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Food waste (FW) comprises carbohydrates, proteins, lipids, and water, posing technical challenges for effective treatment and valorisation. This study addresses these challenges by using black soldier fly larvae (BSFL) as a bioconversion medium to transform FW into biodiesel (BD). BSFL predominantly consumed the carbohydrates and proteins in FW (81 wt%), while showing a lower preference for lipids (<50 wt% consumed). Notwithstanding the lower consumption of lipids in the FW than that of carbohydrates and proteins, BSFL had a high lipid content (48.3 wt%). The subsequent conversion of the lipids extracted from BSFL into BD was tested via catalytic (acid/alkali) and non-catalytic transesterification processes. The BD yield from catalytic transesterification was lower than that from non-catalytic transesterification because of the low tolerance against free fatty acids (FFAs). BD was also produced from the lipid-concentrated residual FW through non-catalytic transesterification. Although the FW residue extracts contained high amounts of FFAs (49.9 wt%), non-catalytic transesterification displayed a high BD yield (92.4 wt%; yields from catalytic transesterification: < 80.0 wt%). Moreover, blending the BD derived from the BSFL and FW residue extracts enhanced the fuel properties. The BSFL-assisted FW management efficiently reduced FW by 90 wt% while producing a high-quality BD., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Pyrolysis has been proposed to stabilize heavy metals present in livestock manure. However, many studies have not considered the applicability of manure-derived biochar containing endogenous heavy metals as an agricultural fertilizer. This study investigated the mechanisms through which pyrolysis stabilizes endogenous heavy metals in swine manure and the long-term stability of endogenous heavy metals in the biochar. As pyrolysis temperature increased from 300 °C to 700 °C, the potential ecological risk index decreased from 46.3 to 4.8 because the unstable fraction converted to organic-sulfide bonds and residues. Biochar prepared at 600 °C was the most stable and met the World Health Organization's phyto-availability standards (Cu 10 mg/kg, Zn 0.6 mg/kg). Fourier transform infrared spectroscopy and X-ray diffraction analyses indicated that endogenous heavy metals were stabilized by complexation with organic matter and precipitated as metal-phosphate forms. After 40 cycles of wet-dry aging, the leachability of heavy metals (Cu 6.0 mg/kg, Zn 460.6 mg/kg) from biochar was still lower than that of swine manure (Cu 102.5 mg/kg and Zn 704.9 mg/kg), indicating the long-term stability of the heavy metals in the biochar. Pyrolysis dramatically lowered the environmental threat posed by endogenous heavy metals, demonstrating the applicability of swine manure-derived biochar compared to manure., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

The annual increase in global organic waste generation emphasises the need to develop a sustainable management platform to address environmental concerns. This study aims to explore sustainable treatments for the conversion of organic waste into energy in pursuit of zero-waste. The organic waste generated from the animal feed industry (referred to as WF) was used for the model compound in this study. 8.5 wt% of lipids were extracted from the WF, which contained unidentified impurities. Acid-catalysed transesterification yielded less than 80 wt% biodiesel might be due to the reversible reaction. In contrast, non-catalytic transesterification resulted in a significantly higher biodiesel yield (95.6 wt%), suggesting that this method was more effective at converting impure lipids into biodiesel compared to acid-catalysed transesterification. These results indicate the potential advantages of the non-catalytic approach, particularly when dealing with impure lipid sources. To minimise the generation of waste in the process, the WF residue produced after lipid extraction was converted into combustible gas (syngas) through pyrolysis. CO 2 was used as a reactive medium in pyrolysis. In one-stage pyrolysis, the gas yield under CO 2 was comparable to that under N 2 , indicating that CO 2 did not react effectively with the volatiles derived from the WF residue. Enhanced CO 2 reactivity was achieved via catalytic pyrolysis using a nickel-impregnated catalyst. Consequently, the combustible gas yield under CO 2 was much higher than that under N 2 . This approach might contribute to maximising the efficiency of converting organic waste into renewable energy while simultaneously consuming CO 2 during pyrolysis, thereby enhancing the sustainability of this approach., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

The escalating volume of sewage sludge (SS) generated poses challenges in disposal, given its potential harm to the environment and human health. This study explored sustainable solutions for SS management with a focus on energy recovery. Employing CO 2 -assisted pyrolysis, we converted SS into flammable gases (H 2 and CO; syngas). Single-stage pyrolysis of SS in a CO 2 conditions demonstrated that CO 2 enhances flammable gas production (especially CO) through gas phase reactions (GPRs) with volatile matter (VM) at temperatures ≥520 °C. Specifically, the CO 2 partially oxidized the VM released from SS and concurrently underwent reduction into CO. To enhance the syngas production at temperatures ≤520 °C, multi-stage pyrolysis setup with additional heat energy and a Ni/Al 2 O 3 catalyst were utilized. These configurations significantly increased flammable gas production, particularly CO, at temperatures ≤520 °C. Indeed, the flammable gas yield in the catalytic pyrolysis of SS increased from 200.3 mmol under N 2 conditions to 219.2 mmol under CO 2 conditions, representing a 4.4-fold increase compared to single-stage pyrolysis under CO 2 conditions (50.0 mmol). By integrating a water-gas-shift reaction, the flammable gases produced from CO 2 -assisted catalytic pyrolysis were expected to have the potential to generate revenue of US$4.04 billion. These findings highlight the effectiveness of employing CO 2 in SS pyrolysis as a sustainable and effective approach for treating and valorising SS into valuable energy resources., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

In response to address the climate crisis, there has been a growing focus on substituting conventional refinery-derived products with those derived from biorefineries. The utilization of lipids as primary materials or intermediates for the synthesis of chemicals and fuels, which are integral to the existing chemical and petrochemical industries, is a key step in this transition. This review provides a comprehensive overview of the production of sustainable chemicals (acids and alcohols), biopolymers, and fuels (including gasoline, kerosene, biodiesel, and heavy fuel oil) from lipids derived from terrestrial and algal biomass. The production of chemicals from lipids involves diverse methods, including polymerization, epoxidation, and separation/purification. Additionally, the transformation of lipids into biofuels can be achieved through processes such as catalytic cracking, hydroprocessing, and transesterification. This review also suggests future research directions that further advance the lipid valorization processes, including enhancement of catalyst durability at harsh conditions, development of deoxygenation process with low H 2 consumption, investigation of precise separation of target compounds, increase in lipid accumulation in algal biomass, and development of methods that utilize residues and byproducts generated during lipid extraction and conversion., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier Inc.)

This study explored the use of waste from the textile industry (silkworm byproducts) as a promising raw feedstock for the production of carbon-based adsorbents (biochar). The silk excreta biochar generated at 600 and 700 °C (referred to as SEB-600 and SEB-700, respectively) were evaluated in terms of their efficacy in adsorbing cationic (methylene blue) and anionic (Congo red) textile dyes. Although the functional groups on the surfaces of SEB-600 and SEB-700 were not significantly different, the specific surface area of SEB-700 was greater than that of SEB-600. The dye adsorption capacity of SEB-700 was higher than that of SEB-600. The adsorption of methylene blue and Congo red on SEB-700 followed Freundlich isotherms (R 2  ≥ 0.963) and pseudo-second-order kinetics (R 2  = 0.999), indicating chemisorption with multilayer characteristics. The mechanism for the adsorption of methylene blue on SEB-700 may involve interactions with the negatively charged functional groups on the surface and the mesopores of SEB-700. For the adsorption of Congo red, the mesopores in the biochar and the electrostatic interaction between biochar (positively charged because of the dye solution pH < pH zpc ) and the anionic dye could affect adsorption. The maximum adsorption capacities of SEB-700 for methylene blue and Congo red were determined to be 168.23 and 185.32 mg g -1 , respectively. Utilising the waste generated from the textile industry to remove pollutants will build a sustainable loop in the industry by minimising waste generation and pollutant emissions., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier Inc.)

