1. Intra-Layer Inhomogeneity of the Anode in Commercial Li-Ion Batteries
- Author
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Tuo Fang, Guangsen Jiang, Yong Xia, and Pengfei Ying
- Subjects
Li-ion battery ,electric vehicle ,battery safety ,inhomogeneity ,operando observation ,Production of electric energy or power. Powerplants. Central stations ,TK1001-1841 ,Industrial electrochemistry ,TP250-261 - Abstract
The Li intercalation reaction exhibits non-uniform behavior along the thickness direction of the electrode in a Li-ion battery. This non-uniformity, or intra-layer inhomogeneity (ILIH), becomes more serious as the charging and discharging speed increases. Substantial ILIH can lead to Li plating and the emergence of inhomogeneous inner stress, resulting in a decrease in battery service life and an increase in battery safety risks. In this study, an operando optical observation was conducted based on the color change reaction during Li intercalation in the anode. Subsequently, we introduce a novel quantitative method to assess ILIH in commercial Li-ion batteries. A specific ILIH value (KILIH) is first used in this article for ILIH characterization. An analysis of KILIH at different charging and discharging rates was conducted, alongside the exploration of KILIH-SOC trends and their underlying mechanisms. The proposed method exhibits favorable mathematical convergence and physical interpretability, as supported by the results and mechanism analysis. By enabling the assessment of ILIH evolution in response to SOC and (dis)charging rate variations, the proposed method holds significant potential for optimizing fast charging protocols in commercial batteries and contributing to the development of refined electrochemical battery models in future research.
- Published
- 2023
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