these olives are destined to the production of olive oils. The main by-products of the olive oil industry are olive-pruning debris, olive stones and di erent pomaces. In cultures with traditional and intensive typologies, one single ha of olive grove annually generates more than 5 t of these by-products. The disposal of these by-products in the field can led to environmental problems. Notwithstanding, these by-products (biomasses) have a huge potential as source of energy. The objective of this paper is to comprehensively review the latest advances focused on energy production from olive-pruning debris, olive stones and pomaces, including processes such as combustion, gasification and pyrolysis, and the production of biofuels such as bioethanol and biodiesel. Future research e orts required for biofuel production are also discussed. The future of the olive oil industry must move towards a greater interrelation between olive oil production, conservation of the environment and energy generation.

The AURA 1.0 prototype is a sustainable social housing proposal, designed by the University of Seville and built for the first Latin American edition of the prestigious Solar Decathlon competition. Different conditioning strategies were integrated into this prototype, optimized for a tropical climate, and focused on contributing positively to the health of the most humble people in society. In this moment, in which a large part of the world population is confined to their homes due to the Covid-19 pandemic, we have the opportunity (and the obligation) to reconsider the relationship between architecture and medicine or in other words, between the daily human habitat and health. For this reason, this analysis of aspects derived from the interior conditioning of the homes is carried out. The main objective of the Aura proposal is to be able to extract data through a housing monitoring system, which allows us to transfer some design strategies to the society to which is a case study, in order to promote environmental comfort and, therefore, people’s health. The AURA 1.0 prototype develops flexible and adaptable living spaces, with a high environmental quality, in order to maintain the variables of temperature, relative humidity and natural lighting within a range of comfort required by the rules of the event. To achieve this end, the prototype develops an architectural proposal that combines passive and active conditioning strategies, using construction qualities and typical costs of social housing. These strategies allowed the project to achieve the first prize in the Comfort Conditions test. So, this paper presents an appropriate and tested solution that can satisfy comfortability and health of residents who live in social housing while maintaining low energy consumption.

Forest biomass is the raw material most commonly used to produce quality pellets for domestic households. However, sustainable forest biomass is not available in all regions, but there are other potential raw material sources for biomass heating systems, based on pellets. There are a large number of olive trees in the Mediterranean area, but these are not used as renewable pellet fuel because the bark cannot be used as raw material to produce quality pellets. The aim of this study is to carry out a methodology to estimate the optimal sustainable bioenergy life cycle, and the amount of sustainable residue available (trunk wood) at the end of the life of the olive grove, by optimizing the benefits, through an analysis of costs and income of the whole life process. The methodology determines the potential value of the trunks of olive trees to be used as biomass, in the form of pellets in domestic contexts and in a specific geographical area. In a case study applied to Andalusia, it has been shown that the optimal renewable life-cycle is 97 years. If policies for agricultural and energy sustainability favouring this model were adopted, this region would produce 160,000 tonnes of pellets per year, and 266,500 tonnes per year, if extended to the whole of Spain. This has a potential for providing 70.17% of the current total pellet consumption. The extension of the model to other Mediterranean countries, such as Greece and Italy, would result in an additional 124,000 and 144,000 tonnes of pellets per year, respectively.

Waste cooking oils (WCO) recycling companies usually have economic losses for buying WCO not suitable for biodiesel production, e.g., WCO with high free acidity (FA). For this reason, the determination of FA of WCO by near infrared (NIR) spectroscopy was studied in this work to assess its potential for in situ application. To do this, FA of 45 WCO was measured by the classical titration method, which ranged between 0.15 and 3.77%. Then, the NIR spectra from 800 to 2200 nm of these WCO were acquired, and a partial least squares model was built, relating the NIR spectra to FA values. The accuracy of the model was quite high, providing r2 of 0.970 and a ratio of performance to deviation (RPD) of 4.05. Subsequently, a model using an NIR range similar to that provided by portable NIR spectrometers (950–1650 nm) was built. The performance was lower (r2 = 0.905; RPD = 2.66), but even so, with good accuracy, which demonstrates the potential of NIR spectroscopy for the in situ determination of FA of WCO.