Although biomass is carbon-neutral, its use as a primary feedstock faces challenges arising from inconsistent supply chains. Therefore, it becomes crucial to explore alternatives with reliable availability. This study proposes a strategic approach for the thermochemical valorization of food processing waste, which is abundantly generated at single sites within large-scale processing plants. As a model biomass waste from the food industry, orange peel waste was particularly chosen considering its substantial consumption. To impart sustainability to the pyrolysis system, CO 2 , a key greenhouse gas, was introduced. As such, this study highlights elucidating the functionality of CO 2 as a reactive feedstock. Specifically, CO 2 has the potential to react with volatile pyrolysates evolved from orange peel waste, leading to CO formation at ≥490 °C. The formation of chemical constituents, encompassing acids, ketones, furans, phenols, and aromatics, simultaneously decreased by 15.1 area% in the presence of CO 2 . To activate the efficacy of CO 2 at the broader temperature spectrum, supplementary measures, such as an additional heating element (700 °C) and a nickel-based catalyst (Ni/Al 2 O 3 ), were implemented. These configurations promote thermal cracking of the volatiles and their reaction kinetics with CO 2 , representing an opportunity for enhanced carbon utilization in the form of CO. Finally, the integrated process of CO 2 -assisted catalytic pyrolysis and water-gas shift reaction was proposed. A potential revenue when maximizing the productivity of H 2 was estimated as 2.62 billion USD, equivalent to 1.11 times higher than the results from the inert (N 2 ) environment. Therefore, utilizing CO 2 in the pyrolysis system creates a promising approach for enhancing the sustainability of the thermochemical valorization platform while maximizing carbon utilization in the form of CO., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Environmental pollution and poor feed quality pose potential threats to aquatic organisms and human health, representing challenges for the aquaculture industry. In light of the rising demand for aquatic organisms, there is an urgent need to improve aquacultural production and protect the products from contamination. Char, a carbonaceous material derived through pyrolysis of organic carbon-rich biomass, has proven advantages in soil, air, and water remediation. While char's performance and the associated physicochemical characteristics depend strongly on the pyrolysis temperature, residence time, and feedstock type, char generally shows advantages in pollutant removal from the environment and livestock. This enables it to enhance the health and growth performance of livestock. Given the growing attention to char application in aquaculture in recent years, this review summarises major studies on three applications: aquacultural water treatment, sediment remediation, and char-feed supplement. Most of these studies have demonstrated char's positive effects on pollutant removal from organisms and aquacultural environments. Moreover, adopting char as fish feed can improve fish growth performance and the condition of their intestinal villi. However, due to insufficient literature, further investigation is needed into the mechanistic aspects of pollutants removal in aquatic organisms by char as a feed additive, such as the transportation of char inside aquatic organisms, the positive and negative effects of char on these products, and how char alters the gut microbiota community of these products. This paper presents an overview of the current application of char in aquaculture and highlights the research areas that require further investigation to enrich future studies., Competing Interests: Declaration of competing interest The authors declare the following financial interests/personal relationships which may be considered as potential competing interests: YU BON MAN reports financial support was provided by Research Grants Council of Hong Kong and The Education University of Hong Kong. If there are other authors, they declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Microplastics are known to negatively affect anaerobic digestion (AD) of waste activated sludge. However, whether thermal hydrolysis (TH) pretreatment alters the impact of microplastics on sludge AD remains unknown. Herein, the effect of TH on the impact of polyethylene (PE) microplastics in sludge AD was investigated. The results showed that the inhibition of methane production by PE at 100 particles/g total solids (TS) was reduced by 31.4% from 12.1% to 8.3% after TH at 170 °C for 30 min. Mechanism analysis indicated TH reduced the potential for reactive oxygen species production induced by PE, resulting in a 29.1 ± 5.5% reduction in cell viability loss. In addition, additive leaching increased as a result of rapid aging of PE microplastics by TH. Acetyl tri-n-butyl citrate (ATBC) release from PE with 10 and 100 particles/g TS increased 11.5-fold and 8.6-fold after TH to 68.2 ± 5.5 μg/L and 124.0 ± 5.1 μg/L, respectively. ATBC at 124.0 μg/L increased methane production by 21.4%. The released ATBC enriched SBR1031 and Euryarchaeota, which facilitate the degradation of proteins and promote methane production. This study reveals the overestimated impact of PE microplastics in sludge AD and provides new insights into the PE microplastics-induced impact in practical sludge treatment and anaerobic biological processes., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

This study explored the valorisation of silkworm by-product, a major by-product of the silk industry (sericulture), which amounts to 16 million tonnes annually. The focus was on transforming waste into energy resources through pyrolysis under CO 2 conditions. In one-stage pyrolysis, the evolution of syngas under N 2 was found to be comparable to that under CO 2 . A notable allocation of carbon to biocrude rather than syngas was observed. The two-stage pyrolysis resulted in increased syngas production. However, achieving a homogeneous reaction between CO 2 and the volatiles liberated from silkworm byproduct proved challenging. Indeed, the reaction kinetics governing CO 2 reactivity was not fast although the temperature windows of the reaction were aligned in the two-stage pyrolysis. To address this issue, pyrolysis was performed using a Ni-based catalyst to expedite the reaction kinetics. Consequently, syngas formation, particularly CO formation, was significantly enhanced under CO 2 conditions compared to that under N 2 conditions. The syngas yield under CO 2 was 36.42 wt% which was 2-fold higher than that of N 2 . This suggested the potential of CO 2 altering the carbon distribution from biocrude to syngas. This strategy would contribute to the establishment of sustainable production of silk by converting sericulture by-product into energy/chemical resources., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Using edible lipids for biodiesel production has been criticized, causing biodiesel production from inedible food resources to be desirable. Lipid extraction must be prioritized to produce biodiesel using an acid/base-catalyzed transesterification process, but this conversion process suffers from technical reliability. Therefore, this study introduced non-catalytic conversion of oil-bearing biomass into biodiesel. Apricot seeds were used as a model compound (oil content 44.3 wt%). The non-catalytic transesterification of apricot seed oil recovered 98.28 wt% biodiesel at 360 °C for 1 min, while alkali-catalysis of apricot seed oil recovered 91.84 wt% at 63 °C for 60 min. The direct conversion of apricot seeds into biodiesel was attempted. The trends in the yields of biodiesel from apricot seeds and seed oil obtained by non-catalytic transesterification as a function of reaction temperature were similar. The yield of biodiesel from apricot seed was 43.06 wt%, suggesting that 97.20 wt% of lipids were converted into biodiesel., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Recently, carbon quantum dots (CQDs) have become popular because of their simple synthesis and potential applications. Although CQDs have high biocompatibility, their biotoxicity must be verified to reduce the possible risks associated with large-scale application. In this study, the hepatotoxicity of three CQD types, namely diammonium citrate (AC)-based (CQDs-AC), spermidine trihydrochloride (Spd)-based (CQDs-Spd), and AC- and Spd-based CQDs (CQDs-AC/Spd), were evaluated in vivo and in vitro. It was observed in vivo that CQDs-Spd and CQDs-AC/Spd, but not CQDs-AC, caused histopathological damage, including liver steatosis and mild mixed inflammatory cell infiltration; however, reduced liver function was only observed in CQD-Spd-treated mice. The in vitro results revealed that only CQDs-Spd significantly decreased the number of viable HepG2 cells (NADH depletion) and induced oxidative stress (heme oxygenase-1 activation) after 24 h of exposure, which promoted inflammatory factor secretion (NF-κB activation). Additionally, decreasing zonula occludens-2 and α1-antitrypsin protein expression in HepG2 cells suggested that CQD-Spd exposure increases the risk of liver diseases. Our results revealed that CQDs-Spd had greater hepatotoxic potential than CQDs-AC and CQDs-AC/Spd, which might be attributable to their high positive surface charge. Overall, the risk of CQD-induced hepatotoxic risk must be considered when applying positively charged CQDs., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

