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X-ray fluorescence (XRF) core scanners are commonly used for fine-scale geochemical analysis in sediment studies, but data are semi-quantitative and require calibration to convert geochemical element counts to concentrations. Application of XRF core scanning in soil science remains largely untapped. This study employed an ITRAX core scanner to scan grassland soil cores and developed a novel calibration method based on a chemometric approach to characterise soil geochemistry. As soil samples are collected based on depth sampling, this study investigated whether higher resolution element concentrations could be inferred from lower resolution reference samples and if regression models from multiple cores could apply to a new core at the same resolution. Reference concentrations were obtained for all cores at 10 cm intervals, with validation conducted at 1 cm for a single core. Two calibration curve types were proposed: one based on the single core's 10 cm data to validate references at 1 cm intervals; and another using all cores, with each core serving as a test item after exclusion from the training set. Various preprocessing measures and feature selection techniques were tested. Results showed successful calibration for elements Ca, P, Zn, Sr, and S, with high R 2 values of 0.94, 0.93, 0.93, 0.92 and 0.91, respectively. The study presents a novel method for calibrating XRF core scanning element counts, demonstrating its potential for high-resolution soil analysis. [ABSTRACT FROM AUTHOR]

Hybrid event beds form when turbidity currents that transport or locally acquire significant quantities of mud decelerate. The mud dampens turbulence driving flow transformations, allowing both mud and sand to settle into dense, near‐bed fluid layers and debris flows. Quantifying details of the mud distribution vertically in what are often complex tiered deposits is critical to reconstructing flow processes and explaining the diverse bed types left by mud‐bearing gravity flows. High‐resolution X‐ray fluorescence core scanning provides continuous vertical compositional profiles that can help to constrain mud distribution at sub‐millimetre scale, offering a significant improvement over discrete sampling. The approach is applied here to cores acquired from the Pennsylvanian Ross Sandstone Formation, western Ireland, where a range of hybrid event beds have been identified. Raw X‐ray fluorescence counts are calibrated against element concentrations and mineral abundances determined on coincident core plugs, with element and element log‐ratios used as proxies to track vertical changes in abundances of quartz, illite (including mica), chlorite and calcite cement. New insights include 'stepped' (to higher values) as opposed to 'saw‐tooth' vertical changes in mud content and the presence of compositional banding that would otherwise be overlooked. Hybrid event beds in basin floor sheets that arrived ahead of the prograding fan system have significantly cleaner sandy components than those in mid‐fan lobes. The latter may imply that the heads of the currents emerging from mid‐fan channels entrained significant mud immediately before they collapsed. Many of the H3 debrites are bipartite with a sandier H3a division attributed to re‐entrainment and mixing of a trailing debris or fluid mud flow (H3b) with sand left by the forward part of the flow. Hybrid event bed structure may thus partly reflect substrate interaction and mixing during deposition, and the texture of the bed divisions may not simply mirror those in the suspensions from which they formed. [ABSTRACT FROM AUTHOR]