Previous work by the authors has shown that broader analyses than those typically found in literature (in terms of operating pressures allowed) can yield interesting conclusions with respect to the best candidate cycles for certain applications. This has been tested for the thermodynamic performance (first and second laws) but it can also be applied from an economic standpoint. This second approach is introduced in this work where typical operating conditions for concentrated solar power (CSP) applications (current and future generations of solar tower plants) are considered (750 °C and 30 MPa). For these, the techno-economic performance of each cycle is assessed in order to identify the most cost-effective layout when it comes to the overnight capital cost (OCC). This analysis accounts for the different contributions to the total cost of the plant, including all the major equipment that is usually found in a CSP power plant such as the solar field and thermal energy storage (TES) system. The work is, thus, aimed at providing guidelines to professionals in the area of basic engineering and prefeasibility study of CSP plants who find themselves in the process of selecting a particular power cycle for a new project (set of specifications and boundary conditions).

Companies in the field of the collection and treatment of waste cooking oils (WCO) for subsequent biodiesel production usually have to cope with high acidity oils, which cannot be directly transformed into fatty acid methyl esters due to soap production. Since glycerine is the main byproduct of biodiesel production, these high acidity oils could be esterified with the glycerine surplus to transform the free fatty acids (FFA) into triglycerides before performing the transesterification. In this work, commercial glycerol was esterified with commercial fatty acids and commercial fatty acid/lampante olive oil mixtures over tin (II) chloride. In the first set of experiments, the esterification of linoleic acid with glycerol excess from 20 to 80% molar over the stoichiometric was performed. From 20% glycerol excess, there was no improvement in FFA reduction. Using 20% glycerol excess, the performance of a biochar obtained from heavy metal-contaminated plant roots was compared to that of SnCl2. Then, the effect of the initial FFA content was assessed using different oleic acid/lampante olive oil mixtures. The results illustrated that glycerolysis was impeded at initial FFA contents lower than 10%. Finally, the glycerolysis of a WCO with 9.94% FFA was assayed, without success.

This work aims to shed light on the use of two biochars, obtained from the pyrolysis at 550 C of heavy-metal-contaminated Jatropha curcas L. roots, as heterogeneous catalysts for glycerol esterification using residual glycerine. To do this, glycerine from biodiesel production was purified. In a first step, H3PO4 or H2SO4 was used to remove non-glycerol organic matter. The glycerol-rich phase was then extracted with ethanol or propanol, which increased the glycerol content from 43.2% to up to 100%. Subsequently, the esterification of both purified glycerine and commercial USP glycerine was assayed with acetic acid (AA) or with acetic anhydride (AH) at 9:1 molar ratio to glycerol using Amberlyst-15 as catalyst. Different reaction times (from 1.5 to 3 h) and temperatures (100–115 C when using AA and 80–135 C when using AH) were assessed. Results revealed that the most suitable conditions were 80 C and 1.5 h reaction time using AH, achieving 100% yield and selectivity towards triacetylglycerol (TAG) almost with both glycerines. Finally, the performance and reuse of the two heterogeneous biocatalysts was assessed. Under these conditions, one of the biocatalysts also achieved 100% TAG yield.