This study investigated the conversion of agricultural biomass waste (specifically, spent mushroom substrate) into syngas via pyrolysis. Carbon dioxide was used to provide a green/sustainable feature in the pyrolysis process. All the experimental data highlight the mechanistic role of carbon dioxide (CO 2 ) in the process, demonstrated by the enhanced carbon monoxide (CO) yield from pyrolysis under CO 2 . Carbon dioxide was indeed reactive at ≥ 500 ˚C. Carbon dioxide was reduced and subsequently oxidized volatiles stemming from the thermolysis of spent mushroom substrate via the gas-phase reaction, thereby resulting in the enhanced formation of CO. Carbon dioxide radically diverted the carbon distribution patterns of the pyrogenic products, as more carbon in the oil was allocated to syngas by the gas-phase reaction of volatiles and CO 2 . To enhance the mechanistic role of CO 2 , a Ni-based catalyst was added to the pyrolysis process, which greatly accelerated the gas-phase reaction of volatiles and CO 2 ., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

The concept of monomer recovery from plastic waste has recently gained broad interest in industry as a powerful strategy to reduce the environmental impacts of chemical production and plastic waste pollution. Herein, we focus on the ethylene recovery from plastic waste via thermochemical pathways, such as pyrolysis, gasification, and steam cracking of pyrolysis oil derived from plastic waste. Ethylene recovery performance of different thermochemical conversion processes is evaluated and compared with respect to plastic waste types, process types, ethylene recovery yields, and process operating conditions. Based on the analysis of available data in earlier literature, future research is recommended to further enhance the viability of the thermochemical ethylene recovery technologies. This review is expected to offer a meaningful guideline on developing efficient platforms for the value-added monomer recovery from plastic waste through thermochemical conversion routes. It is also hoped that this review serves as a preliminary step to encourage the widespread adoption of thermochemical conversion-based ethylene recovery from plastic waste by industries., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier B.V. All rights reserved.)

Meretrix lyrata which is under the family of Veneridae and under the order of Venerida, is a nutritionally and economically important edible mussel in Bangladesh. However, studies on species identification and nutritional value in M. lyrata are scarce. Therefore, a detailed investigation was conducted on (i) species identification of the common edible mussel through DNA-barcoding and morphometrics, (ii) reproductive features, such as size at sexual maturity, spawning, and peak-spawning seasons under different environmental factors, and (iii) nutritional status through proximate analysis of M. lyrata mussel collected from the Bay of Bengal, Bangladesh. The results indicated that the size at sexual maturity for M. lyrata was 4.2 cm and the spawning seasons were significantly affected by the dissolve oxygen and salinity. The study also demonstrated that the spawning of M. lyrata occurred from January to June and December while peak spawning season was May in the Bay of Bengal. The higher protein and moisture contents with lower fat in M. lyrata indicated that are value-added seafood with higher nutritional values for consumers., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

To reduce the nanoplastics (NPs) toxicity assessment error, we established a Transwell-based bronchial epithelial cell exposure system to assess the pulmonary toxicity of polystyrene NPs (PSNPs). Transwell exposure system was more sensitive than submerged culture for toxicity detection of PSNPs. PSNPs adhered to the BEAS-2B cell surface, were ingested by the cell, and accumulated in the cytoplasm. PSNPs induced oxidative stress and inhibited cell growth through apoptosis and autophagy. A noncytotoxic dose of PSNPs (1 ng/cm 2 ) increased the expression levels of inflammatory factors (ROCK-1, NF-κB, NLRP3, ICAM-1, etc) in BEAS-2B cells, whereas a cytotoxic dose (1000 ng/cm 2 ) induced apoptosis and autophagy, which might inhibit the activation of ROCK-1 and contribute to reducing inflammation. In addition, the noncytotoxic dose increased the expression levels of zonula occludens-2 (ZO-2) and α1-antitrypsin (α-AT) proteins in BEAS-2B cells. Therefore, in response to PSNP exposure, a compensatory increase in the activities of inflammatory factors, ZO-2, and α-AT may be triggered at low doses as a mechanism to preserve the survival of BEAS-2B cells. In contrast, exposure to a high dose of PSNPs elicits a noncompensatory response in BEAS-2B cells. Overall, these findings suggest that PSNPs may be harmful to human pulmonary health even at an ultralow concentration., Competing Interests: Declaration of competing interest All the authors declare no conflict of interest., (Copyright © 2023 Elsevier B.V. All rights reserved.)

Bangladesh is not an exception to the growing global environmental problem of plastic pollution. Plastics have been deemed a blessing for today's world thanks to their inexpensive production costs, low weight, toughness, and flexibility, but poor biodegradability and massive misuse of plastics are to blame for widespread contamination of the environmental components. Plastic as well as microplastic pollution and its adverse consequences have attracted significant investigative attention all over the world. Plastic pollution is a rising concern in Bangladesh, but scientific studies, data, and related information are very scarce in numerous areas of the plastic pollution problem. The current study examined the effects of plastic and microplastic pollution on the environment and human health, and it examined Bangladesh's existing knowledge of plastic pollution in aquatic ecosystems in light of the rapidly expanding international research in this field. We also made an effort to investigate the current shortcomings in Bangladesh's assessment of plastic pollution. This study proposed several management approaches to the persistent plastic pollution problem by analyzing studies from industrialized and emerging countries. Finally, this work pushed investigators to investigate Bangladesh's plastic contamination thoroughly and develop guidelines and policies to address the issue., (© 2023. The Author(s), under exclusive licence to Springer Nature B.V.)

