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1. Synthesis of fully fused tetrapyrazinoporphyrazine polymers bearing three-dimensional structures controlled by steric repulsion.

Author

Watanabe, Kosuke, Toya, Teruki, Toyota, Yuto, Kobayashi, Yoichi, Usuba, Junichi, Hijikata, Yuh, Matsuda, Ryotaro, Nishimura, Katsuyuki, Sugiyama, Haruki, and Segawa, Yasutomo

Subjects
POLYMERS, ZINC, POROSITY, ABSORPTION
Abstract

The synthesis and characterization of fused aromatic networks composed of zinc tetrapyrazinoporphyrazines are reported. The steric repulsion of bulky substituents induced the formation of three-dimensional structures. Thus-obtained insoluble polymers adsorbed CO2 and had near-infrared absorption indicating their porosity and extended π-conjugation. [ABSTRACT FROM AUTHOR]

Published
2025
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