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We discuss how x-ray Compton scattering spectra can be used for investigating the evolution of electronic states in cathode materials of Li batteries under the lithiation/delithiation process. In particular, our analysis of the Compton spectra taken from polycrystalline LixCoO2 samples shows that the spectra are dominated by the contribution of the O-2p redox orbital. We identify a distinct signature of d-orbital delocalization, which is tied directly to the conductivity of the material, providing a descriptor based on Compton spectra for monitoring the lithiation range with improved conductivity and kinetics for electrochemical operation. Our study demonstrates that Compton scattering spectroscopy can provide a window for probing complex electronic mechanisms underlying the charging and discharging processes in Li-battery materials., Comment: 12 pages, 2 figures, and 1 table

Non-destructive determination of lithium distribution in a working battery is key for addressing both efficiency and safety issues. Although various techniques have been developed to map the lithium distribution in electrodes, these methods are mostly applicable to test cells. Here we propose the use of high-energy x-ray Compton scattering spectroscopy to measure the local lithium concentration in closed electrochemical cells. A combination of experimental measurements and parallel first-principles computations is used to show that the shape parameter S of the Compton profile is linearly proportional to lithium concentration and thus provides a viable descriptor for this important quantity. The merits and applicability of our method are demonstrated with illustrative examples of LixMn2O4 cathodes and a working commercial lithium coin battery CR2032., Comment: 14 pages, 5 figures

We present an incisive spectroscopic technique for directly probing redox orbitals based on bulk electron momentum density measurements via high-resolution x-ray Compton scattering. Application of our method to spinel LixMn2O4, a lithium ion battery cathode material, is discussed. The orbital involved in the lithium insertion and extraction process is shown to mainly be the oxygen 2p orbital. Moreover, the manganese 3d states are shown to experience spatial delocalization involving 0.16 electrons per Mn site during the battery operation. Our analysis provides a clear understanding of the fundamental redox process involved in the working of a lithium ion battery., Comment: 24 pages, 3 figures

We present results from Submillimeter Array (SMA) 860-micron sub-arcsec astrometry and multiwavelength observations of the brightest millimeter (S_1.1mm = 8.4 mJy) source, SSA22-AzTEC1, found near the core of the SSA22 protocluster that is traced by Ly\alpha emitting galaxies at z = 3.09. We identify a 860-micron counterpart with a flux density of S_860um = 12.2 +/- 2.3 mJy and absolute positional accuracy that is better than 0.3". At the SMA position, we find radio to mid-infrared counterparts, whilst no object is found in Subaru optical and near-infrared deep images at wavelengths \le 1 micron (J > 25.4 in AB, 2\sigma). The photometric redshift estimate, using flux densities at \ge 24 microns, indicates z_phot = 3.19^{+0.26}_{-0.35}, consistent with the protocluster redshift. We then model the near-to-mid-infrared spectral energy distribution (SED) of SSA22-AzTEC1, and find that the SED modeling requires a large extinction (A_V \approx 3.4 mag) of starlight from a stellar component with M_star ~ 10^{10.9} M_sun, assuming z = 3.1. Additionally, we find a significant X-ray counterpart with a very hard spectrum (Gamma_eff = -0.34 ^{+0.57}_{-0.61}), strongly suggesting that SSA22-AzTEC1 harbors a luminous AGN (L_X ~ 3*10^{44} ergs s^{-1}) behind a large hydrogen column (N_H ~ 10^{24} cm^{-2}). The AGN, however, is responsible for only ~10% of the bolometric luminosity of the host galaxy, and therefore the star-formation activity likely dominates the submillimeter emission. It is possible that SSA22-AzTEC1 is the first example of a protoquasar growing at the bottom of the gravitational potential underlying the SSA22 protocluster., Comment: 16 pages, 2 tables, 6 figures, accepted for publication in the Astrophysical Journal

We study the evolution of star formation activity of galaxies at 0.5~1. We found galaxies at 2.51 and becomes significant at z~3, especially in the case with the SFR based on MIPS 24um. In galaxies with Mstar = 10^{10-11.5} Msun, those with a relatively narrow range of SSFR (<~1 dex) dominates the cosmic SFRD at 0.5

We use very deep near-infrared (NIR) imaging data obtained in MOIRCS Deep Survey (MODS) to investigate the evolution of the galaxy stellar mass function back to z~3. The MODS data reach J=24.2, H=23.1, K=23.1 (5sigma, Vega magnitude) over 103 arcmin^2 (wide) and J=25.1, H=23.7, K=24.1 over 28 arcmin^2 (deep) in the GOODS-North region. The wide and very deep NIR data allow us to measure the number density of galaxies down to low stellar mass (10^9-10^10 Msun) even at high redshift with high statistical accuracy. The normalization of the mass function decreases with redshift and the integrated stellar mass density becomes ~ 8-18% of the local value at z~2 and ~ 4-9% at z~3, which are consistent with results of previous studies in general fields. Furthermore, we found that the low-mass slope becomes steeper with redshift from alpha ~- 1.3 at z~1 to alpha ~- 1.6 at z~3, and that the evolution of the number density of low-mass (10^9-10^10 Msun) galaxies is weaker than that of M* (~10^11 Msun) galaxies. This indicates that the contribution of low-mass galaxies to the total stellar mass density has been significant at high redshift. The steepening of the low-mass slope with redshift is opposite trend expected from the stellar mass dependence of the specific star formation rate reported in previous studies. The present result suggests that the hierarchical merging process overwhelmed the effect of the stellar mass growth by star formation and was very important for the stellar mass assembly of these galaxies at 1<~z<~3., Comment: 21 pages, 18 figures, accepted for publication in ApJ

We investigate the X-ray properties of the K-band-selected galaxies at redshift 2 < z < 4 by using our deep near-infrared images obtained in the MOIRCS Deep Survey project and the published Chandra X-ray source catalog. 61 X-ray sources with the 2-10 keV luminosity L_X = 10^{42}-10^{44} erg/s are identified with the K-selected galaxies and we found that they are exclusively (90%) associated with the massive objects with stellar mass larger than 10^{10.5} Msun. Our results are consistent with the idea that the M_BH/M_str ratio of the galaxies at z=2-4 is similar to the present-day value. On the other hand, the AGN detection rate among the very massive galaxies with the stellar mass larger than 10^{11} Msun is high, 33% (26/78). They are active objects in the sense that the black-hole mass accretion rate is ~ 1-50% of the Eddington limit if they indeed have similar M_BH/M_str ratio with those observed in the local universe. The active duration in the AGN duty cycle of the high-redshift massive galaxies seems large., Comment: 33 pages, 12 figures, accepted for publication in ApJ