Crop residues are representative agricultural waste materials, massively generated in the world. However, a large fraction of them is currently being wasted, though they have a high potential to be used as a value-added carbon-rich material. Also, the applications of carbon-rich materials from agricultural waste to industries can have economic benefit because waste-derived carbon materials are considered inexpensive waste materials. In this review, valorization methods for crop residues as carbon-rich materials (i.e., biochars) and their applications to industrial toxic gas removals are discussed. Applications of crop residue biochars to toxic gas removal can have significant environmental benefits and economic feasibility. As such, this review discussed the technical advantages of the use of crop residue biochars as adsorbents for hazardous gaseous pollutants and greenhouse gases (GHGs) stemmed from combustion of fossil fuels and the different refinery processes. Also, the practical benefits from the activation methods in line with the biochar properties were comprehensively discussed. The relationships between the physico-chemical properties of biochars and the removal mechanisms of gaseous pollutants (H 2 S, SO 2 , Hg 0 , and CO 2 ) on biochars were also highlighted in this review study. Porosity controls using physical and chemical activations along with the addition of specific functional groups and metals on biochars have significantly contributed to the enhancement of flue gas adsorption. The adsorption capacity of biochar for each toxic chemical was in the range of 46-76 mg g -1 for H 2 S, 40-182 mg g -1 for SO 2 , 80-952 μg g -1 for Hg 0 , and 82-308 mg g -1 CO 2 , respectively. This helps to find suitable activation methods for adsorption of the target pollutants. In the last part, the benefits from the use of biochars and the research directions were prospectively provided to make crop residue biochars more practical materials in adsorption of pollutant gases., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier B.V. All rights reserved.)

Polycarbonate (PC) microplastics are frequently detected in waste activated sludge. However, understanding the potential impact of PC microplastics on biological sludge treatment remains challenging. By tracking the changes in methane production under different concentrations of PC microplastics, a dose-dependent effect of PC microplastics on anaerobic digestion of sludge was observed. PC microplastics at 10-60 particles/g total solids (TS) improved methane production by up to 24.7 ± 0.1 % (at 30 particles/g TS), while 200 particles/g TS PC microplastics reduced methane production by 8.09 ± 0.1 %. Bisphenol A (BPA) leached from 30 particles/g TS PC microplastics (1.26 ± 0.18 mg/L) down-regulated intracellular reactive oxygen species (ROS) production, thereby enhancing enzyme activity, biomass viability, and abundance of methanogenic (Methanobacterium sp. and Methanosarcina sp.), ultimately boosting methane production. Conversely, BPA leached from 200 particles/g TS PC microplastics (4.02 ± 0.15 mg/L) stimulated ROS production, resulting in decreased biomass viability and even apoptosis. Modulation of oxidative stress by leaching monomeric BPA is an underappreciated transformative mechanism for improving the mastery of the potential behavior of microplastics in biological sludge treatment., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

While Azorubin S (AZRS) is extensively used as a reddish anionic azo dye for textiles and an alimentary colorant in food, AZRS is mutagenic/carcinogenic, and it shall be removed from dye-containing wastewaters. In view of advantages of SO 4 •- -related chemical oxidation technology, oxone (KHSO 5 ) would an ideal source of SO 4 •- for degrading AZRS, and heterogeneous Co 3 O 4 -based catalysts is required and shall be developed for activating oxone. Herein, a facile protocol is proposed for fabricating mesoporous silica (MS)-confined Co 3 O 4 by a templating agent-mediated dry-grinding procedure. As the templating agent retained inside the ordered pores of MS (before calcination) would facilitate insertion and dispersion of Co ions into pores, the resulting Co 3 O 4 nanoparticles (NPs) would be grown and confined within the pores of MS after calcination, affording Co@MS. On the contrary, another analogue, Co/MS, is also prepared using the similar protocol without the templating agent-mediated introduction of Co, but Co 3 O 4 NPs seriously aggregate as clusters on MS. Therefore, Co@MS outperforms Co/MS for activating oxone to eliminate AZRS. Co@MS shows a noticeably lower activation energy of AZRS elimination than the existing catalysts, revealing its advantage over the reported catalysts. Moreover, the mechanistic investigation of AZRS elimination by Co@MS-activated oxone has been also elucidated for identifying the presence of SO 4 •‒ , • OH, and 1 O 2 in AZRS degradation using scavengers, electron paramagnetic resonance spectroscopy, and semi-quantification. The AZRS decomposition pathway is also investigated and unveiled in details via the DFT calculation. These results validate that Co@MS appears as a superior catalyst of oxone activation for AZRS degradation., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022. Published by Elsevier Ltd.)

Amine/hydrazone functionalized dual ligand Cd(II)/Zn(II) based metal-organic frameworks (MOFs) denoted as CdMOF- and ZnMOF-NH 2 , respectively were synthesized via a simple conventional high-yield reflux method using low-cost and readily available starting materials, i.e., a Schiff base linker, 4-pyridylcarboxaldehydeisonicotinoylhydrazone (L 1 ) and 2-aminoterephthalic acid (H 2 ata) linker. Crystallographic and thermogravimetric studies confirmed the formation of MOFs with good crystallinity and thermal stability. Photoluminescence studies point out that both MOFs can be used efficiently for fast sensing of 2,4,6-trinitrophenol (TNP) in water with noticeable turn-off quenching response. Their limits of detection (LODs) for TNP were 7 ppb and 10 ppb, respectively with enhanced selectivity toward TNP (over other nitro explosives) as verified by competitive nitro explosive tests. Density functional theory calculations and spectral overlap were used to assess the sensing mechanism. These MOF-based fluorescent sensing systems for TNP are demonstrated to have easy recoverability and high sensitivity., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

The abuse of Chloramphenicol (CAP) has become the increasingly serious environmental problem for its harmfulness and toxicity. A novel strategy was achieved by photocatalysis coupled with microbial fuel cell (Photo-MFC) over Ni/MXene photocathode for enhancing the degradation efficiency of (CAP). It was demonstrated that the best degradation efficiency of CAP can reach 82.62% (original concentration of 30 mg/L) after 36 h under the optimal conditions (pH = 2). Based on density functional theory (DFT) calculations and high-performance liquid chromatography-mass (HPLC-MS) spectrometry, it was speculated that the degradation mechanism of CAP in Photo-MFC over Ni/MXene photoelectrode was achieved by destroying the two asymmetric centers and nitro, including the hydrodechlorination, nitro reduction reaction, hydroxylation reaction, cleavage of CN bond and ring-opening reaction of benzene ring. Finally, the ecotoxicity evaluation of the degradation products showed that the CAP degradation in the Ni/MXene modified photo-MFC system showed a remarkable tendency to the low-toxicity level., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier Inc. All rights reserved.)