Teaching in Industrial Engineer in Degrees is based on the acquisition of competences. Generally, the training actions are lectures, lectures, classes of problems, seminars, lectures, laboratory practices, research works. In the evaluations to pass the subject, the greater percentage corresponds to the theoretical classes, to the detriment of the others, practical practice. The Remote Laboratory is a very valid training activity as an alternative to real laboratory practices, but it is not suitable for the Fluido mechanical Engineering course. This is because they need the same resources as a real Laboratory and to achieve the same objectives. It would only have advantages if the teaching were online. The viewing of videos, in an accessible manner and with the tutorization of the teacher, allows the student to acquire specific skills and autonomous learning. It is noted that the assimilation of knowledge is better, that the student has been more dedicated and shows more interest in learning and doing real practices., En el Plan de Estudios de Grados de Ingeniería Industrial se contempla la enseñanza por competencias. Las acciones formativas son, generalmente, clases magistrales, teóricas, clases de problemas, seminarios, exposiciones, prácticas de laboratorio, trabajos de investigación, proyectos. En las evaluaciones para la superación de la materia, el porcentaje mayor corresponde a las clases teóricas, en detrimento de las otras, normalmente prácticas. El Laboratorio remoto es una actividad formativa muy válida como alternativa a las prácticas de laboratorio reales, pero no es adecuada para la asignatura de Ingeniería Fluidomecánica. Esto es porque consume los mismos recursos que un Laboratorio real y se consiguen los mismos objetivos. Solo presentaría ventajas si la enseñanza fuera no presencial. El visionado de vídeos, de manera accesible y con la tutorización del profesor, permite que el alumno adquiera las competencias específicas y el aprendizaje autónomo. Se constata que la asimilación del conocimiento es mayor, que el alumno se ha dedicado más y que muestra más interés en aprender y en hacer prácticas reales.

Due to the new technologies development based on renewable sources of energy, in recent years Stirling engines have become very important in the energetic sector. Many of them do not allow the use of fluid lubricants and, thus, the effect of friction losses is important. For this purpose, a mathematical model has been developed based on the force balance in the crankshaft using the pressure distribution in the cylinders. The aim of this work is to characterize the mechanical losses in a Genoa 03 Stirling engine using a numerical model and experimentally via the drag method. The results of this model have been compared with those obtained experimentally on Genoa 03 Stirling engine. In the experimental results, a proportional increase in friction torque due to the average pressure and the speed of the crankshaft is observed. The first of these is caused by an increase of dry friction forces and the second, by the viscous friction between the working fluid and the inner walls of the engine. Also in this paper, irreversible processes in a beta type Stirling engine have been investigated in order to highlight the impact of losses on mechanical power and its performance. This article develops the first study of the mechanical losses of Genoa 03 experimental Stirling engine, which has an output power of 3 kW. Although the model response follows the same trends as the experiments, those simplifications provide errors which become more significant as the engine speed increases.

Biomass heating networks provide renewable heat using low carbon energy sources. They can be powerful tools for economy decarbonization. Heating networks can increase heating efficiency in districts and small size municipalities, using more efficient thermal generation technologies, with higher efficiencies and with more efficient emissions abatement technologies. This paper analyzes the application of a biomass fourth generation district heating, 4GDH (4th Generation Biomass District Heating), in a rural municipality. The heating network is designed to supply 77 residential buildings and eight public buildings, to replace the current individual diesel boilers and electrical heating systems. The development of the new fourth district heating generation implies the challenge of combining using low or very low temperatures in the distribution network pipes and delivery temperatures in existing facilities buildings. In this work biomass district heating designs based on third and fourth generation district heating network criteria are evaluated in terms of design conditions, operating ranges, effect of variable temperature operation, energy efficiency and investment and operating costs. The Internal Rate of Return of the different options ranges from 6.55% for a design based on the third generation network to 7.46% for a design based on the fourth generation network, with a 25 years investment horizon. The results and analyses of this work show the interest and challenges for the next low temperature DH generation for the rural area under analysis.

After the renewed interest in supercritical carbon dioxide cycles, a large number of cycle layouts have been proposed in literature. These works, which are essentially theoretical, consider different operating conditions and modeling assumptions, and thus, the results are not comparable. There are also works that aim to provide a fair comparison between different cycles in order to assess which one is most efficient. These analyses are very interesting but, usually, they combine thermodynamic and technical restrictions, which make it difficult to draw solid and general conclusions with regard to which the cycle of choice in the future should be. With this background, the present work provides a systematic thermodynamic analysis of 12 supercritical carbon dioxide cycles under similar working conditions, with and without technical restriction in terms of pressure and/or temperature. This yields very interesting conclusions regarding the most interesting cycles in the literature. Also, useful recommendations are extracted from the parametric analysis with respect to the directions that must be followed when searching for more efficient cycles. The analysis is based on efficiency and specific work diagrams with respect to pressure ratio and turbine inlet temperature in order to enhance its applicability to plant designs driven by fuel economy and/or footprint.