Adsorption is a widely used technology for removing and separating heavy metal from water, attributed to its eco-friendly, cost-effective, and high efficiency. Adsorption isotherm modeling has been used for many years to predict the adsorption equilibrium mechanism, adsorption capacity, and the inherent characteristics of the adsorption process, all of which are substantial in evaluating the performance of adsorbents. This review summarizes the development history, fundamental characteristics, and mathematical derivations of various isotherm models, along with their applicable conditions and application scenarios in heavy metal adsorption. The latest progress in applying isotherm models with a one-parameter, two-parameter, and three-parameter in heavy metal adsorption using carbon-based materials, which has gained much attention in recent years as low-cost adsorbents, is critically reviewed and discussed. Several experimental factors affecting the adsorption equilibrium, such as solution pH, temperature, ionic strength, adsorbent dose, and initial heavy metal concentration, are briefly discussed. The criteria for selecting the optimum isotherm for heavy metal adsorption are proposed by comparing various adsorption models and analyzing mathematical error functions. Finally, the relative performance of different isotherm models for heavy metal adsorption is compared, and the future research gaps are identified., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that would appear to influence the work reported in this paper., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Plastic is a versatile material broadly used in a variety of industries. However, the current disposal practices for plastic wastes (incineration/landfilling) add the hazardous materials into the environment. To offer a sustainable valorization platform for plastic waste, this study adopted the catalytic pyrolysis process using CO 2 as a co-feedstock. A model plastic waste collected from a seaport was waste buoy (WB), which has been widely used in fishing industry. Prior to the pyrolysis tests, the exact type of plastic in WB and the thermolytic characteristics of WB were examined. Since the WB was made of polystyrene, it was mainly converted into styrene monomer (styrene), dimer (diphenyl-1-butene), and trimer (2,4,6-triphenyl-1-hexene) from pyrolysis of WB. To further valorize/detoxify styrene derivatives into value-added syngas, catalytic pyrolysis of WB was practiced using the Ni-based catalysts (2/5/10 wt% Ni/SiO 2 ). The yield of H 2 from the catalytic pyrolysis process of WB was more than one magnitude higher comparing to that from the non-catalytic one. H 2 formation also increased as catalyst loading increased. When flow gas was switched from inert gas to CO 2 , CO gas formation was enhanced due to the chemical reactions between CO 2 and styrene derivatives over Ni catalysts. Syngas (H 2 /CO) formation under the CO 2 condition was 5 times higher in comparison to the N 2 condition in catalytic pyrolyses of WB with 10 wt% Ni/SiO 2 . CO 2 also effectively suppressed coke deposition on a Ni catalyst. This study proposes a sustainable valorization and disposal platform for used plastic waste and greenhouse gas (CO 2 ), converting them into value-added fuel., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Toys are discarded due to their short life cycle. Unfortunately, development of sustainable disposal platform for toy has not gained particular concern. To establish a reliable disposal platform, this study employed a pyrolysis platform to valorize plastics into value-added fuels. To confer more environmentally resilient process, CO 2 was used as a feedstock to enhance the process efficiency from a perspective of the yield of flammable gases. To this end, waste toy brick (WTB) was used as a model compound. The exact types of plastics (polyacrylonitrile, polybutadiene, polystyrene, and polymethyl methacrylate) in WTB were experimentally determined. In pyrolysis of WTB, the complicated mixture of benzene derivatives was inevitably generated. To detoxify them by means of syngas (H 2 /CO) production, catalytic pyrolysis was performed. Co catalyst effectively induced chemical bond scissions, leading to substantially enhanced H 2 formation. Also, the gas phase reactions (GPRs) between CO 2 and volatile compounds over Co catalyst expedited the production rate of CO, and such CO enhancement effectively offered a chance to mitigate toxic chemical generations. The synergistic contribution of CO 2 and Co catalyst enhanced syngas formation more than 25 times in reference to pyrolysis of WTB without Co catalyst. The GPRs also greatly prevented catalyst deactivation., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Conventional disposal processes (incineration and landfilling) of agricultural plastic wastes release harmful chemicals and microplastics into our ecosystems. To provide a disposal platform not releasing harmful chemicals, pyrolysis of a representative agricultural plastic waste was proposed in this study. Spent plastic mulching film (SMF) was used as a model waste compound. To make pyrolysis process more environmentally benign, CO 2 was used as a raw material in pyrolysis of SMF. H 2 and hydrocarbons were produced from pyrolysis of SMF under the inert (N 2 ) and CO 2 conditions, because SMF is composed of polyethylene. To enhance conversion of hydrocarbons into H 2 , catalytic pyrolysis of SMF was conducted over Ni/SiO 2 . Compared to non-catalytic pyrolysis, total concentration of pyrolytic gases was enhanced up to 3.1 and 11.3 times under N 2 and CO 2 conditions, respectively. The gas phase reactions between CO 2 and hydrocarbons led to formation of CO, which enhanced production of pyrolytic gases under the CO 2 condition. Moreover, gas phase reactions resulted in less production of pyrolytic oil from CO 2 condition (15.9 wt%) in reference to the N 2 condition (22.6 wt%). All experimental results confirmed that CO 2 and SMF can be used as useful feedstocks to produce value-added products. ENVIRONMENTAL IMPLICATION: Plastic waste used from a sector of agriculture is incinerated or/and landfilled, generating hazardous microplastic and volatile compounds into the environment. Thus, an environmentally friendly process for plastic waste materials in the agricultural industry is required. This study converted a spent plastic mulching film (SMF), broadly used for plastic greenhouse, into value-added syngas through catalytic pyrolysis. CO 2 was used as a reactant. We found that concentration of CO 2 was key to improve syngas formation from pyrolysis of SMF. Thus, this study suggested that CO 2 /SMF are used as useful feedstocks through catalytic pyrolysis, while they were previously discarded as waste materials., (Copyright © 2022 Elsevier B.V. All rights reserved.)

As 2-hydroxybenzoic acid (HBA) represents a typical pharmaceutical and personal care product (PPCP), constant releasing of HBA into the environment poses threats to the ecology, and thus it is critical to develop effective techniques to remove HBA from water. Recently, sulfate radical (SO 4 ‒ )-based advanced oxidation processes involved with monopersulfate (MPS) activation are proven as effective approaches for eliminating PPCPs from water, and Co 3 O 4 is recognized as a capable catalyst for activating MPS. Therefore, great interests have arisen to develop Co 3 O 4 -based catalysts with advantageous morphologies and characteristics for enhancing catalytic activities. Therefore, a special Co 3 O 4 -based material is proposed in this work. Through a surfactant-assisted strategy, a cubic Co-MOF is prepared and used as a precursor, which is etched to afford hollow structure, and then transformed into hollow porous Co 3 O 4 nanobox (PCNB). PCNB can exhibit distinct reactive surface with abundant surface oxygen vacancy as well as physical properties in comparison to the commercial Co 3 O 4 NPs (com-Co 3 O 4 NP), thereby leading to the outstanding catalytic activity of PCNB for activating MPS to degrade HBA. The activation energy (E a ) of 46.2 kJ/mol is also calculated using PCNB + MPS system, which is much lower than most of recent reported studies for activating MPS. PCNB could be also reusable over 5 consecutive HBA degradation cycles. The activation mechanism of MPS by PCNB and HBA degradation pathway are also comprehensively elucidated via experimental evidences and the theoretical calculation to offer insightful information of development of Co 3 O 4 for HBA degradation., (Copyright © 2021. Published by Elsevier Ltd.)

Dissolved solids released from biochar (DSRB), including organic and inorganic compounds, may affect the role of biochar as a soil amendment. In this study, the effects of DSRB on soil microbe metabolism, especially CO 2 fixation, were evaluated in liquid soil extract. DSRB were found to be released in large amounts (289.05 mg L -1 at 1 hour) from biochar over a short period of time before their rate of release slowed to a gradual pace. They increased the microbial biomass and provided energy and reducing power to microbes, while reducing their metabolic output of extracellular proteins and polysaccharides. DSRB inputs led to the redistribution of metabolic flux in soil microorganisms and an increased organic carbon content in the short term. This content gradually decreased as it was utilized. DSRB did not improve microbial CO 2 fixation but, rather, enhanced its release, while promoting specific soil microorganism genera, including Cupriavidus , Flavisolibacter , and Pseudoxanthomonas . These heterotrophic genera may compete with autotrophic microorganisms for nutrients but have positive synergistic relationships with autotrophs during CO 2 fixation. These results demonstrated that reducing the DSRB in biochar can improve its role as a soil amendment by enhancing soil carbon storage and CO 2 fixation capabilities.

Perfluorooctanoic acid (PFOA), as a recalcitrant organic pollutant, inevitably enters wastewater treatment facilities and is enriched in settled sludge. However, the potential impact of PFOA on sludge treatment has never been documented. In this study, the effect of PFOA on anaerobic digestion of sewage sludge and its underlying mechanism were investigated through batch and long-term experiments. The presence of PFOA was found to be deleterious for methane production from sewage sludge. 170 mg/kg total solids PFOA reduced the cumulative methane production from 197.1 ± 1.92-159.9 ± 3.10 mL/g volatile solids. PFOA induces the production of reactive oxygen species, which directly leads to cell inactivation and interferes with methane production. PFOA stimulates microorganisms to secrete more extracellular polymeric substances (mainly proteins), which not only hinders the solubilization of organic matter but also down-regulate enzyme activities to inhibit acidification and methanogenesis. In addition, PFOA reduces the diversity of microorganisms, especially the abundance of acid-producing bacteria and methanogens, making the microbial community unfavorable for methane production., (Copyright © 2021 Elsevier B.V. All rights reserved.)

The growing consumption of plastic materials has increased hazardous threats to all environmental media, since current plastic waste management methods release microplastics and toxic chemicals. As such, massive generation of plastic derived pollutants leads to significant public health and environmental problems. In this work, an environmentally sound method for valorization of plastic waste is suggested. In detail, pyrolysis of polycarbonate-containing plastic waste such as automotive headlight housing (AHH) was carried out using CO 2 as a co-reactant. AHH was chosen as it discharges bisphenol A (BPA) and aromatic compounds. Under CO 2 condition, emissions of BPA and its derivatives were suppressed by 14.5% due to gas phase reactions (GPRs) with CO 2 . Nevertheless, reaction kinetics for GPRs was not significant. To impart the GPRs, catalytic pyrolysis was done using Ni and Co-based catalysts. During catalytic pyrolysis, syngas production was more than tenfold up comparing to pyrolysis without catalyst. The expedited GPRs over catalysts resulted in the enhanced syngas formation. Total concentration of the toxic chemicals from CO 2 -assisted catalytic pyrolysis of AHH decreased by 86.1% and 66.7% over Ni and Co catalysts, comparing to those from N 2 environment., (Copyright © 2021 Elsevier B.V. All rights reserved.)

Waste furniture boards (WFBs) contain hazardous formaldehyde and volatile organic compounds when left unmanaged or improperly disposed through landfilling and open burning. In this study, pyrolysis was examined as a disposal and recovery approach to convert three types of WFBs (i.e., particleboard, plywood, and fiberboard) into value-added chemicals using thermogravimetric analysis coupled with Fourier-transform infrared spectrometry (TG-FTIR) and pyrolysis coupled with gas chromatography/mass spectrometry (Py-GC/MS). TG-FTIR analysis shows that pyrolysis performed at an optimum temperature of 250-550 °C produced volatile products mainly consisting of carbon dioxide, carbon monoxide, and light hydrocarbons, such as methane. Py-GC/MS shows that pyrolysis at different final temperatures and heating rates recovered mainly phenols (25.9-54.7%) for potential use as additives in gasoline, colorants, and food. The calorific value of WFBs ranged from 16 to 18 MJ/kg but the WFBs showed high H/C (1.7-1.8) and O/C (0.8-1.0) ratios that provide low chemical energy during combustion. This result indicates that WFBs are not recommended to be burned directly as fuel, however, they can be pyrolyzed and converted into solid pyrolytic products such as biochar with improved properties for fuel application. Hazardous components, such as cyclopropylmethanol, were removed and converted into value-added compounds, such as 1,4:3,6-dianhydro-d-glucopyranose, for use in pharmaceuticals. These results show that the pyrolysis of WFBs at high temperature and low heating rate is a promising feature to produce value-added chemicals and reduce the formation of harmful chemical species. Thus, the release of hazardous formaldehyde and greenhouse gases into the environment is redirected., (Copyright © 2021 Elsevier B.V. All rights reserved.)

Rapid growth of aquatic weeds in treatment pond poses undesirable challenge to shellfish aquaculture, requiring the farmers to dispose these weeds on a regular basis. This article reviews the potential and application of various aquatic weeds for generation of biofuels using recent thermochemical technologies (torrefaction, hydrothermal carbonization/liquefaction, pyrolysis, gasification). The influence of key operational parameters for optimising the aquatic weed conversion efficiency was discussed, including the advantages, drawbacks and techno-economic aspects of the thermochemical technologies, and their viability for large-scale application. Via extensive study in small and large scale operation, and the economic benefits derived, pyrolysis is identified as a promising thermochemical technology for aquatic weed conversion. The perspectives, challenges and future directions in thermochemical conversion of aquatic weeds to biofuels were also reviewed. This review provides useful information to promote circular economy by integrating shellfish aquaculture with thermochemical biorefinery of aquatic weeds rather than disposing them in landfills., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

The impact of pharmaceutical and personal care products (PPCPs) on the performance of biological wastewater treatment plants (WWTPs) has been widely studied using whole-community approaches. These contaminants affect the capacity of microbial communities to transform nutrients; however, most have neither honed their examination on the nitrifying communities directly nor considered the impact on individual populations. In this study, six PPCPs commonly found in WWTPs, including a stimulant (caffeine), an antimicrobial agent (triclosan), an insect repellent ingredient (N,N-diethyl-m-toluamide (DEET)) and antibiotics (ampicillin, colistin and ofloxacin), were selected to assess their short-term toxic effect on enriched nitrifying cultures: Nitrosomonas sp. and Nitrobacter sp. The results showed that triclosan exhibited the greatest inhibition on nitrification with EC 50 of 89.1 μg L -1 . From the selected antibiotics, colistin significantly affected the overall nitrification with the lowest EC 50 of 1 mg L -1 , and a more pronounced inhibitory effect on ammonia-oxidizing bacteria (AOB) compared to nitrite-oxidizing bacteria (NOB). The EC 50 of ampicillin and ofloxacin was 23.7 and 12.7 mg L -1 , respectively. Additionally, experimental data suggested that nitrifying bacteria were insensitive to the presence of caffeine. In the case of DEET, moderate inhibition of nitrification (<40%) was observed at 10 mg L -1 . These findings contribute to the understanding of the response of nitrifying communities in presence of PPCPs, which play an essential role in biological nitrification in WWTPs. Knowing specific community responses helps develop mitigation measures to improve system resilience., (© 2021. The Author(s).)

Consumption of diverse plastics has posed an environmental threat because their disposal practices, landfilling and incineration, release toxic chemicals and microplastics into all environmental media. Indeed, heterogeneous matrix of plastic wastes makes them hard to be disposed. As such, this study aimed to introduce an environmentally benign/reliable disposal platform for complete decomposition of plastic wastes. Pyrolysis process was adapted to convert plastics into syngas, and a disposable diaper (DD) was used as model plastic waste, because it is composed of a variety of polymeric materials. Pyrolysis of DD resulted in the formation of gaseous products and pyrogenic oils, composed of (oxygenated) hydrocarbons. Nonetheless, reactivity of CO 2 as an oxidant in pyrolysis of DD was negligible. To impart the strong/desired reactivity of CO 2 , Ni-based catalyst was adopted. Ni catalyst enhanced H 2 and CO formations 4 and 15 times more than pyrolysis without catalyst at 700 °C under CO 2 . The value-added syngas production was originated from the reduction of polymeric waste, and its derivatives including aromatic compounds. Thus, CO 2 offered a strategic means to produce value-added chemicals and reduce aromaticity of pyrogenic products. The observations could offer an innovative way to control the fate of toxic chemicals derived from plastic pyrolysis., (Copyright © 2021 Elsevier B.V. All rights reserved.)

Powder adsorbents perform well due to their large surface area but are difficult to use because of aggregation and channeling. In this study, pelletization of adsorbents was proposed as a solution to these operating problems. A three-component mixture was extruded into pellets and calcined under air or nitrogen conditions The pellet adsorbent removed 47, 71, 97, and 72% of ammonium, phosphate, sulfathiazole, and sulfamethoxazole, respectively. Bentonite improved greatly the strength of pellets, and a 10 wt% of bentonite was sufficient to maintain pellet shape and mass. No significant difference in individual adsorption and multi-pollutant adsorption was found. Pellet adsorbents with alum sludge, bentonite, and low-grade charcoal are low-cost materials that effectively remove multi-pollutants from the aqueous phase., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

Aflatoxins (AFs) are the extremely hazardous metabolites (carcinogens) that are sporadically observed in crops, and these toxic chemicals are indeed lethal to the health of living organisms including human beings. Thus, AF contaminated food waste needs to be disposed as an environmentally benign way, not releasing it into the environment. This study offered a sustainable disposal and valorization platform for AF contaminated food. Peanut was used as a model food waste, because AF is readily appeared in the peanut during its harvesting, cultivation, storage, transportation process. As the valorization platform, non-catalytic transesterification of AF contaminated peanut was employed to convert it to biodiesel (BD). From the process, lipid in AF contaminated peanut is converted into BD (95.2 wt% yield) at 365°C for 1 min. Since the boiling points of BD and AF are significantly different, this process could also resolve the separation problem of AF (180 °C) from BD (≥ 330 °C) during the transesterification reaction. As a comparison study, alkali-catalyzed reaction was done. The alkali-catalyzed one required a pretreatment process to extract peanut oil for transesterification. The highest yield was 67.8 wt% yield after 6 h of reaction at 65 °C., (Copyright © 2021 Elsevier B.V. All rights reserved.)

Aromatic hydrocarbons (AHCs) are one of the major environmental pollutants introduced from both natural and anthropogenic sources. Many AHCs are well known for their toxic, carcinogenic, and mutagenic impact on human health and ecological systems. Biodegradation is an eco-friendly and cost-effective option as microorganisms (e.g., bacteria, fungi, and algae) can efficiently breakdown or transform such pollutants into less harmful and simple metabolites (e.g., carbon dioxide (aerobic), methane (anaerobic), water, and inorganic salts). This paper is organized to offer a state-of-the-art review on the biodegradation of AHCs (monocyclic aromatic hydrocarbons (MAHs) and polycyclic aromatic hydrocarbons (PAHs)) and associated mechanisms. The recent progress in biological treatment using suspended and attached growth bioreactors for the biodegradation of AHCs is also discussed. In addition, various substrate growth and inhibition models are introduced along with the key factors governing their biodegradation kinetics. The growth and inhibition models have helped gain a better understanding of substrate inhibition in biodegradation. Techno-economic analysis (TEA) and life cycle assessment (LCA) aspects are also described to assess the technical, economical, and environmental impacts of the biological treatment system., (Copyright © 2021 Elsevier B.V. All rights reserved.)

In this study, wasted mask is chosen as a pyrolysis feedstock whose generation has incredibly increased these days due to COVID-19. We suggest a way to produce value-added chemicals (e.g., aromatic compounds) from the mask with high amounts through catalytic fast pyrolysis (CFP). To this end, the effects of zeolite catalyst properties on the upgradation efficiency of pyrolytic products produced from pyrolysis of wasted mask were investigated. The compositions and yields of pyrolytic gases and oils were characterized as functions of pyrolysis temperature and the type of zeolite catalyst (HBeta, HY, and HZSM-5), including the mesoporous catalyst of Al-MCM-41. The mask was pyrolyzed in a fixed bed reactor, and the pyrolysis gases evolved in the reactor was routed to a secondary reactor inside which the zeolite catalyst was loaded. It was chosen 550 °C as the CFP temperature to compare the catalyst performance for the production of benzene, toluene, ethylbenzene, and xylene (BTEX) because this temperature gave the highest oil yield (80.7 wt%) during the non-catalytic pyrolysis process. The large pore zeolite group of HBeta and HY led to 134% and 67% higher BTEX concentrations than HZSM-5, respectively, likely because they had larger pores, higher surface areas, and higher acid site density than the HZSM-5. This is the first report of the effect of zeolite characteristics on BTEX production via CFP., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

Recent abnormal climate changes resulted in the dramatic alternation of rainfall and flood patterns in many countries. The massive generation of flood debris, a mixture of soil (sediment), biomass, plastic, metal, and various hazardous materials, poses various environmental and public health problems. This study suggests a sustainable technical platform to convert the hazardous materials into value-added products. CO 2 -assisted pyrolysis was used to thermally convert flood debris into syngas (H 2 and CO). CO 2 enhanced the syngas production due to gas phase homogeneous reactions (HRs) between CO 2 and volatile hydrocarbons evolved from pyrolysis of flood debris. For improvement of HRs in line with enhancement of syngas production, additional thermal energy and earth abundant catalyst were used. In particular, Ni/SiO 2 catalyst increased more than one order of magnitude higher syngas production, comparing to non-catalytic pyrolysis. Synergistic effect of CO 2 and Ni catalyst showed nearly 50% more production of syngas in reference to catalytic pyrolysis under N 2 . During flood debris pyrolysis, compositional matrix of flood debris was also determined by detecting index chemicals of waste materials that cannot be identified by naked eyes. Thus, this study confirmed that CO 2 -assisted pyrolysis is a useful tool for conversion of flood debris into value-added chemicals., (Copyright © 2021 Elsevier B.V. All rights reserved.)

In China, the utilization and recycling of chicken waste have become a significant environmental issue. In this study, we investigate the efficacy of biogenic hydroxyapatite (HAP) materials, recycled from chicken waste, for Pb(II) sequestration from wastewater. The results from batch experiments indicate that biogenic HAP could effectively remove Pb(II) from an aqueous solution. The maximum removal efficiency of Pb (more than > 99%) was observed under the following operational conditions: initial pH of 3.0, initial Pb(II) concentrations of 208 mg/L, and 1 g/L of HAP adsorbents. The presence of coexisting divalent ions, including Ca 2+ , Mg 2+ , and Mn 2+ , had no significant influence on Pb(II) removal. Spectroscopic analysis suggests that the dissolution-precipitation mechanism was mainly responsible for Pb(II) sequestration under acidic conditions (pH ≤ 3.0). Our findings indicate that biogenic HAP recycled from biowaste can be used as an efficient adsorbent for cleaning Pb(II) from wastewater.

Powder adsorbents show an excellent adsorption capacity for arsenic(As) due to the large specific surface area. However, the performance of powder adsorbents decreases significantly by channeling in the adsorption bed, and the powder is released from the bed. Pelletization of power adsorbent can solve the problems, and bentonite was proposed as a binder to improve the strength. The adsorption capacity and lifetime of pelletized adsorbent were evaluated through a batch and column study. The addition of bentonite decreased adsorption capacity by 16% of pellet without bentonite, but improved compressive strength of adsorbent up to 3.6 times. In the batch test, the maximum adsorption capacity of pelletized adsorbent is 22.2 mg As/g, which is about 40% of powder adsorbent. However, in the column study, pellet adsorbent showed similar adsorption performance and lifetime to commercial and powder adsorbent. As a result, the pellet adsorbent using bentonite is a potential low-cost adsorbent to remove effectively As in the aqueous phase., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

Since the free organic carbon (FOC) generated by chemoautotrophic bacterium self has a feedback inhibition effect on its growth and carbon fixation, a continuous flow membrane bio-reactor was designed to remove extracellular FOC (EFOC) and release its inhibition effect. The promotion effect of membrane reactor on growth and carbon fixation of typical chemoautotrophic bacterium and its mechanism were studied. The accumulated apparent carbon fixation yield in membrane reactor was 3.24 times that in the control reactor. The EFOC per unit bacteria and cbb gene transcription level in membrane reactor were about 0.41 times and 11.18 times that in control reactor in late stage, respectively. Membrane reactor separated out EFOC, especially the small molecules, which facilitated the release of intracellular FOC, thereby releasing the inhibition of FOC on cbb gene transcription, thus promoting growth and carbon fixation of the typical chemoautotrophic bacterium. This study lays a foundation for enhancing carbon fixation by chemoautotrophic bacteria and expands the application field of membrane reactor., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier B.V. All rights reserved.)

Poly- and perfluoroalkyl substances (PFASs) are synthetic chemicals, which are introduced to the environment through anthropogenic activities. Aqueous film forming foam used in firefighting, wastewater effluent, landfill leachate, and biosolids are major sources of PFAS input to soil and groundwater. Remediation of PFAS contaminated solid and aqueous media is challenging, which is attributed to the chemical and thermal stability of PFAS and the complexity of PFAS mixtures. In this review, remediation of PFAS contaminated soils through manipulation of their bioavailability and destruction is presented. While the mobilizing amendments (e.g., surfactants) enhance the mobility and bioavailability of PFAS, the immobilizing amendments (e.g., activated carbon) decrease their bioavailability and mobility. Mobilizing amendments can be applied to facilitate the removal of PFAS though soil washing, phytoremediation, and complete destruction through thermal and chemical redox reactions. Immobilizing amendments are likely to reduce the transfer of PFAS to food chain through plant and biota (e.g., earthworm) uptake, and leaching to potable water sources. Future studies should focus on quantifying the potential leaching of the mobilized PFAS in the absence of removal by plant and biota uptake or soil washing, and regular monitoring of the long-term stability of the immobilized PFAS., (Copyright © 2020 Elsevier B.V. All rights reserved.)

Global consumption of tobacco has been continuously increasing. This results in the considerable generation of toxic waste materials from the tobacco industry and daily life. Conventional disposal methods for them (incineration and landfilling) could be a potential hazard for releasing carcinogens and toxins into our eco-system. Accordingly, an eco-friendly disposal platform for converting tobacco waste (TW) into syngas was mainly studied in this present work. To realize this, pyrolysis of two commercial cigarette products (Marlboro and HEETS (electronic cigarette)) was done under the CO 2 /N 2 conditions. One of the main findings from the present study was that CO 2 reacted with volatile matters (VMs) obtained from the thermolysis of TW through the gas phase reactions (GPRs), which provided a strategic measure to manipulate carbon rearrangement of all pyrolysates. In particular, the GPRs expedited the carbon rearrangement of harmful chemical species, converting toxic chemicals into syngas. When the fraction of VMs in TWs increased, the GPR were more effective. Therefore, the introduced eco-friendly method using CO 2 -mediated thermochemical process could be beneficial for energy recovery from TWs while mitigating the formations of harmful chemical species., (Copyright © 2020 Elsevier B.V. All rights reserved.)

Microbial fuel cells (MFCs) that are bio-energy transducers capture bioelectricity produced from the oxidation of organic matter by using the electro-active bacteria grown on the biofilm attached on anode. Previous studies explored the effect of several limiting factors, such as electrode material, catalyst type, membrane structure, and electrolyte, on the electrochemical performance of MFCs. However, the effects of electrode position on Cr(VI) reduction and bioelectricity production remain unknown. In this study, MFCs with different electrode positions (i.e., 4 cm (MFC-4), 3 cm (MFC-3), 2 cm (MFC-2), and 1 cm (MFC-1)) were designed and fabricated to evaluate the overall performance of MFCs. The results of electrochemical analysis confirmed that MFC-2 exhibited low exchange transfer resistance (4.9 Ω) and strong conductivity, resulting in optimal electrochemical performance. In addition, Cr(VI) was completely removed within 11 h in MFC-2 with a large reduction rate of 0.91 g/m 3 ·h. and COD removal efficiency of 78.25%. The overall performance of MFC-2 was comparatively higher than those of MFC-1 (0.80 g/m 3 ·h and 68.82%), MFC-3 (0.64 g/m 3 ·h and 61.67%), and MFC-4 (0.52 g/m 3 ·h and 39.85%). Meanwhile, MFC-2 generated high open voltage (1.02 V) and power density (535.4 mW/m 2 ), which are 1.4- and 3.1-fold larger than those of MFC-4 (0.72 V and 171.3 mW/m 2 ). High COD removal and power density indicated the strong electrochemical activity of electroactive bacteria in the anode chamber of the MFCs, which was due to the low resistance in the MFCs could accelerate electron transfer and boost electrochemical reaction. Consequently, the optimal electrode spacing in MFCs was 2 cm. Further studies confirmed that Cr(VI) was removed and deposited in the form of Cr(III) on the electrode surface. High-throughput analysis suggested Pseudomonas species are the key electroactive bacteria for electricity generation., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier B.V. All rights reserved.)

Eutrophication is one of the critical water quality issues in the world nowadays. Various studies have been conducted to explore the contributing factors related to eutrophication symptoms. However, in the field of eutrophication modeling, the stochastic nature associated with the eutrophication process has not been sufficiently explored, especially in a multivariate stochastic modeling framework. In this study, a multivariate hidden Markov model (MHMM) that can consider the spatio-temporal dependence in chlorophyll-a concentration over the Nakdong River of South Korea was proposed. The MHMM can effectively cluster the intra-seasonal and inter-annual variability of chlorophyll-a, thereby enabling us to understand the spatio-temporal evolutions of algal blooms. The relationships between hydro-climatic conditions (e.g., temperature and river flow) and chlorophyll-a concentrations were evident, whereas a relatively weak relationship with water quality parameters was observed. The MHMM enables us to effectively infer the conditional probability of the eutrophication state for the following month. The self-transition likelihood of staying in the current state is substantially higher than the likelihood of moving to other states. Moreover, the proposed modeling approach can effectively offer a probabilistic decision-support framework for constructing an alert classification of the eutrophication. The potential use of the proposed modeling framework was also provided., (Copyright © 2020 Elsevier B.V. All rights reserved.)